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采用不同种类的聚醚多元醇、二异氰酸酯和扩链剂为原料合成聚氨酯,讨论了聚醚多元醇的相对分子质量、二异氰酸酯的结构、软硬段比例、二异氰酸酯指数、扩链剂种类及用量对聚氨酯性能的影响。结果表明:采用高相对分子质量的聚醚,聚氨酯的定伸强度、拉伸强度和撕裂强度下降,断裂伸长率提高;聚氨酯的性能随硬段含量的增加而提高;异氰酸酯指数控制在1.01~1.03左右;扩链剂链长越短,聚氨酯的微相分离程度和力学性能越好;聚氨酯性能随1、4-丁二醇用量的增加而提高,达到一定用量时反而下降。 相似文献
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在叠氮聚醚型聚氨酯弹性体材料研究过程中,以叠氮聚醚为基体材料、TDI为固化剂,在配方中添加癸二酸二异辛酯作为增塑剂、1,4-丁二醇作为扩链剂、辛酸亚锡作为催化剂、白碳黑作为填料,对其配比做了适量的调整。对确定的材料配方进行了加速老化、扩大以及重现性试验。结果表明所研究的叠氮聚醚型聚氨酯弹性体材料性能优良、稳定,能够满足使用要求。 相似文献
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木素—聚醚型聚氨酯的合成与性能 总被引:12,自引:0,他引:12
利用低污染的氧碱制方法制取的麦草氧碱木素合成了木素-聚醚型聚氨酯,对其热性能、力学性能进行了研究。结果表明,麦草氧碱木素可取代部分聚乙二醇与二苯甲基二异氰酸合成木素-聚醚型聚氨酯;异氰酸指数和木素含量对合成的木素-聚醚型聚氨酯性能有影响。 相似文献
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受阻酚AO-80/聚醚型热塑性聚氨酯弹性体复合材料的结构与性能 总被引:3,自引:0,他引:3
用熔融共混法制备了受阻酚AO-80/聚醚型热塑性聚氨酯弹性体(PET-TPU)阻尼材料,通过扫描电子显微镜、X射线衍射分析、差示扫描量热分析及动态力学热分析等研究了复合材料的微现结构、玻璃化转变温度、动态力学性能和力学性能.结果表明,AO-80与基质之间具有良好的相客性,且以分子水平溶解在基质中,处于无定型态.随着AO-80用量的增加,PET-TPU软段的玻璃化转变温度逐渐升高,硬段基本保持不变.AO-80/PET-TPU复合材料的损耗因子与温度曲线呈单峰形式,随着AO-80用量增加其峰值明显增大,并且转变峰向高温方向移动.AO-80的加入使PET-TPU基质的力学性能有所下降. 相似文献
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The effects of chemical crosslinking on the thermal and dynamic mechanical properties of a polyurethane system were examined. The polyurethanes were prepared from poly(propylene glycol), a diol; trimethylolpropane propoxylate, a triol; and poly(propylene glycol), tolylene 2,4‐diisocyanate terminated, a diisocyanate monomer. The crosslink density was controlled by varying the triol concentration from 10 to 70 mol % and the isocyanate‐to‐hydroxyl (NCO/OH) ratio from 1.0 to 1.3. All the samples had one glass‐transition temperature and no crystalline regions. In addition, there were larger increases in glass‐transition temperature over the range of triol concentrations studied than over the range of NCO/OH ratios studied. For all samples, the Dibenedetto equation relating glass‐transition temperature to extent of crosslinking fit the data very well. Also, samples with higher crosslink densities had much larger elastic moduli for temperatures above the glass‐transition temperature. By assuming the system was a phantom network, approximate crosslink densities for stoichiometric samples were obtained from the dynamic mechanical data and these agreed fairly well with theoretical predictions. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 212–223, 2002 相似文献
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Shape-memory polyurethanes (PUs) were synthesized by 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butanediol (BD), and poly(tetramethyl oxide)glycol (PTMO). The morphology of PUs was studied using DSC, DMA, and TEM. The results indicated that the PUs would show different morphology by changing the mol ratio of MDI and BD (hard segment). The specimens would show the shape-memory behavior that was fixing and recovering the deformation at different operating temperature ranges. These results demonstrated that the shape-memory behavior of the PUs would be affected by the morphology and the modulus ratio that was defined as in DMA analysis. The amount of the hard-segment-rich phase would affect the ratio of recovery, that is, the low content would lead to the recovery of the deformed specimen being incomplete. The recovering rate would be influenced by the modulus ratio and the size of the dispersed phase in the micromorphology. On the other hand, the shape-memory behavior of PUs could be enhanced by the training process. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 69: 1563–1574, 1998 相似文献
