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1.
All RF sputtering-deposited Pt/SiO2/n-type indium gallium nitride (n-InGaN) metal–oxide–semiconductor (MOS) diodes were investigated before and after annealing at 400 °C. By scanning electron microscopy (SEM), the thickness of Pt, SiO2, n-InGaN layer was measured to be ~250, 70, and 800 nm, respectively. AFM results also show that the grains become a little bigger after annealing, the surface topography of the as-deposited film was smoother with the rms roughness of 1.67 nm and had the slight increase of 1.92 nm for annealed sample. Electrical properties of MOS diodes have been determined by using the current–voltage (IV) and capacitance–voltage (CV) measurements. The results showed that Schottky barrier height (SBH) increased slightly to 0.69 eV (IV) and 0.82 eV (CV) after annealing at 400 °C for 15 min in N2 ambient, compared to that of 0.67 eV (IV) and 0.79 eV (CV) for the as-deposited sample. There was the considerable improvement in the leakage current, dropped from 6.5×10−7 A for the as-deposited to 1.4×10−7 A for the 400 °C-annealed one. The annealed MOS Schottky diode had shown the higher SBH, lower leakage current, smaller ideality factor (n), and denser microstructure. In addition to the SBH, n, and series resistance (Rs) determined by Cheungs׳ and Norde methods, other parameters for MOS diodes tested at room temperature were also calculated by CV measurement.  相似文献   

2.
By employing electric-field-induced optical second-harmonic generation (EFISHG) measurement, we studied the blocking effect of sandwiched Cu-phthalocyanine (CuPc) layer on IZO/pentacene/Cu-phthalocyanine (CuPc)/C60/Al organic solar cells (OSCs). Results evidently showed that the Maxwell–Wagner type interfacial charging appears at both pentacene/CuPc and CuPc/C60 interfaces, depending on the CuPc layer thickness. When the thickness of CuPc layer was 8 nm, the charging at the two interfaces was significantly suppressed and the IV characteristic was improved. CuPc layer is available as a blocking layer for the regulation of interfacial charging induced in IZO/pentacene/C60/Al organic solar cells (OSCs). The blocking effect of the CuPc layer was discussed on the basis of Maxwell–Wagner model analysis.  相似文献   

3.
This work presents the effect of varied thickness of oxide layer and radiation dose on electrical characteristics of Ag/SiO2/Si MOS devices irradiated by 1.5 MeV γ–radiations of varied doses. SiO2 layers of 50, 100, 150 and 200 nm thickness were grown on Si substrates using dry oxidation and exposed to radiation doses of 1, 10 and 100 kGy. The exposure to radiation resulted in generation of fixed charge centers and interface traps in the SiO2 and at the Si/SiO2 interface. Capacitance-conductance-voltage (C-G-V) and capacitance-conductance-frequency (C-G-f) measurements were performed at room temperature for all MOS devices to quantify the active traps and their lifetimes. It is shown that accumulation and minimum capacitances decreased as the thickness of SiO2 layer increased. For the unexposed MOS devices, the flat band voltage VFB decreased at a rate of −0.12 V/nm, density of active traps increased by 4.5 times and depletion capacitance CDP, increased by 2.5 times with the increase of oxide layer thickness from 50 to 200 nm. The density of active traps showed strong dependence on the frequency of the applied signal and the thickness of the oxide layer. The MOS device with 200 nm thick oxide layer irradiated with 100 kGy showed density of active interface traps was high at 50 kHz and was 3.6×1010 eV−1 cm−2. The relaxation time of the interface traps also increased with the exposure of γ–radiation and reached to 9.8 µs at 32 kHz in 200 nm thick oxide MOS device exposed with a dose of 100 kGy. It was inferred that this was due to formation of continuum energy states within the band gap and activation of these defects depended on the thickness of oxide layer, applied reverse bias and the working frequency. The present study highlighted the role of thickness of oxide layer in radiation hard environments and that only at high frequency, radiation induced traps remain passivated due to long relaxation times.  相似文献   

