钴基合金-碳化钨复合涂层材料耐磨性能的研究

采用真空熔烧法制得钴基合金—碳化钨复合涂层材料,借助扫描电子显微镜、X射线衍射仪等先进的测试手段对涂层的组织结构和表面形貌进行观察分析。应用盘销式摩擦磨损试验机对不同碳化钨质量分数的复合涂层材料和淬火态45钢进行了磨损试验。结果表明:在相同试验条件下,复合涂层的耐磨性显著高于淬火钢,且其耐磨性随碳化钨质量分数的增加而提高:淬火钢的耐磨性随着载荷的增加迅速降低,而复合涂层的耐磨性则变化不大。     

等离子喷涂Al_2O_3/ZrO_2涂层耐磨性能研究

采用溶胶-凝胶方法将微米级颗粒团聚成含纳米粒子的颗粒,利用等离子喷涂技术制备出了含有纳米结构的A1_2O_3/ZrO_2涂层,并在MM—200摩擦磨损试验机上进行了干摩擦试验,对纳米结构涂层和常规涂层的耐磨损性能进行了对比。通过对磨损后的磨痕形貌分析可知,纳米涂层的耐磨损性能明显好于传统陶瓷涂层。传统涂层的磨损机理主要是微裂纹和颗粒的剥落,而相同条件下纳米涂层则由于涂层韧性的提高,几乎不存在微裂纹,因而涂层具有较高的耐磨性。     

深海石油钻采工具表面硬化材料研制探讨

选择感应等离子体工艺对球形碳化钨粉进行了研制,混合镍合金粉后研制成球形镍基碳化钨粉。采用等离子体转移弧堆对耐磨耐蚀涂层进行制备,这一涂层的性能主要为耐酸、防锈、耐热以及抗磨损等。因为涂层内具有较高碳化钨含量,有助于机械零件耐蚀性与耐磨性的提升,在深海石油钻采中的应用前景广阔。     

超音速火焰喷涂碳化钨钴合金涂层对橡胶密封件的磨损研究

通过磨合试验,比较了超音速火焰(HVOF)喷涂碳化钨钴合金涂层与传统的含氰镀铬镀层与橡胶密封件对磨时的磨损情况.结果表明:HVOF喷涂碳化钨钴合金涂层具有良好的耐磨性和致密性,始终保持较良好的表面状况,对非金属密封件具有良好的适应性.     

纳米Al2O3弥散强化复合涂层的制备及耐磨性研究

将纳米Al2O3与Ni基自熔性合金F102的复合粉末用氧乙炔焰热喷焊工艺制各复合涂层，研究了纳米Al2O3的加入呈对组织和耐磨性的影响。结果表明，当纳米A12O3质量分数为0．25％时，涂层的耐磨性最好，与25％WC复合涂层的耐磨性相当。     

基于原子沉积法的纳米Al2O3涂层微织构刀具刀-屑界面间摩擦系数研究

采用原子沉积法(Atomic Layer Deposition,ALD)分别在点状微织构和条状微织构YT5硬质合金刀具(微织构刀具)上制备了纳米Al_2O_3涂层,通过直角切削实验研究了纳米Al_2O_3涂层对微织构刀具刀-屑界面间摩擦系数的影响,并将纳米Al_2O_3涂层微织构刀具与微织构刀具、YT5硬质合金刀具进行对比。结果表明,微织构能降低刀具刀-屑界面间的摩擦系数;纳米Al_2O_3涂层能进一步降低微织构刀具刀-屑界面间的摩擦系数,其中厚度为100 nm的Al_2O_3涂层微织构刀具刀-屑界面间的摩擦系数最小,当点状微织构间距为0.15 mm时摩擦系数值最优,当条状微织构方向垂直于主切削刃时摩擦系数值最优;刀具刀-屑界面间的摩擦系数随着切削速度的增加而增大。纳米Al_2O_3涂层与微织构相结合将刀-屑界面间的摩擦由滑动摩擦转变为滑动-滚动复合摩擦的形式,降低了微织构刀具刀-屑界面间的摩擦系数,改善了摩擦性能,有利于提高刀具耐用度。     

火焰喷涂法制备纳米改性陶瓷涂层

研究了纳米改性陶瓷粉的配制。对所制备的纳米改性陶瓷涂层的结合强度、孔隙率、耐磨性、耐蚀性、微观形貌进行了试验研究。结果表明;火粉喷涂法制备的纳米改性陶瓷涂层与等离子喷涂陶瓷涂层性能相近。     

