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由端羟基聚丁二烯(HTPB与甲苯二异氰酸酯(TDI–80反应,合成—NCO封端预聚体,以此预聚体活化己内酰胺单体,在NaOH作用下,由活化的己内酰胺开环聚合,制得MCPA6–预聚体嵌段共聚物。改变预聚体添加量,可制得性能不同的嵌段共聚物。研究发现,随预聚体量的增加,嵌段共聚物材料的断裂伸长率升高,硬度、拉伸强度降低,吸水率呈下降趋势,而密度略有降低,表明预聚体对MCPA6有明显的改性作用。 相似文献
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将聚醚型预聚体与己内酰胺单体共聚,制备单体浇铸尼龙(MC尼龙)/聚氨酯共聚物。研究了预聚体的异氰酸指数(R=—NCO/—OH)和预聚体质量分数对MC尼龙/聚氨酯共聚物的力学性能、维卡软化温度和结晶度的影响。结果表明:PPG和PTMG预聚体对MC尼龙的增韧效果较好,且PTMG预聚体在R=1.6、质量分数为10%时增韧效果最好,缺口冲击强度达到23.1kJ/m2。随聚氨酯预聚体质量分数的增加,MC尼龙的维卡软化温度逐渐下降,结晶度和熔点均降低。 相似文献
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采用熔融缩聚法合成了聚酰胺(PA)6/聚四氢呋喃(PTEMG)嵌段共聚物,研究了PA6、PTEMG链段的相对分子质量、含量对嵌段共聚物热性能的影响,通过傅立叶变换红外光谱、核磁共振、差示扫描量热、热重测试等对产物进行分析.结果表明,嵌段共聚物以羧基封端,当PA6、PTEMG链段相对分子质量分别为2 000、1 000时,共聚物的分子序列长度最长,相对分子质量最大;PTEMG链段相对分子质量越小,共聚物的熔点越低;PTEMG链段相对分子质量相同时,随PA6链段相对分子质量的增加,熔点升高;嵌段共聚物中PA6组分的熔融温度范围随着PTEMG含量的增加而逐步变宽;共聚物具有较高的热分解活化能. 相似文献
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聚醚改性铸型尼龙的研究 总被引:3,自引:0,他引:3
介绍了聚醚改性铸型尼龙的制备方法,以聚醚和异氰酸酯为原料合成预聚体活化剂在该活化剂存在下引发己内酰胺阴离子聚合,聚体韧性被显著改善。讨论了各各绎制备过程的影响,并测试了制品性能与预聚体用量的关系,当预体用量为聚合体重的8%时,材料缺口冲击强度最高。 相似文献
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本论文论述了单体浇铸尼龙的增韧改性制备方法,在绝热条件下通过己内酰胺与十二内酰胺活化阴离子共聚制得冲击强度显著改善的浇铸尼龙制品。探讨了增韧改性单体浇铸尼龙的合成工艺、反应条件及聚合成型过程,研究了十二内酰胺共聚单体对制品试样球晶结构和机械性能的影响。 相似文献
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用1,1,3,3-四甲基二硅氧烷(D2H)和八甲基环四硅氧烷(D4)为原料,经酸催化平衡反应先制得双端含氢聚二甲基硅氧烷(PHMS),再将其和单烯丙基聚乙二醇甲基醚在铂催化下经硅氢加成反应合成嵌段型聚醚聚二甲基硅氧烷(PEPS).用IR和1HNMR对PEPS的结构进行了表征,并通过测定PEPS水溶液的平衡表面张力研究了其表面活性.结果表明,PEPS具有良好的表面活性,其临界胶束浓度(cmc)为0.7 g·L-1,cmc处的表面张力为25.5 mN·m-1.质量分数0.05%的PEPS水溶液在塑料薄膜上30 s时的接触角为37.2°(水在塑料薄膜上30 s时的接触角为59.3°),而铺展面积是水的5倍. 相似文献
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为考察尼龙弹性体(TPAE)作为增韧剂使用的性能,使用马来酸酐接枝乙烯-辛烯共聚物(POE-g-MAH)和两种TPAE(硬度分别为30D,45D)作为增韧剂添加至尼龙6树脂,研究不同增韧剂添加量情况下,改性尼龙6的性能的变化规律.研究发现,材料的拉伸强度、弯曲强度、耐热性能和流动性都随着增韧剂用量的增加而下降,而且下降... 相似文献
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In this study, polyurethane prepolymer (PUP) was prepared by the reaction of Poly‐1,4‐butylene glycol adipate diol (PBA) and 4,4′‐Methylenedi‐p‐phenyl diisocyanate (MDI). The as‐prepared PUP was then blended with Polylactide (PLA), and the impact of the PUP on the blends regarding their structure and properties were thoroughly analyzed. Also, PLA was blended with PU powder without isocyanate groups (NCO) as an important control sample (PLAPW) to study the interface interaction of the blends. Obvious yield and neck stretch were obtained after the addition of PUP, and the elongation ratio at break increased from 2.9% to 231.5%. In contrast, the mechanical properties of PLAPW decreased significantly mainly due to the simple physical blending of the polymers without the formation of covalent bonds. Also, the results of the FTIR, SEM, DSC, and DMA analysis showed that the reactions of NCO groups in PUP with the terminal hydroxyl or carboxyl groups in PLA significantly improved the compatibility of the PUP and PLA blend. Compared to pristine PLA, the highest decomposition temperature of the PLA and PUP blend (PLAPU) increased from 359.3°C to 362.6°C. Additionally the thermal stability and mechanical properties of the blended materials were exceedingly improved even with only 5% of PUP in the blended materials. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42983. 相似文献
