Sr1-xLaxFe12-xCoxO19铁氧体纳米颗粒的结构与磁性

利用溶胶-凝胶法制备出性能优良的Sr1-xLaxFe12-xCoxO19(x=0～0.5)铁氧体,研究了La、Co掺杂量对铁氧体结构和磁学性能的影响.XRD 结果显示,对x≤0.3样品均得到单一的M相,而x=0.4样品出现了CoFe2O4相,x=0.5样品出现了CoFe2O4相和LaFeO3相.VSM结果显示,在适当的代换量(x=0～0.2)范围,剩余磁感应强度增加,同时矫顽力也增加.x=0.2样品的Br、H-c和?s最大值分别为449mT、562.5 kA/m和68 Am2/kg,与未掺杂样品相比,La3+、Co2+的加入能明显提高样品的综合磁性能.     

Y2O3掺杂ZnO-Bi2O3压敏瓷的显微组织和电性能

为了提高氧化锌压敏瓷的综合电性能,采用高能球磨制备Y2O3掺杂ZnO压敏瓷,通过扫描电镜和X射线衍射对其显微组织和相成分进行了分析,探讨了Y2O3对氧化锌压敏瓷电性能和显微组织影响机理。结果表明,Y2O3掺杂摩尔分数在0～1.00%时,压敏瓷的电位梯度为332～597V/mm,非线性系数为23.6～40.1,漏电流为0.06～0.90μA。当Y2O3掺杂摩尔分数为0.60%时氧化锌压敏瓷的综合电性能最好,压敏瓷电位梯度为482V/mm,非线性系数为35,漏电流为0.17μA。掺杂Y2O3使压敏瓷晶粒细化是由于Y2O3或者单独以Y2O3氧化物形式存在,钉扎在晶界,阻碍晶粒长大;或者与Bi2O3固溶形成含Y的富铋相,使Bi2O3促进晶粒生长的作用受到抑制。     

Li(4-x/3)YxTi(5-2x/3)O12/C的合成及电化学性能研究

以氧化钇为Y3+的掺杂源,以蔗糖或导电炭黑为碳源,对Li4Ti5O12同时进行离子掺杂和碳掺杂,采用高温固相法合成负极复合材料Li(4-x/3)YxTi(5-2x3)O/12/C(x=0.1).重点考察了Y掺杂、Y和碳协同掺杂,以及不同碳源对该复合材料形貌、粒径和电化学性能的影响.结果表明:使用蔗糖为碳源合成的复合材料Li(4-x/3)YxTi(5-2x/3)O12(x=0.1)体现了相对较好的倍率性能和循环稳定性,在0.15 C、0.40 C、0.70 C、1.40 C和3.30 C下材料首次放电比容量分别为150.4、144.5、144.5、140.8和116.9 mAh/g,3.3 C下循环10次后容量仍保持为116.7 mAh/g.电化学交流阻抗表明,使用蔗糖为碳源合成的复合材料Li(4-x/3)YxTi(5-2x/3)O12的阻抗从纯Li4Ti5O12的912.5Ω降低到227.7 Ω.     

Cr_2O_3修饰Li_4Ti_5O_(12)的制备及电化学性能

采用湿法球磨工艺和热处理制备三氧化二铬(Cr2O3)修饰钛酸锂(Li4Ti5O12)材料。Cr2O3修饰后,Li4Ti5O12的XRD图中没有出现杂质峰。Cr2O3修饰可提高Li4Ti5O12在高倍率下的容量保持率和循环性能。Li4Ti5O12-1.5%Cr2O3材料的倍率性能和循环性能最好,以5.0 C在1.0~2.5 V充放电,第500次循环的放电比容量为122.8 m Ah/g,容量保持率为96.2%;纯相Li4Ti5O12分别为48.3 m Ah/g、81.1%。Cr2O3修饰降低了Li4Ti5O12的电荷转移阻抗,提高了材料的电化学活性。     

Fe含量对Ca-La-Co联合取代M型锶铁氧体性能的影响

采用传统陶瓷法制备了Ca-La-Co联合取代的M型锶铁氧体.为补偿球磨掉入的铁,通过降低Fe含量(相对理论正分)研究了Fe2O3/SrO摩尔比n对材料磁性能的影响.通过X射线衍射分析仪、场发射扫描电镜、永磁材料自动测试仪表征不同Fe含量样品的成分、结构、微观形貌和磁性能.结果表明:降低Fe含量可抑制α-Fe2O3,并有效提高材料的剩磁、矫顽力和最大磁能积等性能.Ca-La-Co联合取代的M型锶铁氧体Sr0.5La0.3Ca0.2FexCo0.3O19(x=11.3～11.7),Fe含量x=11.4时性能最好,Br=430 mT,Hcb=324 kA/m,Hcj=380 kA/m,(BH)max=35.2 kJ/m3,与未进行铁补偿的理论摩尔比n=6(x=12)的磁体相比,性能分别提高了5.39％、4.52％、2.15％和5.39％.     

