共查询到20条相似文献,搜索用时 140 毫秒
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论述了用于有色冶金热工设备上的高级材料——陶瓷混凝土和氟金云母。介绍了所研制的陶瓷混凝土对冰晶石和电解质溶体抵抗作用的试验方法。给出了俄联盟热力设备制造股份公司不用目前稀缺的硅氟化钾而制取的氟金云母的特性。陶瓷混凝土和氟金云母在有色冶金热工设备上的应用可以延长修理周期,节省能源。 相似文献
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可加工氟云母玻璃陶瓷研究进展 总被引:1,自引:1,他引:0
可加工氟云母玻璃陶瓷是一种新型的结构材料,可用普通的金属刀具进行机械加工,自问世以来一直是陶瓷材料领域的一个研究热点.传统的可加工氟云母玻璃陶瓷中的主晶相是氟金云母和四硅氟云母,近年来又开发出钡云母、钙云母、锂云母和复相氟云母等新型的氟云母玻璃陶瓷,本文综述了近年来国内外在这方面的研究进展. 相似文献
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无铅压电陶瓷铌酸钾钠的常压烧结及其电学性能 总被引:5,自引:2,他引:3
用常压烧结方法制备了Na0.5K0.5NbO3(NKN)无铅压电陶瓷.研究了烧结温度与NKN陶瓷的密度、结构以及电学性能的关系.结果表明:NKN陶瓷与KNbO3相似为正交结构,烧结温度超过1 080 ℃时,出现无压电性第二相.在很小的温度范围内(1020~1100 ℃)烧结体密度有显著不同,当烧结温度为1 080 ℃时,NKN陶瓷烧结密度达到最大值(4.22 g/cm3,相对密度为92%).经1 060℃烧结的NKN陶瓷其压电常数最高,达到122 pC/N;Curie温度为409 ℃;矫顽场为9 kV/cm;剩余极化强度为15 μC/cm2. 相似文献
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以氟金云母为成瓷填料,碳酸锂为助熔剂,制备可瓷化硅橡胶复合材料,研究碳酸锂用量对氟金云母/硅橡胶复合材料瓷化性能的影响。结果表明,当碳酸锂用量为3份时,氟金云母/硅橡胶复合材料的综合性能最好,经1 000℃处理1 h后,其陶瓷体的三点弯曲强度达3.57 MPa。扫描电子显微镜和X射线衍射分析结果表明,1 000℃时碳酸锂产生液相,将氟金云母和白炭黑粘结起来,并与氟金云母发生共晶反应,生成LiAl(SiO3)2晶体,提高了氟金云母/硅橡胶复合材料的瓷化性能。 相似文献
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烧成温度对反应析晶法制备可加工氟闪石玻璃陶瓷的影响 总被引:2,自引:1,他引:1
将氟云母晶体粉末与普通窗玻璃粉末直接混合后烧结制备出可加工氟闪石玻璃陶瓷,与传统的玻璃陶瓷制备工艺不同的是:氟闪石晶体不是从母相玻璃中直接析出,而是通过氟云母和玻璃间的反应析出.用X射线衍射、扫描电镜分析了氟闪石的反应析晶和玻璃陶瓷的组织,研究了烧成温度对玻璃陶瓷密度、可加工性和抗压强度的影响.结果表明:随着烧成温度的提高,氟闪石反应析晶速度加快,玻璃陶瓷加工性得到改善,但密度和强度下降.900℃烧结2h制备的玻璃陶瓷具有良好的可加工性和较高的强度. 相似文献
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以氟金云母、玻璃粉、锆英石为主要原料,研究了锆英石对可加工陶瓷显微结构及性能的影响。结果发现:添加锆英石不会影响氟金云母的物相组成和微观结构;锆英石的加入有助于提高试样的致密性和力学性能,经1130℃烧结制得的添加10 wt%锆英石的氟金云母可加工陶瓷具有最佳的力学性能,其抗弯强度和断裂韧性分别达到105.85 MPa和1.88 MPa·m~(1/2),较原始氟金云母可加工陶瓷的力学性能分别提升了89.02%和3.87%;通过脆性指数判断,添加锆英石之后,氟金云母陶瓷仍然具有良好的可加工性能。 相似文献
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Guangran Zhang Iva Milisavljevic Karina Grzeszkiewicz Piotr Stachowiak Dariusz Hreniak Yiquan Wu 《Journal of the European Ceramic Society》2021,41(6):3621-3628
Highly transparent X2O3 sesquioxide ceramics were obtained from a solid solution of five different oxides (Lu2O3, Y2O3, Yb2O3, Gd2O3, and Dy2O3), mixed in an equal molar ratio according to the principle of high-entropy. The fabricated (Lu, Y, Yb, Gd, Dy)2O3 ceramics achieved 99.97 % of the relative density and exhibited a high degree of optical transparency with the in-line transmittance of almost 80 % in the visible wavelength range. Emissions of Gd3+ (6PJ → 8S7/2 at 312 nm), Dy3+ (4F9/2 → 6H15/2 at 492 nm and 4F9/2 → 6H13/2 at 572 nm), and Yb3+ (2F5/2 → 2F7/2 at 1031 nm) suggested a potential application of the high-entropy ceramics as multi-wavelength emission phosphor transparent ceramics. High-entropy ceramics also exhibited lower specific heat and thermal conductivity compared to single-element sesquioxide ceramics. This work demonstrated that highly transparent oxide ceramics, with complex chemical compositions and good optical properties, could be obtained using the high-entropy principle. 相似文献