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In this article, the damping properties of organic hybrids consisting of chlorinated polyethylene (CPE), N,N‐dicyclohexyl‐2‐benzothia‐zolylsufenamide (DZ), and 4,4′‐thio‐bis(3‐methyl‐6‐tert‐butylphenol) (BPSR) have been investigated by dynamic mechanical analysis (DMA). It is found that DZ and BPSR seem to have a synergistic effect on the damping improvement of CPE/DZ/BPSR hybrids. For CPE/DZ/BPSR three‐component hybrids, when BPSR content is below 20 wt %, the values of damping peak maximum are just the same, while the damping peak position shifts to a higher temperature at a higher BPSR concentration. When BPSR content is fixed at 10 wt %, the damping peak maximum increases with increasing DZ/CPE ratio, while there is little shift in the peak position within the ratio range of 0.75–1.25. The decrease in damping peak maximum against annealing can be attributed to the phase separation resulting from the crystallization of hybrids components. Such a crystalline phase, which has been formed during annealing, contains not only pure DZ crystallites but also some CPE–DZ or CPE–DZ–BPSR eutectic crystals. Furthermore, the damping stability of the hybrids can be improved excellently by adding a small amount of BPSR or changing hot‐pressing temperature. These may imply that a series of high‐performance damping materials possessing both high damping peak maximum and controllable damping peak position can be achieved. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3307–3311, 2006 相似文献
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王丽 《合成材料老化与应用》2014,(4):15-17
分别以聚四氢呋喃醚二醇(PTMEG)、聚氧化丙烯二醇(PPG-1000)为软段,以二苯基甲烷二异氰酸酯(MDI-50、MDI-100LL),以及扩链剂1,4-丁二醇(BDO)、三羟甲基丙烷(TMP)为硬段,采用预聚体法制备了聚氨酯弹性体。并系统研究了聚氨酯体系中各组分的种类对材料机械性能和阻尼性能的影响。 相似文献
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H. C. Jung S. J. Kang W. N. Kim Y.‐B. Lee K. H. Choe S.‐H. Hong S.‐B. Kim 《应用聚合物科学杂志》2000,78(3):624-630
Polyurethanes were synthesized using the high functional 4,4′‐diphenylmethane diisocyanate (MDI), polyester polyol, and 1,4‐butane diol. The synthesized polyurethanes were analyzed using differential scanning calorimeter (DSC), dynamic mechanical thermal analysis (DMTA), Fourier transform infrared (FTIR) spectrometer, and swelling measurement using N,N′‐dimethylformamide. From the result of thermal analysis by DSC and DMTA, single Tgs were observed in the polyurethane samples at all the formulated compositions. From this result, it is suggested that the polyurethanes synthesized in this study have crosslinked structure rather than the phase‐separated segmented structure because of the high functionality (f = 2.9) of the MDI. By annealing the polyurethane samples using DSC, the Tgs were increased by 4.7∼16.0°C at the various annealing temperatures. From the results of FTIR and swelling measurement of polyurethanes, it is suggested that the increase of Tg of the polyurethanes by annealing is not due to increase of the hydrogen bond strength but mainly due to the increase of the crosslink density. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 624–630, 2000 相似文献