ViCo0.98-xTi0.02LaxO2的高温固相法合成及其电化学性能

以Li2CO3、Co3O4为原料,采用高温囿相法制备了钮离子电池正极材料LiCo0.98-xTi0.02LaxO2(x=0,0.01,0.03,0.05).采用扫描电镜(SEM)、恒流充放电研究了材料的表面形貌和电化学性能,结果表明:掺杂La后材料的D50略有增大,放电平台电压升高;在2.75～4.20 V电位范围内,LiCo0.97Ti0.02La0.01O2的首次1 C放电比容量达到143.86 mAh/g,50次循环后容量保持率为97.0%,且具有很好的倍率性能.     

溶胶-凝胶法制备La1-xSrxCoO3-δ导电陶瓷

采用溶胶-凝胶法制备了单相的La1-xSrxCoO3-δ系列导电陶瓷,对其结构性能进行了表征,并探讨了La1-xSrxCoO3-δ导电陶瓷在电接触材料中应用的可能性。结果表明,随着样品中Sr掺杂量的增加,La1-xSrxCoO3-δ样品的衍射峰峰位向大角度方向略有偏移,衍射峰峰值减小,并发生宽化。溶胶-凝胶法制备的La1-xSrxCoO3-(δx=0.1~0.7)陶瓷普遍具有较好的导电性,其中La0.4Sr0.6CoO3-δ样品在1 000℃热处理条件下,会部分转变为La0.5Sr0.5CoO2.91,同时生成La2O3、Co3O4、SrCoLaO4等氧化物并释放出O2,这与AgC-dO电接触材料中CdO的特性有类似之处,在电接触材料领域具有潜在的应用价值。     

LiCo_(0.98-x)Ti_(0.02)La_xO_2的高温固相法合成及其电化学性能

以Li2CO3、Co3O4为原料,采用高温固相法制备了锂离子电池正极材料LiCo0.98-xTi0.02LaxO2(x=0,0.01,0.03,0.05)。采用扫描电镜(SEM)、恒流充放电研究了材料的表面形貌和电化学性能,结果表明:掺杂La后材料的D50略有增大,放电平台电压升高;在2.75～4.20 V电位范围内,LiCo0.97Ti0.02La0.01O2的首次1 C放电比容量达到143.86 mAh/g,50次循环后容量保持率为97.0%,且具有很好的倍率性能。     

La0.6Sr0.4CoO3催化H2O2电还原的性能研究

以溶胶-凝胶法制备La1-xSrxCoO3电极材料,通过循环伏安和恒流充放电等方法研究了La1-xSrxCoO3催化H2O2电还原的性能.结果表明当x=0.4时,在3 mol/L KOH溶液中,粉末电极电催化还原H2O2的活性最高.电极电势为-0.4 V时,电流密度达到-123 mA/cm2.不同的H2O2浓度下电极性能测试的结果表明,H2O2浓度为0.6 mol/L时,电流密度最大.计时电流法测试表明La0.4Sr0.6CoO3粉末电极在碱性溶液中稳定性良好.     

钛酸铋钙和稀土复合掺杂对BaTiO3陶瓷微结构和介电性能的影响

研究了稀土及CaBi4Ti4O15（CBT）的复合掺杂对BaTiO3（BT）陶瓷微结构及介电性能的影响。结果表明：单独添加CBT使晶粒细化,促进了陶瓷的烧结致密化,居里温度随着CBT含量的增加（≤0．5mol％）而逐渐移向高温端;当CBT含量由0．3mol％增加到0．5mol％时,BT陶瓷的电容量变化率逐渐减小;当CBT含量超过0．5mol％时,电容量变化率又增大。在BaTiO,CBT（BT—CBT）基础上单独添加1．0mol％La2O3,四方率减小,居里点移向低温端;保持La2O3掺杂量不变,随着CeO2含量的增加,BT—CBT陶瓷的晶胞体积呈现先减小后增大的变化趋势,四方率保持不变;1．0mol％La2O3和0．01mol％CeO2掺杂BT—CBT（0．5m01％）陶瓷在-55℃和125℃的电容变化率分别为-14．78％和-11．44％。完全符合EIAX7R标准,有望用于X7R型多层陶瓷电容器的制备。     

Micro-Raman Characterization of the Phase Transition Behavior in Lanthanum Doped Lead Titanate Thin Films

Lanthanum-modified lead titanate, Pb 1 m x La x Ti 1 m x/4 O 3 (PLT), films with different compositions, such as x = 0.05, 0.10, 0.15, 0.20, 0.25 and 0.30 were deposited on platinized silicon substrates using the sol-gel process. Raman scattering technique was utilized to study the dynamics of phase transitions and possible relaxor behavior in these compositions in a wide range of temperatures 100-873K. The outcome indicates change of the structure with the increase of La doping, as well as an increase in diffused phase transition behavior. The residual intensities of phonons above the tetragonal-to-cubic phase transition temperature suggest a diffuse nature of the ferroelectric phase transition, due to the short-range structural disorder in the paraelectric cubic phase. The Lyddane-Sachs-Teller (LST) relations were employed to analyze changes in the Raman mode positions in order to obtain the optical dielectric constants. The results are in good agreement with the previous dielectric studies.     

