双生表面活性剂对烷基多苷洗涤性能的影响

对双生表面活性剂与烷基多苷不同配比体系表面张力，临界胶团浓度、去污性及泡沫性的实验结果表明：在烷基多苷中加入少量双生表面活性剂后，体系表面活性、去污力显著提高，而泡沫性表现特殊；当双生表面活性剂烷基多苷摩尔比增加到1：10时，产生协同效应，此时Y cmc和cmc值分别下降到26.3mN·m-1和0.43mM，低于各单一组分，而与标准粉去污力比值达1.5。双生表面活性剂有助于调节烷基多苷泡沫性，拓宽洗涤配方范围。     

洗涤剂工业中的表面活性剂新进展

绿色表面活性剂是近几年洗涤剂工业中的又一个新亮点。烷基多苷以其低刺激性、高泡沫性、良好的配伍性和环境友好性，在洗涤用品中有着美好的应用前景；新一代表面活性剂Gemini的出现，以其优良的钙皂分散性、低cmc、水溶助长性及生物安全性，倍受人们青睐；多功能表面活性剂，兼具表面活性剂和螯合功能物质ED3A、单烷基二苯醚磺酸盐(MADS)和双烷基苯醚磺酸盐(DADS)具有优良的去污力，等显现出广阔的应用前景。     

烷基多苷─—应用于洗涤剂和化妆品工业的新一代表面活性剂

本文系统地介绍了烷基多苷表面活性剂的表面化学性能，讨论了一系列不同烷链长度的烷基多苷的应用配方和性能特征。     

烷基多苷的应用及其生态学评价

从生物降解情况、生态毒理学、环境风险3方面介绍了烷基多苷的生态学性质,表明烷基多苷是一类环境相容性很好的绿色表面活性剂;概括介绍了烷基多苷的性质/性能;重点综述了烷基多苷在各领域的应用,其应用领域广泛,包括个人护理用品、清洗剂、纺织印染、农业、石油、皮革等行业;同时对烷基多苷的未来进行了展望,提出了今后烷基多苷应从高质量、多品种、广应用等方面进行深入化研究,使烷基多苷这一世界级绿色表面活性剂取得更大的发展。     

烷基多苷—应用于洗涤剂和化妆品工业的新一代表面活性剂

本文系统地介绍了烷基多苷表央活性剂的表面化学性能，讨论了一系列不同烷链长度的烷基多苷的应用配方和性能特征。     

推荐项目

烷基苷生产技术烷基苷(APG)是由葡萄糖和C8～C16脂肪醇在酸催化剂的作用下,直接缩醛反应生成烷基苷,经脱醇、漂白制得。是一种新型的兼有非离子和阴离子特性的绿色表面活性剂,除具有各类表面活性剂优良特性外,更具有无毒和生物降解迅速彻底的特点,可广泛用于香波、餐洗剂、化妆     

糖基表面活性剂综述（英）

糖基表面活性剂取自可再生资源，与环境相容性好，对皮肤温和，具有良好的起泡力，在个人护理用品，家用洗涤和餐具洗涤中可用作辅助表面活性剂，介绍了蔗糖酯，烷基多苷，葡糖胺，糖基磺基琥珀酸钠表面活性剂的性能及应用，它们在家秀及个人护理用品中将继续流行。     

科研动态

一种绿色表面活性剂开发成功 由吉化公司研究院承担的吉化公司科技攻关项目──１００吨／年烷基苷质量提高项目，最近通过吉化公司组织的专家验收。 烷基苷是由天然淀粉和天然植物油的脂肪醇合成的一种新型非离子表面活性剂，具有泡沫细腻、稳定，去污力强，对皮肤和眼睛刺激性小，易于被生物降解等特点，是一种符合现代人体安全和环境保护要求的新型绿色表面活性剂，可广泛应用于日用洗涤剂、个人保护用品、工业清洗剂、生化用品的复配。 吉化研究院于１９９８年开发成功烷基苷小试，并建成了１００吨／年烷基音中试装置。１９９９年采用…     

烷基多苷研究进展

介绍了新型表面活性剂—烷基多苷的特点,从烷基多苷合成工艺的改进、烷基多苷的催化剂的选择、产物的处理、降解、机理和动力学模型、相研究等几方面综述了烷基多苷的研究进展,指出我国目前在烷基多苷产品研究方面和国外存在的差距,强调了开发在外观、色泽、气味等方面性能良好的多功能APG ,扩大生产规模。提高产品质量的重要性。     

