A systemic review of hydrogen supply chain in energy transition

Targeting the net-zero emission (NZE) by 2050, the hydrogen industry is drastically developing in recent years. However, the technologies of hydrogen upstream production, midstream transportation and storage, and downstream utilization are facing obstacles. In this paper, the development of hydrogen industry from the production, transportation and storage, and sustainable economic development perspectives were reviewed. The current challenges and future outlooks were summarized consequently. In the upstream, blue hydrogen is dominating the current hydrogen supply, and an implementation of carbon capture and sequestration (CCS) can raise its cost by 30%. To achieve an economic feasibility, green hydrogen needs to reduce its cost by 75% to approximately 2 $/kg at the large scale. The research progress in the midterm sector is still in a preliminary stage, where experimental and theoretical investigations need to be conducted in addressing the impact of embrittlement, contamination, and flammability so that they could provide a solid support for material selection and large-scale feasibility studies. In the downstream utilization, blue hydrogen will be used in producing value-added chemicals in the short-term. Over the long-term, green hydrogen will dominate the market owing to its high energy intensity and zero carbon intensity which provides a promising option for energy storage. Technologies in the hydrogen industry require a comprehensive understanding of their economic and environmental benefits over the whole life cycle in supporting operators and policymakers.     

Opportunities for green hydrogen production in petroleum refining and ammonia synthesis industries in India

Increasing penetration of renewable electricity in the power systems coupled with reduction in its cost has resulted in increased interest in green hydrogen globally. Industry has been using fossil fuel-based hydrogen as an input for several decades. This paper makes an assessment of existing hydrogen production capacities in petroleum refineries and ammonia synthesis units in India along with estimating the potential for installing solar photovoltaic (SPV) powered alkaline electrolysers for producing green hydrogen and SPV capacity required for this purpose. Levelised cost of hydrogen production in these industries in India has been analysed and found to be competitive. The paper also discusses about water requirement, land requirement for SPV power plants, CO₂ emissions avoided and likely investment to be made for establishing infrastructure for green hydrogen production. With launching of national hydrogen mission in India, a transition to green hydrogen by the industry appears to be a near term possibility.     

Prospects for the production of green hydrogen: Review of countries with high potential

The article provides a review of the current hydrogen production and the prospects for the development of the production of “green” hydrogen using renewable energy sources in various countries of the world that are leaders in this field. The potential of hydrogen energy in such countries and regions as Australia, the European Union, India, Canada, China, the Russian Federation, United States of America, South Korea, the Republic of South Africa, Japan and the northern countries of Africa is considered. These countries have significant potential for the production of hydrogen and “green” hydrogen, in particular through mining of fossil fuels and the use of renewable energy sources. The quantitative indicators of the production of “green” hydrogen in the future and the direction of its export are considered; the most developed hydrogen technologies in these countries are presented. The production of “green” hydrogen in most countries is the way to transition from the consumption of fossil fuels to the clean energy of the future, which will significantly improve the environmental situation, reduce greenhouse gas emissions and improve the energy independence of the regions.     

Insights into low-carbon hydrogen production methods: Green,blue and aqua hydrogen

The primary aim of this study is to provide insights into different low-carbon hydrogen production methods. Low-carbon hydrogen includes green hydrogen (hydrogen from renewable electricity), blue hydrogen (hydrogen from fossil fuels with CO₂ emissions reduced by the use of Carbon Capture Use and Storage) and aqua hydrogen (hydrogen from fossil fuels via the new technology). Green hydrogen is an expensive strategy compared to fossil-based hydrogen. Blue hydrogen has some attractive features, but the CCUS technology is high cost and blue hydrogen is not inherently carbon free. Therefore, engineering scientists have been focusing on developing other low-cost and low-carbon hydrogen technology. A new economical technology to extract hydrogen from oil sands (natural bitumen) and oil fields with very low cost and without carbon emissions has been developed and commercialized in Western Canada. Aqua hydrogen is a term we have coined for production of hydrogen from this new hydrogen production technology. Aqua is a color halfway between green and blue and thus represents a form of hydrogen production that does not emit CO₂, like green hydrogen, yet is produced from fossil fuel energy, like blue hydrogen. Unlike CCUS, blue hydrogen, which is clearly compensatory with respect to carbon emissions as it captures, uses and stores produced CO₂, the new production method is transformative in that it does not emit CO₂ in the first place. In order to promote the development of the low-carbon hydrogen economy, the current challenges, future directions and policy recommendations of low-carbon hydrogen production methods including green hydrogen, blue hydrogen, and aqua hydrogen are investigated in the paper.     