Preparation and dielectric properties of La doped NBCCTO ceramics

Journal of Electroceramics - CaCu3Ti4O12 ceramics have great dielectric constant, excellent temperature stability and good frequency stability. However, due to high dielectric loss, its practical...     

Dielectric Properties of Acceptor-Doped (Ba,Ca)(Ti,Zr)O3 Ceramics

The dielectric properties of (Ba,Ca)(Ti,Zr)O₃ ceramics containing various acceptor and donor dopants on the B sites have been studied. Formation of charge compensating complexes between acceptors, donors and oxygen vacancies has been observed. All acceptors cause a reduction of the Curie point. The maximum dielectric constant increases with the average grain size almost independent of the acceptor incorporated. Ceramics fired in reducive atmospheres reveal pronounced changes of the dielectric properties after annealing in oxidizing atmosphere. In particular the losses and the maximum dielectric constants are significantly affected by the annealing time, temperature and partial pressure of oxygen.     

Structures and Dielectric Properties of La-Substituted SrBi8Ti7O27 Ceramics

SrBi₈Ti₇O₂₇ ferroelectric ceramics with mixed Aurivillius structure were modified by La-substitution for Bi, and the dielectric properties were investigated together with the microstructure characterization. Solid solution of Sr(Bi_{1 – x} La _x )₈Ti₇O₂₇ was formed in the present ceramics for x 0.1, and (Bi,La)₄Ti₃O₁₂ secondary phase appeared at x = 0.15. For x 0.25, another phase Sr(Bi,La)₄Ti₄O₁₅ appeared, and (Bi,La)₄Ti₃O₁₂ disappeared gradually with increasing x, and vanished entirely at x = 0.35. With increasing x, both the dielectric constant and dielectric loss of the present ceramics increased firstly and reached their maximums 291 and 0.023 at 1 MHz, then decreased after x > 0.25. The temperature stable high- dielectric ceramics with low dielectric loss were created at the composition x = 0.5: = 122, tan = 0.0003 and = –619 ppm/°C at 1 MHz.     

Structural and microwave dielectric properties of Ba5-xLaxTixNb4-xO15 ceramics

The structural and microwave dielectric properties of Ba_5?x La _x Ti _x Nb_4?x O₁₅ (1?≤?x?≤?3) was investigated. The single phase with A₅B₄O₁₅-type cation-deficient hexagonal perovskite structure was obtained over the whole composition range. These ceramics have high dielectric constant up to 56, high quality factors (Q?×?f ) up to 35,000, and low temperature coefficient of resonant frequencies (τ _f ) in the range +69 to ?3 ppm °C^?1. The dielectric constants and τ _f of these ceramics gradually decrease parallel to an increase in B-site bond valence with increasing La and Ti content.     

Dielectric and nonlinear electrical behaviors of Ce-doped CaCu3Ti4O12 ceramics

We present a remarkable effect of Ce doping on the dielectric and nonlinear electric properties of CaCu₃Ti₄O₁₂ ceramics. Microstructure analysis indicates that Ce-doped CCTO ceramics are composed of large and small grains. Our results indicate that only 2.5 at. % Ce doping can suppress the dielectric permittivity in CaCu₃Ti₄O₁₂ by up to two orders of magnitude (from 10⁴ to 10² ), and the nonlinear varistor characteristics disappear completely, which may be due mainly to the Cu⁺ ions?? disappearing caused by the Ce doping.     

The Microstructure and Electrical Behavior of TiO2 Varistors Processed by Magnetized Water

A comparative study of the microstructures of two kinds of TiO₂ based varistor materials processed from the slurry using magnetized water and regular deionized water is conducted. The additives in the form of oxides of Nb, Ce, Ca, and Si were used in the recipe. The electrical behavior reveals that the water magnetized at 0.2 T yielded lower varistor voltage while the water magnetized at 0.3 T yielded higher varistor voltage compared to the regular deionized water. A second phase comprising of Ce, Si, and Ti was found in each of these samples. The distribution of second phase was found strongly dependent on the type of water used. Thus, the magnetized water shows influence on the TiO₂ varistor microstructures. It apprehended that the application of magnetized water in the general arena of advanced electronic ceramics may bring novel experimental results as demonstrated in the present work.     

添加CoFe_2O_4和CaB_2Si_(0.67)O_(5.34)助溶剂对永磁铁氧体磁性能的影响

通过常规陶瓷工艺,结合离子取代,以CaB_2Si_(0.67)O_(5.34)作为助溶剂,添加Co Fe_2O_4铁氧体制备了Ca_(0.218)Sr_(0.43)La_(0.432)Fe_(12)O_(19+δ)永磁铁氧体材料。实验结果显示,在成分相同的情况下,与传统的离子取代相比,以Co Fe2O4的形式添加,更能有效发挥Co2+改善永磁铁氧体磁性能的潜力,所获材料的Br可以提高4%,同时其Hcj可以提高3%。当Co Fe2O4的添加量为7.8wt%时,在空气中1190~1200℃下保温2h烧结,材料的显微结构、密度得到了显著改善,磁性能Hcb为331k A/m,Hcj为416k A/m时,Br可以达到0.458T。