烷基多苷的功能特性及其在洗面奶中应用

烷基多苷是一种适用于各种清洗产品的非离子表面活性剂与其它应用密切相关的物理性、泡沫、去污力、配伍性等功能特性及其在洗面奶中应用。     

生物基表面活性剂的应用

简要概述生物基表面活性剂烷基糖苷的物理性和溶解性、表面活性、安全性和生物降解等性能。重点介绍其作为表面活性剂在衣用洗涤剂、餐具洗涤剂、化妆品、食品工业、生物化工和农药增效剂等方面的应用。同时指出烷基糖苷可进一步衍生化,从而拓宽其应用领域。     

环保型餐具洗涤剂用表面活性剂复配体系研究

表面活性剂的许多特性在单独使用时往往不能充分发挥。但当一种表面活性剂与其他表面活性剂复配时 ,溶液的物理化学性质会发生明显的变化 ,其表面活性优于各个组分的性能。从表面活性剂复配着手 ,选择阴离子型表面活性剂仲烷基磺酸钠 (SAS)、脂肪醇聚氧乙烯醚硫酸钠 (AES)和非离子型表面活性剂烷基多糖苷 (APG)进行复配实验。改变不同表面活性剂之间的配比 ,通过对临界胶团浓度 (CMC)的分析研究 ,解释了胶团的形成过程和胶团的具体组成。APG SAS、APG AES体系分子间相互作用系数 βm 为负值 ,表明它们在胶团中分子间的相互作用比同种分子间的相互作用要强 ;而且| βm|的值在 3附近 ,表明APG SAS、APG AES体系分子间存在中等强度的相互作用 ;同时在形成胶团能力方面符合增效作用判断准则 ,这些结论将有助于实际配方的确定     

Physical and functional properties of some higher alkyl polyglucosides

The higher alkyl polyglucosides are a new class of nonionic surfactants which can be formulated to give properties ranging from soft greases to hard glassy water-soluble solids melting from about 30 C to above 300 C and which are insoluble in common organic solvents. The aqueous solutions do not exhibit inverse solubility with temperature or concentration. They show low eye and skin irritation and a very low degree of toxicity (LD₅₀ greater than 35 g/kg). They have a bland taste, are good foamers with low surface tension, are compatible with inorganic detergent builders, and are biodegradable. They show good functionality in various applications such as detergents, food emulsifiers, cosmetic surfactants, pharmaceutical granulating agents and industrial emulsifiers.     

有效阻断紫外线透过衣物对人体的伤害应用于织物洗涤剂中的高效全波段紫外线吸收剂--天来施(R)FD(Tinosorb(R)FD)

介绍了一种洗涤剂用高效全波段紫外线吸收剂－天来施ＦＤ。它可以通过简单的织物洗涤,增强织物对紫外线的阻断作用,使皮肤免受紫外线的伤害。它广泛适用于普通粉,浓缩粉及液体洗涤剂的配方,可使被洗织物获得优异均匀的防护效能,且织物的紫外线防护指数ＵＰＦ值随洗涤次数的增加而不断提高。     

Assessing detergent safety: A comparison of a nonphosphate laundry detergent with phosphate detergents

The potential hazard of a carbonate-based, phosphate-free detergent was compared with that of a variety of granular and liquid phosphate detergents. Evaluations were made using methods prescribed by the Federal Hazardous Substances Act (FHSA) and others designed to more closely approximate exposure in actual use. Some phosphate products produced esophageal and gastric mucosal irritation similar to that produced by the nonphosphate detergent, while others caused varying, lesser degrees of injury. The nonphosphate detergent, as well as several phosphate products, was seriously irritating to the unwashed eye at required FHSA test levels. Under more realistic conditions, eye irritation was reduced significantly. Skin irritation by the nonphosphate product was comparable to that by phosphate detergents, and in some cases was lower. In skin irritation tests with human subjects, results with the carbonate detergent were equal to or lower than those obtained with phosphate detergents. The carbonate detergent was found not to be phototoxic, nor a contact- nor photo-sensitizer. Total alkalinity was shown not to correlate with the severity of tissue injury in either test animals or in man. Presented at the AOCS Short Course, “Update on Detergents and Raw Materials,” Lake Placid, New York, June 1971.     