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微波介质陶瓷及其展望 总被引:7,自引:0,他引:7
综述了微波介质陶瓷材料的特性和发展现状,介绍了几种重要的微波介质陶瓷体系,讨论了微波介质陶瓷性能的影响因素,指出了改善其性能的途径和微波介质陶瓷的预期进展。 相似文献
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BaPbO3/BaTiO3系复合陶瓷的研究 总被引:6,自引:0,他引:6
报道了导电陶瓷BaPbO3与铁电陶瓷BaTiO3进行复合的结果,研究了该复合功能陶瓷的物相、导电性和低温电阻温度特性。结果表明:采用合理的合成工艺,可得到呈现混和分布的两相复合功能陶瓷材料,该复合材料的电导特征符合三维渗流导电行为。 相似文献
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Yuan Si Ying Li Li Li Hao Li Zhihao Zhao Yejing Dai 《Journal of the American Ceramic Society》2020,103(3):1765-1772
Texturing is an effective approach to improving the piezoelectricity of piezoelectric ceramics. In this work, <001> textured Li+-doped 0.852Bi0.5Na0.5TiO3–0.11Bi0.5K0.5TiO3–0.038BaTiO3 ternary lead-free piezoelectric ceramics are prepared by the reactive templates grain growth (RTGG) method. X-ray diffraction (XRD) results demonstrate a high orientation degree of 77% along the <001> direction. Outstanding electro-strain response, which is higher than most of reported BNT-based textured ceramics, is achieved due to the contribution of oriented-grains along the <001> direction. A large electro-strain of 0.55% with a relatively low hysteresis is obtained at 6.5 kV/mm with corresponding large signal piezoelectric coefficient () of 846 pm/V in the textured ceramics, which is 49% higher than that of the random ceramics. Besides, the electro-strain could reach as high as 0.52%@5.5 kV/mm ( = 945 pm/V) at 100°C. These results indicate that the RTGG is an effective way to design high performance lead-free piezoelectric materials. 相似文献
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《Ceramics International》2023,49(19):31210-31217
Herein, a pohotosentive polysiloxane (PSO)/talc/Al2O3 slurry was prepared for the digital light processing printing. Liquid photosensitive PSO was exploited as a triple-functioned material, acting both as the resin matrix, a high reactive Si source and a pore generator. Through adjusting the raw material components, polysiloxane can be sintered with talc and Al2O3 fillers after being pyrolyzed to 1200 oC while pores with variable diameters can be generated. Ternary component slurry prepared based on the above strategy possesses the characteristics of low viscosity, high reaction activity and good homogeneity. Sintering schedule of the printed thin-walled precursor was investigated to guarantee the morphology of cordierite product was consistent with the printed model. This work aims to provide a new strategy for DLP printing of MgO-Al2O3-SiO2 ternary and other polymer derived ceramics. 相似文献