Concentrating solar thermal power as a viable alternative in China's electricity supply

Study of low-carbon and pollution renewable alternatives for China revealed that concentrating solar thermal (CST) electric power generation was underemphasized in China's renewable energy plan. The analysis shows the competitive viability of CST: (1) China has the key prerequisites to make CST power generation economical including high-quality insolation and appropriate land, (2) CST's proven history, scale, and dispatchability makes it a good utility-scale power option, especially in the economically underdeveloped Western regions, (3) while CST power is currently more expensive than coal-fired electricity on a nominal basis, when costs of externalities are accounted for, CST, at 11.4 US cents/kWh, can become 57% cheaper than scrubbed coal and 29% cheaper than nuclear power, (4) CST power continues dropping in cost due to economies of scale and technological improvements and can potentially realize a levelized electricity cost of around 4 cents/kWh within ten years, (5) it would significantly rise in competitiveness if and when China completes the extensive smart grid for connecting its solar-abundant western regions with the high-demand eastern regions, (6) CST has the potential to positively impact Western China's economy, but proper policy and deal structure must be in place to ensure that the local community shares the benefit.     

Two-step thermochemical electrolysis: An approach for green hydrogen production

Electrolysis and thermochemical water splitting are approaches to produce green hydrogen that use either an electrical potential (electrolysis) or a chemical potential (thermochemical water splitting) to split water. Electrolysis is technologically mature when applied at low temperatures, but it requires large quantities of electrical energy. In contrast to electrolysis, thermochemical water splitting uses thermal energy, as thermal energy can typically be supplied at a lower unit cost than electrical energy using concentrating solar power. Thermochemical water splitting, however, typically suffers from high thermal losses at the extremely high process temperatures required, substantially increasing the total energy required. We show how, by combining electrical and chemical potentials, a novel and cost-efficient water splitting process can be envisioned that overcomes some of the challenges faced by conventional electrolysis and thermochemical water splitting. It uses a mixed ionic and electronic conducting perovskite with temperature-dependent oxygen non-stoichiometry as an anode in an electrolyzer. If solar energy is used as the primary source of all energy required in the process, the cost of the energy required to produce hydrogen could be lower than in high-temperature electrolysis by up to 7%.     

Operational strategy of a two-step thermochemical process for solar hydrogen production

A two-step thermochemical cycle process for solar hydrogen production from water has been developed using ferrite-based redox systems at moderate temperatures. The cycle offers promising properties concerning thermodynamics and efficiency and produces pure hydrogen without need for product separation.     

Analysis of CSP plants for the definition of energy policies: The influence on electricity cost of solar multiples,capacity factors and energy storage

The effect on the cost of electricity from concentrating solar power (CSP) plants of the solar multiple, the capacity factor and the storage capacity is studied. The interplay among these factors can be used to search for a minimal-cost objective that can serve as a technical criterion to guide in the design of economic incentives for CSP plants. The probability-density function of irradiation is used in conjunction with screening models to evaluate the performance characteristics and costs of concentrating solar power plants. Two technologies have been analyzed in this study: parabolic-trough and tower plants. The results provide information to define the optimal operational range as a function of the desired objective. Thus, it is possible to derive a technical criterion for the design of CSP plants which optimizes the solar electricity produced and its generation cost. The methodology is applied to Spain, and the analysis of the results shows that a solar energy production of 37 kWh/m²/year for tower plants and 66 kWh/m²/year for parabolic-trough ones define the approximate optimal working conditions for the mean DNI in Spain.     

Potential application of concentrating solar power systems for the generation of electricity in Thailand

This study aims to investigate a potential application of concentrating solar power (CSP) systems for producing electricity in the tropical environment of Thailand. An 8-year period (1995–2002) of satellite data was used to generate the direct normal irradiation map of the country. The map reveals that the areas which receive the highest irradiation are mainly in the Northeast and the Central regions of the country, with the yearly sum of direct normal irradiation in the range of 1350–1400 kW h/m² year. The location of Ubon Ratchathani (15.25 °N, 104.87 °E) situated in the Northeast was selected as a target area for investigating the potential application of CSP systems. The performance of three 10 MW CSP systems, namely the parabolic trough, the tower and the dish/Stirling engine systems was investigated. A software named TRNSYS together with the solar thermal electric components (STEC) subroutines were used to simulate the systems. The yearly production of electricity from these systems was estimated and used for the economic evaluation of the systems. It was found that the parabolic trough system afforded the lowest levelized electricity cost of 0.30 USD/kW h. Based on the technical and economic considerations, this system has a sufficient potential for producing electricity in this region.     

