A novel 3D Co(II) complex [Co(Hhmt)(H2O)∙H2O] (1) (H3hmt = 3,5-bis (hydroxymethyl)-1,2,4-triazole) has been hydrothermally synthesized. X-ray single crystal diffraction experiment reveals that each Hhmt2 − ligand connects three Co(II) ions to form a 3D lvt topological framework with the (42 ∙ 84) point symbol, especially for the existence of a considerable 2D channel. The magnetic and electrochemical properties of 1 are also discussed. 相似文献
One new Cu(II) coordination polymer (1) based on 6,6′-dihydroxy-2,2′-bipyridine (H2dhbp) was successfully prepared, with the formula of [Cu(μ2-OH)(Hdhbp)]n (1). Single-crystal X-ray analysis shows that compound 1 crystallizes in orthorhombic chiral space group P212121 and exhibits a left-handed (L) helical [Cu(μ2-OH)]n-chain. Luminescence of 1 exhibits a broad emission around 440 nm, attributing to the metal to ligand charge transfer (MLCT). Magnetic susceptibility shows antiferromagnetic coupling within compound 1. Cyclic voltammetry (CV) experiments indicate a potential water oxidation electrocatalyst. 相似文献
One new dinuclear multioxomolybdenum(VI) complex containing long MoO bands with imidazole, [Mo2O6(imi)4] (1) (imi = imidazole), has been prepared and characterized, and the geometric structure, electronic structure and spectroscopic properties, investigated experimentally and theoretically. The rarely observed long MoO bonds in 1 (ca. 0.15 Å longer than documents previously) are analysed by orbital structure analysis. The electronic origins of the optical transitions are also mainly related to the MoO groups with ligand-to-metal charge transfer (LMCT) nature (Pterminal-oxo → dMo). 相似文献
The complex [FeII(Imz-phen)3](PF6)2, (Imz-phen = imidazolidine-[4,5-f]-1,10-phenanthroline) has been prepared and characterized using X-ray diffraction, UV–vis and IR spectroscopy, elemental analysis, fast atomic bombardment (FAB) mass spectrometry, and cyclic voltammetry. Its crystal lattice includes acetonitrile (π–π bound to phenanthroline), methanol, and water molecules. Scanning continuously between 1000 mV and 1650 mV in CH3CN, a modified electrode that includes the iron (II) complex is obtained; after the 25th continuous cycle a stable film is formed that is electrocatalytically active in the reduction of sulfur oxoanions. When the electrocatalytic properties are evaluated in ethanol/water solution, the current achieved from the electroreduction of these sulfur species is linearly dependent on the respective concentrations, suggesting potential application in sulfite determination. 相似文献
1,4-benzeneditetrazolate [H2BDT] (1) and its 3D coordination polymer [Zn(BDT)]n (2), have been synthesized and structurally characterized by infrared spectroscopy (IR), thermal gravimetric analysis (TG), and single-crystal/powder X-ray diffraction. The result of the single-crystal X-ray diffraction analysis indicates that 1 is a 3D supramolecular structure stabilized by intermolecular hydrogen bonds and π…π stacking interactions. 2 is a 3D (4,4)-connected coordination polymer with the central metal Zn(II) ions linked together by BDT2? anions. Photoluminescent measurement for 2 in the solid state elucidates that 2 displays a strong photoluminescence at 469 nm, which suggests that 2 may be a potential blue-light material. 相似文献
A novel two-dimensional helical coordination polymer [Ag(CH3CN)4][Ag3(CH3CN)8(SiMo12O40)] (1) has been gained by the conventional self-assembly reaction, and characterized by IR, elemental analysis, UV, TG technique and X-ray single crystal diffraction. Each [SiMo12O40]4? cluster interconnects with three bimetallic cation subunits through three Mo–O–Ag bridges, meanwhile, each bimetallic cation subunit is surrounded by three [SiMo12O40]4? to form an unprecedented two-dimensional network structure. The metal–metal bonds between Ag(1) and Ag(2) atoms from the adjacent helical chains connects the chains together into a chiral 2D helical network. The 2D network structures are further interconnected with each other to form a 3D supramolecular network through multiform intermolecular hydrogen bonds. The luminescent properties of the coordination polymer in the solid state were investigated. 相似文献
A new cobalt complex, [Co(L)2·(H2O)2](HL = 4-hexanoyl-3-methyl-1-phenyl-1H -pyrazol-5(4H)-one), was synthesized by us. The complex was characterized by single crystal X-ray diffraction, IR, UV, fluorescence spectra and thermogravimetric analysis. The results of characterization showed that the crystal is monoclinic system with crystal parameters: a = 15.2439(12) Å, b = 7.4101(6) Å, c = 15.7381(18) Å, and Z = 2, S = 1.074. It was found that the Co2+ is located in the inversion center of the complex. The Co(II) had an ideal octahedral coordination environment with four oxygen atoms of HL ligands in the equatorial plane and two water molecules in axial positions. The complex exhibits yellow emission as the result of the fluorescence from the intraligand emission excited state. 相似文献
A novel ruthenium complex with 2-(2-pyridyl)-4-methylcarbonylquinoline ligand has been prepared and characterized: the first crystal structure of such complex along with its physical and chemical properties are also described. 相似文献
