Quantitative risk assessment of a hydrogen refueling station by using a dynamic physical model based on multi-physics system-level modeling

Numerous accidents in HRSs have been reported worldwide in accident databases; therefore, many researchers have performed quantitative risk assessments (QRAs) of HRSs to enable risk-informed decision making in determining the safety distances or risk mitigation measures. The HRSs, located in urban areas such as Tokyo in Japan, are situated in congested areas with tall buildings and high population density; thus, they have relatively narrow station areas. However, the QRAs are generally suitable for large plants such as nuclear power plants or chemical plants; therefore, relatively small plants or installations, such as HRSs, have not yet been considered as QRA objects. Hence, it is necessary to conduct detailed QRAs with risk analyses and reduce the applied uncertainties for relatively small plants or installations. We applied a model-based approach of risk assessment to model the HRS process using multi-physics system-level modeling and simulated a target system using Modelica—an equation-based, object-oriented modeling language that allows acausal modeling of complex cyber-physical systems The primary aim of this study was to conduct a QRA of an HRS based on multi-physics system-level modeling. First, we modeled the HRS components and physical relationships between the components using basic physical equations. Then, we elucidate a QRA based on the constructed model. The difference in the leakage rates due to the leak positions and dynamic behavior of the model parameters were calculated using the constructed model. Finally, we estimated the individual risks of all the scenarios and compared the resulting risk contours based on the constructed model that includes the hydrogen-fuel dynamic behavior with those based on the traditional model. These results indicate that it is possible to assess whether the risks around the station boundary are acceptable based on the scenario information obtained by evaluating the risks near the station.     

Quantitative risk assessment using a Japanese hydrogen refueling station model

Although hydrogen refueling stations (HRSs) are becoming widespread across Japan and are essential for the operation of fuel cell vehicles, they present potential hazards. A large number of accidents such as explosions or fires have been reported, rendering it necessary to conduct a number of qualitative and quantitative risk assessments for HRSs. Current safety codes and technical standards related to Japanese HRSs have been established based on the results of a qualitative risk assessment and quantitative effectiveness validation of safety measures over ten years ago. In the last decade, there has been much development in the technologies of the components or facilities used in domestic HRSs and much operational experience as well as knowledge to use hydrogen in HRSs safely have been gained through years of commercial operation. The purpose of the present study is to conduct a quantitative risk assessment (QRA) of the latest HRS model representing Japanese HRSs with the most current information and to identify the most significant scenarios that pose the greatest risks to the physical surroundings in the HRS model. The results of the QRA show that the risk contours of 10^?3 and 10^?4 per year were confined within the HRS boundaries, whereas the risk contours of 10^?5 and 10^?6 per year are still present outside the HRS. Comparing the breakdown of the individual risks (IRs) at the risk ranking points, we conclude that the risk of jet fire demonstrates the highest contribution to the risks at all of the risk ranking points and outside the station. To reduce these risks and confine the risk contour of 10^?6 per year within the HRS boundaries, it is necessary to consider risk mitigation measures for jet fires.     

Quantitative risk assessment of an urban hydrogen refueling station

Hydrogen is one of important energy source in the next generation of renewable energy. It has powerful strength such as no emission from CO2 for fuel, Nevertheless, many countries have difficulties to expand hydrogen infra due to high risky from hydrogen. Especially, the hydrogen refueling station which is located in urban area has congested structure and high population around, it has higher risk than conventional refueling station. This paper presents a quantitative risk assessment (QRA) of a high pressure hydrogen refueling station in an urban area with a large population and high congestion between the instruments and equipment. The results show that leaks from the tube-trailer and dispenser as well as potential explosion of the tube-trailer are the main risks. For the safety of the station operator, customers and people surrounding the refueling station, additional mitigation plans such as adding additional safety barrier system have to be implemented on the compressor and dispenser in order to prevent continuous release of hydrogen from an accident.     