Low-emission hydrogen production via the thermo-catalytic decomposition of methane for the decarbonisation of iron ore mines in Western Australia

The Pilbara, located in Western Australia is one of the largest iron ore-mining regions in the world and will need to achieve significant emission reductions in the short term to conserve the limited carbon budget and abide by the Paris Agreement targets. Green hydrogen has been communicated as the desired solution, however, the high production cost limits the deployment of these systems. The thermo-catalytic methane decomposition (TCMD) process is an alternative solution, which could be implemented as a bridge technology to produce low-emission hydrogen at a potentially lower cost. This is especially attractive for iron ore mines due to the utilisation of iron ore as a process catalyst, which reduces the catalyst turnover costs and can increase the grade of spent iron ore catalyst. In this study, a preliminary techno-economic assessment was carried out in comparison with green hydrogen to determine the feasibility of the TCMD process for the decarbonisation of iron ore mine sites in the Pilbara. The results show that the TCMD process had a CO₂ abatement cost between 25 and 40% less than green hydrogen, however, the magnitude of these costs was lowest for mining operations >60 Mt/yr at approximately $150 and $200 USD/t CO₂ respectively. Since green hydrogen is expected to have significant cost reductions in the future, integrating renewables already into the mine could reduce emissions in the short term, which could then be extended for green hydrogen production once it becomes viable. The TCMD process, therefore, only has a narrow window of opportunity, although considering the uncertainty of the process and that green hydrogen is a proven technology with greater emission-reduction potential, green hydrogen may be the most suitable solution despite the model results presented in this work.     

Techno-economic assessment of green hydrogen production via two-step thermochemical water splitting using microwave

This study evaluates a two-step thermochemical water-splitting method for green hydrogen production and considers the economic feasibility of technically available designs under harsh hydrogen production conditions. As layouts of hydrogen production, two thermochemical water–splitting systems are evaluated in this study. One system is the process via high temperature from solar concentration power systems. The other system uses microwaves for thermochemical water splitting under low temperatures from advanced nuclear power plants. As part of the hydrogen production system, possible solid–solid and fluid–fluid heat recuperators of printed circuit heat exchanger (PCHE) are proposed and evaluated through the effectiveness-number of transfer units (ε-NTU) method and logarithmic mean temperature difference (LMTD) method. The required heat transfer area and volume are calculated according to the operating conditions and considered in the economic assessment of the hydrogen production system. Optimum geometries of the PCHE are proposed considering the cost analysis. The Levelized cost of hydrogen (LCOH) and system efficiency are calculated for the conventional system with solar power and system-using microwave with HTGR. The importance of heat recuperation systems is confirmed in that they account for approximately 10–20% of the cost for both system layouts. To evaluate the technology development level to achieve the ultimate target, LCOH according to various cost factors is evaluated and further research areas essential for commercialization are represented.     

Catching the hydrogen train: economics-driven green hydrogen adoption potential in the United Arab Emirates

The establishment of a hydrogen economy for domestic use and energy exports is increasingly attractive to fossil fuel exporting countries. This paper quantifies the potential of green hydrogen in the United Arab Emirates, using an integrated adoption model based on global technoeconomic trends and local costs. We consider the impact of varying hydrogen, oil, natural gas, and carbon prices on the economics of green H₂ adoption. In our Business-As-Usual (BAU) scenario, we observe economic viability in UAE industries between 2032 and 2038 at H₂ prices between $0.95/kg and $1.35/kg based on electrolyzer cost assumptions, solar forecasts and learning rates. We also note rapid scale-up to large export-oriented production capacities across our scenarios. However, if cost reductions slow or gas prices return to historical lows, additional interventions such as carbon pricing would be required to fully decarbonize in alignment with the 2050 net-zero target.     