This article presents novel N-propargylurea-based copolymers that contain both carbazole and urea moieties in their side chains. The homopolymer of monomer 1 with a carbazole group exhibited interesting fluorescence properties, while the homopolymer of monomer 2 with a chiral center formed helical structures. The copolymerizations of monomers 1 and 2 provided optically active helical copolymers, which had fluorescence properties, even for the copolymer that contained as low as 20 mol% of monomer unit 1. Fluorescent and optically active composite films were further prepared based on the copolymers and with poly(vinyl butyl) as the supporting material. This study contributes to the intriguing research field of optically active helical polymers and their practical applications. 相似文献
Carbon nanofibers (CNFs) have been synthesized by co-catalyst deoxidization process by a reaction between C2H5OC2H5, Zn and Fe powder at 650 °C for 10 h. These nanofibers exhibit diameters of ∼80 nm and lengths ranging from several micrometers to tens of micrometers. X-ray diffraction, Raman spectroscopy, and high-resolution transmission electron microscopy indicate that as-prepared CNFs possess low graphitic crystallinity. The resultant CNFs as electrode shows capacity of ∼220 mAh/g and high reversibility with little hysteresis in the insertion/deintercalation reactions of lithium-ion. In addition, the possible growth of CNFs is discussed. 相似文献
Nitrilotriacetato oxomolybdenum(V) dinuclear complex (NH4)4[cis-Mo2O4(nta)2] · 7H2O (1) (H3nta = nitrilotriacetic acid) and its incomplete cubane-type trinuclear molybdenum(IV) complex [Mo3O(OH)3(Hnta)3] · Cl · 3H2O (2) are isolated in a weak acidic and an acidic solutions, respectively (pH 4.5 and 1.0). The nitrilotriacetate ligand in the anion 1 or the cation 2 displays tridentate mode through the nitrogen atom and the oxygen atoms of β-carboxy groups. Unusual protonations of bridged oxygen atoms in 2 have not effect on the skeleton of molybdenum(IV) cap Mo3O unit. There are obvious dissociations of molybdenum(V) complexes based on 13C NMR observations in solution. 相似文献
A series of symmetrical surfactants containing two arylsulfonate groups in the molecule, of general structure,
where n=4, 6, 8, 10 and 12, has been synthesized. The synthesis involves sulfonation of the corresponding diaryl ethers,
isolation, purification, and characterization of the free para-disulfonic acids, followed by conversion of the latter to the
disodium salts. The nuclear magnetic resonance (NMR) spectra of the products indicate that they are the para-sulfonated compounds
substantially free of the ortho isomers. The Krafft points, surface tension-log concentration curves, critical micelle concentrations,
and areas/molecule at the liquid/air interface have been determined. The surface area/molecule indicate that these compounds
are lying flat in the liquid/air interface. 相似文献
Two three-dimensional coordinationcomplexes containing metal-triazolate helical chains wereobtained. Their fluorescent andnonlinear optical properties were explored.
In this work, the Al doped high entropy perovskite Li0.2La0.2Ca0.2Sr0.2Ba0.2TiO3 ceramic is synthesized by using a solid state reaction method, and the effect of different doping amount on the crystal structures and conductivity are also studied. The result proves that doping leads to a positive influence on the conductivity of ceramic. The material of Li0.1(LiLaCaSrBa)Ti0.9Al0.1O3 (LLCSBTA-0.1) exhibits a high total conductivity with approximately 3.92 × 10-7 S cm-1 at 30 °C and an activation energy of 0.39 eV. The beneficial result can be ascribed to the increase of Li + concentration. The Li0.2La0.2Ca0.2Sr0.2Ba0.2TiO3 presents a pure cubic perovskite structure, but with partial tetragonal structure due to the addition of Al2O3. However, these high entropy perovskite ceramics showed porous structures which are unfavourable for lithium ion conduction. The electrochemical property of the Li0.1(LiLaCaSrBa)Ti0.9Al0.1O3 as electrode is investigated as well. The results show that the Li0.1(LiLaCaSrBa)Ti0.9Al0.1O3 electrode exhibits good cyclability and stability for the insert-extraction of lithium ions with the specific capacity of 58.6 mA h g?1. 相似文献
In this study, the novel low band gap and thermally stable poly(azomethine-urethane)s (PAMUs) were synthesized to investigate aliphatic and aromatic group effects on some physical properties such as thermal stability, optical and electrochemical properties. For this reason, we firstly synthesized the new Schiff bases via condensation reaction of 5-nitrovanilin with aromatic and aliphatic diamines. Then, these monomers were converted to PAMUs derivatives by the step-polymerization reaction with aromatic and aliphatic diisocyanates. The structures of the compounds were confirmed by FT-IR, UV–vis, 1H NMR, and 13C NMR techniques. The molecular weight distribution parameters of the compounds were determined by the size exclusion chromatography (SEC). The compounds were also characterized by solubility tests, TG–DTA, and DSC techniques. Cyclic voltammetry (CV) measurements were carried out and HOMO–LUMO energy levels and electrochemical band gaps (E′g) were calculated from their absorption edges. Additionally, optical band gaps (Eg) were determined by using UV–vis spectra of the materials. Fluorescence measurements were carried out in THF, DMF, and DMSO solutions to determine the optimum concentrations and the maximal emission and excitation intensities. 相似文献
A new mononuclear Fe(III)–catecholate complex, which exhibits an incomplete spin transition without hysteresis, had been synthesized and structurally characterized. Analyzed from the structural characteristics, the tripodal ligand must play the important role in affecting the spin crossover (SCO) behavior. The larger steric strain effect and weak cooperativity existed in the crystal lattice are inclined to favor the incomplete transition. 相似文献