质子交换膜燃料电池的研发动态

质子交换膜燃料电池(PEMFC)因其独特的优点具有很好的市场前景,国际上已经形成了一种研究热潮.电催化剂、质子交换膜、双极板、燃料、水管理、热管理是其关键技术.文章介绍了PEMFC的特点及开发应用状况,综述了PEMFC的研究进展.     

质子交换膜燃料电池的研究与应用

文章介绍了PEMFC(质子交换膜燃料电池)的结构、工作原理、性能特点及其关键技术与关键材料，并对其广阔的应用前景进行了展望。     

质子交换膜燃料电池的膜电极及其湿度特性

质子交换膜燃料电池的膜电极结构与电池性能密切相关，膜的湿度直接影响膜的性能。膜内水的迁移受到多个参数的影响：较大的电流密度使水的净迁移量下降；电池温度的提高将增大电池水平衡的电流密度；提高湿化程度可以减小膜的欧姆损失。膜内的湿度不足以保证燃料电池正常工作，就必须采用湿化方法。水的迁移过程涉及到电池的压降和温度变化。实际的湿度状态是各种因素的综合．电池的工作条件最终决定了它自身的水平衡状态。     

质子交换膜燃料电池可靠性分析

可靠性是质子交换膜燃料电池(PEMFC)的重要指标，文中定性分析了PEMFC组成元件、装配工艺和工作过程的可靠性。提出了提高PEMFC可靠性的措施和可靠性的设计原则。     

质子交换膜燃料电池的开发应用

质子交换膜燃料电池（PEMFC）作为一种新一代的发电技术,已成为世界各国特别是发达国家的研发重点被纳入发展规划,应用领域从特殊应用到商品化、产业化不断开拓.但PEMFC的产业化和推广应用受关键材料和工艺技术的制约,为了加速我国PEMFC的发展,今后必须投入足够的财力,组织相关学科的人才,制定可行的规划,加大科研力度.     

质子交换膜燃料电池自增湿研究进展

概述了质子交换膜燃料电池自增湿研究状况，指出自增湿的出发点是有效利用电池阴极过程生成水。综述了薄电解质膜、新型自增湿膜、自增湿流场结构三种方法的研究进展及适用空间。对自增湿技术发展前景进行了探讨。     

质子交换膜燃料电池膜电极组件温度分布的神经网络预测模型

质子交换膜燃料电池膜电极组件表面的温度分布会影响质子交换膜燃料电池的性能、寿命和可靠性.为探究质子交换膜燃料电池传热规律,本文提出了一种基于神经网络的质子交换膜燃料电池膜电极组件温度分布的预测模型.本研究选取径向基函数神经网络(RBF)和广义回归神经网络(GRNN)两种神经网络,以电流密度、温度点的位置作为网络输入,不同位置的温度作为网络输出,对平行流道质子交换膜燃料电池、蛇形流道质子交换膜燃料电池分别建立了神经网络预测模型.结果显示,RBF神经网络预测的均方根误差平均为0.464、平均绝对百分误差为1.179％,GRNN神经网络预测的均方根误差平均为0.7155、平均绝对百分误差为2.27％;相较于GRNN神经网络,RBF神经网络精度更高;基于RBF神经网络的平行流道质子交换膜燃料电池膜电极组件温度分布预测模型预测值与96％的实验值的相对误差在5％以内.基于RBF神经网络的蛇形流道质子交换膜燃料电池膜电极组件温度分布预测模型预测值与95％的实验值的相对误差在5％以内.     

质子交换膜燃料电池的应用研究

质子交换膜燃料电池（PEMFC）与其它燃料电池一样，是利用氧化、还原反应产生电子流的装置。它以氢为燃料、以氧为氧化剂，把化学能直接转化为电能。由于该电池以氢气为燃料，生成的产物是水，对环境造成的污染少。在化石燃料日益短缺及环境污染日益严峻的条件下，燃料电池倍受关注。而近几年发展起来的质子交换膜燃料电池（PEMFC）由于其无污染、发电效率高等特点正受到各国各部门的重视。主要评述了PEMFC的主要用途、工作原理及其实现商业化所面临的几个主要问题。     

