V含量对TaVCN复合膜微结构、力学性能和摩擦磨损性能的影响

采用多靶磁控溅射技术,制备一系列不同V含量的TaVCN复合膜。利用X射线衍射仪、纳米压痕仪和高温摩擦磨损仪研究该复合膜的微结构、力学性能和摩擦磨损性能。结果表明, TaVCN复合膜为面心立方和底心斜方的双相结构。随V含量增加,复合膜的硬度先升高后降低,当V原子分数为26.85%时,复合膜的硬度达到最大值,为31.7 GPa。室温下随V含量增加,复合膜的摩擦因数和磨损率均先减小后增大,V原子分数为32.60%时,摩擦因数达到最小值,为0.213;V原子分数为26.85%时,磨损率达到最小值,为2.1×10?7 mm2/N。随温度升高,复合膜的摩擦因数逐渐减小,磨损率逐渐增大。并对不同温度下 TaVCN 和 TaCN 复合膜的摩擦磨损性能进行了讨论。     

碳／铜复合材料摩擦磨损性能的研究

将粉末冶金法制备的碳／铜复合材料进行放电等离子烧结。对烧结后的样品进行了摩擦磨损性能研究。结果表明,复合材料的摩擦系数均随含碳量的增加呈下降趋势;当含碳量为6％时,磨损率最低。     

SiC含量对C/C-SiC摩擦材料摩擦磨损性能的影响

以整体碳毡为预制体,经化学气相渗透法制得C/C多孔坯体,然后采用反应熔融浸渗法制得C/C-SiC摩擦材料,探究SiC含量对C/C-SiC摩擦材料摩擦磨损性能的影响。结果表明:C/C-SiC试样的摩擦因数随着SiC含量的增加呈现先上升后下降的趋势,当SiC含量为29.88%时摩擦因数达到最大值0.62。当SiC含量低于33.56%时磨损率的变化规律与摩擦因数比较一致,当SiC含量高于33.56%时磨损率的变化规律与摩擦因数则呈相反的变化趋势。因此,SiC含量为33.56%时是该摩擦材料摩擦磨损性能的拐点。     

热解碳结构对炭/炭复合材料摩擦磨损性能的影响

通过控制化学气相沉积(CVD)工艺条件,得到粗糙层、光滑层、过渡层等几种具有不同微观结构的热解碳。金相观察、摩擦磨损性能的测试结果表明:热解碳的微观结构对炭/炭复合材料的摩擦磨损性能有重大影响;粗糙层结构的炭/炭复合材料摩擦因数高,热稳定性好,是一种优良的摩擦材料;光滑层结构的炭/炭复合材料摩擦因数低,磨损小,可以用作耐磨材料。     

热解炭结构对C/C复合材料摩擦磨损性能的影响

以炭纤维整体毡为预制体,采用热梯度化学气相渗透(CVI)工艺制备了2种不同结构基体炭的C/C复合材料,即粗糙层结构材料与光滑层结构材料。研究了2种不同结构基体炭的C/C复合材料在沉积态和热处理态的显微结构、热物理性能及摩擦磨损性能。研究结果表明,在沉积态,2种结构材料都产生严重的氧化磨损,提高材料的石墨化度可显著降低材料的氧化磨损;不管是在沉积态还是在热处理态,RL结构材料的刹车性能曲线都明显优于SL结构材料的刹车性能曲线,这表明热解炭的微观结构不同是造成C/C复合材料摩擦性能差异的根本原因。     

粉末冶金渗铜钢的摩擦磨损性能

通过压制、预烧和熔渗,制备1种液压零件用粉末冶金渗铜钢。用UMT 3型摩擦磨损实验机评价该材料在边界润滑条件下的耐磨性,研究基体密度对渗铜钢摩擦磨损性能的影响,并与目前常用的耐磨合金进行摩擦磨损性能对比。结果表明:在边界润滑条件下,渗铜量相同,基体材料密度分别为6.40、6.60、6.80 g/cm3的粉末冶金渗铜钢摩擦副的摩擦因数相差不大,4 h的质量磨损量分别为1.70、1.50和3.10 mg;而传统耐磨合金中硬度较低的HMn58 2铜合金磨损量为24.10 mg,磨损较快。     

稀土化合物对粉末冶金镍基合金摩擦磨损性能的影响

用粉末冶金热压方法制备了几种含不同稀土化合物（LaF3,CeO2,La2O3)的Ni基合金，将合金制备为块样，45^#钢为环样，在环－块摩擦试验机上考察了稀土化合物含量及其种类对Ni基合金摩擦磨损性能的影响，研究结果表明：添加稀土化合物可明显改善合金在高载高速下的耐磨性能，这与其摩擦表面形成摩擦保护性“釉质层”密切相关。     

