Amplifier based on a field-effect triode with negative current feedback

Conclusions A field-effect triode amplifier with series negative current feedback allows a voltage gain of the order of 200–300 to be obtained for a load resistance R_s1 M. The coefficient K_u begins to decrease noticeably only for a feedback resistance above 500 .The current gain reaches (8–10)·10³. Increasing the resistances R_s and R_L to hundreds of ohms has practically no effect on K_i. For a further increase of R_s and R_L the coefficient K_i decreases.The power gain reaches its maximum value (of the order of 10⁴ or more) for R_s100 and R_L=10–100 k. An increase in R_s leads to a reduction of K_pmax and to a shift of the extremum of the function K_p=f(R_L) into the range of higher values of R_L.A large input resistance of the amplifier (tens of megohms and higher) is obtained when R_s increases to 10–100 M. The maximum input resistance is obtained for R_L and R_s and may exceed values of from hundreds of megohms to several gigaohms. The minimum input resistance is hundreds of kilohms for R_L and R_s0.The minimum input resistance (5–10 k or less) is ensured for R_g and R_L0. An increase of the output resistance to hundreds of megohms or higher occurs for R_g and R_s.Translated from Izmeritel'naya Tekhnika, No. 9, pp. 67–70, September, 1971.     

Long term stability of H atoms in HD-D2-He solids

No Heading We employed en electron spin resonance (ESR) technique for investigating the long term behavior of hydrogen and deuterium atoms in the HD-D₂ impurity helium solids that were created by sending a gas mixture [H₂]:[D₂]:[He]= 1:4:100 through a radio-frequency electrical discharge into a volume of superfluid ⁴He at T = 1.5 K. H and D atoms were stabilized inside nanoclusters of impurity molecules. The exchange tunneling reactions D + H₂ HD + H and D + HDD₂ + H proceeded to eliminate D atoms and increase the concentration of H atoms in the HD-D₂ impurity-helium solids. Local concentrations of H atoms inside the molecular nanoclusters of order 10²⁰ cm^–3 were achieved. The high concentration of H atoms was stable during 40 hours storage of the sample at T = 1.35 K. These solids are possible candidates for collective quantum phenomena of atomic hydrogen if the Bose-Einstein degeneracy regime can be attained.PACS numbers: 61.46. +w, 67.40.Yv, 76.30.–v.     

Effect of thermal cycling on as-quenched and aged nickel-rich Ni-Ti alloy

The effect of Ni₄Ti₃ precipitates on the structure and transformation sequences in Ni-49%Ti alloy has been investigated using internal friction, electrical resistivity and electron microscopy studies. It has been confirmed that in the alloy without precipitates the transformation occurs following the sequence B2 R M on cooling and M B2 on heating with easily distinguished peaks on the internal friction curves and typical behaviour of the electrical resistivity, while the presence of the precipitates brings about complicated internal friction curves indicating either the appearance of two types of martensite or the transformation sequence: B2 ® B2 + R B2 + M M.     

Phase decomposition of liquid-quenched β-type Ti-Cr alloys

Phase decomposition behaviour of liquid-quenched (bcc) type Ti-Cr alloys was investigated by means of transmission electron microscopy and hardness measurements. It was found that decomposition of to ₁ (Ti-rich, bcc) + ₂ (Ti-lean, bcc) takes place in the intermediate composition range of the Ti-Cr system. This experimental result proves the theoretical prediction made by Menon and Aaronson, but the observed ₁ + ₂ two-phase field expands towards higher temperatures than the predicted binodal line. The coherent ₁ + ₂ two-phase state exhibits the so-called 100 modulated structure and it was concluded that the formation of such a structure is a result of spinodal decomposition of the -phase. We obtained time-temperature-transformation (TTT) diagrams of -type Ti-30, 40 and 50 at % Cr alloys. A typical sequence of structural change is coherent ₁ + ₂ incoherent ₁ + ₂ incoherent ₁ + ₂ + grain boundary precipitates stable state of + TiCr₂ or + TiCr₂. Not all the states in the above sequence appear, depending on alloy composition, liquid-quenching rate and ageing temperature.     

