Soil carbon sequestration beneath hybrid poplar plantations in the North Central United States

Hybrid poplar plantations grown on tilled agricultural lands previously in prairie, sequester significant quantities of soil carbon. Comparisons are made between hybrid poplar plantations and adjacent row crops or mowed grass. Establishing and tending plantations often results in early soil carbon loss, but soil carbon is significantly related (positive) to tree age. Increasing tree age eventually results in a net addition of soil carbon from plantations older than about 6 to 12 years of age. Soil carbon loss under trees occurred most frequently from the surface 30 cm early in the plantation history—evidence that the loss was due to mineralization. Soil carbon gain was most significant in the 30–50 cm layer and was attributed to tree root growth. Soil carbon accretion rate beneath 12- to 18-year-old poplar plantations exceeded that of adjacent agricultural crops by l.63 ± 0.16 Mg ha⁻¹ yr⁻¹. There was a significant crop × soil depth interaction for bulk density with bulk density lower beneath trees in the 0–30 cm layer and higher in the 30–50 cm layer. There was little evidence of carbon trapping of wind-blown organic detritus by tree plantations in the prairie environment.     

Soil carbon, after 3 years, under short-rotation woody crops grown under varying nutrient and water availability

Soil carbon contents were measured on a short-rotation woody crop study located on the US Department of Energy's Savannah River Site outside Aiken, SC. This study included fertilization and irrigation treatments on five tree genotypes (sweetgum, loblolly pine, sycamore and two eastern cottonwood clones). Prior to study installation, the previous pine stand was harvested and the remaining slash and stumps were pulverized and incorporated 30 cm into the soil. One year after harvest soil carbon levels were consistent with pre-harvest levels but dropped in the third year below pre-harvest levels. Tillage increased soil carbon contents, after three years, as compared with adjacent plots that were not part of the study but where harvested, but not tilled, at the same time. When the soil response to the individual treatments for each genotype was examined, one cottonwood clone (ST66), when irrigated and fertilized, had higher total soil carbon and mineral associated carbon in the upper 30 cm compared with the other tree genotypes. This suggests that root development in ST66 may have been stimulated by the irrigation plus fertilization treatment.     

Gasification biochar as a valuable by-product for carbon sequestration and soil amendment

Thermal gasification of various biomass residues is a promising technology for combining bioenergy production with soil fertility management through the application of the resulting biochar as soil amendment. In this study, we investigated gasification biochar (GB) materials originating from two major global biomass fuels: straw gasification biochar (SGB) and wood gasification biochar (WGB), produced by a Low Temperature Circulating Fluidized Bed gasifier (LT-CFB) and a TwoStage gasifier, respectively, optimized for energy conversion. Stability of carbon in GB against microbial degradation was assessed in a short-term soil incubation study and compared to the traditional practice of direct incorporation of cereal straw. The GBs were chemically and physically characterized to evaluate their potential to improve soil quality parameters. After 110 days of incubation, about 3% of the added GB carbon was respired as CO₂, compared to 80% of the straw carbon added. The stability of GB was also confirmed by low H/C and O/C atomic ratios with lowest values for WGB (H/C 0.12 and O/C 0.10). The soil application of GBs exhibited a liming effect increasing the soil pH from ca 8 to 9. Results from scanning electron microscopy and BET analyses showed high porosity and specific surface area of both GBs, indicating a high potential to increase important soil quality parameters such as soil structure, nutrient and water retention, especially for WGB. These results seem promising regarding the possibility to combine an efficient bioenergy production with various soil aspects such as carbon sequestration and soil quality improvements.     

Increment and biomass in hybrid poplar and some practical implications

Growth data were collected from 41 stands of poplar (Populus sp.) growing on former farmland in Sweden, situated between latitudes 55 and 63° N. The mean age of the poplar was 20 years (range 4-73), the mean stand density 1327 stems ha⁻¹ (range 155-4690), and the mean diameter at breast height (over bark) 210 mm (range 49-447 mm). Soil types in the poplar stands were mainly clay (25 stands), other sediments (six stands) and sandy-silty till (10 stands).The mean total standing dry weight above stump level (≈200 mm) for poplar was 141.9 ± 13.9 ton ha⁻¹ with a range of 19-438 ton ha⁻¹. In addition to estimating conventional dry weights of trees and tree components, SLA, PLA and LAI, among other measures, were estimated and were in agreement with published figures.The results indicate that poplar stands could produce 70-105 ton ha⁻¹ after 10-15 years growth mainly used for biofuel. Otherwise, the stands could be thinned for pulpwood and timber production with a rotation period of 25-30 years and the thinnings used for biofuel.     