Exploring supply chain design and expansion planning of China's green ammonia production with an optimization-based simulation approach

Green ammonia production as an important application for propelling the upcoming hydrogen economy has not been paid much attention by China, the world's largest ammonia producer. As a result, related studies are limited. This paper explores potential supply chain design and planning strategies of green ammonia production in the next decade of China with a case study in Inner Mongolia. A hybrid optimization-based simulation approach is applied, considering traditional optimization approaches are insufficient to address uncertainties and dynamics in a long-term energy transition. Results show that the production cost of green ammonia will be at least twice that of the current level due to higher costs of hydrogen supply. Production accounts for the largest share of the total expense of green hydrogen (~80 %). The decline of electricity and electrolyser prices are key in driving down the overall costs. In addition, by-product oxygen is also considered in the model to assess its economic benefits. We found that by-product oxygen sales could partly reduce the total expense of green hydrogen (~12 % at a price of USD 85/t), but it also should be noted that the volatile price of oxygen may pose uncertainties and risks to the effectiveness of the offset. Since the case study may represent the favourable conditions in China due to the abundant renewable energy resources and large-scale ammonia industry in this region, we propose to take a moderate step towards green ammonia production, and policies should be focused on reducing the electricity price and capital investments in green hydrogen production. We assume the findings and implications are informative to planning future green ammonia production in China.     

可再生能源发电制绿氢和氢能储运技术现状与发展分析

氢能已纳入我国能源发展战略。绿氢作为一种绿色二次能源,能够助推实现“双碳”目标。氢气制备和储运是氢能产业链的关键环节。重点阐述了电解水制绿氢和氢能储运的技术类型与发展现状,并对其应用前景和发展趋势进行了分析;提出氢气生产成本和储运方式是限制氢大规模部署的主要技术瓶颈;最后为传统电力企业进入绿氢制备和储运产业提供了一些思考和建议。     

The sustainability of green hydrogen: An uncertain proposition

Green hydrogen is increasingly considered a vital element for the long-term decarbonization of the global energy system. For regions with scarce land resources, this means importing significant volumes of green hydrogen from regions with abundance of renewable energy. In producing countries, this raises significant sustainability questions related to production and export. To assess these sustainability-related opportunities and challenges, the authors first present a review of renewable energy deployment in the electricity sector, and then extend it to the foreseeable opportunities and risks of green hydrogen production in exporting countries. The paper finds that questions of freshwater and land availability are critical from an environmental and a socio-economic point of view, and that the development of international standards for the governance of hydrogen-related projects will be crucial. These should also address potential conflicts between the deployment of renewable energy for the decarbonization of local power grids, and the export of green hydrogen.     

Recent advances in hydrogen compressors for use in large-scale renewable energy integration

Given global warming, which limits the use of classical energy sources, renewables can provide a solution to the dilemma between environmental protection and sustainable economic growth. In this complex and changing context, green hydrogen can become a promising link between renewable energy sources and end users. However, although hydrogen has a high gravitational energy density, it has a very low volumetric energy density. This challenge requires hydrogen compression at several stages in the supply chain from electrolysis units to conversion, storage, and distribution. Recently, many studies have focused on hydrogen compression technologies. This paper provides an overview of recent advances in large-scale hydrogen compression. First, the role of hydrogen compression in providing clean energy for the future is explored. Then the thermodynamic concept of hydrogen compression is investigated. Gaining a proper understanding of compressor operating conditions in various operations in the large hydrogen industry is the next focus of this paper. Later, the capabilities and limitations of available mechanical compressors for the hydrogen industry, including reciprocation and centrifugal, are summarized. Finally, research gap and recommended new areas in this field are recognized. The presented insightful concepts provide students, experts, researchers, and decision-making working on large-scale hydrogen industry with the state of the art in hydrogen compressors industry.     

The potential of green ammonia production to reduce renewable power curtailment and encourage the energy transition in China

The pursuing of inter-regional power transmission to address renewable power curtailment in China has resulted in disappointing gains. This paper evaluates the case of local green ammonia production to address this issue. An improved optimization-based simulation model is applied to simulate lifetime green manufacturing, and the impacts of main institutional incentives and oxygen synergy on investment are analysed. Levelized cost of ammonia is estimated at around 820 USD/t, which is about twice the present price. The operating rate, ammonia price, the electrical efficiency of electrolysers and the electricity price are found to be the key factors in green ammonia investment. Carbon pricing and value-added tax exemption exert obvious influences on the energy transition in China. A subsidy of approximately 450 USD/t will be required according to the present price; however, this can be reduced by 100 USD/t through oxygen synergy. Compared to inter-regional power transmission, green ammonia production shows both economic and environmental advantages. Therefore, we propose an appropriate combination of both options to address renewable power curtailment and the integration of oxygen manufacturing into hydrogen production. We consider the findings and policy implications will contribute to addressing renewable power curtailment and boosting the hydrogen economy in China.     

