共查询到18条相似文献,搜索用时 950 毫秒
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以甲苯、丙烯、一氧化碳为代表物研究了在金属壁与催化层一体化催化剂上的催化燃烧 ,假设吸附解离态的氧与吸附态的反应物反应建立了催化燃烧反应动力学模型 ,得到了甲苯、丙烯、一氧化碳混合物在空气中催化燃烧反应动力学方程 . 相似文献
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本文研究了“活性炭吸附+催化燃烧”工艺在挥发性有机化合物(VOCs)治理中的联合应用,以提高现代化工废气处理系统的效率和环保性能。首先,详细介绍了该工艺的基本原理,包括活性炭吸附、脱附和催化燃烧的机理,以及影响催化燃烧反应的主要因素。随后,阐述了活性炭废气处理系统的主要处理工序与原理,包括废气的捕集、多级过滤、活性炭吸附和催化燃烧等阶段。在活性炭吸附+催化燃烧系统方案中,系统通过多级过滤确保废气在进入设备前达到清洁无害的标准。活性炭在吸附阶段通过其巨大表面积和微孔结构有效吸附废气中的有机物,将其转化为对人体无害的气体。随着活性炭吸附的饱和,通过吹扫干热空气进行脱附再生,维持活性炭床的吸附能力。脱附后的废气进入催化燃烧装置,在催化剂的作用下高效氧化燃烧,将有机物完全分解为水和二氧化碳。系统设计中,燃烧产生的热量被用于加热活性炭吸附系统和预处理废气,提高整个系统的能源利用率。 相似文献
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建立了甲苯、二甲苯、环己烷催化燃烧反应器的一维拟均相数学模型 ,在MnCuOx/Al2 O3 催化剂上催化燃烧反应动力学采用Langmuir双曲型动力学方程。模拟计算了废气处理量、废气中有机化合物的浓度、床层入口温度对净化率的影响 相似文献
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一、前言在涂料制造过程,尤其在它的施工过程中,要释放大量有机溶剂,危害人体健康和环境,因此急待治理。目前,废气净化方法很多,如直接燃烧、催化燃烧、活性碳吸附等。但权衡其利弊,燃烧虽有优点,但也有一些缺点,如大风量、低浓度的废气不能完全燃烧,间歇作业中余热不能充分利用,燃烧需大量能源以及不完全燃烧产生二次污染等。理想的废气处理方法应该是:废气→燃烧(直接燃烧800~1200℃,催化燃烧500-550℃)→活性碳(活性碳纤维) 相似文献
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Catalytic combustion of toluene on Cu-Mn/MCM-41 catalyst was performed in tubular flow reactor operated at atmospheric pressure. The effect of catalyst pre-treatment temperatures on the catalytic activity and stability was investigated. Some reaction variables, such as inlet concentration of toluene and oxygen, reaction temperatures and space velocities were varied over wide ranges, and the influence of different reaction conditions on toluene conversion was discussed. It is showed that the catalytic activity was significantly affected by calcination temperatures between 300 and 800 °C, and oxygen concentration, toluene concentration and space velocity are all key experimental factors to optimize the toluene combustion activities. The objective of this study was to investigate catalytic properties of Cu-Mn/MCM-41 catalysts prepared at different calcination temperatures, in order to obtain additional information to prepare an efficient and highly active catalyst at low temperature. 相似文献
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消除内外扩散影响后, 在微型固定床积分反应器中开展了国产HPA型负载贵金属催化剂上一氧化碳、丙烯和丙烷单组分及其三组分混合物催化燃烧的实验研究。采用程序升温脱附(TPD)手段考察了反应物在催化剂上的吸附脱附情况, 据此推测可能的反应机理, 建立了单组分催化燃烧的Eley-Rideal速率模型。运用最小二乘估计和单纯形优化搜索方法对模型参数进行了估值, 反应物转化率的模型计算值与实验值吻合良好。同时, 将所得单组分动力学模型叠加用于预测多组分催化燃烧时, 转化率的计算值与多组分实验结果相容。 相似文献
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The Purification experiments of waste gas containing low concentration toluene were made in trickling biofilter with ceramic spheres. The effects of liquid flow rate,gas flow rate,pH of circulation liquid, and toluene concentration in inlet gas on the purification efficiency of trickling biofilter were investigated. The pressure drop of the trickling biofilter was also measured during experiments.Increasing liquid flow rate and gas flow rate resulted in the decrease of purification efficiency of trickling biofilter. The highest purification efficiency of trickling biofilter was found at the circulation liquid pH of 7. The porosity of the packing material at the inlet of gas was higher than that at the outlet of gas in biofilter after continuous operation in 50 days. The decrease in the porosity of packing material caused a great increase in the pressure drop of the biofilter. 相似文献
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This study was conducted to investigate the decomposition of volatile organic compounds in air by the rotating arc plasma system. The rotating arc plasma decomposed benzene, toluene, and m-xylene (BTX) gases diluted in air. The effects of the gas flow rate and arc rotation speed on conversion rate and energy efficiency were evaluated by high speed images and Fourier transform infrared spectroscopy. Perfect conversions of toluene and m-xylene into environmentally benign species were achieved at the lowest waste gas flow rate of 20 L/min, while the conversion rate of benzene was 79% under the same operating conditions due to the highest chemical bond strength of benzene among BTX. Although the conversion rate decreased with increasing the gas flow rate, the energy efficiency had an optimal gas flow rate, which influenced arc rotation speed. In addition, the oxidation rates of BTX were examined based on analysis of carbon oxides generated under different operating conditions. 相似文献
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A. Prakash 《Chemical Engineering Communications》1994,128(1):143-158
Water gas shift reaction plays an important role in the Fischer-Tropsch synthesis reaction over iron-based catalysts. A slurry reactor model which accounted for the kinetics of both Fischer-Tropsch synthesis and water gas shift reaction was used to investigate the effects of hydrogen to carbon monoxide ratio, water vapor concentration and reactor temperature on synthesis gas conversion. The model was used to determine optimum concentration of water in the feed gas. For a given reactor temperature, the optimum concentration of water in the feed gas was found to increase with decreasing hydrogen to carbon monoxide ratio. The optimum concentration of water in the feed gas was found to decrease with increasing reactor temperature. Increasing the water gas shift reaction rate improved syngas conversion for low reaction temperatures. 相似文献
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The non-steady-state behaviour of a fixed bed reactor controlled by periodical direction reversal of reactant feed, applied in catalytic oxidation of industrial waste gases, containing organic compounds and carbon monoxide, has been investigated. The effects of the type of oxidized compound, its initial feed concentration, linear gas velocity, inerts-to-catalyst ratio and inerts thermophysical characteristics on the formation of reactor concentration and temperature fields were elucidated. It was shown that autothermal reactor behaviour is guaranteed by concentrations of the oxidized component which ensure an adiabatic temperature increase in excess of 20 °C. Deviations of either flow rate or initial concentration of the oxidized compound do not disturb the operational stability. 相似文献
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在固定床反应器中利用HPA型催化剂进行了丙烯腈尾气流向变换催化燃烧实验。考察了在不同尾气组成、不同空速及不同换向周期下流向变换催化燃烧反应系统的热波特性、可燃物的转化率等特性。结果表明,在广泛的操作条件变化范围内,可燃物的转化率均能维持在96%以上,即使空速、气体组成在一定范围内短期波动,流向变换催化燃烧反应系统仍然能够维持正常操作,但在可燃物浓度较低且空速、换向周期与可燃物浓度匹配不合理时反应系统将熄火,浓度较高时将飞温。 相似文献