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应用化学镀镍的方法实现了氮化铝的金属化。为得到较大的氮化铝金属化层粘附力,运用基于稳健估计的神经网络研究氮化铝金属化中化学镀镍的反应参数与金属层粘附力的关系。为使神经网络更加稳健,本文根据统计学原理,在前馈神经网络基础上,采取稳健估计方法改进神经网络。建立了定量预测粘附力性能的模型,并进行实验验证。确定金属化工艺中稳定的优化工作区域。结果表明,稳健估计方法既有传统神经网络的优点,又有较强的抵抗异常 相似文献
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地震勘探数字信号处理领域中一个重要而基本的方法是地震信号的反褶积方法.在地震数据的采集过程中往往会遇到异常点的干扰,这种干扰严重影响了利用反褶积方法对真实反射系数与地震子波的重构效果.本文在Canadas等人提出的针对高斯噪声的贝叶斯反褶积数学框架的基础之上,提出一种能够克服异常点干扰的稳健稀疏反褶积方法.新方法针对具有重尾分布的异常点噪声与稀疏的反射系数建模,并使用交替迭代与线性规划的算法求解.最后,通过实验证明该方法在克服异常点噪声的基础上,能实现对地震子波与反射系数的同步估计,所得到的估计有效地消除了重尾分布异常点噪声的影响,提高了地震信号反褶积处理的精度.这也能证明所提算法是收敛的,并且模型是有效的. 相似文献
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铁氧体贴片电感要求金属化薄膜具有高的抗拉强度和高温焊接性,传统金属化工艺不能满足要求.本文采用磁控溅射技术对铁氧体电感磁芯进行金属化,研究了不同金属膜系以及不同工艺对薄膜抗拉强度和高温焊接性能的影响,结果表明磁控溅射金属化在抗拉强度及耐焊性方面明显优于电镀和蒸发,结合强度高达70N以上.推荐膜层结构是Cr/NiCu/Ag,其中NiCu厚度150~200 nm较宜.金属化膜焊接情况较符合凝固模型,金属间化合物会降低焊接性和抗拉强度,但是可以起到阻挡作用.更好的相结构是形成固溶体组织,并设计膜层结构来防止反浸蚀.该技术已经成功应用于国内最大铁氧体贴片电感厂的规模化生产中. 相似文献
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Currently, the surface preparation of aluminum nitride (AlN) substrates prior to metallization includes an aqueous cleaning step. Surface reactions that occur in this step cause performance and reliability issues with AlN substrates to be used in microelectronic packaging. There is a lack of published data on the reactivity of AlN substrates with common solvents. This study investigated the effects of different solvents on the surface corrosion of AlN substrates. The variables studied were pH, aqueous vs. organic solutions, prior surface condition, and time (up to 3.6 Ms or 42 days). The solvents tested were hydrochloric acid (HCl) with pH values ranging from 2 to 5, sulfuric acid (H2SO4) with pH values ranging from 2 to 5, sodium hydroxide (NaOH) with pH values ranging from 8 to 12, 1 M citric acid, oleic acid, Micro-90, methanol, ethanol, isopropanol, acetone, and deionized water. Three types of surface reaction behavior were observed in this study. The substrates either showed no reaction (HCl pH = 2, methanol, ethanol, isopropanol, acetone, citric acid, and oleic acid), slight corrosion without spalling (Micro-90, HCl pH = 3, H2SO4pH = 3), or they were severely corroded and spalled (HCl pH = 5, H2SO4pH = 5, all NaOH solutions, and deionized water). 相似文献
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AlN陶瓷的薄膜金属化及其与金属的焊接研究 总被引:2,自引:1,他引:1
针对AlN陶瓷在微波管中的应用特点 ,采用磁控溅射镀膜方法对AlN陶瓷进行表面金属化 ,并与无氧铜焊接 ,测试焊接体的抗拉强度并对陶瓷 金属接合界面进行了微观分析。 相似文献
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The current aqueous cleaning step in the surface preparation of aluminum nitride (AlN) prior to metallization causes performance and reliability issues for the substrates used for microelectronic packaging due to surface reactions. These issues limit the use of AlN and its replacing of BeO, an environmentally hazardous material currently used. The aim of this investigation was to determine the effects of different solutions on the surface of AlN substrates under varying conditions at times up to 2419.2 ks (28 days). Concentration of the solutions, temperature, and immersion time were varied for the AlN samples in the solutions. Both elevated temperatures (50°C and 90°C) and low temperatures (5°C) were investigated.
