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西南稀土矿的矿石性质及分选工艺研究 总被引:2,自引:0,他引:2
研究了西南稀土矿的矿石性质及分选工艺.原矿风化强烈,产生大约20%的黑色风化物矿泥。-矿石中可工业利用的稀土赋存形式有矿物相和胶态相。矿物相稀土以氟碳铈矿为主,占96%以上,重选或重浮选联合工艺可得到REO30%,50%和60%的氟碳铈矿精矿,稀土回收率65%。胶态相稀土则吸附在Fe-Mn非晶质氧化物矿物上,用热盐酸浸出,氨水除杂,草酸沉淀回收稀土,稀土回收率74.3%,并副产铅。矿石和黑色风化物中稀土都强烈选择铈族稀土,∑CeO2在90%以上,且CeO2>La2O3>Nd2O3。 相似文献
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四川昌北M稀土矿床稀土元素的赋存状态及其配分特征 总被引:4,自引:0,他引:4
昌北M稀土矿是我国西南地区唯一的大型轻稀土矿床。它不仅含有丰富的轻稀土,而且铕、钇等中重稀土较国内外同类型矿床高。该矿的特点是工业稀土矿物单一,矿石易采、易选、易冶。矿石中90%左右的REO呈稀土矿物产出,其中氟碳铈矿占稀土矿物总量的80%~97%。矿石和主要稀土矿物的REE配分均属Ce>La>Nd富LREE的强选择配分型。矿石中轻稀土配分值高达97.48%~98.81%。矿石中Eu、Y配分值较高,而氟碳铈矿反而比矿石低。矿石中的黑色风化土状物富含次生稀土,其Eu、Y配分值比矿石、氟碳铈矿都高。 相似文献
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本文根据西南某稀土矿的矿石性质,探讨了该矿可利用的稀土(氟碳铈矿),钡(重晶石)和氟(萤石)等有价元素的综合利用价值。特别是对该风化矿泥中胶态相稀土的赋存形式进行了化学解析,得出了它是一种新的稀土资源,可用热盐酸浸取回收。 相似文献
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矿石储量约110万吨的Dong Pao小型氟碳铈矿矿床位于越南的最北端。在重晶石-氟石-氟碳铈矿矿化过程中形成的碳酸盐矿体,其部位和成因与第三纪碱性岩岩浆作用有密切联系。该矿床的特点在于形成了厚度超过30m的剧烈风化带,从而明显提高了稀土含量。而矿石的成因和共生组合决定了选矿工艺的复杂性。根据实验室和半工业试验,提出一种对氟碳铈矿稀土矿石来说属非常规的选矿方法,即作为一个主要工序在第一阶段对原矿石进行洗选。洗选后的细粒产品中含有30%的稀土氧化物,稀土回收率为63%。这种品位相当低的精矿,由于其性能特殊,需采用一种新的分解方法进行冶金加工。其特点是在温度仅仅200—300℃的条件下,用硫酸进行固相化学分解。该选矿方法的其它工序还包括重晶石精矿浮选,和提取含有约38%稀土氧化物的二次氟碳铈矿精矿的强磁场磁选,二次精矿可与一次精矿混合。 相似文献
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2002年稀土矿产量换算成氧化物是8.7万吨,2003年上半年1~6月推算是9万吨,比上一年稍有增长。主要增长矿石是四川省的氟碳铈矿,其他矿石大体与去年持平。稀土价格也未见有大的升落。 相似文献
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本文针对四川冕宁稀土矿床中含锰高(17.56% )的黑色风化物难以用氯化法回收稀土这一问题,采用SO2 作为还原剂,在液固比3∶1 的条件下,常温浸取黑色风化物中的锰,经3h 通SO2 浸取,锰浸出率达90% 以上。经预处理脱锰的浸渣,进一步采用氯化铵焙烧- 水浸方法回收稀土,稀土浸出率达75.6% 。 相似文献
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《稀土》2021,(4)
采用化学分析、能谱分析、扫描电镜、全自动矿物分析系统(MLA)等分析手段对白云鄂博白云石型稀土-铁矿石中化学元素、粒度组成、矿物解离度和嵌布特征等进行研究。结果表明,矿石中铁的含量为15.52%,稀土氧化物含量为6.56%;矿石中可利用的铁矿物主要为磁铁矿,稀土矿物主要为氟碳铈矿和独居石,氟碳铈矿中La、Ce、Pr、Nd的相对含量为66.39%(原子分数),独居石中La、Ce、Pr、Nd的相对含量为61.33%(原子分数),脉石矿物主要是白云石、萤石和磷灰石等;磁铁矿多以半自形至他形粒状变晶结构以及集合体形式出现,与稀土和脉石矿物共生关系密切,20μm~74μm粒级之间,分布率为63.23%;氟碳铈矿常以星散状和不规则粒状集合体嵌布在脉石中,主要分布在43μm以下;独居石粒度大小以及在矿石中的嵌布特征与氟碳铈矿基本相同,常呈粒状或椭粒状嵌布在脉石矿物中;磨矿细度-74μm占90%时磁铁矿、氟碳铈矿和独居石的单体解离度分别为87.21%、77.36%和69.44%。因此,矿石细磨和微细粒高效分选是解决现有问题的关键。 相似文献
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Existing State and Partitioning of Rare Earth on Weathered Ores 总被引:5,自引:0,他引:5
The existing state and partitioning of rare earth (RE) on weathered ores in Longnan County(LN), Xingfeng County(XF) and Ninghua County(NH) were characterized systematically by standard geological analytical methods. It is found that RE in the weathered rare earth ores exist as four phases: (a) water soluble, (b) ion-exchangeable, (c) colloidal sediment (oxides), (d) minerals, in which mainly as ion exchangeable phase, accounting for nearly 80% of total RE, with about 20% in the form of colloid sediment phase and mineral phase, but very little as aqueous soluble phase. These rare earth partitioning were mainly chosen mid-heavy RE elements, occupying above 60%, but not equal in the four phases. The mid-heavy RE elements were primarily enriched in the ion exchangeable phase up to 40%, while the containment of cerium dioxide is below 2 %. The cerium deficiency occurs in the ion exchangeable phase in weathered ore. It results from that the Ce^3+ is oxidized into Ce^4+ and changes into CeO2. For LN ore, the containment of Y is high in weathered ore because Y-minerals are abundant in original rock. 相似文献
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The crystalline precipitate of rare earth carbonates has been produced by the ammonium bicar-bonate precipitation method in the recovery of RE from the ammonium sulfate leaching liquor of the weath-ered leach-deposited rare earth ore.Various influencing factors such as time,temperature and reagent con-centration have been studied.And chemical analysis,XRD,SEM,IR spectrography,TGA and DTA havebeen used to analyze and examine the crystalline RE carbonates.Good results were obtained. 相似文献
