Tb对Ni50Mn29Ga21合金的组织和磁感生应变的影响

运用X光衍射的方法研究了稀土元素Tb对形状记忆合金Ni50Mn29Ga21金相组织的影响.结果表明,稀土元素Tb的加入可以明显地减小合金的晶粒尺寸,提高马氏体在合金中的含量,但是也使得合金的磁感生应变在经历一段上升后发生回落.     

Ni52Mn24.5Ga23.5单晶的磁感生应变及孪晶界移动的能量损耗

测量了不同温度下Ni52Mn24.5Ga23.5单晶的磁感生应变。温度在280 K（略低于马氏体相变完成温度）时,测量得到的磁感生应变量高达-1.2%;随着温度的降低,磁感生应变量会迅速减小;在250 K的温度下,磁感生应变量仅为-0.37%,结果说明：铁磁形状记忆合金NiMn-Ga材料的磁感生应变具有明显的温度依赖性。此外,根据热力学理论,计算了在不同温度下,1个循环（升、降磁场）磁感生应变过程中孪晶界移动的能量损耗,结果表明：同种样品、不同温度下的磁感生应变量可定性地反映一个循环过程中孪晶界移动的能量损耗的大小。     

Influence of stresses on martensitic transformation in ferromagnetic shape memory Ni_(50)Mn_(19)Fe_6Ga_(25) ribbons

~~Influence of stresses on martensitic transformation in ferromagnetic shape memory Ni_(50)Mn_(19)Fe_6Ga_(25) ribbons1. Ullakko, K., Huang, J. K., O'Handley, R. C. et al., Large magnetic-field-induced strains in Ni2MnGa single crystals, Appl. Phys. Lett., 1996, 69(13): 1966-1968. 2. James, R. D., Wuttig, M., Magnetostriciton of martensite, Philos. Mag., 1998, A 77: 1273-1275. 3. Wu, G. H., Yu, C. H., Meng, L. Q. et al., Giant magnetic-field-induced strains in H…     

加热速度对Cu－Zn－Al－Mn淬火态合金马氏体逆相变的影响

用直流电阻法对Ｃｕ－Ｚｎ－Ａｌ－Ｍｎ淬火态试样在不同加热速度下的马氏体逆相变进行了研究．结果表明，加热速度对Ｃｕ－Ｚｎ－Ａｌ－Ｍｎ水淬及油淬试样的逆相变有较大的影响，尤其对水淬试样，加热速度慢到一定程度可以阻止马氏体逆相变的发生，或者使逆相变中出现反向过程，即ＤＯ３→ＭＩ８Ｒ转变．在慢速加热时，同时存在着马氏体时效及母相时效两种时效作用，加热速度越慢，这两种时效作用影响越大，从而使马氏体逆相变表现出对加热速度的敏感性．     

Simulation of transformation mechanism of martensites in Ni62.5Al37.5 alloy

Thermally induced L1₀ martensitic transformation in an ordered B2 Ni_62.5 Al_37.5 alloy has been studied by using molecular dynamics computer simulations and embedded atorn method (EAM) potential. The nucleation mechanism and growth process of martensites were investigated by analyzing the difference between the lattice vibrational properties, strain distributions in transforming and non-transforming regions. The effect of the difference between vibrational properties of Ni and Al atoms on the transformation was discussed.     

Influence of Tb substitution on low-field magnetocaloric effect in Gd5Si1.72Ge2.28 alloy

The lattice parameters, magnetic phase transition, Curie temperature and magnetocaloric properties for (Gd1-xTbx)5Si1.72-Ge2.28 alloys with x = 0, 0.15, 0.20 and 0.25 were investigated by X-ray powder diffractometry and magnetization measurements. The results show that suitable partial substitution of Tb in Gd5Si1.72Ge2.28 compound remains the first-order magnetic-crystallographic transition and enhances the magnetic entropy change, although Tb substitution decreases the Curie temperature (Tc) of the compounds. The magnetic entropy change of (Gd1-xTbx)5Si1.72Ge2.28 alloys retains a large value in the low magnetic field of 1.0 T.The maximum magnetic entropy change for (Gd0.80Tb0.20)5Si1.72Ge2.28 alloy in the magnetic field from 0 to 1.0 T reaches 8.7 J/(kg·K),which is nearly 4 times as large as that of (Gd0.3Dy0.7)5Si4 compound (|△Smax| = 2.24 J/(kg·K), TC = 198 K).     

