共查询到20条相似文献,搜索用时 640 毫秒
1.
2.
Jian-Guang Yang Chao-Bo Tang Yong-Ming Chen Mo-Tang Tang 《Metallurgical and Materials Transactions B》2011,42(1):30-36
The main purpose of this study is to characterize and separate antimony from a stibnite concentrate through a low-temperature
sulfur-fixing smelting process. This article reports on a study conducted on the optimization of process parameters, such
as flux and zinc oxide weight percentage, in charging, smelting temperature, smelting duration on the antimony yield, resultant
crude antimony grade, and sulfur-fixing rate. A maximum antimony recovery of 97.07 pct, crude antimony grade of 96.45 pct,
and 98.61 pct sulfur-fixing rate are obtained when a charge (containing 63.20 wt pct of flux and 21.30 wt pct of stibnite,
a flux composition of
W\textNaOH /W\textNa 2 \textCO3 W_{\text{NaOH}} /W_{{{\text{Na}}_{ 2} {\text{CO}}_{3} }} = 10/147, where W represents weight, and more than 10 pct of the stoichiometric requirement of zinc oxide dosage) is smelted at 1153 K (880 °C)
for 120 minutes. This smelting operation is free from atmospheric pollution because zinc oxide is used as the sulfur-fixing
agent. The solid residue is subjected to mineral dressing operation to obtain suspension, which is filtered ultimately to
produce a cake, representing the solid particles of zinc sulfide. Based on the results of the chemical content analysis of
as-resultant zinc sulfide, more than 90 pct zinc sulfide can be recovered, and the recovered zinc sulfide grade can reach
66.70 pct. This material can be sold as zinc sulfide concentrate or roasted to regenerate into zinc oxide. 相似文献
3.
4.
Gitanjaly Goyal Harpreet Singh Surindra Singh Satya Prakash 《Metallurgical and Materials Transactions A》2011,42(11):3269-3276
Inhibitors and oxide additives have been investigated with varying success to control high-temperature corrosion. Effect of
Y2O3 on high-temperature corrosion of Superni 718 and Superni 601 superalloys was investigated in the Na2SO4-60 pct V2O5 environment at 1173 K (900 °C) for 50 cycles. Y2O3 was applied as a coating on the surfaces of the specimens. Superni 601 was found to have better corrosion resistance in comparison
with Superni 718 in the Na2SO4-60 pct V2O5 environment. The Y2O3 superficial coating was successful in decreasing the reaction rate for both the superalloys. In the oxide scale of the alloy
Superni 601, Y and V were observed to coexist, thereby indicating the formation of a protective YVO4 phase. There was a distinct presence of a protective Cr2O3-rich layer just above the substrate/scale interface in the alloy. Whereas Cr2O3 was present with Fe and Ni in the scale of Superni 718. Y2O3 seemed to be contributing to better adhesion of the scale, as comparatively lesser spalling was noticed in the presence of
Y2O3. 相似文献
5.
6.
Sachin Tyagi Himanshu B. Baskey Ramesh Chandra Agarwala Vijaya Agarwala Trilok Chand Shami 《Transactions of the Indian Institute of Metals》2011,64(6):607-614
Zinc ferrite and strontium hexaferrite; SrFe12O19/ZnFe2O4 (SrFe11.6Zn0.4O19) nanoparticles having super paramagnetic nature were synthesized by simultaneous co-precipitation of iron, zinc and strontium
chloride salts using 5 M sodium hydroxide solution. The resulting precursors were heat treated (HT) at 850, 950 and 1150°C
for 4 h in nitrogen atmosphere. The hysteresis loops showed an increase in saturation magnetization from 1.040 to 58.938 emu/g
with increasing HT temperatures. The ‘as-synthesized’ particles have size in the range of 20–25 nm with spherical and needle
shapes. Further, these spherical and needle shaped nanoparticles tend to change their morphology to hexagonal plate shape
with increase in HT temperatures. The effect of such a systematic morphological transformation of nanoparticles on dielectric
(complex permittivity and permeability) and microwave absorption properties were estimated in X band (8.2–12.2 GHz). The maximum
reflection loss of the composite reaches −26.51 dB (more than 99% power attenuation) at 10.636 GHz which suits its application
in RADAR absorbing materials. 相似文献
7.
8.
Luckman Muhmood Nurni Neelakandan Viswanathan Masanori Iwase Seshadri Seetharaman 《Metallurgical and Materials Transactions B》2011,42(2):274-280
The chemical diffusion coefficient of sulfur in the ternary slag of composition 51.5 pct CaO-9.6 pct SiO2-38.9 pct Al2O3 slag was measured at 1680 K, 1700 K, and 1723 K (1403 °C, 1427 °C, and 1450 °C) using the experimental method proposed earlier
by the authors. The
P\textS2 P_{{{\text{S}}_{2} }} and
P\textO2 P_{{{\text{O}}_{2} }} pressures were calculated from the Gibbs energy of the equilibrium reaction between CaO in the slag and solid CaS. The density
of the slag was obtained from earlier experiments. Initially, the order of magnitude for the diffusion coefficient was taken
from the works of Saito and Kawai but later was modified so that the concentration curve for sulfur obtained from the program
was in good fit with the experimental results. The diffusion coefficient of sulfur in 51.5 pct CaO-9.6 pct SiO2-38.9 pct Al2O3 slag was estimated to be in the range 3.98 to 4.14 × 10−6 cm2/s for the temperature range 1680 K to 1723 K (1403 °C to 1450 °C), which is in good agreement with the results available
in literature 相似文献
9.