质子交换膜燃料电池系统控制与应用现状

描述了质子交换膜燃料电池(PEMFC)系统的控制及其在中低功率领域中的应用现状。首先概述了过程模型和电压预测模型，对影响电堆性能的各参数进行分析。其次，从目前运用的简单控制方法、混合动力驱动、效率优化、故障容许等方面对PEMFC系统的分析与控制结构作了说明。然后介绍了PEMFC的几种具体应用。最后结合国内外的相关研究进展，提出了一些有待进一步研究的方向。     

质子交换膜燃料电池（PEMFC）最新进展

评述了质子交换膜燃料电池的发展背景、最新进展、目前发展障碍和我国发展现状。     

Surrogate model for proton exchange membrane fuel cell (PEMFC)

The main goal of this work is to realize a PEMFC model that can be used efficiently for the global modelling of the fuel cell system. The modelling method proposed in the paper is an approach from an empirical point of view that allows a PEMFC model of “black-box” class to be developed. Moving least squares (MLS) have therefore been employed to approximate the cell voltage characteristics V, using an experimental dataset measured in determinate conditions. The MLS approach appears to present a good balance of response surface accuracy, smoothness, robustness, and ease of use. This kind of numerical model offers good perspectives for the systems identification, the simulation of the systems, the design and the optimization of process control, etc. The results prove that the method is suitable for predicting and describing the fuel cell behaviour in all the points of the approximation domain. The proposed model can be included in a numerical application to optimize the operation of an existing fuel cell system.     

Transport phenomena effect on the performance of proton exchange membrane fuel cell (PEMFC)

The aim of this work is to present a two-dimensional transient model, of heat and mass transfer in a proton exchange membrane fuel cell (PEMFC). The model includes various conservation equations such as mass (hydrogen, oxygen, water concentration), Momentum and energy equations this model is combined with the electrochemical model.     

Characterisation of proton exchange membrane fuel cell (PEMFC) failures via electrochemical impedance spectroscopy

Two PEMFC failure modes (dehydration and flooding) were investigated using in situ electrochemical impedance spectroscopy (EIS) on a four-cell stack under load. The EIS measurements were made at different temperatures (70 and 80 °C), covering the current density range 0.1–1.0 A cm⁻², and the frequency range 0.1–2 × 10⁵ Hz. Dehydration and flooding effects were observed in the frequency ranges 0.5–10⁵ and 0.5–10² Hz, respectively.We propose that impedance measurements at separate frequency ranges (or narrow bands thereof) can be used to distinguish between flooding and dehydration events. Similar approaches may be used to diagnose other important PEMFC failures.     

The development of air-breathing proton exchange membrane fuel cell (PEMFC) with a cylindrical configuration

A small air-breathing proton exchange membrane fuel cell with a cylindrical configuration (Cy-PEMFC) and a helical flow-channel was developed to provide a uniform contact pressure to the membrane electrode assembly (MEA) with a thin cathode current collector. A comparison of the contact pressure and performance of the Cy-PEMFC and general planar PEMFC was performed to determine the effect of the cylindrical configuration. For the contact pressure comparison, numerical analysis was performed using commercial software. Numerical analysis showed that the Cy-PEMFC has its own structural advantage of changing the applied clamping pressure to a uniformly distributed contact pressure. The actual pressure measurements were carried out with pressure-sensitive film to support results of numerical analysis. These results also showed that the Cy-PEMFC had a uniformly distributed contact pressure, whereas the planar PEMFC did not. The polarization curves of both PEMFCs were measured to determine the performance variations caused by the uniform contact pressure and better mass transfer. The maximum power density of the Cy-PEMFC was 220 mW/cm², which was approximately 24% higher than the planar PEMFC.     

Nafion degradation mechanisms in proton exchange membrane fuel cell (PEMFC) system: A review

Nafion is one of the polymer materials used as polymer electrode membrane (PEM) for fuel cells. However, the electrochemical reaction and water management processes that occur at the catalyst layer affect the performance and degradation of the membrane in the fuel cell resulting in various degradation mechanisms. Understanding the degradation mechanisms of the Nafion membrane in operation, the anhydrous and electrochemical conditions in the fuel cell is highly a necessity as outlined in this review. This review further recommends that further improvement in the Nafion membrane can be made by fabrication and coating the Nafion membrane with materials that can withstand the electrochemical environment in the fuel cell.     