A management tool for estimating bioenergy production and carbon sequestration in Eucalyptus globulus and Eucalyptus nitens grown as short rotation woody crops in north-west Spain

This study proposes stand level models for estimating biomass yield, total energy and carbon sequestration in Eucalyptus globulus and Eucalyptus nitens plantations, on the basis of measurements made in 131 plots established at the usual range of initial forest densities for southwestern Europe. The timber volume, total aboveground biomass, logging residue biomass, crown biomass, carbon in aboveground biomass and soil organic layer, energy in aboveground biomass, energy in logging residue biomass and usable cellulose yield were represented in the form of isolines (taking mortality into account) and plotted against dominant height. These variables were calculated and compared with previously published data on two silvicultural options for short rotation forestry, one destined for bioenergy production and the other consisting of the standard silviculture regime applied to both species in southern Europe, considering the average site index for each species. Yield levels were higher in E. nitens than in E. globulus for all variables because of faster diameter increment at similar densities. The total yield in terms of biomass was 13.9-14.6 Mg ha⁻¹ y⁻¹ for E. globulus and 20.4-21.5 Mg ha⁻¹ y⁻¹ for E. nitens. Energy in aboveground biomass ranged between 233 and 245 GJ ha⁻¹ y⁻¹ for E. globulus and 345 and 364 GJ ha⁻¹ y⁻¹ for E. nitens, carbon accumulation rate in aboveground biomass and soil organic layer was 6.9-7.2 Mg ha⁻¹ y⁻¹ for E. globulus and 12.7-13.5 Mg ha⁻¹ y⁻¹ for E. nitens, and usable cellulose was 5.7-5.9 Mg ha⁻¹ y⁻¹ for E. globulus and 9.0-10.1 Mg ha⁻¹ y⁻¹ for E. nitens. It was found that 50% increments in the initial density result in only marginal increments in biomass and usable cellulose yields.     

The carbon sequestration potential of unmanaged forest stands in Finland under changing climatic conditions

Changes in stand-level carbon (C) storage and C flows in biomass, litter and soil organic matter in the humus layer were studied under current and changing climatic conditions in Finland with the help of a gan-type simulation model. The changing climate scenario assumed increases in mean annual temperature of 0.4°C per decade for the first one hundred years and 0.2°C per decade for the second hundred years. Warming was assumed to be larger during the winter than during the other seasons.

In southern Finland, the long term average (over 200 years) net forest ecosystem production (NEP) at the stand level was 0.4–1.0 Mg C/ha/a under the current climatic conditions, and 0.1–0.9 Mg C/ha/a under changing conditions, depending on the tree species. Under the climate change scenario, NEP decreased in Scots pine, Norway spruce and Pubescent birch stands, but increased in Pendula birch stands. During the first 25–50 years, however, NEP was found to be larger both in Scots pine and Pubescent birch stands. In northern Finland, the long term average NEP increaed, regardless of tree species, from 0.3–0.8 Mg C/ha/a to 0.4–1.0 Mg C/ha/a. The biggest changes took place in Norway spruce and Pendula birch stands.

During the early and late phases of stand development, the stands were C sources, since emissions from decaying litter and soil organic matter in the humus layer exceeded the growth of vegetation. Stands became C sources earlier under the changing climatic conditions than under the current conditions. In southern Finland, the long term average C storage was 107–201 Mg C/ha under the current climatic conditions, and 88–142 Mg C/ha under the changing conditions, depending on tree species. In northern Finland, the long term average C storage was 77–151 Mg C/ha under the current climatic conditions and 89–177 Mg C/ha under the changing conditions.     

