磷酸酯型透明阻燃涂料的合成与检测

探讨了磷酸酯型防火涂料的合成配方筛选、防火机理及性能检测。阻燃时间达到17～19min,可应用于木材及其他一些合成材料的防火。     

防火涂料

防火地坪覆盖物及用于生物质、木材和有机覆盖物的防火涂料 防火地坪覆盖组合物用于处理纤维材料如生物质、木材和有机覆盖物以提高其防火性，含≤1%（体积分数）选自硫酸铵盐或磷酸单铵盐的防火化合物。另外，本发明溶液还可含表面活性剂（1％-3%），特别是洗涤皂液。     

防火涂料

防火性好、燃烧时不释放有毒气体的带夹层的光纤绳,硅丙乳液膨胀型防火涂料,硅丙乳液膨胀型防火涂料的研制,用废聚苯乙烯泡沫研制木材用膨胀型阻燃涂料,     

木器涂料

200910106室外木材用高耐磨防火涂料：DE102007043362[德国专利]／德国：（Kremers，Christina）．-2009．03．19．-2页．-102007043362（2007．09．12）；IPCC09D5／18     

防火涂料

具有优异的阻燃性和贮存稳定性的水稀释发泡型防火涂料;木材保护用防火涂料组合物;改进了湿度调节性的建筑墙面漆层用耐热防火涂料;水性超薄膨胀型钢结构防火涂料的制备与性能;无溶剂环氧膨胀型钢结构防火涂料的研制     

建筑防火涂料

1前言防火涂料又称阻燃涂料，建筑防火涂料除具备一定装饰性外，还具备对被保护基林的防火、阻燃特性。近年来建筑防火涂料发展很快。不断有新的品种问世，目前建筑防火涂料按其使用范围大致可以分为两类，一类是饰面型防火涂料，涂有防火涂料的表面遇到火焰后，可延缓基材的引燃时间，一但基材燃烧后，还可以阻止火焰继续传播。这种涂料应用广泛。另一类是钢结构防火涂料，它主要用于建筑物钢结构表面，使其提高建筑物的耐火极限。2饰面型防火涂料饰面型防火涂料主要是涂于可燃材料表面，平时可起装饰作用，涂层表面遇到火源燃烧后，涂层可…     

B60—2乳胶防火涂料

研制了既能防火阻燃、又具有装饰效果的新型丙烯酸乳胶膨胀型防火涂料。介绍了该涂料的阻燃体系和配方,并列举了它的防火阻燃性能和其他性能。试验结果表明,该涂料的防火性能各项指标均达到一级,其他性能也较理想,是第二代乳胶防火涂料。     

膨胀防火涂料阻燃性能与乳液玻璃化温度研究

研究了乳液的玻璃化温度对防火涂料阻燃性能的影响。试验发现：不同玻璃化温度的不同类型乳液制备的防火涂料，阻燃性能不同，玻璃化温度越低其阻燃性能越好；玻璃化温度相近的防火涂料，阻燃性能相近；不同玻璃化温度的同一类型乳液防火涂料，阻燃性能不同。乳液玻璃化温度对防火涂料的阻燃性能有关键作用。     

环保型防火涂料发展现状

介绍了水性防火涂料和液体无溶剂防火涂料的研究现状，指出了目前存在的问题及相应的解决措施，展望了我国防火涂料的发展趋势。     

防火涂料的制备与应用研究进展

防火涂料是一种涂覆于基材表面,防止基材燃烧,阻止火势蔓延的特殊功能材料。防火涂料可以提高材料表面的耐火能力,在一定程度上阻止燃烧的进行,一般常用于木质结构建筑和钢结构建筑。对近年来国内外用于木材和钢结构的防火涂料的制备和应用进行了详细的介绍,尤其是对具有安全、环保、无污染、易于操作和清洗等特性的水性防火涂料,分析了它们的优点,并对未来行业的需求以及防火涂料的发展方向进行了展望。     

Insect antifeedant properties of anthranoids from the genusVismia

Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria.     

Direct observation of freeze-thaw instability of latex coatings via high pressure freezing and cryogenic SEM

Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively. There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized. High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing, and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually preserves suspension stability during freezing. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago, IL. Tied for first place in The John A. Gordon Best Paper Competition.     

Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US

In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures (release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species (Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles from the southeastern region of the US.     

Methyl 2,4,6-decatrienoates Attract Stink Bugs and Tachinid Parasitoids

Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed.     

2007～2008年世界塑料工业进展

收集了2007年7月～2008年6月世界塑料工业的相关资料,介绍了2007～2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍.     

2005～2006年国外塑料工业进展

收集了2005年7月～2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂（聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂）、工程塑料（聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚）、通用热固性树脂（酚醛、聚氨酯、不饱和树脂、环氧树脂）、特种工程塑料（聚苯硫醚、液晶聚合物、聚醚醚酮）的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。