4.
We investigated the effect of active layer thickness on recombination kinetics of poly[N-9″-hepta-decanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)] (PCDTBT) and [6,6]-phenyl C71-butyric acid methyl ester (PC71BM) based solar cells. Analysis of the fitted Lambert W-function of illuminated current density–voltage (JV) characteristics revealed increased recombination processes with increased active layer thicknesses. The ideality factor extracted from PCDTBT:PCBM solar cells continuously increased from 1.89 to 3.88 when photoactive layer thickness was increased from 70 to 150 nm. We found that such increase in ideality factor is closely related to the defect density which is increased with increased photoactive layer thickness beyond 110 nm. Therefore, the different density of defect states in PCDTBT:PCBM solar cells causes the different recombination paths where solar cells with a thicker active layer (?110 nm) are considered to undergo coupled trap-assisted recombination processes while single-defect trap-assisted recombination is dominant for thinner (70–90 nm) PCDTBT:PCBM solar cells. As a result, we found that the optimal efficiencies of PCDTBT:PC71BM solar cells were limited to the active layers between 70 and 90 nm. Particularly, when PCDTBT:PC71BM solar cells were optimized with an active layer thickness of 70 nm, energy conversion efficiency reached 6.5% while an increase in thickness led to the reduction of efficiency to 4.7% at 133 nm but then an increase to 5.02% at 150 nm.  相似文献   

5.
Cd1−xZnxS thin films were grown on soda–lime glass substrates by chemical-bath deposition (CBD) at 80 °C with stirring. All the samples were annealed at 200 °C for 60 min in the air. The crystal structure, surface morphology, thickness and optical properties of the films were studied with transmission electron microscopy (TEM), X-ray diffraction (XRD), scanning electron microscopy (SEM), step height measurement instrument and spectrophotometer respectively. The results revealed that Cd1−xZnxS thin films had cubic crystal structure and the intensity of the diffraction peak increased gradually as ammonia concentration rose and the grain size varied from 5.1 to 8.3 nm. All of Cd1−xZnxS thin films had a granular surface with some smaller pores and the average granule sizes increased from 92 to 163 nm with an increase in ammonia concentration. The Cd1−xZnxS thin films had the highest transmittance with ammonia concentration of 0.5 M L−1, whose thickness was 50 nm and band gap was 2.62 eV.  相似文献   

6.
A new multi-recessed 4H-SiC MESFET with recessed metal ring for RF embedded circuits is proposed (MR2-MESFET). The key idea in the proposed structure is based on the elimination of the spaces adjacent to gate and stopped the depletion region extending towards drain and source and the reduction of the channel thickness between gate and drain to increase breakdown voltage (VBR); meanwhile the elimination of the gate depletion layer extension to source/drain to decrease gate-source capacitance (Cgs). The influence of multi-recessed drift region and recessed metal ring structures on the characteristics of the MR2-MESFET is studied by numerical simulation. The optimized results show that the VBR of the MR2-MESFET is 119% larger than that of the conventional 4H–SiC MESFET (C-MESFET); meanwhile maintain 85% higher saturation drain current. Therefore, the maximum output power density of the MR2-MESFET is 23.1 W/mm compared to 5.5 W/mm of the C-MESFET. Also, the cut-off frequency (fT) and the maximum oscillation frequency (fmax) of 24.9 and 91.7 GHz are obtained for the MR2-MESFET compared to 11 and 40 GHz of the C-MESFET structure, respectively. The proposed MR2-MESFET shows a maximum stable gain (MSG) exceeding 23.6 dB at 3.1 GHz which is the highest gain yet reported for SiC MESFETs, showing the potential of this device for high power RF applications.  相似文献   

7.
This article reports on the epitaxy of crystalline high κ oxide Gd2O3 layers on Si(1 1 1) for CMOS gate application. Epitaxial Gd2O3 thin films have been grown by Molecular Beam Epitaxy (MBE) on Si(1 1 1) substrates between 650 and 750 °C. The structural and electrical properties were investigated depending on the growth temperature. The CV measurements reveal that equivalent oxide thickness (EOT) equals 0.7 nm for the sample deposited at the optimal temperature of 700 °C with a relatively low leakage current of 3.6 × 10?2 A/cm2 at |Vg ? VFB| = 1 V.  相似文献   