Kinetics of Reactions of Np and Pu Ions with Hydrazine Derivatives: XVII. Reaction of Pu(VI) with Hydroxyethylhydrazine

Reduction of Pu(VI) to Pu(III) with hydroxyethylhydrazine (HOC₂H₄N₂H₃) in HNO₃ solutions involves the following consecutive steps²: Pu(VI) + HOC₂H₄N₂H₄ Pu(V) + ...; Pu(V) + HOC₂H₄N₂H₄ ⁺ Pu(IV) + ...; Pu(V) + Pu(III) 2Pu(IV); and Pu(IV) + HOC_2H4N₂H₄ ⁺ Pu(III) + .... The overall kinetic equations of these steps were suggested, and their rate constants and activation energies were determined. The mechanisms of the four reaction steps, consistent with the experimental kinetic data, are discussed.     

The preparation of alumina fibre by sol-gel processing

Attempts have been made to prepare alumina fibre from the colloidal sol and polymerized alkoxides. The aluminium chloride or aluminium nitrate systems were found to be potential methods for producing continuous alumina fibre: the aluminium nitrate system had a better sintering behaviour than the aluminium chloride system. The aluminium isopropoxide system, however, was unsuitable for preparing alumina fibre but was suitable for the preparation of monoliths, membranes, powders, and multicomponent ceramics. The thermal changes of these precursors were studied by transmission electron microscopy, Fourier-transform infrared spectroscopy and X-ray diffraction. The results demonstrated the different routes of phase transformation as the temperature increases. The aluminium chloride system exhibits two routes for phase transformation: (a) boehmite -Al₂O₃, and (b) gibbsite -Al₂O₃.     

The athermal α → ω transformation in Zr-2 at% Nb alloy

The athermal transformation in Zr-2 at.% Nb alloy has been investigated by transmission electron microscopy. Analysis of the selected-area diffraction pattern has shown that the orientation relationships between the omega and the parent-phase in quenched Zr-2 at.% Nb alloy are the same as have been previously observed for the reaction in pure zirconium. Thus it was deduced that the direct transition has taken place in the alloy during cooling. The-originated -particles were visualized using the dark-field technique. The formation of the athermal omega in the-region of-stabilized Zr-Nb alloy is discussed in terms of the relative positions of the free energy equilibrium curvesT ₀ ,T ₀ ,T ₀ and the correspondingM _s ,M _s andT _s start curves. It is concluded that the omega phase can occur over a much wider range of alloy compositions than is usually recognized on the basis of transformation data.     

Standard Gibbs' energies of formation of BaCuO2, Y2Cu2O5 and Y2BaCuO5

The Gibbs' energies of formation of BaCuO₂, Y₂Cu₂O₅ and Y₂BaCuO₅ from component oxides have been measured using solid state galvanic cells incorporating CaF₂ as the solid electrolyte under pure oxygen at a pressure of 1.01×10⁵ Pa BaO + CuO BaCuO₂ G _f,ox ^o (± 0.3) (kJ mol^–1)=–63.4–0.0525T(K) Y₂O₃ + 2CuO Y₂Cu₂O₂ G _f,ox ^o (± 0.3) (kJ mol^–1)=18.47–0.0219T(K) Y₂O₃ + BaO + CuO Y₂BaCuO₅ G _f,ox ^o (± 0.7) (kJ mol^–1)=–72.5–0.0793T(K) Because the superconducting compound YBa₂Cu₃O_7– coexists with any two of the phases CuO, BaCuO₂ and Y₂BaCuO₅, the data on BaCuO₂ and Y₂BaCuO₅ obtained in this study provide the basis for the evaluation of the Gibbs' energy of formation of the 1-2-3 compound at high temperatures.     