Comparative risk assessment of liquefied and gaseous hydrogen refueling stations

Several countries are incentivizing the use of hydrogen (H₂) fuel cell vehicles, thereby increasing the number of H₂ refueling stations (HRSs), particularly in urban areas with high population density and heavy traffic. Therefore, it is necessary to assess the risks of gaseous H₂ refueling stations (GHRSs) and liquefied H₂ refueling stations (LHRSs). This study aimed to perform a quantitative risk assessment (QRA) of GHRSs and LHRSs. A comparative study is performed to enhance the decision-making of engineers in setting safety goals and defining design options. A systematic QRA approach is proposed to estimate the likelihood and consequences of hazardous events occurring at HRSs. Consequence analysis results indicate that catastrophic ruptures of tube trailer and liquid hydrogen storage tanks are the worst accidents, as they cause fires and explosions. An assessment of individual and societal risks indicates that LHRSs present a lower hazard risk than GHRSs. However, both station types require additional safety barrier devices for risk reduction, such as detachable couplings, hydrogen detection sensors, and automatic and manual emergency shutdown systems, which are required for risk acceptance.     

Quantitative risk assessment of the interior of a hydrogen refueling station considering safety barrier systems

A quantitative risk assessment of human life during the operation of a hydrogen refueling station (HRS) is conducted. We calculate the risks for three accident scenarios: a hydrogen leak from the external piping surrounding a dispenser, a hydrogen leak from an accumulator connection piping and a hydrogen leak from a compressor/connection piping in the HRS. We first calculate the probability of accident by multiplying the estimated leak frequency with the incident occurrence probability considering the ignition probability and failure probability of the safety barrier systems obtained through event tree analysis for each scenario. We next simulate the blast and flame effects of the ignition of concentration fields formed by hydrogen leakage. We then use existing probit functions to estimate the consequences of eardrum rupture, fatalities due to displacement by the blast wave, fatalities due to head injuries, first-degree burns, second-degree burns, and fatal burn injuries by accident scenario, leak size, and incident event, and we estimate the risk distribution in 1-m cells. We finally assess the risk reduction effects of barrier placement and the distance to the dispenser and quantify the risk level that HRSs can achieve under existing law. Quantitative risk assessment reveals that the risk for a leak near the dispenser is less than 10⁻⁶ per year outside a distance of 6 m to the dispenser. The risk for a leak near the accumulators and compressors exceeds 10⁻⁴ per year within a distance of 10 m from the ignition point. A separation of 6 m to the dispenser and a barrier height of 3 m keep the fatal risk from burns to the workers, consumers and residents and passersby below the acceptable level of risk. Our results therefore show that current laws sufficiently mitigate the risks posed by HRSs and open up the possibility for a regulatory review.     

Improved safety by crossanalyzing quantitative risk assessment of hydrogen refueling stations

With the goal of building 310 hydrogen refueling stations (HRSs) in Korea by 2022, restrictions, such as location restrictions and separation distances, are being eased, so developing ways to improve technology and safety. As HRSs contain major facilities such as compressors, storage tanks, dispenser, and priority control panels, and a leakage could result in a large fire or explosion caused by an ignition source. To perform quantitative risk assessment, programs, namely, Hy-KoRAM and Phast/Safeti were used in this study. It could determine the damage range and effect on radiant heat and flame length, as well as personal and societal risks, using these programs. The crossanalysis of the two programs also improves the facility's safety and the reliability of the results.     

Research on sealing performance and self-acting valve reliability in high-pressure oil-free hydrogen compressors for hydrogen refueling stations

Piston ring sealing and valve design play an important role in high-pressure oil-free reciprocating compressors for hydrogen refueling stations. The severe non-uniformity of the pressure distribution was suggested to be the root cause of the premature failure of the sealing rings, and therefore a mathematical model was established to simulate the unsteady flow within the gaps of piston rings, based on which the pressure distribution was obtained and the mechanism of the non-uniform abrasion of the rings was disclosed. The method to equalize the pressure difference through each ring was proposed by re-distributing the cut size of each ring, and it was validated experimentally. Aiming at the problem that the self-acting valves in hydrogen compressors could be easily destroyed by severe impact, this paper investigated the motion and impact of valves theoretically and experimentally, based on which the methodology was explored to design the parameters of valves for hydrogen compressors.     