8.
For thin Bi films with thicknesses d=10–60 nm the dependences of the Hall coefficient, Seebeck coefficient, electrical conductivity, and Hall carrier mobility on d have been obtained at room temperature. Distinct oscillations of the transport properties with period Δd=(5±1) nm have been observed in the thickness range d=25–60 nm and attributed to quantization of the energy spectrum of holes. It has been suggested that a deep minimum observed in the thickness dependences of the kinetic coefficients at d~25 nm is connected with the manifestation of the electronic spectrum quantization and/or manifestation of a semimetal–semiconductor transition. The experimental data are in good agreement with the results of theoretical calculations.  相似文献   

9.
This paper describes a simple method utilizing electrophoretic deposition (EPD) of commercial P25 nanoparticles (NPs) films on fluoride-doped tin oxide (FTO) substrate. In this process, voltage and the number of deposition cycles are well controlled to achieve TiO2 film thickness of around 1.5–26 μm, without any mechanical compression processing. The experimental results indicate that the TiO2 film thickness plays an important role as the photoelectrode in DSSCs because it adsorbs a large number of dye molecules which are responsible for electrons supply. Furthermore, it was found that effects of the bulk traps and surface states within the TiO2 films on the recombination of the photo-injected electrons (electron–hole pairs) strongly depend on the TiO2 electrode annealing temperature. Finally, a DSSC with a 24 μm thick TiO2 film and annealed at 500 °C produced the highest conversion efficiency (η=6.56%, ISC=16.4, VOC=0.72, FF=0.55) with an incident solar energy of 100 mW/cm2.  相似文献   

10.
We report on the fabrication and electrical characterization of deep sub-micron (gate length down to 105 nm) GeOI pMOSFETs. The Ge layer obtained by hetero-epitaxy on Si wafers has been transferred using the Smart CutTM process to fabricate 200 mm GeOI wafers with Ge thickness down to 60–80 nm. A full Si MOS compatible pMOSFET process was implemented with HfO2/TiN gate stack. The electrical characterization of the fabricated devices and the systematic analysis of the measured performances (ION, IOFF, transconductance, low field mobility, S, DIBL) demonstrate the potential of pMOSFET on GeOI for advanced technological nodes. The dependence of these parameters have been analyzed with respect to the gate length, showing very good transport properties (μh  250 cm2/V/s, ION = 436 μA/μm for LG = 105 nm), and OFF current densities comparable or better than those reported in the literature.  相似文献   

11.
We have fabricated an improved organic photovoltaic (OPV) cell in which organic heterointerface layer is inserted between indium-tin-oxide (ITO) anode and copper-phthalocyanine (CuPc) donor layer in the conventional OPV cell of ITO/CuPc/fullerene (C60)/bathophenanthroline (Bphen)/Al to enhance the power conversion efficiency (PCE) and fill factor (FF). The inserted ITO-buffer layer consists of electron-transporting layer (ETL) and hole-transporting layer (HTL). We have changed the ETL and HTL materials variously and also changed their layer thickness variously. It is confirmed that ETL materials with higher LUMO level than the work function of ITO give low PCE and FF. All the double layer buffers give higher PCE than a single layer buffer of TAPC. The highest PCE of 1.67% and FF of 0.57% are obtained from an ITO buffer consisted of 3 nm thick ETL of hexadecafkluoro-copper-phthalocyanine (F16CuPc) and 3 nm thick HTL of 1,1-bis-(4-methyl-phenyl)-aminophenylcyclohexane (TAPC). This PCE is 1.64 times higher than PCE of the cell without ITO buffer and 2.98 times higher than PCE of the cell with single layer ITO buffer of TAPC. PCE is found to increase with increasing energy difference (ΔE) between the HOMO level of HTL and LUMO level of F16CuPc in a range of ΔE < 0.6 eV. From the ΔE dependence of PCE, it is suggested that electrons moved from ITO to the LUMO level of the electron-transporting F16CuPc are recombined, at the F16CuPc/HTL-interface, with holes transported from CuPc to the HOMO level of HTL in the double layer ITO buffer ETL, leading to efficient extraction of holes photo-generated in CuPc donor layer.  相似文献   