Prospects and economic feasibility analysis of wind and solar photovoltaic hybrid systems for hydrogen production and storage: A case study of the Brazilian electric power sector

The work aims to verify the economic feasibility of renewable hybrid systems for hydrogen production and storage in the Brazilian electric power sector. The methodology applied is based on economic cost analyses of the two largest wind and solar photovoltaic plants in the country. As a result, the number of hours of electricity available for hydrogen production directly influences its cost. However, fully dedicated plants to produce green hydrogen have shown economically feasible to the exporter or other sectors, being trading hydrogen is more profitable than transforming it back into power. The model also concludes that wind and solar hybrid systems for hydrogen production and storage are still not economically viable in Brazil. The CAPEX of electrolysers and their operating losses are still very significant. Finally, hydrogen production and storage become economically feasible only from plants operating above 3000 h and for electrolysers with a CAPEX of USD 650/kWe.     

Nuclear hydrogen: An assessment of product flexibility and market viability

Nuclear energy has the potential to play an important role in the future energy system as a large-scale source of hydrogen without greenhouse gas emissions. Thus far, economic studies of nuclear hydrogen tend to focus on the levelized cost of hydrogen without accounting for the risks and uncertainties that potential investors would face. We present a financial model based on real options theory to assess the profitability of different nuclear hydrogen production technologies in evolving electricity and hydrogen markets. The model uses Monte Carlo simulations to represent uncertainty in future hydrogen and electricity prices. It computes the expected value and the distribution of discounted profits from nuclear hydrogen production plants. Moreover, the model quantifies the value of the option to switch between hydrogen and electricity production, depending on what is more profitable to sell. We use the model to analyze the market viability of four potential nuclear hydrogen technologies and conclude that flexibility in output product is likely to add significant economic value for an investor in nuclear hydrogen. This should be taken into account in the development phase of nuclear hydrogen technologies.     

Techno-economic assessment of green hydrogen and ammonia production from wind and solar energy in Iran

This paper presents a comprehensive technical and economic assessment of potential green hydrogen and ammonia production plants in different locations in Iran with strong wind and solar resources. The study was organized in five steps. First, regarding the wind density and solar PV potential data, three locations in Iran were chosen with the highest wind power, solar radiation, and a combination of both wind/solar energy. All these locations are inland spots, but since the produced ammonia is planned to be exported, it must be transported to the export harbor in the South of Iran. For comparison, a base case was also considered next to the export harbor with normal solar and wind potential, but no distance from the export harbor. In the second step, a similar large-scale hydrogen production facility with proton exchange membrane electrolyzers was modeled for all these locations using the HOMER Pro simulation platform. In the next step, the produced hydrogen and the nitrogen obtained from an air separation unit are supplied to a Haber-Bosch process to synthesize ammonia as a hydrogen carrier. Since water electrolysis requires a considerable amount of water with specific quality and because Iran suffers from water scarcity, this paper, unlike many similar research studies, addresses the challenges associated with the water supply system in the hydrogen production process. In this regard, in the fourth step of this study, it is assumed that seawater from the nearest sea is treated in a desalination plant and sent to the site locations. Finally, since this study intends to evaluate the possibility of green hydrogen export from Iran, a detailed piping model for the transportation of water, hydrogen, and ammonia from/to the production site and the export harbor is created in the last step, which considers the real routs using satellite images, and takes into account all pump/compression stations required to transport these media. This study provides a realistic cost of green hydrogen/ammonia production in Iran, which is ready to be exported, considering all related processes involved in the hydrogen supply chain.     

Evaluating the economic fairways for hydrogen production in Australia

Assessments of hydrogen project viability typically focus on evaluating specific sites for development, or providing generic cost-estimates that are independent of location. In reality, the success of hydrogen projects will be intimately linked to the availability of local energy resources, access to key infrastructure and water supplies, and the distance to export ports and energy markets. In this paper, we present an economic model that incorporates assessments of these regional factors to identify areas of high economic potential for hydrogen production – the so-called “Economic Fairways” for such projects. In doing so, the model provides a tool that can be used to inform investors and policy makers on the available opportunities for hydrogen development and their infrastructure requirements. The model includes analysis of the regional economic potential for both blue and green hydrogen projects. It accounts for hydrogen production from renewable (wind and solar) sources, as well as non-renewable sources (steam-methane reformation and coal gasification) combined with carbon capture and storage. Results from case studies conducted with the tool are presented, illustrating the potential for hydrogen production across Australia.     