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A poly(phenylsulfone)-urea (PPSUU) macro-activator is synthesized by in situ anionic polymerization of 4,4′-diaminodiphenylsulfone and hexamethylene diisocyanate. The PPSUU segment is embedded into the nylon molecular chain through copolymerization to improve the wear resistance and flame retardancy of monomer cast nylon 6 (MC PA6) materials. The mechanical properties, thermal stability, friction and wear properties and combustion heat release rate of copolymers with different macro-activator contents are tested. Results indicate that a small amount of PPSUU can improve the wear resistance and impact properties of nylon materials. The wear loss of MC nylon is 54.8% less than pure MC nylon from 1.049 × 10−8 to 0.474 × 10−8 g/Nm with 6 wt% PPSUU. Moreover, better flame retardancy is verified. The peak of HRR reduced 36.8% from 654 to 413 kw/m2 with 4 wt% PPSUU, accompanied by advanced ignition time and flame extinction time, thus reducing the risk of fire. 相似文献
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ABSTRACT: Toluene-2,4-diisocyanate and dodecanol were used to chemically functionalize nanosilica (TDID-SiO2). Composites of TDID-SiO2 and oil-impregnated monomer casting nylon (OMC nylon) were prepared by an in situ anionic ring-opening polymerization. The dispersion of the TDID-SiO2 in oil was studied along with the mechanical and friction properties of the composites. The results show that the dispersion of the TDID-SiO2 in oil was significantly enhanced. Specifically, some TDID-SiO2 was wrapped in oil droplets, and the size of the oil droplets increased from 2.3 to 3.3 μm for 0–0.125 wt % of the TDID-SiO2 nanoparticles, which was confirmed by scanning electron microscopy. The composites exhibited excellent mechanical properties when 0.10 wt % TDID-SiO2 was integrated into OMC nylon. The tensile strength, elastic modulus, notched impact strength, flexural strength, and flexural modulus increased by 6.9%, 7.1%, 33.2%, 15%, and 77.5%, respectively, compared to OMC nylon without TDID-SiO2 nanoparticles. The friction coefficient was effectively controlled and the abrasion quantity was reduced. Thermogravimetric analysis showed that the thermal decomposition temperature was also improved. The improved mechanical and frictional properties of TDID-SiO2/OMC nylon composite will enhance its application in wear-resistant products in heavy industry. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 46994. 相似文献
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This study of waterborne polyurethane prepolymer blends was done to investigate the effects of different types of soft segments on the dispersion properties and other properties of treated nylon fabrics. The particle size of the dispersion increased, the surface tension of the dispersion decreased, and the contact angle of the nylon fabric with the dispersion decreased when the blending amount of the polydimethylsiloxane polyurethane prepolymer increased. The add‐on of ether‐type polyurethane increased rapidly when the ether‐type polyurethane was blended with a small amount of the polydimethylsiloxane polyurethane prepolymer, whereas the add‐on of the ether‐type polyurethane reached a maximum at a blending content