Quantitative risk assessment on a gaseous hydrogen refueling station in Shanghai

The potential risk exposure of people for hydrogen refueling stations is often a critical factor to gain authority approval and public acceptance. Quantitative risk assessment (QRA) is often used to quantify the risk around hydrogen facilities and support the communication with authorities during the permitting process. This paper shows a case study on a gaseous hydrogen refueling station using QRA methodology. Risks to station personnel, to refueling customers and to third parties are evaluated respectively. Both individual risk measure and societal risk measure are used in risk assessment. Results show that the compressor leak is the main contributor to risks of all three parties. Elevating compressors can be considered as an effective mitigation measure to reduce occupational risks while setting enclosure around compressors cannot. Both measures are effective to reduce risks to customers. As for third parties, societal risks can be reduced to ALARP region by either elevating compressors or setting enclosure around compressors. External safety distance of compressors cannot be considerably reduced by elevation of compressors, but can significantly be reduced by setting compressor enclosure. However, safety distances of the station are not very sensitive to both mitigation measures.     

Current standards and configurations for the permitting and operation of hydrogen refueling stations

The literature lacks a systematic analysis of HRS equipment and operating standards. Researchers, policymakers, and HRS operators could find this information relevant for planning the network's future expansion. This study is intended to address this information need by providing a comprehensive strategic overview of the regulations currently in place for the construction and maintenance of hydrogen fueling stations.A quick introduction to fundamental hydrogen precautions and hydrogen design is offered. The paper, therefore, provides a quick overview of hydrogen's safety to emphasize HRS standards, rules, and regulations. Both gaseous and liquid safety issues are detailed, including possible threats and installation and operating expertise.After the safety evaluation, layouts, equipment, and operating strategies for HRSs are presented, followed by a review of in-force regulations: internationally, by presenting ISO, IEC, and SAE standards, and Europeanly, by reviewing the CEN/CENELEC standards. A brief and concise analysis of Italy's HRS regulations is conducted, with the goal of identifying potential insights for strategic development and more convenient technology deployment.     

Dynamic planning and energy management strategy of integrated charging and hydrogen refueling at highway energy supply stations considering on-site green hydrogen production

The layout of electric vehicles charging stations and hydrogen refueling stations (HRSs) is more and more necessary with the development of electric vehicles (EVs) and progress in hydrogen energy storage technology. Due to the high costs of HRSs and the low demand for hydrogen, it is difficult for independent HRSs to make a profit. This study focuses on the dynamic planning of energy supply stations on highways in the medium and long term, considering the growth of EV charging demand and the change in the proportion of hydrogen fuel cell vehicles (HFCVs). Based on the perspective of renewable energy generators (REGs), this study seeks the dynamic optimal configuration and comprehensive benefits of adding HRS and battery to existing EVCS considering the travel rules of new energy vehicles (NEVs). The results show that (1) It is profitable for REGs to invest in HRSs; (2) The economy of investment in batteries by REGs depends on the source-load matching. It is feasible only when the output of renewable energy is difficult to meet the demand. (3) The business model of REGs producing hydrogen on-site and supplying both electricity and hydrogen is feasible.     

Quantitative risk assessment on 2010 Expo hydrogen station

This paper presents a QRA study on a gaseous hydrogen refueling station of 2010 World Expo. Risks to station personnel, to refueling customers and to third parties are evaluated respectively. Uncertainties that intervene in the risk analysis are also discussed. The results show that the leaks from compressors and dispensers are the main risk contributors to first party and second party risks of the Expo station, indicating that risk mitigation measures should in the first place be implemented on compressors and dispensers. For the sake of the safety of station personnel, customers, and people outside the Expo station, additional safety barrier systems must be implemented on compressors and dispensers to prevent continuous release of hydrogen from happening. With appropriate mitigation measures on compressors and dispensers, risks to all three parties of the Expo station can be reduced to the value lower than the risk acceptance criteria.     

An advanced framework for leakage risk assessment of hydrogen refueling stations using interval-valued spherical fuzzy sets (IV-SFS)

The extensive population growth calls for substantial studies on sustainable development in urban areas. Thus, it is vital for cities to be resilient to new situations and adequately manage the changes. Investing in renewable and green energy, including high-tech hydrogen infrastructure, is crucial for sustainable economic progress and for preserving environmental quality. However, implementing new technology needs an effective and efficient risk assessment investigation to minimize the risk to an acceptable level or ALARP (As low as reasonably practicable). The present study proposes an advanced decision-making framework to manage the risk of hydrogen refueling station leakage by adopting the Bow-tie analysis and Interval-Value Spherical Fuzzy Sets to properly deal with the subjectivity of the risk assessment process. The outcomes of the case study illustrate the causality of hydrogen refueling stations' undesired events and enhance the decision-maker's thoughts about risk management under uncertainty. According to the findings, jet fire is a more likely accident in the case of liquid hydrogen leakage. Furthermore, equipment failure has been recognized as the most likely cause of hydrogen leakage. Thus, in order to maintain the reliability of liquid hydrogen refueling stations, it is crucial that decision-makers develop a trustworthy safety management system that integrates a variety of risk mitigation measures including asset management strategies.     