制动速度与压力对飞机炭刹车盘摩擦磨损性能的影响

采用HJDS-Ⅱ惯性台在各种制动速度/压力及外场装机使用的条件下,对西安超码科技公司采用自主创新专利技术生产的Chaoma B757,Chaoma A320炭刹车盘与Dunlop公司的B757,以及Messier-Bugatti公司的A320Sepcarb?ⅢOR炭刹车盘的摩擦因数、平均力矩和磨损率进行对比试验。结果表明:4种类型炭刹车盘材料的能量、力矩均随制动速度和制动压力增加而增大;摩擦因数在低速阶段均出现低能峰值特性,然后随着制动速度与压力增加呈降低趋势。ChaomaB757,A320炭刹车盘凸显2个特色:在飞机中止起飞能量下制动压力比国外原件低25%,摩擦因数比国外原件高25%～29%;B757炭刹车盘的装机应用的最长使用寿命达到2823~3289次起落,与国外B757原件的使用寿命相当,凸显出优异的低磨损率特色。     

Y_2O_3对硬质合金晶粒尺寸和摩擦磨损性能的影响

研究了稀土Y2O3对WC-10Co硬质合金晶粒尺寸、矫顽力的影响,对比了Y2O3含量0.10%(质量分数,下同)和0.30%硬质合金的摩擦磨损性能。结果表明:微量Y2O3能细化WC晶粒,有效改善合金的硬度,影响硬质合金的磁性能。低于0.15%时,WC-10Co合金晶粒尺寸随着Y2O3增加而明显细化,硬度显著增加;Y2O3含量达到0.2%以上,WC-10Co合金的晶粒尺寸基本稳定,硬度也变化不大。在相同条件下,细晶粒0.30%Y2O3的WC-10Co硬质合金比0.10%Y2O3的WC-10Co硬质合金的摩擦因数稍高,但磨损体积损失低于0.10%Y2O3合金。     

NiAl／BN可磨耗封严涂层摩擦磨损性能研究

利用大气等离子喷涂技术制备NiAl／BN可磨耗封严涂层,采用可模拟可磨耗封严涂层工况的高速／高温摩擦磨损试验机研究了涂层在650℃下的摩擦磨损性能,探究了涂层磨损机理。结果表明,涂层硬度对NiAl／BN封严涂层与K24镍基高温合金叶片间的摩擦系数、涂层磨损量和磨损机理均有明显影响。摩擦系数随涂层硬度增大而增大;涂层磨损量随硬度增大而减小;当硬度为35HR15y和45HR15y时,涂层磨损机理为切削、涂抹、摩擦氧化,当硬度为55HR15y时,涂层磨损机理为涂抹和摩擦氧化。     

纳米铜自修复添加剂的制备及其摩擦学性能

采用液相还原法制备纳米铜润滑油添加剂。通过摩擦磨损试验机测试纳米铜添加剂在不同载荷下的摩擦学性能。利用扫描电子显微镜和纳米压痕仪分析纳米铜添加剂的自修复性能和机理。结果表明：纳米铜添加剂为粒径约20nm的球形颗粒，其分散性能稳定，摩擦过程中可以在摩擦表面形成低剪切强度的保护膜，具有良好的自修复性能；高载荷时，添加纳米铜添加剂的润滑油摩擦因数和钢球磨斑直径分别比原基础油减少29．1％和27．4％，表现出良好的抗磨减摩性能。     

Characterization and tribological investigation of self-assembled MPTS-MPTES/RE composite films

γ-mercapto-propyl trimethoxysilane (MPTS) and γ-methacryloxy propyltrimethoxysilane (MPTES) were self-assembled on a hy-droxylated glass substrate to form a two-dimensional organic monolayer (MPTS-MPTES SAM). The terminal thiol groups (-SH) in the MPTS-MPTES SAM were in-situ oxidized into sulfonic acid groups (-SO3H) to endow the film with good chemisorption ability. Then rare earth (RE) (lanthanum-based) composite thin films were prepared by serf-assembly technique based on the as-prepared SAM, taking advan-tage of the chemisorption ability of the sulfonic acid groups. Automatic force microscope (AFM), X-ray photoelectron spectrometry (XPS), contact angle measurement and eUipsometer were used to characterize MPTS-MPTES/RE composite films. The macrofriction and wear be-haviors of the films sliding against an AISI-52100 steel ball were examined on a unidirectional friction and wear tester, and the worn surface morphologies were observed on an AFM. The results showed that MPTS-MPTES/RE films had a low friction coefficient (0.09) and a longwear life (5980 sliding pass) at a light load (50 mN). It indicated that the superior tribological properties of the MPTS-MPTES/RE composite films were attributed to the special characteristic of RE elements, the mobility of the fdms and good bonding strength.     