of 10%. The add‐on of the ester‐type polyurethane prepolymer constantly decreased with increasing blending amount of the polydimethylsiloxane polyurethane prepolymer. The vertical wicking height of the treated nylon fabrics decreased slightly when the treating agent contained a small amount of the polydimethylsiloxane polyurethane prepolymer. For the treated nylon fabrics with blended prepolymers, the drying time was faster than for the untreated fabric, and the moisture ratio reached about 10% in 15 min © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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Epoxy resins are increasingly finding applications in the field of structural engineering. A wide variety of epoxy resins are available, and some of them are characterized by a relatively low toughness. One approach to improve epoxy resin toughness includes the addition of either a rigid phase or a rubbery phase. A more recent approach to toughen brittle polymers is through interpenetrating network (IPN) grafting. It has been found that the mechanical properties of polymer materials with an IPN structure are fairly superior to those of ordinary polymers. Therefore, the present work deals with epoxy resin toughening using a polyurethane (PU) prepolymer as modifier via IPN grafting. For this purpose, a PU prepolymer based on hydroxyl-terminated polyester has been synthesized and used as a modifier at different concentrations. First, the PU-based hydroxyl-terminated polyester has been characterized. Next, an IPN (Epoxy–PU) has been prepared and characterized using Fourier transform infrared (FTIR) spectroscopy, thin-layer chromatography (TLC), and scanning electron microscopy (SEM) prior to mechanical testing in terms of impact strength and toughness. In this study, a Desmophen 1200-based PU prepolymer was used as a modifier at different concentrations within the epoxy resin. The results also showed that, further to the IPN formation, the epoxy and the PU prepolymer reacted chemically (via grafting). Compared to virgin resin, the effect on the mechanical properties was minor. The impact strength varies from 3–9 J/m and Kc from 0.9–1.2 MPa m1/2. Furthermore, the incorporation of a chain extender with the PU prepolymer as a modifier into the mixture caused a drastic improvement in toughness. The impact strength increases continuously and reaches a maximum value (seven-fold that of virgin resin) at a modifier critical concentration (40 phr). Kc reaches 2.5 MPa m1/2 compared to 0.9 MPa m1/2 of the virgin resin. Finally, the SEM analysis results suggested that internal cavitation of the modifier particles followed by localized plastics shear yielding is probably the prevailing toughening mechanism for the epoxy resin considered in the present study. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 2603–2618, 1998 相似文献
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采用超支化聚酯Boltorn H 20与丁二酸酐反应,制备了亲水性超支化聚酯,然后与甲基丙烯酸酯基改性的聚醚基聚氨酯预聚体和3-异氰酸酯基丙基三乙氧基硅烷(IPTS)反应,合成了有机硅烷偶联剂改性紫外光固化聚醚基超支化水性聚氨酯(WHPU)。考察了有机硅烷偶联剂用量对WHPU的耐酸性、固化时间、凝胶质量分数、附着力、水接触角、水吸附率、乳液粒径分布及热稳定性的影响。结果表明,当IPTS与Boltorn H 20中羟基的摩尔比为6/16时,固化后的WHPU膜的凝胶质量分数为92%,在玻璃表面的附着力达到0级;与不含有机硅烷偶联剂的WHPU相比,该涂膜的水接触角和热稳定性分别提高了34°和22℃,其吸水率从13.8%降低到4.3%。 相似文献
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