Single-tank storage versus multi-tank cascade system in hydrogen refueling stations for fuel cell buses

Many countries in Europe are investing in fuel cell bus technology with the expected mobilization of more than 1200 buses across Europe in the following years. The scaling-up will make indispensable a more effective design and management of hydrogen refueling stations to improve the refueling phase in terms of refueling time and dispensed quantity while containing the investment and operation costs. In the present study, a previously developed dynamic lumped model of a hydrogen refueling process, developed in MATLAB, is used to analyze tank-to-tank fuel cell buses (30–40 kg_H2 at 350 bar) refueling operations comparing a single-tank storage with a multi-tank cascade system. The new-built Aalborg (DK) hydrogen refueling station serves as a case study for the cascade design. In general, a cascading refueling approach from multiple storage tanks at different pressure levels provides the opportunity for a more optimized management of the station storage, reducing the pressure differential between the refueling and refueled tanks throughout the whole refueling process, thus reducing compression energy. This study demonstrates the validity of these aspects for heavy-duty applications through the technical evaluation of the refueling time, gas heating, compression energy consumption and hydrogen utilization, filling the literature gap on cascade versus single tank refueling comparison. Furthermore, a simplified calculation of the capital and operating expenditures is conducted, denoting the cost-effectiveness of the cascade configuration under study. Finally, the effect of different pressure switching points between the storage tanks is investigated, showing that a lower medium pressure usage reduces the compression energy consumption and increases the station flexibility.     

A study of hydrogen leak and explosion in different regions of a hydrogen refueling station

The consequences of hydrogen leaks and explosions are predicted for the sake of the safety in hydrogen refueling stations. In this paper, the effect of wind speed on hydrogen leak and diffusion is analyzed in different regions of a hydrogen refueling station, and the influence of delayed ignition time on hydrogen explosion after an accidental hydrogen leak is further studied by numerical simulation. Results show that the effect of wind speed on the probability of hydrogen fires is distinctive in different regions of hydrogen refueling station. The size of combustible clouds in the trailer front region and the outer region increases in the low wind speed case, and the front of combustible clouds is formed in a spherical shape in the outer region, which can greatly increase the probability of hydrogen explosion. However, the high wind speed may cause an increase of the risk of accidents in the near ground region. Moreover, a non-linear correlation is shown between the rate of combustible cloud dissipation and wind speed after the hydrogen stops leaking. In addition, it is found that an increase in delayed ignition time may lead to an increase in explosion intensity, which is related with the larger high temperature area and stronger explosion overpressure. Two flame fronts and the reverse propagation of the explosion overpressure can be observed, when the delayed ignition time is larger.     

Evaluating uncertainty in accident rate estimation at hydrogen refueling station using time correlation model

Hydrogen, as a future energy carrier, is receiving a significant amount of attention in Japan. From the viewpoint of safety, risk evaluation is required in order to increase the number of hydrogen refueling stations (HRSs) implemented in Japan. Collecting data about accidents in the past will provide a hint to understand the trend in the possibility of accidents occurrence by identifying its operation time However, in new technology; accident rate estimation can have a high degree of uncertainty due to absence of major accident direct data in the late operational period. The uncertainty in the estimation is proportional to the data unavailability, which increases over long operation period due to decrease in number of stations. In this paper, a suitable time correlation model is adopted in the estimation to reflect lack (due to the limited operation period of HRS) or abundance of accident data, which is not well supported by conventional approaches. The model adopted in this paper shows that the uncertainty in the estimation increases when the operation time is long owing to the decreasing data.     