12.
We have investigated the semiconducting and photoelectrochemical properties of SnO films grown potentiostatically on tin substrate. The oxide is characterized by X-ray diffraction, scanning electron microscopy and Raman spectroscopy. The anodic process corresponds to the formation of SnO·nH2O pre-passive layer that is removed upon increasing potential due to surface etching at the metal/oxide interface. SnO films deposited for long durations (>50 mn) are uniform and well adhered; they thicken up to ~50 nm by diffusion-controlled process and the growth follows a direct logarithmic law. The thickness is determined by coulometry and the X-ray diffraction indicates the tetragonal SnO phase (SG: P4/mmm) with a crystallite size of 32 nm. The Mott–Schottky plot is characteristic of n type conductivity with an electrons density of 5.72×1018 cm−3, a flat band potential of −0.09 VSCE and a depletion width of ~10 nm. The valence band, located at 5.91 eV below, vacuum is made up of hybridized O2−:2p Sn2+:5s while the conduction band (4.45 eV) derives from Sn2+:5p orbital. The electrochemical impedance spectroscopy (EIS) measured in the range (10−2–105 Hz) shows the contribution of the bulk and grain boundaries. The energy band diagram predicts the photodegradation of methylene blue on SnO films. 67% of the initial concentration (10 mg L−1) disappears after 3 h of exposure to visible light (9 mW cm−2) with a quantum yield of 0.072.  相似文献   

13.
Gallium arsenide diodes with and without indium arsenide quantum dots were electron irradiated to investigate radiation induced defects. Baseline and quantum dot gallium arsenide pn-junction diodes were characterized by capacitance–voltage measurements, and deep level transient spectroscopy. Carrier accumulation was observed in the gallium arsenide quantum dot sample at the designed depth for the quantum dots via capacitance–voltage measurements. Prior to irradiation, a defect 0.84 eV below the conduction band (EC – 0.84 eV) was observed in the baseline sample which is consistent with the native EL2 defect seen in gallium arsenide. After 1 MeV electron irradiation three new defects were observed in the baseline sample, labeled as E3 (EC – 0.25 eV), E4 (EC – 0.55 eV), and E5 (EC – 0.76 eV), consistent with literature reports of electron irradiated gallium arsenide. Prior to irradiation, the addition of quantum dots appeared to have introduced defect levels at EC – 0.21, EC – 0.38, and EC – 0.75 eV denoted as QD–DX1, QD–DX2, and QD–EL2 respectively. In the quantum dot sample after 1 MeV electron irradiation, QD–E3 (EC – 0.28 eV), QD–E4 (EC – 0.49 eV), and QD–EL2 (EC – 0.72 eV) defects, similar to the baseline sample, were observed, although the trap density was dissimilar to that of the baseline sample. The quantum dot sample showed a higher density of the QD–E4 defect and a lower density of QD–E3, while the QD–EL2 defect seemed to be unaffected by electron irradiation. These findings suggest that the quantum dot sample may be more radiation tolerant to the E3 defect as compared to the baseline sample.  相似文献   

14.
Using extensive numerical analysis we investigate the impact of Sn ranging 0–6% in compressively strained GeSn on insulator (GeSnOI) MOSFETs for mixed-mode circuit performance at channel lengths (Lg) ranging 100–20 nm with channel thickness values of 10 and 5 nm. Our results reveal that 10 nm thick Ge0.94Sn0.06 channel MOSFETs produce improvement of peak transconductance gm, peak gain Av, peak cut-off frequency fT and maximum frequency of oscillations fmax by 80.5%, 18.8%, 83.5% and 81.7%, respectively compared with equivalent GeOI device at Lg =20 nm. Furthermore, such devices exhibit 78.8% increase in ON-current ION while yield 44.5% reduction in delay as compared to Ge control devices enabling them attractive for logic applications. Thinning of the channel thickness from 10 to 5 nm increases peak Av, peak transconductance efficiency and reduces output conductance and OFF-current IOFF while degrading other parameters in all GeSnOI and control Ge devices.  相似文献   