Four general types of behavior were observed: minor changes in average surface roughness and microstructure, linear change in average surface roughness and pitted grains, nonlinear change in average surface roughness and product formation on AlN surface, and miscellaneous change in average surface roughness with surface product formation.
The surface roughening kinetics were very complex due to changes in both the reaction product morphology and reaction mechanism with temperature, solvent, and pH for a specific solvent. Minor changes in average surface roughness and microstructure were observed for HCl pH = 5, H2 SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, deionized water and Alfred tap water at 5°C, HCl pH = 3 and oleic acid at 50°C and citric acid and oleic acid at 90°C. Linear changes in average surface roughness and pitted grains were observed for HCl pH = 2 and H2SO4 pH = 3 at 50°C and HCl pH = 2, H2SO4 pH = 3, and deionized water at 90°C. Non-linear change in average surface roughness and product formation on AlN surface was observed for HCl pH = 5, NaOH pH = 8 and Alfred tap water at 50°C and HCl pH = 5 and H2SO4 pH = 2 at 90°C. Miscellaneous changes in average surface roughness with surface product formation were observed for H2SO4 pH = 2, H2SO4 pH = 5, NaOH pH = 10, NaOH pH = 12, citric acid, Micro-90 and deionized water at 50°C and HCl pH = 3, H2SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, Micro-90 and Alfred tap water at 90°C. 相似文献
Four general types of behavior were observed: minor changes in average surface roughness and microstructure, linear change in average surface roughness and pitted grains, nonlinear change in average surface roughness and product formation on AlN surface, and miscellaneous change in average surface roughness with surface product formation.
The surface roughening kinetics were very complex due to changes in both the reaction product morphology and reaction mechanism with temperature, solvent, and pH for a specific solvent. Minor changes in average surface roughness and microstructure were observed for HCl pH = 5, H2 SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, deionized water and Alfred tap water at 5°C, HCl pH = 3 and oleic acid at 50°C and citric acid and oleic acid at 90°C. Linear changes in average surface roughness and pitted grains were observed for HCl pH = 2 and H2SO4 pH = 3 at 50°C and HCl pH = 2, H2SO4 pH = 3, and deionized water at 90°C. Non-linear change in average surface roughness and product formation on AlN surface was observed for HCl pH = 5, NaOH pH = 8 and Alfred tap water at 50°C and HCl pH = 5 and H2SO4 pH = 2 at 90°C. Miscellaneous changes in average surface roughness with surface product formation were observed for H2SO4 pH = 2, H2SO4 pH = 5, NaOH pH = 10, NaOH pH = 12, citric acid, Micro-90 and deionized water at 50°C and HCl pH = 3, H2SO4 pH = 5, NaOH pH = 8, NaOH pH = 10, NaOH pH = 12, Micro-90 and Alfred tap water at 90°C. 相似文献
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本实验分别采用打磨、混合碱处理、水合肼处理和电晕处理四种方式对AA5052铝合金基体表面进行预处理,探讨了预处理方式对铝合金表面润湿性和表面形貌的影响,并在此基础上对铝合金表面镀镍工艺参数进行优化。通过接触角仪和扫描电子显微镜对镀层润湿性以及表面形貌进行表征,得到最佳化学镀镍条件:镀液温度为75℃,镀液pH值在6.2~6.4之间,化学镀时间40min。通过循环伏安法(CV)探索得到了最佳电化学镀镍条件:电镀时间为240s,电流密度为5mA/cm2,镀液温度为60℃。实验表明,该实验条件下可以得到理想的镍镀层,且该方法可以广泛应用于其他相关的材料研究领域。 相似文献
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AIN是一种重要的近紫外、蓝光半导体材料。本文就AIN的物理特性,薄膜生长,性能测试分析的研究进展作一些阐述。对AIN在制作发光器件、固溶体合金、电学绝缘等方面的应用也作了探讨 相似文献
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