Simulation of transformation mechanism of martensites in Ni_(62.5)Al_(37.5) alloy

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Influence of Tb substitution on low-field magnetocaloric effect in Gd5Si1.72Ge2.28 alloy

The lattice parameters, magnetic phase transition, Curie temperature and magnetocaloric properties for (Gd_1−x Tb _x )₅Si_1.72-Ge_2.28 alloys with x = 0, 0.15, 0.20 and 0.25 were investigated by X-ray powder diffractometry and magnetization measurements. The results show that suitable partial substitution of Tb in Gd₅Si_1.72Ge_2.28 compound remains the first-order magnetic-crystallographic transition and enhances the magnetic entropy change, although Tb substitution decreases the Curie temperature (T _C) of the compounds. The magnetic entropy change of (Gd_1−x Tb _x )₅Si_1.72Ge_2.28 alloys retains a large value in the low magnetic field of 1.0 T. The maximum magnetic entropy change for (Gd_0.80Tb_0.20)₅Si_1.72Ge_2.28 alloy in the magnetic field from 0 to 1.0 T reaches 8.7 J/(kg·K), which is nearly 4 times as large as that of (Gd_0.3Dy_0.7)₅Si₄ compound (|ΔS _max| = 2.24 J/(kg·K), T _C = 198 K). Foundation item: Project (50371058) supported by the National Natural Science Foundation of China     

稀土在镁合金中的应用

镁合金材料具有高的比强度、优异的阻尼减震、密度小等特性,是非常理想的轻质结构材料;但是,镁合金熔炼时极易燃烧,耐热性、耐腐蚀性差等问题严重制约了镁合金的开发和广泛应用．浅述了稀土在镁合金材料开发中的应用,通过分析金相图,研究了稀土-镁合金体系和多元Re—Mg合金体系的特点,讨论了稀土镁合金耐热性能的影响机理和稀土耐热镁合金的时效析出物。并对稀土阻燃镁合金研究现状进行了概括和总结．     

Phase transformation behaviors and shape memory effects of TiNiFeAl shape memory alloys

Measurements of electrical resistivity, X-ray diffraction, and tensile test at room temperature and ?196°C were performed to investigate the effects of Al addition substituting Ni on the phase transformation behaviors, the mechanical properties, and the shape memory effects of Ti50Ni47Fe2Al1 and Ti50Ni46.5Fe2.5Al1 alloys. It is found that 1at% Al addition dramatically decreases the martensitic start transformation temperature and expands the transformation temperature range of R-phase for TiNiFeAl alloys. The results of tensile test indicate that 1at% Al improves the yield strength of Ti50Ni47Fe2Al1 and Ti50Ni46.5Fe2.5Al1 alloys by 40% and 64%, but de- creases the plasticity to 11% and 12% from 26% and 27% respectively. Moreover, excellent shape memory effect of 6.6% and 7.5% were found in Ti50Ni47Fe2Al1 and Ti50Ni46.5Fe2.5Al1 alloys, which results from the stress-induced martensite transformation from the R-phase.     

稀土元素Nd在热挤压AZ61镁合金中的作用

为了确定稀土元素Nd对热挤压AZ61镁合金显微组织和力学性能的影响，利用光学显微镜对不同含Nd量的AZ61+Nd镁合金进行了显微组织观察，并通过进行位移控制的拉伸试验测定了合金的室温和高温拉伸性能.结果表明，当热挤压AZ61+Nd镁合金中的Nd含量为0.5%时，其晶粒最细，力学性能最佳；随着Nd含量的增加，热挤压AZ61+Nd镁合金的强度有所降低，而伸长率则呈现先升高后降低的变化趋势；随着实验温度的升高，热挤压AZ61+Nd镁合金的抗拉强度和屈服强度均呈降低趋势，而伸长率则呈增加趋势.