15.
Engineering and controlling the bandgap of semiconducting metal oxide (TiO2) to enhance photoactivity under visible light is challenging. Impact of the changing CdS thickness (50–150 nm) on the structure and optical properties of the CdS/TiO2 heterostructure films (HSFs) which fabricated by pulsed laser deposition (PLD) was observed. XRD, FE-SEM, AFM, UV–vis and PL spectroscopy measurements were utilized to characterize structural and optical behaviors of the films. XRD measurement shows gradual increments of the lattice constants of the films with the increase of CdS thickness. The mean values of the calculated lattice constants and cell volume (V) were a=b=0.3785 nm, c=0.9475 nm and V=13.58 nm3 respectively. The average of crystallite sizes estimated for TiO2 and CdS/TiO2 at various CdS thickness is 12.20, 13.49, 24.24 and 43.10 nm. FESEM images prove the high quality nanocrystalline nature of the films without cracks and dislocation. The root means square roughness of the films was increased with the increase of CdS thickness as showed by AFM images. UV–vis measurement reveals an improvement in the optical absorbance of HSFs in the range of 380–550 nm due to presence of CdS. Interestingly, the PL intensity was enhanced by a factor of nineteen compare to pure TiO2 attributed to the charge carrier recombination in the band gap. The current results suggest that possibility to improve the optical and structural properties of the TiO2 films and also it possible to fabricate high quality CdS/TiO2 HSFs by variation of the CdS thickness.  相似文献   

16.
In this work, we examine the optical properties of tin naphthalocyanine dichloride (SnNcCl2), and its performance as an electron donor material in organic photovoltaic cells (OPVs). As an active material, SnNcCl2 is attractive for its narrow energy gap which facilitates optical absorption past a wavelength of λ = 1100 nm. We demonstrate a power conversion efficiency of ηP = (1.2 ± 0.1)% under simulated AM1.5G solar illumination at 100 mW/cm2 using the electron donor–acceptor pairing of SnNcCl2 and C60 in a bilayer device architecture. While some phthalocyanines have been previously used to improve infrared absorption, this is often realized through the formation of molecular dimers. In SnNcCl2, the infrared absorption is intrinsic to the molecule, arising as a result of the extended conjugation. Consequently, it is expected that SnNcCl2 could be utilized in bulk heterojunction OPVs without sacrificing infrared absorption.  相似文献   

17.
The electrical analysis of Ni/n-GaP structure has been investigated by means of current–voltage (IV), capacitance–voltage (CV) and capacitance–frequency (Cf) measurements in the temperature range of 120–320 K in dark conditions. The forward bias IV characteristics have been analyzed on the basis of standard thermionic emission (TE) theory and the characteristic parameters of the Schottky contacts (SCs) such as Schottky barrier height (SBH), ideality factor (n) and series resistance (Rs) have been determined from the IV measurements. The experimental values of SBH and n for the device ranged from 1.01 eV and 1.27 (at 320 K) to 0.38 eV and 5.93 (at 120 K) for Ni/n-GaP diode, respectively. The interface states in the semiconductor bandgap and their relaxation time have been determined from the Cf characteristics. The interface state density Nss has ranged from 2.08 × 1015 (eV?1 m?2) at 120 K to 2.7 × 1015 (eV?1 m?2) at 320 K. Css has increased with increasing temperature. The relaxation time has ranged from 4.7 × 10?7 s at 120 K to 5.15 × 10?7 s at 320 K.  相似文献   