Comparison of the performance of several hybrid poplar clones and their potential suitability for use in northern China

The performance of 14 North American hybrid poplar clones was evaluated near Beijing in short-rotation plantations grown at a 1 × 1 m spacing. Significant clonal differences were found in eco-physiological and morphological characteristics. Clones DN-17, DN-2, DN-182, DN-14274, 328-162, and NM6 exhibited high emergence and survival rates, and DN-17, DN-14274, DN-182 and NE-222 had a short growing period. Other clones (306-45, 195-522, 184-411 and 328-162) had a long growing period and may be more suitable in southern China. Clones DN-2, DN-182, and 195-522, had the highest productivity and the best potential as biomass producers. Clones DN-14274, DN-17, DN-182, NE-222, and DTAC-7 allocated more belowground biomass than the other clones during the first growing season, indicating that they might be better adapted to arid regions such as those in northern China. Clones 195-522, 184-411, DTAC-7, NE-222, R-270 and 306-45 had a higher capacity for CO₂ assimilation. Clones NE-222, 306-45, DTAC-7, 195-522, R-270, 15-29, and DN-17 had a higher photosynthetic potential and could potentially adapt to a wide range of environmental conditions. Clones 195-522, 184-411, 328-162, DN-182, and NM6 had higher water-use efficiency than the others, suggesting that they would utilize soil water more effectively, especially in the dry season and in arid regions. Clones R-270, DN-14274, 15-29, DN-2, and DTAC-7 had higher transpiration rates, indicating that they would require frequent irrigation in the dry season and in arid regions to ensure normal survival and growth.     

Catalysis and oxidation of carbon in a hybrid direct carbon fuel cell

The hybrid direct carbon fuel cell (HDCFC), combining molten carbonate fuel cell and solid oxide fuel cell technology, is capable of converting solid carbon directly into electrical energy without intermediate reforming. Here, we report the investigation of the HDCFC with yttria stabilized zirconia (YSZ) electrolyte, NiO-YSZ anode and lanthanum strontium manganite (LSM) cathode using the eutectic mixture of 62 mol% Li₂CO₃ and 38 mol% K₂CO₃. An open circuit voltage (OCV) of 0.71 V at 800 °C is recorded without the carbonate which increases to 1.15-1.23 V in the presence of the carbonate at the same temperature. In addition, the cell's OCV is enhanced not only by the thermal history but also by the carbonate, which is in excess of 1.57 V after the high temperature treatment. Electrochemical performance analysis indicates a suitable amount of the carbonate enhanced the carbon oxidation. With 1 mm robust thick electrolyte and commercial carbon, the cell (1.13 cm² active area) generates the peak density of 50 mW cm⁻² at 800 °C. There are significant losses from electrolyte resistance, which would be overcome by the application of a thinner electrolyte.     

Covalent hybrid of hemin and mesoporous carbon as a high performance electrocatalyst for oxygen reduction

A high performance hemin and mesoporous carbon hybrid electrocatalyst for the oxygen reduction reaction (ORR) is developed by using hemin as the Fe–N-containing precursor to control the chemistry of the metal and the chemical composition of the carbon surface. As a first step, Hemin is used as the Fe–N-containing precursor to prepare the Fe–N-doped mesoporous carbon (H-MC) via a nano-casting process by using sucrose as a carbon source and mesoporous silica as a hard template. Hemin is then used as the Fe–N₄-containing precursor to prepare H-MC supported hybrid catalyst. The Fe-doped and N-doped mesoporous carbons are also prepared and the catalytic properties of the prepared catalysts for ORR in alkaline media are investigated. The results show that as compared with the much more expensive Pt/C catalyst, the hybrid catalyst obtained in this work exhibits not only a higher onset potential, but also a higher current density.     

Soil organic carbon changes in the cultivation of energy crops: Implications for GHG balances and soil quality for use in LCA

The environmental impact of different land-use systems for energy, up to the farm or forest “gate”, has been quantified with Life Cycle Assessment (LCA). Four representative crops are considered: OilSeed Rape (OSR), Miscanthus, Short-Rotation Coppice (SRC) willow and forest residues. The focus of the LCA is on changes in Soil Organic Carbon (SOC) but energy use, emissions of GreenHouse Gases (GHGs), acidification and eutrophication are also considered. In addition to providing an indicator of soil quality, changes in SOC are shown to have a dominant effect on total GHG emissions. Miscanthus is the best land-use option for GHG emissions and soil quality as it sequesters C at a higher rate than the other crops, but this has to be weighed against other environmental impacts where Miscanthus performs worse, such as acidification and eutrophication. OSR shows the worst performance across all categories. Because forest residues are treated as a by-product, their environmental impacts are small in all categories. The analysis highlights the need for detailed site-specific modelling of SOC changes, and for consequential LCAs of the whole fuel cycle including transport and use.     