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ResearchandDevelopmentofRareEarthAdvancedMaterialsinChinaWangDianzuo(王淀佐),WanQun(万群),YangYuchun(杨遇春)(GeneralResearchInstitute... 相似文献
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Caili Xu Chengbin Zhong Renliang Lyu Yaoyang Ruan Zhenyue Zhang Ru′an Chi 《中国稀土学报(英文版)》2019,37(3):334-338
Mineral liberation analyser (MLA) was applied to quantitatively analyze the rare earth ore from Weishan in Shandong. Mineralogy parameters, such as mineral composition, occurrence states of rare earth elements (REEs) and valuable elements, mineral embedded grain size distribution, mineral association and liberation, are obtained. Results show that the contents of REEs and other valuable elements mainly contained in the ore were La 1.02 wt%, Ce 4.29 wt%, Pr 0.34 wt%, Nd 0.84 wt%, Sr 3.4 wt% and Ba 26.53 wt%, respectively. The REEs mainly occur in bastnaesite and carbocernaite in the form of independent mineral and the contents of bastnaesite and carbocernaite in the ore were 5.96 wt% and 12.30 wt%, respectively. 67.34% of strontium occurs in carbocernaite and the rest occurs in celestobarite and strontianite mineral. 92.71% of barium occurs in barite. Liberation of main rare-earth minerals such as bastnaesite and carbocernaite is more than 80% when the grinding fineness is 78.42% passing 74 μm. The research results could be employed to provide detailed basic theoretical data for further improvement of the beneficiation process flow and the processing index of rare earth ore, the recycling of other valuable minerals and the comprehensive utilization of tailings. 相似文献
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采用复合铵盐作浸出剂浸出风化壳淋积型稀土矿中的稀土。考察浸出剂的配比、浓度、液固比、流速、pH等因素对稀土浸出率的影响。结果表明,NH4Cl、NH4NO3、(NH4)2SO4质量比为4∶5∶6的复合铵盐浸出剂为最佳组合;液固比越大、流速越慢,浸出率越高;当浸出剂浓度为10g/L、pH=3.5时浸出效果最好。 相似文献
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为查明建水稀土矿的稀土数值特征,在长岭岗岩体风化壳的黏土层、全风化层、半风化层、弱风化层中采集了82件样品,进行全相稀土氧化物、离子相稀土氧化物质量分数分析,包括全相稀土氧化物的质量分数、离子相稀土氧化物的质量分数、全相与离子相稀土氧化物质量分数的相关系数、全相稀土氧化物在各个风化层位中的变化系数、离子相稀土氧化物在各个风化层位中的变化系数、结晶相稀土氧化物的质量分数。经资料整理,黏土层、全风化层、半风化层、弱风化层中的稀土数值有明显差异。造成稀土数值差异的主要原因为:成矿母岩的风化程度,稀土矿物离解程度,离子相稀土氧化物的迁移富集程度。加强稀土数值的研究,有助于深化风化壳离子吸附型稀土矿的成矿机理认识。 相似文献
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Chengbin Zhong Caili Xu Renliang Lyu Zhenyue Zhang Xiaoyan Wu Ruan Chi 《中国稀土学报(英文版)》2018,36(2):215-224
Liberation, as an attribute of mineralogy characteristic, whose impacts on finely disseminated Canadian rare earth ore was studied with microwave pretreatment. Samples of a light rare earth ore along with mostly ankerite and biotite as dominant gangue minerals as well as bastnaesite, strontianite and goethite as dominated minerals were exposed to further comminution by ball mill and microwave pretreatment fragmentation. Mineralogical characteristics were analyzed by using a mineral liberation analyzer (MLA). The results indicated that tight association mutually penetrates among dominated minerals in the range size of ?300 + 212 μm and ?212 + 150 μm and gangue minerals in the form of adjacent type, fine vein type, shell type and packing type. Temperature in the ore samples pre-treated by microwave can rapidly rise to 250 °C with microwave power of 0–1.5 kW and microwave time of 0–2 min. Applying the microwave pretreatment merely reduces the hardness of the ore causing the fracture of rare earth ore, but this does not transform or change the original mineralogy characteristics of the ore samples. On the basis of above study, the liberation value of bastnaesite, strontianite and goethite with microwave pretreatment is greater than with conventional comminution when the liberation class is above 75%. The distribution of particle size of rare earth ore samples is better with microwave pretreatment than with conventional comminution for particle size of 7.4 × 10?5 m. With microwave pretreatment, the theoretical grade–recovery of bastnaesite, strontianite and goethite in the rare earth ore attains better results than with conventional comminution at a given grade. 相似文献