纳米α-Al2O3颗粒弥散强化镍基复合涂层的耐磨性能研究

将纳米α-Al2O3颗粒或Ni包裹的纳米α-Al2O3复合粉和镍基粉用湿法混合，采用火焰热喷涂工艺制备了复合涂层，用磨粒磨损试验机进行磨损试验，研究了纳米α-Al2O3的体积分数、粒径和是否预先进行包裹处理对涂层喷焊性和耐磨粒磨损性能的影响。结果表明，纳米α-Al2O3以包裹形式加入能有效改善弥散相与Ni基涂层的相容性，相应涂层的耐磨性优于未包裹处理；当纳米Al2O3的体积分数为2％时，涂层的耐磨性能最好，为Ni基涂层的2倍多；在相同的体积分数下，随着涂层中弥散强化相尺寸的减小，涂层的耐磨性提高。     

微/纳米CVD金刚石涂层的制备

使用热丝化学气相沉积(HFCVD)装置,在以WC - CO硬质合金为衬底,采用调节涂层生长参数,制备出性能优良的微/纳米金刚石涂层.用SEM,AFM,Raman表征微观结构和表面品质.采用压痕法评估涂层的结合性能,并与微米金刚石涂层、纳米金刚石涂层进行比较.结果显示,当生长气压由3.3 kPa降为1.0 kPa时,底层的微米级晶粒逐渐被上层纳米级晶粒覆盖,并且涂层表面显露出纳米金刚石涂层特性.在结合性能实验中也指出,微/纳米金刚石涂层的结合性能比纳米金刚石涂层要优异.     

基于热喷涂材料电化学极化特性的电解磨削液研究

碳化钨硬质合金涂层材料由于其高硬度、高耐磨性等特性在航空航天和国防等领域具有重要的应用,电解磨削加工是实现其高效低损伤加工的重要方法,而电解磨削液是影响电解磨削加工表面完整性和效率的重要因素。针对碳化钨硬质合金涂层材料的电解磨削加工,研究了阳极极化曲线对于电解磨削液选择的影响规律,通过分析动电位、恒电位阳极极化曲线,选择适合于加工该材料的电解磨削液配方,并使用所选电解磨削液通过实际加工验证效果。     

WC颗粒增强镍基合金喷熔层腐蚀磨损行为及其人工神经网络预测分析

采用氧一乙炔焰喷熔工艺制备了碳化钨（WC）颗粒增强镍基合金喷熔层,研究了它的腐蚀磨损行为。结果表明：喷熔层耐腐蚀磨损性能随WC含量增加而提高,WC含量在20％～30％范围内,喷熔层耐腐蚀磨损性能最佳,超过30％时,其耐腐蚀磨损性能下降。载荷增加,腐蚀磨损率增大;速度增加,腐蚀磨损率下降。低速重载荷时,WC颗粒增强效果明显,且含30％WC喷熔层耐腐蚀磨损性能最好;高速轻载荷时,因WC原电池效应显著,WC颗粒增强效果减弱。基于人工神经网络的喷熔层腐蚀磨损行为预测与实验结果吻合较好,对喷熔层的应用具有重要指导作用。     

碳纳米管镍基复合刷镀层的组织和性能

研究了碳纳米管镍基复合刷镀层的组织、显微硬度和耐磨性等。结果表明：与常规镀层相比，含有碳纳米管的复合镀层组织明显细化，显微硬度有较大的提高，硬度热稳定性和耐磨性得到了明显的提高。     

等离子喷涂WC/Co Fe基涂层摩擦与磨损性能

以普通铸铁为基体,碳化钨陶瓷粉末WC 12Co为热喷涂材料,采用大气等离子法制备WC/Co Fe复合涂层.通过SEM、EDS、XRD等手段对WC/Co Fe涂层微观组织与结构进行表征,并对WC/Co Fe复合涂层耐磨损性能进行测试.结果表明,等离子喷涂制备的WC/Co Fe涂层物相以WC相为主;WC涂层摩擦因数波动小于铸铁材料摩擦因数,表明WC复合涂层具有良好的抗摩擦性能.WC涂层耐磨损性能高于铸铁,主要归因于WC颗粒韧性好、硬度高、抗冲击及抗磨损性能强,与基体金属的结合性好.     

超音速火焰喷涂微米和纳米结构WC-12Co涂层及其性能

以纳米和微米级WC-12Co粉末为原料,采用超音速火焰喷涂(HVOF)方法在16Mn基体上制备了两种涂层.利用X射线衍射仪对喷涂粉末及涂层进行了相结构分析,用扫描电镜对喷涂粉末、磨粒磨损前后的涂层表面形貌进行了观察,探讨了粉末结构、涂层的组织和结构以及抗磨粒磨损的性能.结果表明:WC-12Co粉末结构对涂层的组织结构影响非常显著,微米WC-12Co粉末中的WC的分解基本上得到了抑止,而纳米结构的粉末由于出现了WC的部分分解,导致了纳米涂层的抗磨粒磨损性能相对于微米涂层提高不多,但是与基体16Mn相比,两种涂层均表现出优异的抗磨粒磨损性能.     