M. BAHGAT M.H. KHEDR M.I. NASR E.K. SEDEEK 《Metallurgical and Materials Transactions B》2007,38(1):5-11
Pure nanocrystalline hematite (40 to 100 nm) compacts were prepared and sintered at various temperatures (300 °C to 600 °C)
and then reduced with 100 pct H2 at 500 °C. On the other hand, fired compacts at 500 °C were reduced with a H2-Ar gas mixture containing different concentration of hydrogen (100, 75, 50, and 25 pct) at 500 °C using thermogravimetric
techniques. Nanocrystalline Fe2O3 compacts were characterized before and after reduction with X-ray diffraction, scanning electron microscopy (SEM), vibrating
sample magnetometer (VSM), and reflected light microscope. It was found that the fired compacts at 400 °C to 600 °C have relatively
faster reaction behaviors compared to that at lower firing temperature 300 °C. By decreasing the firing temperature to 300 °C,
partial sintering with grain growth was observed clearly during reduction. Also, it was found that the reduction rate increased
with increasing hydrogen content in the reducing gas. Comparatively, grain growth and partial coalescence took place during
reduction with 25 pct H2 due to long reaction time.
相似文献
M. BAHGAT (Researcher)Email: |
10.
11.
Joo Hyun Park Sang-Beom Lee Henri R. Gaye 《Metallurgical and Materials Transactions B》2008,39(6):853-861
12.
Fengshan Li Xianpeng Li Shufeng Yang Yanling Zhang 《Metallurgical and Materials Transactions B》2017,48(5):2367-2378
In order to effectively enhance the efficiency of dephosphorization, the distribution ratios of phosphorus between CaO-FeO-SiO2-Al2O3/Na2O/TiO2 slags and carbon-saturated iron (\( L_{\text{P}}^{\text{Fe-C}} \)) were examined through laboratory experiments in this study, along with the effects of different influencing factors such as the temperature and concentrations of the various slag components. Thermodynamic simulations showed that, with the addition of Na2O and Al2O3, the liquid areas of the CaO-FeO-SiO2 slag are enlarged significantly, with Al2O3 and Na2O acting as fluxes when added to the slag in the appropriate concentrations. The experimental data suggested that \( L_{\text{P}}^{\text{Fe-C}} \) increases with an increase in the binary basicity of the slag, with the basicity having a greater effect than the temperature and FeO content; \( L_{\text{P}}^{\text{Fe-C}} \) increases with an increase in the Na2O content and decrease in the Al2O3 content. In contrast to the case for the dephosphorization of molten steel, for the hot-metal dephosphorization process investigated in this study, the FeO content of the slag had a smaller effect on \( L_{\text{P}}^{\text{Fe-C}} \) than did the other factors such as the temperature and slag basicity. Based on the experimental data, by using regression analysis, \( \log L_{\text{P}}^{\text{Fe-C}} \) could be expressed as a function of the temperature and the slag component concentrations as follows:
相似文献
$$ \begin{aligned} \log L_{\text{P}}^{\text{Fe-C}} & = 0.059({\text{pct}}\;{\text{CaO}}) + 1.583\log ({\text{TFe}}) - 0.052\left( {{\text{pct}}\;{\text{SiO}}_{2} } \right) - 0.014\left( {{\text{pct}}\;{\text{Al}}_{2} {\text{O}}_{3} } \right) \\ \, & \quad + 0.142\left( {{\text{pct}}\;{\text{Na}}_{2} {\text{O}}} \right) - 0.003\left( {{\text{pct}}\;{\text{TiO}}_{2} } \right) + 0.049\left( {{\text{pct}}\;{\text{P}}_{2} {\text{O}}_{5} } \right) + \frac{13{,}527}{T} - 9.87. \\ \end{aligned} $$
13.
Saeed Sheibani Abolghasem Ataie Saeed Heshmati-Manesh 《Metallurgical and Materials Transactions A》2010,41(10):2606-2612
In this article, a novel method has been used to prepare a copper matrix nanocomposite containing Cu-10 wt pct Cr-10 wt pct
Al2O3 by heat treatment of the mechanically activated Cu, Al, and Cr2O3 powder mixture. Structural evolutions were investigated using the X-ray diffraction (XRD) technique. The microstructure of
samples was examined using scanning electron microscopy (SEM). It was found that during the milling process, Cu(Al) solid
solution and Cu9Al4 phase were formed as the intermediate products, and therefore, Al activity was decreased. Hence, the reduction of Cr2O3 with Al was prevented during the ball milling stage. Further heat treatment carried out under argon atmosphere at 900 °C
for 8 hours resulted in completion of Cr2O3 reduction by Al. 相似文献
14.