Synthesis and Luminescent Properties of ZnGa2S4:Eu,F and ZnGa2O4:Eu,F

ZnGa₂S₄:Eu,F and ZnGa₂O₄:Eu,F were synthesized and characterized by x-ray diffraction and photoluminescence (PL) measurements. ZnGa₂S₄:Eu,F has a tetragonal structure (sp. gr. ) with a= 5.272 Å and c= 10.451 Å, and ZnGa₂O₄:Eu,F has a cubic structure (sp. gr. Fd3m) with a= 8.32 Å. The PL spectrum of ZnGa₂S₄:Eu,F consists of a broad band (FWHM = 1.11 eV) at 565 nm due to the Eu²⁺ 5D ¹ 7F ² transition, and the spectrum of ZnGa₂O₄:Eu,F shows four emissions due to the Eu^{3+ 5} D ₀ ⁷ F ₄ (_max = 682 nm), ⁵ D ₀ ⁷ F ₂ (_max = 615 nm), ⁵ D ₀ ⁷ F ₁ (_max = 595 nm), and ⁵ D ₀ ⁷ F ₀ (_max = 584 nm) transitions.     

Microstructural development and mechanical properties of pressureless-sintered SiC with plate-like grains using Al2O3-Y2O3 additives

Dense SiC ceramics with plate-like grains were obtained by pressureless sintering using -SiC powder with the addition of 6 wt% Al₂O₃ and 4 wt% Y₂O₃. The relationships between sintering conditions, microstructural development, and mechanical properties for the obtained ceramics were established. During sintering of the -SiC powder compact the equiaxed grain structure gradually changed into the plate-like grain structure that is closely entangled and linked together through the grain growth associated with the phase transformation. With increasing holding time, the fraction of phase transformation, the grain size, and the aspect ratio of grains, increased. Fracture toughness increased from 4.5 MPa m^1/2 to 8.3 MPa m^1/2 with increasing size and aspect ratio of the grains. Crack deflection and crack bridging were considered to be the main operative mechanisms that led to improved fracture toughness.     

Phase equilibria and thermodynamic properties in the system Ni-Mo-O

Coexisting phases in the Ni-Mo-O ternary system at 1373 K have been identified by X-ray diffraction, optical microscopy and scanning electron microscopy. The samples were equilibrated in evacuated quartz capsules. Only one ternary phase, NiMoO₄, was found to exist in the system. The reversible e.m.f. values of the following solid-state galvanic cells were measured in the temperature range 900 to 1500 K: (I) Pt, Ni + NiO/(CaO) ZrO₂/NiO + MoO₂ + NiMoO₄, Pt; (II) Pt, Mo + MoO₂/(CaO) ZrO₂/O₂, Pt; and (III) Pt, Mo + MoO₂/(CaO) ZrO₂/Ni-Mo + MoO₂, Pt. The Gibbs energies of formation of NiMoO₄ and MoO₂ and activities in Ni-Mo alloys were derived from the e.m.f. data. For the reaction NiO + MoO₂ + 2(02) NiMoO₄ we obtain G _r ⁰ = -201 195 + 69.70T (±400) J mol^–1; for Mo + (02) MoO₂ we obtain G _f ⁰ = –578880 + 168.5T (+500) J mol^–1. Based on the information from phase identification studies and thermodynamic stabilities, the isothermal section and oxygen potential diagram for the Ni-Mo-O system at 1373 K have been developed.     

Reaction mechanism for the formation of intermetallic compounds from layered Sm/Fe powder obtained by mechanical milling

Solid-state reactions in layered Sm/Fe powder particles with an overall composition of Sm₁₂Fe₈₈, obtained by ball milling, have been investigated by X-ray diffraction. During annealing at 500C, one reaction, Sm+2FeSmFe₂ was observed in the time-range studied. However, during annealing at 800C, five reactions were observed: Sm+2FeSmFe₂, Sm +3FeSmFe₃, 2Sm+17FeSm₂Fe₁₇, 2SmFe₂+13FeSm₂Fe₁₇, and 2SmFe₃ +11FeSm₂Fe₁₇. It is proposed that such reactions occur by a nucleation and growth process. Reactions of samarium with iron can be governed by nucleation; Sm/Fe interfaces possessing a higher free energy per unit area can play an important role in the nucleation. The observed results are discussed.     