激光重熔纳米SiC复合陶瓷涂层组织和性能研究

研究了WC／Co-NiCrAl等离子复合陶瓷涂层、激光重熔等离子涂层、激光渗入纳米SiC涂层的组织结构、耐磨性能。结果证明：在所定的工艺参数下，等离子喷涂层组织呈层片状，层间为机械结合界面；经激光重熔后，激光作用区涂层组织细化，孔隙率降低，耐磨性能是原等离子涂层的1．3倍；渗入纳米SiC后，组织进一步细化，孔隙率进一步降低，SiC颗粒仍处于纳米尺度，分布在粗颗粒表面及粗颗粒之间，其耐磨性能是原等离子涂层的2．6倍。     

不同激光熔覆材料涂层的耐磨性能比较

本文研究了宽带激光熔覆不同熔覆材料的复合涂层的耐磨性能。结果表明:Ni60B熔覆层的硬度高于40Cr基材的硬度,Ni60B+WC梯度复合涂层具有最高的硬度,对于提高零件的抗磨损性能比较有利;Ni60B熔覆层和Ni60B+WC熔覆层均适合修复轴类零件;三层梯度复合涂层磨痕宽度最小,具有最好的耐磨性。     

Sliding wear behavior of Fe-Al and Fe-Al/WC coatings prepared by high velocity arc spraying

A comparative study was carried out to investigate the microstructure and tribological behavior of Fe-Al and Fe-Al/WC iron aluminide based coatings against Si₃N₄ under dry sliding at room temperature using a pin-on-disc tribotester. The coatings were prepared by high velocity arc spraying (HVAS) and cored wires. The effect of normal load on friction coefficient and wear rate of the coatings was studied. The microstructure and the worn surfaces of the coatings were analysed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersion spectroscope (EDS). The results showed that, the main phases in both coatings were iron aluminide (Fe₃Al and FeAl) and α. WC/W₂C particles were embedded in the matrix of the composite coating. With adding WC hard particles, the Fe-Al/WC composite coating exhibited higher wear-resistance than Fe-Al coating. But the friction coefficient of both coatings showed little difference. As the load increased, the friction coefficient decreases slightly due to a rise of friction contact temperature and larger areas of oxide film formation on the worn surface, which act as a solid lubricant. Increasing load causes the maximum shear stress occurring at the deeper position below the surface, thereby aggravating the wear. The coating surface is subjected to alternately tensile stress and compression stress during sliding, and the predominant wear mechanism of the coatings appears to be delamination.     

基体表面粗糙度对纳米复合镀层组织及性能的影响

采用电刷镀技术在不同表面粗糙度的W18Cr4V高速钢基体上制备了纳米PTFE和纳米WC颗粒增强的镍基复合镀层,采用扫描电镜对纳米复合镀层的表面和截面形貌进行了观察,研究了基体表面粗糙度对纳米复合镀层耐磨性、耐蚀性和结合强度的影响.结果表明:随着基体表面粗糙度的减小,纳米复合镀层的表面更加平整致密,组织更加细小均匀,镀层厚度减小,镀层中的裂纹数量减少,镀层的耐磨性、耐蚀性和结合强度均得到明显提高.     

Wear study of Ni–WC composite coating modified with CeO2

In the present investigation, Ni–WC composite powder was modified with the addition of CeO₂ in order to form a new composition of Ni–WC–CeO₂. The Ni–WC and Ni–WC–CeO₂ compositions were used for coating deposition by high-velocity oxy-fuel (HVOF) spraying process so as to study the effect of CeO₂ addition on microstructure, distribution of various elements, hardness, formation of new phases, and abrasive wear behavior. Further, the effect of load, abrasive size, sliding distance, and temperature on abrasive wear behavior of these HVOF-sprayed coatings was investigated by response surface methodology. To investigate the abrasive wear behavior of HVOF-sprayed coatings four factors such as load, abrasive size (size in micrometers), sliding distance (meters), and temperature (°C) with three levels of each factor were investigated. Analysis of variance was carried out to determine the significant factors and interactions. Investigation showed that the load, abrasive size, and sliding distance were the main significant factors while load and abrasive size, load and sliding distance, abrasive size and sliding distance were the main significant interactions. Thus an abrasive wear model was developed in terms of main factors and their significant interactions. The validity of the model was evaluated by conducting experiments under different wear conditions. A comparison of modeled and experimental results showed 4–9% error. The abrasive wear resistance of coatings increases with the addition of CeO₂. This is due to increase in hardness with the addition of CeO₂ in Ni–WC coatings.     

Study of tribological properties of detonation nanostructured WC-Co-based coatings

The study deals with tribological properties of the nanostructured WC-12%Co coatings deposited by the detonation method. It is found experimentally that their wear resistance depends on the concentration of monocarbide WC. The dependence of the WC concentration in the coating on deposition conditions is obtained. The microstructure of the coatings, their physical-mechanical properties, phase composition, porosity, hardness, and modulus of elasticity are studied. The advantage of the nanostructured coatings over the coatings deposited from micropowders is shown.