Large-scale decomposition of green ammonia for pure hydrogen production

It is acknowledged that Hydrogen has a decisive role to play in insuring a reliable and efficient penetration of renewable electricity in the energy mix. Nonetheless, building a sustainable Hydrogen Economy is faced with numerous challenges across the value chain. Namely, large-scale production and storage are still open issues that need to be addressed. A promising solution is to store renewable H₂ in the form of green ammonia often referred to as Power-to-Ammonia. Thus unlocking all available infrastructure for ammonia to effectively store and export hydrogen in bulk. In this value chain, the missing link is ammonia cracking to recover back hydrogen at high purities. The present work explores a technical solution to recover hydrogen from ammonia at large-scale. Through an exhaustive technoeconomic analysis, we have demonstrated the feasibility of large-scale production of pure H₂ from ammonia. The designed Ammonia-to-H₂ plant operates at a thermal efficiency of 68.5% to produce 200 MTPD of pure hydrogen at 250 bar. Furthermore, this study has established a final estimation of the Levelized Cost of Hydrogen (LCOH) from green ammonia. It was revealed that LCOH is mostly dependent on green ammonia cost, which in turn varies with renewable electricity cost.     

Green hydrogen: A new flexibility source for security constrained scheduling of power systems with renewable energies

Green hydrogen, i.e. the hydrogen generated from renewable energy sources (RES) will significantly contribute to a successful energy transition. Besides, to facilitate the integration and storage of RES, this promising energy carrier is well capable to efficiently link various energy sectors. By introduction of green hydrogen as a new flexibility source to power systems, it is necessary to investigate its possible impacts on the generation scheduling and power system security. In this paper, a security-constrained multi-period optimal power flow (SC-MPOPF) model is developed aiming to determine the optimal hourly dispatch of generators as well as power to hydrogen (P2H) units in the presence of large-scale renewable energy sources (RES). The proposed model characterizes the P2H demand flexibility in the proposed SC-MPOPF model, taking into account the electrolyzer behavior, reactive power support of P2H demands and hydrogen storage capability. The developed SC-MPOPF model is applied to IEEE 39-bus system and the obtained numerical results demonstrate the role of P2H flexibility on cost as well as RES's power curtailment reduction.     

Estimating global production and supply costs for green hydrogen and hydrogen-based green energy commodities

Green energy commodities are expected to be central in decarbonising the global energy system. Such green energy commodities could be hydrogen or other hydrogen-based energy commodities produced from renewable energy sources (RES) such as solar or wind energy. We quantify the production cost and potentials of hydrogen and hydrogen-based energy commodities ammonia, methane, methanol, gasoline, diesel and kerosene in 113 countries. Moreover, we evaluate total supply costs to Germany, considering both pipeline-based and maritime transport. We determine production costs by optimising the investment and operation of commodity production from dedicated RES based on country-level RES potentials and country-specific weighted average costs of capital. Analysing the geographic distribution of production and supply costs, we find that production costs dominate the supply cost composition for liquid or easily liquefiable commodities, while transport costs dominate for gaseous commodities. In the case of Germany, importing green ammonia could be more cost-efficient than domestic production from locally produced or imported hydrogen. Green ammonia could be supplied to Germany from many regions worldwide at below the cost of domestic production, with costs ranging from 624 to 874 $/t NH₃ and Norway being the cheapest supplier. Ammonia production using imported hydrogen from Spain could be cost-effective if a pan-European hydrogen pipeline grid based on repurposed natural gas pipelines exists.     

Techno-economic calculation of green hydrogen production and export from Colombia

In the present paper a techno-economic hydrogen production and transportation costs to export from Colombia to Europe and Asia were determined using the open-source Python tools, such as WindPowerLIB, PVLIB, ERA5 weather data, and the Hydrogen-2-Central (H2C) model. Calculations were performed as well for Chile, for comparison as a regional competitor. In addition, a detailed overview of Colombia's energy system and national efforts for a market ramp-up of renewable energy and hydrogen is provided. The application of the model in different scenarios shows Colombia's potential to produce green hydrogen using renewable energies. The prices estimated are 1.5 and 1.02 USD/kgH₂ for 2030 and 2050 with wind power, and 3.24 and 1.65 USD/kgH₂ for 2030 and 2050 using solar energy. Colombia can become one of the most promising hydrogen suppliers to Asian and European countries with one of the lowest prices in the production and transportation of green hydrogen.