烷基糖苷专利申请进展及分析

烷基糖苷是一种新型非离子表面活性剂,以其天然来源及可降解等各项优越性能被誉为世界级绿色表面活性剂。随着制备技术的完善,天然可再生的原料来源及大规模商业化,作为传统表面活性剂的替代品,烷基糖苷将会越来越广泛应用于洗涤剂和化妆品等领域。根据国内烷基糖苷的专利申请情况,围绕技术发展趋势、技术领域、主要申请人和主要发明人几个方面,进行定量分析和定性分析,为烷基糖苷的进一步技术研究提供参考依据。同时,也为企业寻求技术合作提供寻求方向。     

Use of bacteriostats in soap and household cleansing agents

In recent years there has been increasing use of antibacterial agents employed in toilet bars to provide deodorant and degerming activity. The common desirable properties of these agents are antibacterial activity at low concentrations, skin substantivity, acceptable color and odor, compatibility with the vehicle, and low irritation and sensitization potential. Bacteriostats used for such pruposes are principally bisphenolies, halogenated salicylanilides, and halogenated carbanilides. Methods for assessing their effectiveness and safety are discussed. The polybrominated salicylanilides represent a versatile group of bacteriostats which enjoys increasing acceptability in toilet bars and also provides benefits in such household products as liquid detergents, granulated detergents, hard-surface disinfectant cleansers, and aerosol disinfectant sprays.     

烷基葡糖苷合成反应的动力学模型与复配性能

在烷基葡糖多苷 (APG)合成反应研究的基础上 ,探讨了葡萄糖与脂肪醇反应直接合成APG的反应机理 ,提出了直接法合成APG时葡萄糖浓度cA 和反应时间t的反应动力学模型为 :ln(cA- 0 0 0 0 2 5 ) =- (Kt +2 0 8)。同时 ,以APG为主要原料〔w(APG) =10 %～ 15 %〕 ,通过多种表面活性剂的复配及添加特效吸附渗透剂 ,研制开发出一种适宜于各种行业工人使用的劳保浴液 ,产品集净洗、调理、护肤、洗发等多种功用于一体。该浴液经推广应用 ,并采用“模糊数学综合评价法”对其质量进行评判 ,证明APG复配产品的质量性能优异     

Lower Irritation Potential of Laureth‐3 Carboxylate Amino Acid Salt

Sodium laureth sulfate and amino acid type surfactants have been categorized as low‐skin irritation chemicals based on results of previous skin irritation tests. However, detergent‐induced skin irritation still occurs. Detergents with a low‐skin irritation effect are required, since the number of cosmetics for sensitive skin has increased. Therefore, an in vitro method of testing the safety of cosmetics for sensitive skin is required. Skin irritation by anionic surfactants was investigated to determine the effect of laureth‐3 carboxylate (polyoxyethylene lauryl carboxymethyl ether) amino acid salt on skin irritation. In addition, sodium laureth sulfate and amino acid type surfactants, regarded as low‐irritation surfactants, were also tested for skin irritation. The skin irritation effect of laureth‐3 carboxylate lysine salt (Surfactant 1 ), sodium laureth sulfate (Surfactant 2 ), and sodium N‐lauroyl glutamate (Surfactant 3 ) were investigated using a reconstructed human cultured epidermal model, LabCyte EPI‐MODEL24 6D. Cell viabilities of cultured epidermal cells exposed to Surfactant 1 (5.0 % aq.), Surfactant 2 , and Surfactant 3 were 82.0, 45.0 and 19.1 %, respectively. There were significant differences in cell viability upon exposure to 5.0 % aqueous test solutions of the three test chemicals. The results of the current investigation indicate that Surfactant 1 has a low skin‐irritation effect.     

烷基多苷的特性及其配伍的研究

烷基多苷（ＡＰＧ）作为和洗涤和化妆用品的表面活性剂，应用范围日闪扩大。本文以烷基多苷作为泡沫浴剂的基料，进行了一系列的复配实验，并加入了中药提取液，使之成为一种具有较好性能特征和与环境友好，且具有较高附加值的溶液产品。