Economic biogas and cooling water rates in a lithium bromide—water absorption system

An economic analysis of the role of biogas and cooling water in a lithium bromide—water absorption system has been carried out to optimize the generator, condenser and absorber temperatures at a given evaporator temperature and solution pumping rate. The analysis has been repeated for different pumping rates (PR) to determine the optimum PR corresponding to the minimum over-all operating cost of the system. The study has also been carried out for the condition when biogas in the generator and cooling water in the absorber and condenser are supplied at equal flow-rates. It is found that the performance of the LiBr-H₂O system at equal biogas and cooling water flow-rates is about 5.988% higher than when operated at the minimum over-all operating cost, the latter being cheaper by only 2.71%. For low evaporation temperatures, use of a preheater in a LiBr-H₂O system creates a crystallization problem when operated at low pumping rates. The study has therefore been extended for a system without preheater. The parameters under study are illustrated graphically against the generator temperature. Equations to obtain the corresponding optimum condenser and absorber temperature are given. The functional relationship between crystallization limit and absorbent temperature has also been obtained. The optimum operating parameters are presented graphically.     

Influence of adsorption cycle limitations on the system performance

The economics of heat driven heat pumps are governed by two thermodynamic quantities: the performance on the one hand and the size of the heat exchangers, which is required to obtain this performance, on the other hand. The aim of this paper is to discuss the influence of the main features of adsorption cycles in comparison to absorption cycles on these quantities. In our case, a Zeolite UCC16×40-type 13X has been taken as the adsorbent. The analysis has already been used for absorption heat pumps. In the case of adsorption and other solid sorption chillers, additional limitations appear, e.g. identical design of all adsorbers, incomplete heat recovery between adsorbers, cycling of inert mass, etc., which all contribute to a lowering of the system performance or to an increase of the exchange area required. To show the basic differences between absorption and adsorption cycle optimization, and also to show the impact of physical or technical limitations on the adsorption chiller performance, a detailed analysis has been performed. It is confirmed that it is mainly the lack of a solution heat exchanger which lowers the adsorption system COP and not physical properties of the working pair, so there is still a lot of room for improvement in the solid-sorption of heat pumps.     

Experimental investigation of mass recovery adsorption refrigeration cycle

The study investigates the performance of silica gel–water adsorption refrigeration cycle with mass recovery process by experimental prototype machine. In an adsorption refrigeration cycle, the pressures in adsorber and desorber are different. The mass recovery cycle utilizes the pressure difference to enhance the refrigerant mass circulation. Moreover, novel cycle was proposed for improvement of cooling output. In our previous study, simulation analysis shows that mass recovery cycle has the advantage over conventional single-stage. Experiments with prototype machine were conducted to investigate the performance improvement of mass recovery cycle in the present paper. Specific cooling power (SCP) and coefficient of performance (COP) were calculated with experimental data to analyze the influences of operating conditions. The proposed cycle was compared with the single-stage cycle in terms of SCP and COP. The results show that SCP of mass recovery cycle is superior to that of conventional cycle and mass recovery cycle is effective with low temperature heat source.     

Experimental investigation on R134a vapour ejector refrigeration system

The experimental investigation of the performance of a vapour ejector refrigeration system is described. The system uses R134a as working fluid and has a rated cooling capacity of 0.5 kW. The influence of generator, evaporator and condenser temperatures on the system performance is studied. This kind of system can be operated with low grade thermal energy such as solar energy, waste heat, etc. The operating conditions are chosen accordingly as, generator temperature between 338 K and 363 K, condenser temperature between 299 K and 310.5 K, and evaporator temperature between 275 K and 285.5 K. Six configurations of ejectors of different geometrical dimensions are selected for the parametric study. The performance of the refrigeration system at different operating temperatures is presented.     

Maximum mass flow ratio due to secondary flow choking in an ejector refrigeration system

The occurrence of flow choking in an ejector of an ejector refrigeration system (ERS) was analysed and a model for predicting the maximum flow ratio of the ejector was developed. The multi-parameter equation to calculate the mass flow ratio takes into account the performance of the primary nozzle, the flow entrainment and mixing relating to ejector geometry and operating conditions. We validated the model using the reported experimental data of refrigerant R113, R141b and steam ERS. The present model was shown to provide better accuracy compared with results obtained by applying the existing 1-D ejector theory. We discussed the application of the model and highlighted the significance of the parameters for future work.     

