共查询到19条相似文献,搜索用时 93 毫秒
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对不同三环化合物含量组成的聚合MDI分别与CFC-11型组合聚醚和环戊烷(CP)型组合聚醚混合制备硬质聚氨酯泡沫的发泡性能进行了研究。实验表明,随着聚合MDI中三环化合物含量的增加,聚合MDI发泡的高度指数升高、密度分布系数下降,改善了聚合MDI的发泡流动性;但泡沫的脱模变形量加大,后熟化性能下降。 相似文献
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采用二乙醇胺、自制四溴双酚A环氧树脂(E-21)为原料合成了阻燃聚醚多元醇组分;采用2,4-甲苯二异氰酸酯(TDI)、聚乙二醇(PEG)、三羟甲基丙烷(TMP)为原料,在二月桂酸二丁基锡的作用下,通过逐步聚合反应得到异氰酸酯组分;将两组分按一定比例进行发泡得到阻燃聚氨酯硬质泡沫塑料。利用热重分析仪、水平燃烧测定仪等手段进行了表征,研究了异氰酸酯指数、发泡剂以及阻燃剂对聚氨酯硬质泡沫塑料性能的影响。结果表明,与不添加阻燃剂的聚氨酯硬质泡沫塑料相比,阻燃聚氨酯硬质泡沫塑料的吸热峰温度从294.8℃提高到303.8℃。 相似文献
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笔者通过以聚醚多元醇、异氰酸酯作为实验的主要材料,通过添加阻燃剂甲基磷酸二甲酯∞MMP)、三聚氰胺等按成了对聚氨酯硬质泡沫塑料的制备,并探讨异氰酸酯指数、水、三聚氰胺和DMMP的用量对于聚氨酯硬质泡沫塑料垂直燃烧性能的影响程度,最后从实验中进行总结。 相似文献
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耐高温聚异氰脲酸酯硬质泡沫塑料的制备 总被引:2,自引:0,他引:2
以聚醚多元醇、MDI、三聚催化刑DMP-30、发泡刑、均泡刑等原料,制备了聚氨基甲酸酯改性聚异氰脲酸酯(PU—PIR)硬质泡沫塑料。该硬质泡沫塑料可长期在150℃下使用,是相对于聚氨酯硬质泡塑料的一种耐高温硬质泡沫塑料。可广泛应用于工矿企业设备、管道及建筑业等的隔热保温。 相似文献
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全水发泡阻燃聚氨酯硬质泡沫塑料的制备与性能 总被引:3,自引:0,他引:3
采用多元醇、异氰酸酯、催化剂、发泡剂和阻燃剂等为原料制备了全水发泡阻燃聚氨酯硬质泡沫(PURF),讨论了聚醚多元醇种类、催化剂、发泡剂、异氰酸酯指数以及阻燃剂对PURF性能的影响。结果表明,聚酯多元醇能够改善泡孔结构,但降低压缩强度和尺寸稳定性;不同催化剂复配,可以控制发泡工艺;水发泡剂与泡沫的密度、泡孔结构、力学性能有关;异氰酸酯指数在1.1~1.2时,泡沫的压缩强度、尺寸稳定性等较好;三(2-氯异丙基)磷酸酯(TCPP)可赋予PURF一定的阻燃性,但对泡体结构、压缩强度和尺寸稳定性有影响。 相似文献
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将水稻秸秆粉碎为粒径250~590 μm的粉末,利用成熟的催化常压加热液化技术将水稻秸秆粉末液化制得液化物,以其为原料,五甲基二乙烯三胺(PC5)和N,N-二甲基环己胺(PC8)为复合催化剂,正戊烷为发泡剂,与多苯基甲烷多异氰酸酯(PAPI)反应通过物理发泡法制备硬质聚氨酯泡沫(PURF)。另外采用全水发泡法制备了聚氨酯泡沫作为对比。对物理发泡制备PURF的条件进行了优化,较优的制备条件为催化剂中PC5和PC8的质量比4:5,泡沫稳定剂硅油B8462用量(以液化物质量计,下同)4%,发泡剂用量15%,该条件下制备的PURF的拉伸强度为347 kPa,压缩强度为181 kPa。采用傅里叶变换红外光谱(FT-IR)和扫描电镜(SEM)对比了物理发泡和全水发泡制得的泡沫,结果显示,通过物理发泡制得的水稻秸秆基聚氨酯泡沫相比于全水发泡聚氨酯泡沫,体系中异氰酸根浓度低,泡沫泡孔开孔率低,制得的泡沫力学性能略优。 相似文献
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Both rigid and flexible water-blown polyurethane foams were made by replacing 0–50% of Voranol® 490 for rigid foams and Voranol® 4701 for flexible foams in the B-side of foam formulation by epoxidized soybean oil. For rigid water-blown polyurethane foams, density, compressive strength, and thermal conductivity were measured. Although there were no significant changes in density, compressive strength decreased and thermal conductivity decreased first and then increased with increasing epoxidized soybean oil. For flexible water-blown polyurethane foams, density, 50% compression force deflection, 50% constant force deflection, and resilience of foams were measured. Density decreased first and then increased, no changes in 50% compression force deflection first and then increased, increasing 50% constant force