Experimental investigation of heterogeneous hydrolysis with Zn vapor under a temperature gradient

The hydrolysis step of the Zn/ZnO thermochemical cycle for hydrogen production is experimentally investigated in a laboratory-scale tube-reactor. The current work uses a new approach in which the heterogeneous oxidation of gaseous Zn with steam is carried out under a negative axial temperature gradient in order to improve cycle efficiency by reducing the proportion of steam and inert carrier gas used. It is shown that complete conversion of Zn to ZnO is possible at steam-to-Zn stoichiometries greater than 5.0. As the steam-to-Zn stoichiometry approaches unity at reduced inert gas fractions, condensation of Zn on the reactor walls becomes more likely. In addition, the observed gas-phase equilibrium shift toward increased production of ZnO at temperatures under 800 K is consistent with earlier theoretical predictions. While complete conversion with low inert gas and steam usage was not achieved, our approach shows great improvement over previous aerosol-based approaches when considering the total amounts of steam and inert gas used per unit of hydrogen produced. Therefore, the current temperature gradient approach is promising for the design of an efficient reactor for water splitting via Zn vapor.     

Thermochemical hydrogen production by a redox system of ZrO2-supported Co(II)-ferrite

The thermochemical two-step water splitting was examined on ZrO₂-supported Co(II)-ferrites below 1400 °C, for purpose of converting solar high-temperature heat to clean hydrogen energy as storage and transport of solar energy. The ferrite on the ZrO₂-support was thermally decomposed to the reduced phase of wustite at 1400 °C under an inert atmosphere. The reduced phase was reoxidized with steam on the ZrO₂-support to generate hydrogen below 1000 °C in a separate step. The ZrO₂-supporting alleviated the high-temperature sintering of iron oxide. As the results, the ZrO₂-supported ferrite realized a greater reactivity and a better repeatability of the cyclic water splitting than the conventional unsupported ferrites. The Co_xFe_3−xO₄/ZrO₂ with the x value of around 0.4–0.7 was found to be the promising working material for the two-step water splitting when thermally reduced at 1400 °C under an inert atmosphere.     

Techno-economic evaluation of concentrating solar power generation in India

The Jawaharlal Nehru National Solar Mission (JNNSM) of the recently announced National Action Plan on Climate Change (NAPCC) by the Government of India aims to promote the development and use of solar energy for power generation and other uses with the ultimate objective of making solar competitive with fossil-based energy options. The plan includes specific goals to (a) create an enabling policy framework for the deployment of 20,000 MW of solar power by 2022; (b) create favourable conditions for solar manufacturing capability, particularly solar thermal for indigenous production and market leadership; (c) promote programmes for off grid applications, reaching 1000 MW by 2017 and 2000 MW by 2022, (d) achieve 15 million m² solar thermal collector area by 2017 and 20 million by 2022, and (e) deploy 20 million solar lighting systems for rural areas by 2022. The installed capacity of grid interactive solar power projects were 6 MW until October 2009 that is far below from their respective potential.     

Thermochemical cycles over redox structured reactors

Structured bodies from redox materials are a key element for the implementation of thermochemical cycles on suitable reactors for the solar H₂O splitting. In the current work different configurations of nickel ferrite were investigated with respect to their performance in H₂O splitting: i) powder, ii) disk, iii) honeycomb flow-through monoliths. The structured bodies were prepared via pressing and extrusion techniques. The performance of the different structures was affected significantly by differences in the structural characteristics. Alternative approaches involving casting techniques for the structuring of nickel ferrite porous bodies were also investigated. This work constitutes a preliminary attempt towards tuning such characteristics to achieve enhanced and cycle-to-cycle stable production yields.     