Experimental investigation of silica gel–water adsorption chillers with and without a passive heat recovery scheme

We experimentally show that for the same heat exchanger inventory allocation, a four-bed adsorption chiller delivers a 12% higher ultimate cooling capacity than its two-bed counterpart. In addition it delivers a significantly improved quality of instantaneous cooling than a two-bed chiller at the same cooling capacity. The COP-enhancing feature of a passive heat recovery scheme that does not involve additional pumping action or valves is experimentally proven. It improves the COPs of a two-bed chiller and a four-bed chiller by as much as 38 and 25%, respectively, without any effect on their cooling capacities. The highest COPs achieved with a two-bed and four-bed chillers are 0.46±0.02 and 0.45±0.02, respectively. These are measured at a hot-water inlet temperature of 85 °C, cooling-water inlet temperature of 29.4 °C and chilled-water inlet temperature of 12.2 °C.     

Characteristics of Voorhees refrigerating machine with hermetic piston compressor producing refrigeration at one or two temperature levels

Research on the operation of the refrigerating machine working on the Voorhees cycle which permits two-stage compression in a single-cylinder compressor has been carried out. The purpose of this research was to study the possibilities of using the Voorhees machine in a domestic refrigerator for production of refrigeration at one or two temperature levels. The experiments were carried out on the basis of a small hermetic lubricated compressor with a low refrigerating capacity operating on a commonly used R12 and natural refrigerant isobutane R600a. The improved refrigerating capacity in the Voorhees cycle with isobutane makes the latter an alternative substitute for conventional refrigerants. Some peculiarities in the operation of a hermetic piston compressor as part of the Voorhees refrigerating machine have been revealed. They require the use of a compressor developed specially for the Voorhees cycle. The method of optimizing the cycle parameters for a one temperature refrigerating system is suggested in this paper. The research carried out proved that the optimum intermediate pressures of the Voorhees refrigerating machine producing refrigeration either at one or two temperature levels are different.     

Multi-bed regenerative adsorption chiller — improving the utilization of waste heat and reducing the chilled water outlet temperature fluctuation

A multi-bed regenerative adsorption chiller design is proposed. The concept aims to extract the most enthalpy from the low-grade waste heat before it is purged into the drain. It is also able to minimise the chilled water temperature fluctuation so that downstream temperature smoothing device may be downsized or even eliminated in applications where tighter temperature control may be required. The design also avoids a master-and-slave configuration so that materials invested are not under-utilised. Because of the nature of low-grade waste heat utilization, the performance of adsorption chillers is measured in terms of the recovery efficiency, η instead of the conventional COP. For the same waste heat source flowrate and inlet temperature, a four-bed chiller generates 70% more cooling capacity than a typical two-bed chiller. A six-bed chiller in turn generates 40% more than that of a four-bed chiller. Since the beds can be triggered into operation sequentially during start-up, the risk of ice formation in the evaporator during start-up is greatly reduced compared with that of a two-bed chiller.     

Zeolite heat pump — adsorption of methanol in synthetic zeolites 13X, 4A and 5A

The adsorption isotherms for methanol adsorption in synthetic zeolites 13X, 4A and 5A were measured gravimetrically at various temperatures. The model of Langmuir and the potential theory were used for correlating the equilibrium data. The monolayer capacity was calculated using these two models. A small deviation at elevated temperatures was observed. The differential heat of adsorption was measured calorimetrically for all three zeolites. The isosteric heat of adsorption was calculated for zeolite 13X using measured equilibrium data. The log p, 1/T equilibrium diagram for zeolite 13X was computed using the Langmuir equation.     

Experimental investigation on the performance of NH3/CO2 cascade refrigeration system with twin-screw compressor

This paper describes the experiment carried out to analyze the performance of a refrigeration system in cascade with ammonia and carbon dioxide as working fluids. The effect of operation parameters, such as the evaporating temperature of the low temperature cycle, the condensing temperature of low temperature cycle, temperature difference in cascade heat exchanger and superheat degree, on the system performance was investigated. Performance of the cascade system with NH₃/CO₂ was compared with that of two-stage NH₃ system and single-stage NH₃ system with or without economizer. It was found that the COP of the cascade system is the best among all the systems, when the evaporating temperature is below −40 °C. Also, the cascade system performance is greatly affected by evaporating temperature, condensing temperature of low temperature cycle, temperature difference in cascade heat exchanger and is only slightly sensitive to superheat degree. All the experimental results indicate that the NH₃/CO₂ cascade system is very competitive in low temperature applications.     