deflection, and decreasing resilience with increase in epoxidized soybean oil. It appears that up to 20% of Voranol® 490 could be replaced by epoxidized soybean oil in rigid polyurethane foams. When replacing up to 20% of Voranol® 4701 by epoxidized soybean oil in flexible polyurethane foams, density and 50% compression deflection properties were similar or better than control, but resilience and 50% constant deflection compression properties were inferior. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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Ground granulated blast furnace slag (BFS) and fly ash (FA) are iron-making industry and power plant byproducts, respectively. Although their use in concrete is quite common, investigation of the effects of these inorganic compounds on polymer properties is quite new, and their use as fillers in polymer foam composites has not yet been really explored. Their properties, such as high electrical resistivity, make them a good asset for use in rigid polyurethane foams that are widely used for insulation. In this study, a comprehensive investigation of the effect of BFS and FA on morphology, electrical and thermal conductivity, and rheological and mechanical properties of water-blown rigid polyurethane foams was performed. The relationship between these properties was examined. A relative enhancement of the properties is observed for filled foams, especially up to the percolation threshold. The results highlight a noticeable effect of the electrical percolation threshold on the different properties of foams. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47433. 相似文献
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涤纶废产物用于制备聚氨酯泡沫塑料 总被引:2,自引:0,他引:2
将涤纶废产物用二甘醇和三元醇经酯基转移合成齐聚酯多元醇,并用其制备聚氨酯硬质泡沫塑料。该泡沫塑料具有良好的力学性能,且随着齐聚酯多元醇平均官能度的影响,力学性能随之提高;由于齐聚酯多元醇中芳香族基团含量高,泡沫塑料的铖一明显高于普通聚氨酯泡沫塑料。 相似文献
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以水稻秸秆液化产物为原料,以N,N,N,N,N-五甲基二乙烯三胺(P5)和N,N-二甲基环己胺(P8)为复合催化剂,制备了全水发泡聚氨酯泡沫(PUF)材料。通过调节水用量、催化剂比例、异氰酸酯指数及泡沫稳定剂用量,对不同条件下制备的泡沫性能进行测试,确定较优的制备工艺。利用万能试验机、热重分析仪(TGA)、傅里叶变换红外光谱仪(FT-IR)和扫描电子显微镜(SEM)对PUF的力学性能、热稳定性、结构和表观形貌进行了测试和表征。结果表明:当发泡剂水的用量为2%,催化剂P5/P8用量2%、催化剂P5/P8质量比值为1.5,异氰酸酯指数为1.2,硅油B8462用量为4%时,制得的聚氨酯泡沫性能最佳,密度为40 kg/m3、拉伸强度为309 kPa、压缩强度为154 kPa,其力学性能优于以有机锡和叔胺类化合物为催化剂制备的水稻秸秆PUF,且具有较好的热稳定性。 相似文献
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用聚醚多元醇A、聚醚二醇B、聚酯多元醇PS-2915、三乙醇胺、水和其他助剂制备了喷涂管道用全水发泡聚氨酯硬泡组合聚醚,并对其反应性能、黏度进行评价,对使用该组合聚醚和多异氰酸酯PM-200制得的聚氨酯泡沫材料的性能进行研究。结果表明,在合适的原料用量时,制得的组合聚醚黏度较低,与多异氰酸酯PM-200的反应速度满足喷涂管道生产工艺要求。当喷涂制得的聚氨酯泡沫单层厚度7 mm左右,泡沫体具有较高的粘接强度、较好的韧性和较低的导热系数,密度61 kg/m^3的泡沫压缩强度达到526 kPa。制得的喷涂管道产品满足GB/T 34611—2017要求。 相似文献