TiN/TiCN/Al2O3/TiN CVD多层涂层硬质合金的氧化行为

采用高温化学气相沉积(HT-CVD)和中温化学气相沉积(MT-CVD)相结合的复合化学气相沉积新技术在硬质合金基体WC-(W,Ti)C-(Ta,Nb)C-6%Co上分别沉积TiN/TiCN/TiN和TiN/TiCN/Al2O3/TiN涂层,制备TiN/TiCN/TiN和TiN/TiCN/Al2O3/TiN CVD多层涂...     

Effect of Rare Earths on Mechanical Properties and Microstructure of TiCN/Al2O3 Ceramics

The effects of Y on mechanical properties and microstructure of TiCN/Al2O3 ceramics were studied in details. The experimental results show that the mechanical properties and microstructure can be improved by adding rare earth in TiCN/Al2 O3 ceramics, flexural strength and fracture toughness of the composites increased when Y is doped by 18.99% and 18.58% than those of the matrix, respectively. Microstructure of cracks extension was observed through SEM and TEM. The mechanics of particles bridge, cracks branch and cracks deflection are enforced obviously during the processes of cracks extension because strong interfaces and weak interfaces coexist, so manifold mechanics of enforcement of toughness act upon together to increase fracture toughness of TiCN/Al2 O3 doped with Y.     

Mechanical properties of multilayer materials

Conclusions A multilayer composite material consisting of a soft, ductile and hard, strong component possesses, at a high level of hardness, much higher impact and tensile strengths compared with a single-layer material. A greater improvement in impact strength is exhibited by a system whose soft component, other things being equal, is more ductile. A better combination of mechanical properties is attainable in a MLC produced by the metallurgical process. The increase in impact strength is apparently due to the inhibition of crack propagation in the ductile component of a MLC and to an increase in the strength of the hard component associated with the small thickness of its layers.Translated from Poroshkovaya Metallurgiya, No. 5(233), pp. 70–74, May, 1982.     

Strain-induced self-organization of steps and islands in SiGe/Si multilayer films

It has recently been recognized that “stress management” may become a unique way of fabricating nanostructures, because structural self-assembly and self-organization can be strongly influenced by strain. In this article, we review recent studies of growth and ordering processes in multilayer films of alternating Si and SiGe layers with nanometer-layer spacing. The formation of ordered arrays, superlattices of step bunches, and three-dimensional (3-D) islands that exhibit remarkable spatial and size uniformity and very good long-range order, are demonstrated. Theoretical analyses and simulations based on elastic models are discussed to elucidate the lattice strain-induced formation and self-organization processes. The self-organized steps and 3-D islands provide a possible route for fabricating novel devices based on quantum wires and quantum dots. This article is based on a presentation made in the symposium “Kinetically Determined Particle Shapes and the Dynamics of Solid:Solid Interfaces,” presented at the October 1996 Fall meeting of TMS/ASM in Cincinnati, Ohio, under the auspices of the ASM Phase Transformations Committee.     

Mechanical properties of multilayer steel-copper composites

Conclusions The tensile strength _t and fatigue limit _–1 of powder metallurgical and cast MLCs grow with decreasing mean layer thickness h starting from 5000 Å. In cast Type 45 steel/copper composites high tensile strength _t (222 kgf/mm²) combines with high impact strengtha _n (8 kgf-m/cm²) and hardness (42–45 HRC). With powder metallurgical and cast MLCs, at any given life NG the cycle stress necessary for fatigue fracture grows with decreasing mean layer thickness (within the h = 5000-500 Å range investigated).Translated from Poroshkovaya Metallurgiya, No. 11(203), pp. 33–37, November, 1979.     

Effect of chromium interlayer on magnetic exchange coupling of SmCo/Cr/TbFeCo multilayer thin films

A series of SmCo/Cr/TbFeCo multilayer thin films with perpendicular anisotropy were prepared by RF- magnetron sputtering system, and the effects of Cr interlayer thickness on magnetic properties and interlayer exchange coupling were investigated. It was found that the magnetic properties varied with the thickness of Cr interlayer, especially the values of saturation magnetization Ms and the coercivity Hc fluctuated periodically with the thickness of Cr interlayer. STM images revealed that the variation of coercivity Hc was attributed to the microstructure change of SmCo layer influenced by Cr interlayer, and the variation of Ms was related to interlayer exchange coupling.