共查询到20条相似文献,搜索用时 15 毫秒
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YANG Hongying SHEN Baogen YANG Linyuan GUO Huiqun Laboratory of Magnetics Institute of Physics Academia Sinica Beijing China 《金属学报(英文版)》1992,5(11):396-400
The Curie temperature increases but crystallization temperature decreases with the in-crease of Ga content,x,of amorphous(Fe_(1-x)Ga_x)_(77.5)Nd_4B_(18.5) alloys.The averagemagnetic moment of Fe atoms is almost a constant.By X-ray diffraction and ther-momagnetic measurements,the crystalline phases of the alloys,an unknown phase andα-(Fe,Ga)besides Fe_3 B as major one,were identified.The relationship between roomtemperature coercive field and Ga.content was also studied. 相似文献
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LIU Jian QIU Baoqin LIU Muyi XIAO Yaofu University of Science Technology Beijing Beijing China associate professor Department of Materials University of Science Technology Beijing Beijing China 《金属学报(英文版)》1993,6(6):379-382
The phase constitution and variation of Nd_(14)Fe_(73)Co_6B_7 alloy after hydriding and subsequentdehydriding treatment at 770℃ have been investigated respectively by means of X-raydiffraction,SEM,TEM and magnetic measurement techniques.The original coarse,as castgrain structure,is dissolved into α-Fe,Nd hydride and Fe_2B mixture with average dimensionof 0.1 μm,during hydriding process,and subsequently the triphase mixture recombined intofinely unique Nd_2Fe_(14)B phase with dimension of 0.3 μm by desorbing the hydrogen.It wasfound that the Nd-rich phase distributed at the boundary of as-cast grain structure diffusedinto matrix Nd_2Fe_(14)B grain during hydriding.It remains during dehydriding and distributehomogeneously around some colonies composed of fine grains of Nd_2Fe_(14)B. 相似文献
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氢作用下Nd14Fe73Co6B7的相转变 总被引:2,自引:0,他引:2
利用X射线衍射、透射电子显微镜、扫描电镜及磁测量技术观察和分析了Nd_(14)Fe_(73)Co_6B_7合金于770℃吸氢后相结构组成与变化发现铸锭中的Nd_2Fe_(14)B基体吸氢后分解成约为0.1μm的NdH_2,α-Fe和Fe_2B三相混合物,脱氢后重新结合的Nd_2Fe_(14)B相尺寸约为0.3μm;铸锭中分布在基体相周围的富Nd边界相在吸氢时扩散入Nd_2Fe_(14)B基体,在脱氢过程中保留下来,均匀地分布在由若干Nd_2Fe_(14)B细小晶粒组成的晶粒团周围 相似文献
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XING Feng JIANG Chao HE Wenwang Department of Physics Peking University Beijing China Originally published in ACTA METALL SIN 《金属学报(英文版)》1989,2(8):122-126
The magnetic properties of Nd_2(Fe_(1-x)M_x)_(14)B(M=C and Si) compounds have been investi-gated.Substituting Fe by small amount of metalloid C and Si atoms,the compounds are intetragonal structure and have uniaxial anisotropy.The substitution of C for part of Fe de-creases the Curie temperature of the compounds and the intrinsic coercivity of bond samples atlow temperature.The replacement of Fe by Si makes the Curie temperature increase with amaximum at the vicinity of x=0.15.When the range of the content of Si is 0≤x≤0.10,thecoercivity distinctly increases at room temperature.from 62.7 kA/m at x=0 to138.7kA/m at x=0.06,where the residual magnetization has a maximum:in the mean timethe saturation magnetization decreases only by a small amount. 相似文献
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本文研究了Nd_2(Fe_(1-x)M_x)_(14)B的磁性。少量类金属原子C和Si取代部分Fe,能形成四方结构,且具有单轴各向异性。碳取代Fe,使化合物的Curie温度降低,低温下粘结体样品的内禀矫顽力减少;而Si对Fe的取代可使Curie温度升高,并在x=0.15附近达到极大值。含Si样品在0≤x≤0.10范围内,矫顽力显著增加,室温下从x=0的62.7kA/m增加到x=0.06的138.7 kA/m,并且在x=0.06附近,剩磁有一个极值,饱和磁化强度减少不多。 相似文献
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LI Yinfeng GUO Huiqun XU Rufeng SHEN Baogen Laboratory of Magnetics Institute of Physics Academia Sinica Beijing China 《金属学报(英文版)》1992,5(11):340-345