18.
《Organic Electronics》2008,9(2):171-182
Two novel iridium complexes both containing carbazole-functionalized β-diketonate, Ir(ppy)2(CBDK) [bis(2-phenylpyridinato-N,C2)iridium(1-(carbazol-9-yl)-5,5-dimethylhexane-2,4-diketonate)], Ir(dfppy)2(CBDK) [bis(2-(2,4-difluorophenyl)pyridinato-N,C2)iridium(1-(carbazol-9-yl)-5,5-dimethylhexane-2,4-diketonate)] and two reported complexes, Ir(ppy)2(acac) (acac = acetylacetonate), Ir(dfppy)2(acac) were synthesized and characterized. The electrophosphorescent properties of non-doped device using the four complexes as emitter, respectively, with a configuration of ITO/N,N′-diphenyl-N,N′-bis(1-naphthyl)-1,1′-diphenyl-4,4′-diamine (NPB) (20 nm)/iridium complex (20 nm)/2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) (5 nm)/tris(8-hydroxyquinoline)aluminum (AlQ) (45 nm)/Mg0.9Ag0.1 (200 nm)/Ag (80 nm) were examined. In addition, a most simplest device, ITO/Ir(ppy)2(CBDK) (80 nm)/Mg0.9Ag0.1 (200 nm)/Ag (80 nm), and two double-layer devices with configurations of ITO/NPB (30 nm)/Ir(ppy)2(CBDK) (30 nm)/Mg0.9Ag0.1 (200 nm)/Ag (80 nm) and ITO/Ir(ppy)2(CBDK) (30 nm)/AlQ (30 nm)/Mg0.9Ag0.1 (200 nm)/Ag (80 nm) were also fabricated and examined. The results show that the non-doped four-layer device for Ir(ppy)2(CBDK) achieves maximum lumen efficiency of 4.54 lm/W and which is far higher than that of Ir(ppy)2(acac), 0.53 lm/W, the device for Ir(dfppy)2(CBDK) achieves maximum lumen efficiency of 0.51 lm/W and which is also far higher than that of Ir(dfppy)2(acac), 0.06 lm/W. The results of simple devices involved Ir(ppy)2(CBDK) show that the designed complex not only has a good hole transporting ability, but also has a good electron transporting ability. The improved performance of Ir(ppy)2(CBDK) and Ir(dfppy)2(CBDK) can be attributed to that the bulky carbazole-functionalized β-diketonate was introduced, therefore the carrier transporting property was improved and the triplet–triplet annihilation was reduced.  相似文献   

19.
High-quality YBa2Cu3O7?δ/La2/3Ca1/3MnO3 (YBCO/LCMO) bilayers were fabricated on (0 0 1)-oriented SrTiO3 (STO) substrates by dc-sputtering technique. Bottom layer was always LCMO since it grows better on STO than on YBCO. The thickness of the ferromagnetic layer varied between 5 and 35 monolayers (~2–13 nm) and that of the top YBCO was fixed at 10 monolayers (~12 nm). The transport properties of the YBCO layers as well as the magnetic properties of the LCMO counterparts were studied as a function of the LCMO layer thickness. A sizeable depression of the Curie temperature (TC) of the LCMO layers from the bulk to lower temperatures is observed when decreasing their layer thickness dLCMO, which might be ascribed to intrinsic dimensionality effects or strain-induced phenomena. On the contrary, the superconducting critical temperature of the YBCO layer TS displays a sudden strong decrease at a critical LCMO thickness of ~12 nm. Since no dramatic change of the structural and morphological quality of the YBCO top layers with increasing dLCMO is observed, the suppression of TS of the YBCO layers should take place via proximity effect due to the increasing magnetization strength in the LCMO layer. However, extrinsic factors like interface strain, interdiffusion of cations between YBCO and LCMO or injection of spin-polarized carriers from the magnetic into the superconducting layer could also play an important role or even to be directly responsible for the observed depressed TS.  相似文献   

20.
《Microelectronics Reliability》2014,54(9-10):1883-1886
Hot carrier (HC) injection, inducing drain and gate leakage current increase in 5 nm oxide p-channel LDMOS transistors, is investigated. Devices with two different drain implants are studied. At low gate voltage (VGS) and high drain voltage (VDS), reduction of the ON-resistance (RON) is observed. At stress times at which RON almost reaches its constant level, an increase of the drain leakage in OFF state (VDS = −60 V, VGS = 0 V) is observed. Longer stress time leads to increased gate leakage and in some cases oxide breakdown. In contrast to what was reported for devices with 25 nm gate oxide thickness, the threshold voltage of 5 nm gate oxide PLDMOS transistors does not drift. The experimental data can be fully explained by hot carrier injection and the oxide damage can be explained by two different and competing degradation mechanisms. By combining experimental data and TCAD simulations we are further capable to locate the hot spot of maximum oxide damage in the accumulation (Acc) region of the PLDMOS.  相似文献   

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