A numerical study of hydrogen leakage and diffusion in a hydrogen refueling station

Studies focused on the behavior of the hydrogen leakage and diffusion are of great importance for facilitating the large scale application of the hydrogen energy. In this paper, the hydrogen leakage and diffusion in six scenarios which including comparison of different leakage position and different wind effect are analyzed numerically. The studied geometry is derived from the hydrogen refueling station in China. Due to the high pressure in hydrogen storage take, the hydrogen leakage is momentum dominated. The hydrogen volume concentration with the variation of the leakage time in different scenarios is plotted. More importantly, profiles of the flammable gas cloud at the end of the leakage are quantitatively studied. Results indicate that a more narrow space between the leakage hole and the obstacle and a smaller contact area with the obstacle make the profile of the flammable gas cloud more irregular and unpredictable. In addition, results highlight the wind effect on the hydrogen leakage and diffusion. Comparing with scenario which the wind direction consistent with the leakage direction, the opposite wind direction may result in a larger profile of the flammable gas cloud. With wind velocity increasing, the profile of the flammable gas cloud is confined in a smaller range. However, the presence of the wind facilitates the form of the recirculation zone near the obstacle. With an increase of the wind velocity, the recirculation zone moves downward along the obstacle. Thus, the hydrogen accumulation is more prominent near the obstacle.     

Effect of hydraulic oil compressibility on the volumetric efficiency of a diaphragm compressor for hydrogen refueling stations

The low volumetric efficiency of the diaphragm compressor under hydrogen refueling process, which hereby results in poor energy efficiency and high cost of hydrogen applications, should be paid attention to. This paper presents theoretical analysis and experimental investigation of the factors affecting the volumetric efficiency of the diaphragm compressor for hydrogen refueling process, focusing on the influence of hydraulic oil compressibility. A mathematical model was established to estimate the volumetric efficiency of diaphragm compressors, in which the effects of clearance volume, superheating of suction gas and pressure loss were taken into account and the emphasis was focused on the compressibility of hydraulic oil. A test rig was built to validate the theoretical model and further experimental investigations were carried out to identify the factors influencing the oil compressibility and hereby the volumetric efficiency. The volumetric efficiency was measured and compared under varied oil compressibility conditions by varying elastic modulus, oil overflow pressure and oil volume. The results indicated that the measured volumetric efficiency agrees well with the calculated value. The compression and expansion of hydraulic oil have a dominant influence on the volumetric efficiency, resulting in a loss of 37% of volumetric efficiency as compared to 2.4%, 18% and 1%, respectively for losses associated with clearance volume, superheating of suction gas and pressure loss, for a diagram compressor under refueling conditions with suction pressure of 30 MPa and discharge pressure of 90 MPa. The volumetric efficiency reduced rapidly with the increased oil overflow pressure, at a rate of 5% decrease with every 10 MPa rise in oil overflow pressure. As the oil volume increased by 100% of the stroke volume, the volumetric efficiency droped by 5.5%.     

An optimized control method for a high utilization ratio and fast filling speed in hydrogen refueling stations

A well-designed control system with a high utilization ratio of hydrogen and a fast filling speed are two critical objectives to ensure the reduction of cost and time required in the refueling process. In this paper, the popular three-stage refueling process is modeled with the aim to address both objectives. Using the real gas law of hydrogen, the utilization ratio of hydrogen filling is analyzed and the filling flowrate and time of each stage are evaluated. A multi-objective iterative optimization model is established and an optimization algorithm for the filling process is proposed to achieve both fast refueling and high utilization. Numerical results can be applied to the optimization of an actual hydrogen filling process. Besides, the tests show that an optimized control method can significantly improve the utilization ratio and allow refueling in a widely acceptable time.     

Experimental correlations and integration of gas boosters in a hydrogen refueling station

Air driven gas boosters are often deployed in small scale compression systems. Manufacturers specifications, reporting outlet flow for a fixed inlet pressure, do not reflect the batch operation from a limited source storage. Thus, the dynamic variation of critical process parameters such as efficiency, temperature and flow are not documented.Using a hydrogen refueling station demonstrator, the data from more than 20′000 compression cycles is compiled and analyzed. Experimentally derived correlations are determined for an air driven gas booster feeding a cascade storage. A specific analysis of the clearance volume and the working air pressure is introduced.An engineering tool was developed in MATLAB for performance forecasting. It allows the user to simulate the process trends with an accuracy of ±5%. In the context of a hydrogen refueling station, duration, temperature, compression cycles and air consumption data can be used for process management and maintenance planning.