The disaccommodation(DA)measurements of initial susceptibility were performed inamorphous Fe_(90-x)Ni_xZr_(10)(x=10,20,30)alloys.The DA was measured for two differentamorphous states:as-quenched and pretreated at 537 K for 45 min.For all the as-quenched samples,in the isochronal spectra of DA a well defined relaxation peak around350 K is accompanied by a samll but distinct peak near the Curie temperature ofFe_(90)Zr_(10) phase(T_c=230 K).The reversibility and annealing effect on DA are analyzedwithin the framework of two-level model.The fits of the theory to the experimentaldata of reversible relaxation processes gave a spectrum,of activation energies and pre-exponential factor. 相似文献
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用液态快淬法制备非晶合金条带时,通过加入15—30%的B与Si等类金属含量是形成非晶状态的必要条件。但是,由于Si与B等类金属元素的加入,使非晶态合金的磁性受到明显的影响。本文实验研究了Si与B含量间的相对变化对(Fe_(80)Ni_(20))_(78)Si_(22-x)B_x合金的饱和磁矩、平均原子磁矩与Curie温度的影响关系。利用电子转移模型与分子场近似理论定性的解释了(Fe_(80)Ni_(20))_(78)-Si_(22-x)B_x合金的磁矩(M_s)与Curie温度(T_c)随 相似文献
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LUO Yang JI Qigen ZHANG Ning SU Xiujin Central Iron Steel Research Institute Ministry of Metallurgical Industry Beijing ChinaSUN Daliang Shandong University Jinan China senior engineer Department of Precious Alloys Central Iron Steel Research Institute Beijing China 《金属学报(英文版)》1989,2(7):27-32
Based on the observation of temperature variation of both domain structure and magnetic con-trast.the thermal demagnetization and randomness of domain nucleation was discussed. 相似文献
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非晶态Fe_(90-x)Si_xZr_(10)(x=0,4,7,10)合金是用单辊急冷方法制备的,用提拉样品磁强计测量了样品的磁化曲线和热磁曲线。发现每个磁性原子的平均磁矩μ和Curie温度T_c随Si含量的增加而增加,与相应的非晶态FeSiB合金相比,非晶态FeSiZr合金的μ和T_c明显偏低,认为这一反常现象是Fe-Fe原子间的反铁磁耦合的存在所致。低温下样品的磁化强度与温度的关系较好地符合Bloch T~(3/2)定律,得到自旋波劲度系数D从x=0时的0.37meV·um~2增加到x=10时的0.538meV·um~2,计算出交换相互作用范围都是在最近邻原子间的距离。 相似文献
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研究了作晶态Fe_(90-x)Co_xZr_(10)合金的磁体积效应和广义声子谱.通过热膨胀测量和磁测量给出了自发体积磁致伸缩ωs和平均磁矩μ_(FeCo)与平均价电子数N_(eff)的关系,发现ωs的峰值位置与μ_(FeCo)开始急剧下降的位置(N_(eff)=8.1-8.2)相对应,从而证实了金属-金属型非晶态因瓦合金中的Invar效应与铁磁态的不稳性有关.用非弹性中子散射方法测量了广义声子谱,从中观察到了与Invar效应相关的声子谱软化现象. 相似文献
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1.IntroductionTheternaryRMn2X2compounds(Risrareearth,andXisGeorSi)crystallizeinthebodycenteredtetrag0nalThCr2Si2-typestructurewithspacegr0upI4/mmm,inwhichtheR,TandXatomsoccuPythe2a,4dand4csites,respectivelyl1t2].Theyexhibitillterestingmagneticpr0perties['].InSmMn2Ge2tlireedifferentmagneticorderingtypeshavebeendetermined:ferromagnetismfor153K相似文献
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NANOCRYSTALLINESTRUCTUREANDINITIALPERMEABILITYOFANNEALEDFe_(73.5)Cu_1W_3Si_(13.5)B_9AlloyZHANGXiangyi,ZHANGJingwuandZHENGYangze?.. 相似文献
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MAGNETIC MOMENT,CURIE TEMPERATURE AND SPIN WAVE EXCITATION FOR AMORPHOUS Fe_(90-x)Si_xZr_(10) ALLOYS
SHEN Baogen ZHANG Zhiying GUO Huiqun ZHAO Jiangao Institute of Physics Academia Sinica Beijing ChinaGU Benxi Nanjing University Nanjing China 《金属学报(英文版)》1991,4(7):31-36
The magnetization curves at 1.5 K and thermomagnetic curves for amorphous Fe_(90-x)Si_xZr_(10)(x=0,4,7 and 10)alloys prepared by the drum spinning technique have been measured with an extracting sample magnetometer.It is obtained that the average magnetic moment,,per magnetic atom and Curie temperature,T_c,in the amorphous FeSiZr alloys increase with increasing Si content.The and T_c are found to be quite small,compared with amorphous FeSiB alloys.This unusual behavior is suggested to be due to the presence of the Fe—Fe antiferromagnetic interactions.The temperature dependence of magnetization at lower temperature is in accordance with Bloch's T~(3/2) law.Calculation shows that the spin wave stiffness constant,D,increases with increasing Si content from 0.37 meV·nm~2 for x=0 to 0.538 meV·nm~2 for x=10.The values ofindicate that the range of the exchange interaction is roughly the mean atomic distance of nearest neighbours. 相似文献