Microstructure and properties of supersaturated ZA27 alloy during natural ageing

The decomposition of the supersaturated solid solution of ZA27 alloy at room temperature has been investigated by X-ray diffraction, TEM and mechanical properties testing. Based on the results obtained, both continuous precipitation and cellular reaction occur during the decomposition process. The continuous precipitation follows the sequence: ₁ + spherical GP zones ₂ + elliptical GP zones ₃ + R + . The cellular reaction can be written: + + . The properties of the alloy depend on the microstructure. After 1 month of ageing, a series of changes of microstructure have taken place. The properties of the alloy are: _b=500 MPa, =13%,H _v=148.     

Phase transformation behavior in a multipurpose dental casting gold alloy during continuous heating

Phase transformation in a multipurpose dental casting gold alloy during continuous heating was studied by electrical resistivity measurements, hardness tests, X-ray diffraction and scanning and transmission electron microscopy. The behavior can be explained by the following reaction sequences in the nodule: ₁(FCC) + ₂ (L1₂) ₁(fcc) + ₂(L1₂) + (L1₀), where fcc is face centred cubic. A discontinuous precipitation with very fine nodules contributed to the hardening and the growth produced the softening. This multipurpose gold alloy is characterized by the introduction of a PtZn ordered phase with L1₀ structure instead of a CuAu I phase.     

Thermal Conductivity of Sm3S4 System with Mixed Valence Sm Ions

The thermal conductivity () and electrical resistivity () of mixed-valence compound Sm₃S₄ have been measured in the temperature range 5 to 300 K. The present results and those presented previously [1] for the thermal conductivity between 80 to 850 K are interpreted in terms of the temperature-dependent fluctuating valence of Sm ions. Sm₃S₄ crystallizes in the cubic Th₃P₄ structure, and the cations with different valences occupy equivalent lattice sites. Divalent and trivalent Sm ions are randomly distributed in the ratio of 1:2 over all possible crystallographic cation positions (Sm²⁺ ₂Sm³⁺ ₂S^2– ₄). The behavior of the Sm₃S₄ lattice thermal conductivity _ph is extraordinary since valences of Sm ions are fluctuating (Sm³⁺Sm²⁺) with a temperature dependent frequency. In the interval 20 to 50 K (low hopping frequencies), _ph of Sm₃S₄ varies as _ph T ^–1 (it is similar to materials with static distribution of cations with different valences): at 95 to 300 K (average hopping frequencies 10⁷ to 10¹¹ Hz), _ph changes as _ph T ^–0.3 (it is similar to materials with defects). Defects in Sm₃S₄ appear because of local strains in the lattice by the electrons hopping from Sm²⁺ ions (with big ionic radii) to Sm³⁺ ions (with small ionic radii) and back (Sm²⁺Sm³⁺), at T>300 K (high hopping frequencies), _ph becomes similar to materials with homogenous mixed valence states [1].     

Reactive processing of nickel-aluminide intermetallic compounds

NiAl have been fabricated by reactive sintering compacts of ball-milled powder mixtures containing Ni and Al. The reaction mechanism, as well as phase and microstructural development, were investigated by analyzing compacts quenched from different temperatures during reactive hot compaction. It was found that the reaction process was strongly affected by pressure, heating rates, heat loss from the sample to the environment. The application of 50 MPa prior to the reaction resulted in the intermetallic-formation reaction initiating at a temperature (480°C) much lower than that (550°C) when no pressure was applied. At high heating rate (50°C/min), when the heat loss is small, the formation of NiAl occurs rapidly via combustion reaction. On the other hand, if the heat loss is significant as in slow heating rate (10°C/min), the reaction process is controlled by solid-state diffusion. The phase formation sequence for the slow solid-state reaction was determined to be: NiAl₃ Ni₂Al₃ NiAl NiAl (Al-rich) + Ni₃Al NiAl.     