Platinum degradation mechanisms in proton exchange membrane fuel cell (PEMFC) system: A review

Proton Exchange Membrane Fuel Cells (PEMFCs) have the perspective to intensely decrease global emission through environmentally-friendly potential. This review paper summarizes the degradation of platinum catalyst layer that has become a significant issue in the improvement of PEMFCs. The review intends to categorise and provide a clear understanding between disintegration and agglomerate that occurs during platinum degradation. In each process, different degradation mechanisms and their migration processes are presented. The improvement in platinum degradation as a function of increasing the performance of PEMFC is established. Prospects for addressing platinum degradation through the exploration of further experimental and numerical research are recommended. Lastly, this paper through recommendation attempts to prevent platinum degradation and reduces high costs associated with the replacement of catalysts in the PEMFCs.     

The voltage characteristics of proton exchange membrane fuel cell (PEMFC) under steady and transient states

In this paper, voltage sensors were developed to explore the voltage distribution characteristics inside the fuel cell under both steady and transient states. The effects of air stoichiometry and current density on the voltage distribution under steady state were discussed, and the dynamic voltage response due to the load change under transient state was also investigated. Results showed that under transient state, the fuel cell would experience a temporary voltage fluctuation due to the air starvation. Thus could probably lead to the degradation of materials, such as the catalyst, membrane, etc. To lessen the degree of air starvation, a method of pre-supplying certain amount of air before loading was adopted. The relationship between the voltage response at the loading transient and the amount of pre-supplied air was also studied, and a minimum value of the pre-supplied air was obtained. The experimental results of this paper could be applied to the optimization of vehicular fuel cell system.     

Modelling,simulation and control of a proton exchange membrane fuel cell (PEMFC) power system

Fuel cell power systems are emerging as promising means of electrical power generation on account of the associated clean electricity generation process, as well as their suitability for use in a wide range of applications. During the design stage, the development of a computer model for simulating the behaviour of a system under development can facilitate the experimentation and testing of that system's performance. Since the electrical power output of a fuel cell stack is seldom at a suitable fixed voltage, conditioning circuits and their associated controllers must be incorporated in the design of the fuel cell power system. This paper presents a MATLAB/Simulink model that simulates the behaviour of a Proton Exchange Membrane Fuel Cell (PEMFC), conditioning circuits and their controllers. The computer modelling of the PEMFC was based on adopted mathematical models that describe the fuel cell's operational voltage, while accounting for the irreversibilities associated with the fuel cell stack. The conditioning circuits that are included in the Simulink model are a DC–DC converter and DC–AC inverter circuits. These circuits are the commonly utilized power electronics circuits for regulating and conditioning the output voltage from a fuel cell stack. The modelling of the circuits is based on relationships that govern the output voltage behaviour with respect to their input voltages, switching duty cycle and efficiency. In addition, this paper describes a Fuzzy Logic Controller (FLC) design that is aimed at regulating the conditioning circuits to provide and maintain suitable electrical power for a wide range of applications. The model presented demonstrates the use of the FLC in conjunction with the PEMFC Simulink model and that it is the basis for more in-depth analytical models.     

Proton exchange membrane fuel cell performance prediction using artificial neural network

Polarization curves remain one of the parameters used to check the performance of fuels in terms of efficiency and durability. This investigation explores the application of artificial neutral network (ANN) to determine the voltage and current from a proton exchange membrane fuel cell having membrane area of 11.46 cm². Performance predictability for the group method of data handling (GMDH) as well as feed forward back propagation (FFBP) neutral networks were employed for the estimation of the current and voltage obtained from the Proton Exchange Membrane Fuel cell under investigation. The investigation presented models with good predictions even though GMDH neural network performed better than the FFBP neural network. The study therefore proposes the GMDH neural network as the best model for predicting the performance of a Proton Exchange Membrane Fuel cell. It was further deduced that an increase in reactant flow rate has direct effect on the performance of the fuel cell but this is directly proportional to the total irreversibilities in the cell hence to operate fuel cell economically, it is imperative that the hydrogen flow is made lower compare to the oxygen flow rate. This in effect will reduce the pumping power required for the flow of the fuel hence reducing the net loss in the cell.