Characterization of fine root system and potential contribution to soil organic carbon of six perennial bioenergy crops

Perennial bioenergy crops provide biomass for renewable energy production, but also sequester atmospheric carbon (C) in the soil. Roots represent one of the most important soil C inputs-root length density (RLD, cm cm⁻³), root diameter and fine root biomass (FRB, Mg ha⁻¹) in the top 1 m of soil were characterized for three woody (poplar, black locust, willow) and three herbaceous (giant reed, miscanthus, switchgrass) perennial crops in the same location. The vertical distribution of FRB and RLD was described by fitting the “beta” (β) model to the experimental data. The herbaceous species had higher β values for FRB and RLD than woody crops, suggesting that the former explore the deeper soil layers with a greater proportion of roots. In particular, 3.7 Mg ha⁻¹, or 43% of the whole root mass, was found below the ploughing soil layer (0.3 m) for the herbaceous species, while only 1.2 Mg ha⁻¹, or 26% of the whole root mass, was allocated by woody crops to the same soil layer. In all the species, the majority of the sampled roots (99.1%) had a diameter lower than 2 mm, and in the first 10 cm of the soil the woody species tended to produce roots with a smaller diameter than those of the herbaceous species. Overall, the herbaceous crops have a higher potential to contribute to C storage in the deep soil layers, while the woody species, have a greater potential to affect soil organic carbon in the top soil layer.     

Facile synthesis of hybrid porous composites and its porous carbon for enhanced H2 and CH4 storage

The anticipated energy crisis due to the extensive use of limited stock fossil fuels forces the scientific society for find prompt solution for commercialization of hydrogen as a clean source of energy. Hence, convenient and efficient solid-state hydrogen storage adsorbents are required. Additionally, the safe commercialization of huge reservoir natural gas (CH₄) as an on-board vehicle fuel and alternative to gasoline due to its environmentally friendly combustion is also a vital issue. To this end, in this study we report facile synthesis of polymer-based composites for H₂ and CH₄ uptake. The cross-linked polymer and its porous composites with activated carbon were developed through in-situ synthesis method. The mass loadings of activated carbon were varied from 7 to 20 wt%. The developed hybrid porous composites achieved high specific surface area (SSA) of 1420 m²/g and total pore volume (TPV) of 0.932 cm³/g as compared to 695 m²/g and 0.857 cm³/g for pristine porous polymer. Additionally, the porous composite was activated converted to a highly porous carbon material achieving SSA and TPV of 2679 m²/g and 1.335 cm³/g, respectively. The H₂ adsorption for all developed porous materials was studied at 77 and 298 K and 20 bar achieving excess uptake of 4.4 wt% and 0.17 wt% respectively, which is comparable to the highest reported value for porous carbon. Furthermore, the developed porous materials achieved CH₄ uptake of 8.15 mmol/g at 298 K and 20 bar which is also among the top reported values for porous carbon.     

Performance analysis of hybrid power configurations: Impact on primary energy intensity,carbon dioxide emissions,and life cycle costs

Utilization of Natural gas and Hydrogen to support current and future building energy needs to offset the total electric demand while improving the grid resiliency and energy efficiency was investigated. Demand side energy management will play an important role in efficiently managing the available energy resources. Performance assessment of different power generation and energy management configurations is presented in this paper. Development of solutions in addressing grid resiliency by providing the ability to design suitable configurations for meeting individual building energy needs is discussed. Primary movers (PM) such as internal combustion engines (ICE) and fuel cells (FC) along with small scale auxiliary renewable energy source such as photovoltaics (PV) were considered. Key attributes of total carbon foot-print, life cycle costs including capital and operational expenditure, electric grid offset or peak shaving capability, thermal energy availability and its further potential to offset total electric demand, and primary energy intensity are analyzed and discussed in detail.