Haijuan Wang Lidong Teng Jiayun Zhang Seshadri Seetharaman 《Metallurgical and Materials Transactions B》2010,41(5):1042-1051
The oxidation mechanism of liquid Fe-V alloys with V content from 5 to 20 mass pct under different oxygen partial pressures
using CO2-O2 mixtures with CO2 varying from 80 pct to 100 pct was investigated by thermogravimetric analysis between 1823 K and 1923 K (1550 °C and 1650 °C).
The products after oxidation were identified by scanning electron microscopy energy-dispersive spectrograph and X-ray diffraction.
The results indicate that the oxidation process can be divided into the following steps: an apparent incubation period, followed
by a chemical reaction step with a transition step before the reaction, and diffusion as the last stage. At the initial stage,
a period of slow mass increase was observed that could be attributed to possible oxygen dissolution in the liquid iron-vanadium
coupled with the vaporization of V2O. The length of this period increased with increasing temperature as well as vanadium content in the melt and decreased with
increasing oxygen partial pressure of the oxidant gas. This analysis was followed by a region of chemical oxidation. The oxidation
rate increased with the increase of the O2 ratio in the CO2-O2 gas mixtures. During the final stage, the oxidation seemed to proceed with the diffusion of oxygen through the product layer
to the reaction front. The Arrhenius activation energies for chemical reaction and diffusion were calculated, and kinetic
equations for various steps were setup to describe the experimental results. The transition from one reaction mechanism to
the next was described mathematically as mixed-control equations. Thus, uniform kinetic equations have been setup that could
simulate the experimental results with good precision. 相似文献
15.
Cu-10Cr-3Ag (wt pct) alloy with nanocrystalline Al2O3 dispersion was prepared by mechanical alloying and consolidated by high pressure sintering at different temperatures. Characterization
by X-ray diffraction and scanning electron microscopy or transmission electron microscopy shows the formation of nanocrystalline
matrix grains of about 40 nm after 25 hours of milling with nanometric (<20 nm) Al2O3 particles dispersed in it. After consolidation by high pressure sintering (8 GPa at 400 °C to 800 °C), the dispersoids retain
their ultrafine size and uniform distribution, while the alloyed matrix undergoes significant grain growth. The hardness and
wear resistance of the pellets increase significantly with the addition of nano-Al2O3 particles. The electrical conductivity of the pellets without and with nano-Al2O3 dispersion is about 30 pct IACS (international annealing copper standard) and 25 pct IACS, respectively. Thus, mechanical
alloying followed by high pressure sintering seems a potential route for developing nano-Al2O3 dispersed Cu-Cr-Ag alloy for heavy duty electrical contact. 相似文献
16.
《Canadian Metallurgical Quarterly》1999,38(3):175-186
Electric arc furnace (EAF) dust is produced when iron and steel scrap is remelted in an electric arc furnace. There are still significant problems associated with the pyrometallurgical and/or hydrometallurgical processes for the treatment of this dust. In the present research, the dust was roasted with caustic soda at low temperatures. It was found that the zinc ferrite (ZnFe2O4) in the dust was converted into sodium zincate (Na2ZnO2) and iron oxide (Fe2O3). In the subsequent dilute caustic leaching process both the zincite (ZnO) and the sodium zincate were soluble and the hematite was relatively insoluble. After roasting and leaching, the zinc recovery was found to be about 95%, while the majority of the iron oxide remained in the leach residue. The lead, cadmium and chromium recoveries were approximately 85, 89 and 37%, respectively, for roasting tests in which moisture was added. Without a moisture addition in roasting, the lead recovery decreased to 63% while the chromium recovery increased to 81%. Based on the experimental results, a hybrid low temperature roasting and dilute caustic leaching process followed by zinc cementation and electrowinning is proposed and discussed. This proposed hybrid EAF dust treatment process provides some potential advantages in comparison to the other hybrid processes which have been described in the literature. 相似文献
17.
18.
19.
Christian Thales Mutale Alan W. Cramb Thomas Claudon 《Metallurgical and Materials Transactions B》2005,36(3):417-418
In this work, isothermal crystallization of a synthetic slag containing 46 wt pct CaO, 46 wt pct SiO2, 6 wt pct Al2O3, and 2 wt pct Na2O has been investigated by means of double hot thermocouple technique (DHTT). The effect of Na2O content on crystallization time was confirmed. Two different types of calcium silicate crystals were observed. Calcium di-silicate
forms at temperatures above 1150 °C and calcium tri-silicate precipitate at temperatures below 1050 °C. A mixture of the two
types of calcium silicate has been observed between the two temperatures. The tendency of crystals to become richer in calcium
at low temperatures that has also been observed in previous published works has been confirmed. No effect of the cooling rate
on crystallization start time was confirmed in the range of cooling rates applied in this investigation. 相似文献