Experimental results for a hydraulic refrigeration system using n-butane

The hydraulic refrigeration system (HRS) is a vapor-compression system that accomplishes the compression and condensation of the refrigerant in a unique manner, by entraining refrigerant vapor in a down-flowing stream of water and utilizing the pressure head of the water to compress and condense the refrigerant. A multi-stage HRS was designed, fabricated, and tested using n-butane as the refrigerant. In general, both the refrigeration rate and the coefficient of performance (COP) increased with a corresponding decrease in the compression fluid temperature of the third and final stage. The refrigeration rate and COP were also found to increase with a corresponding increase in evaporator temperature. The predictions of an enhanced model incorporating two-phase hydraulic losses show excellent agreement with the experimental data with a maximum error of ±20%. The results of the experimental investigation indicate that the HRS offers an attractive and feasible alternative to conventional vapor-compression systems, especially in applications where direct-contact heat exchange in the evaporator is desirable.     

Study of a novel silica gel–water adsorption chiller. Part II. Experimental study

The prototype of a novel silica gel–water adsorption chiller is built and its performance is tested in detail. The experimental results show that the refrigerating capacity (RC) and COP of the chiller are 7.15 and 0.38 kW, respectively, when the hot water temperature is 84.8 °C, the cooling water temperature is 30.6 °C, and the chilled water outlet temperature is 11.7 °C. The RC will reach 6 kW under the condition of 65 °C hot water temperature, 30.5 °C cooling water temperature and 17.6 °C chilled water temperature. The results confirm that this kind of adsorption chiller is an effective refrigerating machine though its performance is not as fine as the prediction results. Also it is well effectively driven by a low-grade heat source. Therefore, its applications to the low-grade heat source are much attractive.     

Experimental investigation of a vapor absorption refrigeration system

An experimental investigation of the performance of a commercially available vapor absorption refrigeration (VAR) system is described. The natural gas-fired VAR system uses aqua-ammonia solution with ammonia as the refrigerant and water as the absorbent and has a rated cooling capacity of 10 kW. The unit was extensively modified to allow fluid pressures and temperatures to be measured at strategic points in the system. The mass flow rates of refrigerant, weak solution, and strong solution were also measured. The system as supplied incorporates air-cooled condenser and absorber units. Water-cooled absorber and condenser units were fitted to extend the VAR unit's range of operating conditions by varying the cooling water inlet temperature and/or flow rates to these units. The response of the refrigeration system to variations in chilled water inlet temperature, chilled water level in the evaporator drum, chilled water flow rate, and variable heat input are presented.     

Waste heat driven dual-mode, multi-stage, multi-bed regenerative adsorption system

Over the past few decades there have been considerable efforts to use adsorption (solid/vapor) for cooling and heat pump applications, but intensified efforts were initiated only since the imposition of international restrictions on the production and utilization of CFCs and HCFCs. In this paper, a dual-mode silica gel–water adsorption chiller design is outlined along with the performance evaluation of the innovative chiller. This adsorption chiller utilizes effectively low-temperature solar or waste heat sources of temperature between 40 and 95 °C. Two operation modes are possible for the advanced chiller. The first operation mode will be to work as a highly efficient conventional chiller where the driving source temperature is between 60 and 95 °C. The second operation mode will be to work as an advanced three-stage adsorption chiller where the available driving source temperature is very low (between 40 and 60 °C). With this very low driving source temperature in combination with a coolant at 30 °C, no other cycle except an advanced adsorption cycle with staged regeneration will be operational. The drawback of this operational mode is its poor efficiency in terms of cooling capacity and COP. Simulation results show that the optimum COP values are obtained at driving source temperatures between 50 and 55 °C in three-stage mode, and between 80 and 85 °C in single-stage, multi-bed mode.     

A combined-cycle refrigeration system using ejector-cooling cycle as the bottom cycle

A combined-cycle refrigeration system (CCRS) that comprises a conventional refrigeration and air-conditioning system using mechanical compressor (RAC/MC) and an ejector-cooling cycle (EJC) is proposed and studied. The EJC is driven by the waste heat from the RAC/MC and acts as the bottom cycle of the RAC/MC. A system analysis shows that the COP of a CCRS is significantly higher than a single-stage refrigeration system. Improvement in COP can be as high as 18.4% for evaporating temperature of the RAC/MC T_e at −5°C. A prototype of the CCRS was built and tested in the present study. Experimental results show that at T_e=−4.5°C, COP is improved by 14% for a CCRS. For T_e at 5°C, COP can be improved by 24% for a CCRS with higher condensing temperature of the RAC/MC. The present study shows that the CCRS using the ejector-cooling cycle as the bottom cycle of the RAC/MC is viable. Further improvement in COP is possible since the prototype is not designed and operated at an optimal condition.     