Electron spin resonance spectra of Gd3+ ions in K2SO4-ZnSO4 glasses

Electron spin resonance (ESR) spectra of Gd³⁺ ions doped in K₂SO₄-ZnSO₄ glasses have been studied on an X-band ESR spectrometer at different temperatures (–120 to 150 C). The ESR spectrum at room temperature exhibits three prominent features with effectiveg-values of 5.6, 2.83 and 2.02. The spectra are similar to the U spectra familiar in many oxide and fluoride glasses, indicating very low and disordered site symmetries with a broad distribution of crystal fields. Remarkable changes have been observed in the spectrum with changes in the temperature, concentration and glass composition. The broadening of theg 2.02 line with increasing Gd³⁺ ion content indicates that the dipole-dipole interaction between the resonant centres increases with increase in Gd³⁺ ion content. A weak band at 36350cm^–1 is observed in the optical absorption spectrum of 0.5mol% Gd³⁺ in K₂SO₄-ZnSO₄ glass which has been assigned to the transition⁸S_7/2⁶P_7/2.     

Sorption of Radioactive Iodine and Fluoride Ion on Hydroxyapatite from the Aqueous Phase

Sorption of the ¹³¹I^-, ¹³¹IO₃ ^-, and F^- ions on various samples of hydroxyapatite (HAP) from aqueous solutions was studied. The HAP samples were prepared by the following reactions: Ca(OH)₂ + H₃PO₄ HAP, CACl₂ + Na₃PO₄ + NaOH HAP, and Ca(NO₃)₂ + HAP seed + (NH₄)₂HPO₄ + NH₃ HAP. None of the HAP samples sorb ionic species of radioactive iodine from aqueous solutions. As for F^-, the best sorption properties are exhibited by the HAP sample prepared by the second reaction. The degree of recovery of fluoride ion with the HAP precipitate in 5 min, 4 h, and 5 days of the contact of the solid and liquid phases is 54, 66, and >95% of the initial F^- amount, respectively. The distribution factor K _d of the fluoride ion between the HAP solid phase and solution decreases with increasing V/m ratio and pH of the initial solution.     

Solid Rare Gas Isolated Ionic Exciplexes for Deep UV and VUV Lasers

Emissions of ionic alkalihalide exciplexes (AX) ⁺ due to the B ²X ² transitions of Cs ²⁺ F ^–, Cs ²⁺ Cl ^– and Rb ²⁺ F ^– are reported for CsF (196.5 nm), CsCl (220.1 nm) and RbF (136 nm) isolated in Ne and Ar matrices under e–beam excitation. The C ² A ² transition could be only observed in the condensed phase (solid Ne) at 227 nm (CsF) and at 249.2 nm (CsCl). A higher emission efficiency of the ionic excimers in the condensed phase compared to gas phase is obtained. Apparently, a strong quenching of the BX bands is observed at AX concentrations larger than 0.6%. These band lineshapes are explained and attributed to the transition from      

Absorption and Circular Dichroism Spectra of Bi12SiO20<Nd> Crystals

The absorption and circular dichroism spectra of Nd-doped Bi₁₂SiO₂₀ crystals were measured in the range 10000 to 20000 cm^–1. The spectra showed electronic transitions related to only one type of Nd-related center: Nd substituting for Bi in position with symmetry C ₁. The bands due to the transitions from the first Stark component of the ground state to Stark components of excites states (⁴ I _9/2 ⁴ G _5/2, ⁴ I _9/2 ² G _7/2, and ⁴ I _9/2 ⁴ G _7/2) were analyzed in detail. The dipole strength D _0k , rotatory power R _0k , and anisotropy factor G _0k of these transitions were calculated. The intensities of transitions to Stark components were shown to vary by more than one order of magnitude within an excited-state multiplet. The anisotropy factors of the ⁴ I _9/2 ² G _7/2 and ⁴ I _9/2 ⁴ G _7/2 transitions, allowed in the magnetic dipole approximation, are, on the average, larger than that of the ⁴ I _9/2 ⁴ G _5/2 transition, which points to a significant contribution of the magnetic moment (<>²) to the total intensity of the transition.