Thermochemical two-step water splitting by internally circulating fluidized bed of NiFe2O4 particles: Successive reaction of thermal-reduction and water-decomposition steps

Thermochemical two-step water splitting using a redox system of iron-based oxides or ferrites is a promising process for producing hydrogen without CO₂ emission by the use of high-temperature solar heat as an energy source and water as a chemical source. In this study, thermochemical hydrogen production by two-step water splitting was demonstrated on a laboratory scale by using a single reactor of an internally circulating fluidized bed. This involved the successive reactions of thermal-reduction (T-R) and water-decomposition (W-D). The internally circulating fluidized bed was exposed to simulated solar light from Xe lamps with an input power of 2.4-2.6 kW_th for the T-R step and 1.6-1.7 kW_th for the subsequent W-D step. The feed gas was switched from an inert gas (N₂) in the T-R step to a gas mixture of N₂ and steam in the W-D step. NiFe₂O₄/m-ZrO₂ and unsupported NiFe₂O₄ particles were tested as a fluidized bed of reacting particles, and the production rate and productivity of hydrogen and the reactivity of reacting particles were examined.     

Molten-salt thermal energy storage in thermoclines under different environmental boundary conditions

Operation during the charge and discharge cycles of molten-salt thermoclines used for solar thermal energy storage depends strongly on the environmental boundary conditions to which the tanks are exposed. A comprehensive model which accounts for thermal transport in the molten-salt heat transfer fluid and the filler material in the tank is developed for exploring the effects of boundary conditions on thermocline performance. Heat loss from the tank under non-adiabatic boundary conditions is found to distort the temperature and salt flow distributions relative to the uniform conditions found in adiabatic thermoclines; as a result, the outflow temperature drops more rapidly in the former case. Such effects of non-adiabatic boundaries become insignificant at large salt-flow Reynolds numbers. As the Reynolds number increases beyond 250, the discharge efficiency of non-adiabatic thermoclines approaches that of the adiabatic counterparts. In the case of significant heat loss at the walls, the discharge efficiency of thermoclines increases with increasing Reynolds number, a trend that is opposite to that in adiabatic thermoclines.     

Manganese oxide based thermochemical hydrogen production cycle

A MnO/NaOH based three-step thermochemical water splitting cycle was modified to improve the hydrolysis of α-NaMnO₂ (sodium manganate) and to recover Mn(III) oxides for the high-temperature reduction step. Sodium manganate forms in the reaction of NaOH with MnO that releases hydrogen. The hydrolysis of α-NaMnO₂ to manganese oxides and NaOH is incomplete even with a large excess of water and more than 10% sodium cannot be removed prior to the high-temperature reduction step.When mixed oxides of manganese with iron were used in the cycle, the NaOH recovery in the hydrolysis step improved from about 10% to 35% at NaOH concentrations above 1M. Only 60% sodium was removed at 0.5M from the mixed oxides whereas more than 80% can be recovered at the same NaOH concentration when only manganese oxides are used. A 10:1 Mn/Fe sample was cycled through all steps three times to confirm that multiple cycles are possible. The high-temperature reduction was carried out for 5h at 1773 K under vacuum and the conversion was about 65% after the 3rd cycle.Since sodium carryover into the high-temperature reduction cannot be avoided, even with the energy intensive hydrolysis step, a modified two-step cycle without low-temperature sodium recovery is proposed where α-NaMnO₂ is reduced directly to MnO at 1773 K under vacuum. On a laboratory scale, about 60% of the sodium that volatilized at the high temperatures was trapped with a water-cooled cold finger and conversions were stable at about 35% after three completed cycles.     

Study of the first step of the Mn2O3/MnO thermochemical cycle for solar hydrogen production

In this work, a complete thermodynamic study of the first step of the Mn₂O₃/MnO thermochemical cycle for solar hydrogen production has been performed. The thermal reduction of Mn₂O₃ takes place through a sequential mechanism of two reaction steps. The first step (reduction of Mn₂O₃ to Mn₃O₄) takes place at teomperatures above 700 °C, whereas the second reaction step (reduction of Mn₃O₄ to MnO) requires temperatures above 1350 °C to achieve satisfactory reaction rates and conversions. Equilibrium can be displaced to lower temperatures by increasing the inert gas/Mn₂O₃ ratio or decreasing the pressure. The thermodynamic calculations have been validated by thermogravimetric experiments carried out in a high temperature tubular furnace. Experimental results corroborate the theoretical predictions although a dramatically influence of chemical kinetics and diffusion process has been also demonstrated, displacing the reactions to higher temperatures than those predicted by thermodynamics. Finally, this work demonstrates that the first step of the manganese oxide thermochemical cycle for hydrogen production can be carried out with total conversion at temperatures compatible with solar energy concentration devices. The range of required temperatures is lower than those commonly reported in literature for the manganese oxide cycle obtained from theoretical and thermodynamic studies.