Experimental investigation of oil retention in air conditioning systems

In air conditioning and refrigeration systems a small amount of oil is carried with the refrigerant and is retained in the system components. Oil retention characteristics in the condenser, evaporator, liquid and suction lines were measured and are presented and discussed here. Refrigerants R22, R410A, and R134a with miscible and non-miscible lubricants were considered to investigate oil retention physics in the widest possible range of transport properties. A parametric analysis in the suction line showed that oil retention depends on the oil mass fraction, vapor refrigerant mass flux, mixture viscosity ratio and orientation of the pipe. In the suction line, an increase in mixture viscosity of about 55% caused a rise in oil retention in the range of 50%, depending on the oil mass fraction. Oil retention in the upward vertical suction line is about 50% higher than in the horizontal line at similar conditions.     

Comparative study of irreversibilities in an aqua-ammonia absorption refrigeration system

Irreversibilities in components of an aqua-ammonia absorption refrigeratio system (ARS) have been determined by second law analysis. The components of the ARS are as follows: condenser, evaporator, absorber, generator, pump, expansion valves, mixture heat exchanger and refrigerant heat exchanger. It is assumed that the ammonia concentration at the generator exit is, independent of the other parameters, equal to 0.999 and at the evaporator exit the gas is saturated vapour. Pressrre losses between the generator and condenser, and the evaporator and absorber are taken into consideration. In the results the dimensionless exergy loss of each component, the exergetic coefficient of performance, the coefficient of performance and the circulation ratio are given graphically for each different generator, evaporator, condenser and absorber temperature.     

Experimental investigation of a micro-combined cooling, heating and power system driven by a gas engine

An experimental investigation of the performance of a micro-combined cooling, heating and power (CCHP) system is described. The natural gas and LPG-fired micro-CCHP system uses a small-scale generator set driven by a gas engine and a new small-scale adsorption chiller, which has a rated electricity power of 12 kW, a rated cooling of 9 kW and a rated heating capacity of 28 kW. Silica gel–water is used as working pair in the adsorption cooling system. The refrigeration COP of the adsorption chiller is over 0.3 for 13 °C evaporation temperature. The test facility designed and built is described, which supplies better test-rig platform for cooling, heating and power cogeneration. Experimental methodology of this system is presented and the results are discussed. An energetic analysis of micro-CCHP system is performed as well. The overall thermal and electrical efficiency is over 70%.     

A novel hybrid absorption–compression refrigeration cycle

When used in traditional pool-boiling type refrigeration cycles, non-azeotropic mixed refrigerants tend to result in a reduced efficiency compared to pure refrigerants. This results from the composition shift effect, which distributes the mixture components: concentrating the more volatile component in the high pressure part of the cycle, and the less volatile component in the low pressure part. The obvious effect of this is to increase the compression ratio relative to a single component. This article investigates a way of manipulating the composition change of a refrigerant mixture, using two components of similar volatility, in order to reduce the compression ratio. Counter-current vapour–liquid contact is used in a “refrigeration column”, which is combined with a distillation column. The cycle is able to exploit heat sources below 100°C as input to the distillation column and the designer is able to optimise the consumption of compressor power and distillation heat input.     

Study on an activated carbon fiber–ethanol adsorption chiller: Part I – system description and modelling

This article presents the transient modelling for a two-bed, activated carbon fiber (ACF)–ethanol adsorption chiller. This innovative adsorption chiller employs pitch based ACF of type A-20 as adsorbent which is a fibrous adsorbent having the advantages of fast adsorption rate, high porosity and ease of handling when compared with granular adsorbents and powdered adsorbents. Ethanol is used as refrigerant as it has no harm to environment, it is a non-toxic substance, moreover, ethanol has comparatively higher vapor pressure even at low temperature. This innovative system utilizes effectively low-temperature waste heat sources of temperature between 60 and 95 °C along with a coolant at 30 °C. We have found that, regardless of the initial mass distribution, the ACF–ethanol adsorption chiller is able to achieve the same cyclic-steady-state within three cycles or 1890 s.