三光子吸收效应对孤子对传输的影响

用分步傅里叶变换法求解含三光子吸收效应的光孤子NLS方程，研究了三光子吸收效应对孤子对在传输中相互作用的影响。研究发现，在特定条件下，三光子吸收效应能使孤子对无离合地平行传输。     

光纤放大器中孤子传输的三光子吸收效应

本文用普通数学方法近似求解了含三光子吸收效应的ＮＬＳ方程，由此孤子解讨论了三光子吸收效应对孤子传输的影响。     

光纤放大器中孤子传输的高阶效应

本文求解了含三光子吸收、非线性高阶色散和自感应Raman效应的NLS方程,由此解讨论了光纤放大器的高阶效应对孤子传输的影响.     

GaAs半导体中三光子吸收的非线性光电导测量

采用非线性光电导技术测量2.06μm激光激发的GaAs本征半导体三光子吸收,观察到三光子和单光子吸收的混合光电导,测得了三光子吸收系数.测量结果与理论计算符合较好.     

多光子吸收对差频产生太赫兹波影响的理论研究

理论分析了双光子和三光子吸收对非线性材料差频产生太赫兹(THz)波的影响,在不同抽运功率下,计算了相位失配情况下晶体的最佳作用长度和THz的最大量子转化效率,并将其与相位匹配情况进行对比。研究结果表明,抽运功率不太高时,多光子吸收对差频产生THz波影响不大;随着抽运功率的提高,多光子吸收的影响变得显著;抽运功率较高时,相位匹配与相位失配情况下,双光子和三光子吸收效应都增加了晶体的最佳作用长度,降低了THz的最大转化效率。研究了降低多光子吸收的方法。     

光纤放大器中的孤子传输特性

本文求解了含高阶色散和双光子吸收效应的ＮＬＳ方程，由此孤子解讨论了高阶色散和双光子吸收效应对光纤放大器孤子传输的影响。     

光纤放大器中孤子传输的双光子吸收效应

本文求解了含双光子吸收效应和喇曼自感应效应的ＮＬＳ方程，由此孤子解讨论了双光子吸收和喇曼自感应效应对光纤放大器中孤子传输的影响。     

双光子吸收和啁啾效应对孤子脉宽的影响

本文求解了含频率啁啾和双光子吸收效应的ＮＬＳ方程，由得到的孤子解讨论了中啁啾和双光子吸收效应对孤子脉宽的影响。     

暗孤子传输中的双光子吸收效应的特性研究

用行波法求解了含双光子吸收效应的暗孤子非线性薛定格（NLS）方程,由此孤子解讨论了暗孤子传输特性。     

直接以三光子激发的受激发射

多光子过程，1931年就有人做过理论预言^[1]，长期以来主要从学术兴趣方面去考虑。由于双光子吸收与强度的平方关系。吸收过程能产生空间隙限定激发，可用于三维数据存储和三维成像^[2,3]。高效双光子灵敏材料的发展，带来很多技术应用^[4-28]。并且激起了开发以三光子激发为基础的应用^[29]兴趣。三光子过程可使用较长的激发波长，如光能信中通常使用的那些波长。而且，三光子过程和输入光强的立方关系提供更强的空间限定，在成像中间可得到更高的对比度。本文报道在有机发色团溶液中，在1.3μm同时发现强烈的三光子吸收，以放大自发辐射产生高度定向上转换受激发射的检测，这个进展意味着，在频率上转换激光领域、短脉冲光通信领域和新兴的生物光子学领域为三光子过程提供了机遇。     

两种新型芴类衍生物的三光子吸收特性研究

为了研究分子结构对三光子吸收的影响,合成了两种新型芴类衍生物,分别是2,7-二（2-4（甲氧基苯基）乙炔基）-9,9-二辛基-9H-芴（A）和2-溴-7-（2-（4-甲氧基苯基）乙炔基）-9,9-二辛基-9H-芴（B）,采用1064nm的Nd∶YAG激光器测试其三光子吸收截面的方法,得到了它们的三光子吸收截面分别高达（6.03±0.6）×10-76cm6·s2/photon2和（4.25±0.4）×10-76cm6·s2/photon2的结果,在高斯03软件下,用密度泛函方法对这两个分子进行了结构优化,并用含时密度泛函理论计算了它们的激发态能量和电子轨道。结果表明,分子内电荷转移方向对三光子吸收存在影响。     

Two- and three-photon absorption based optical limiting and stabilization using a liquid dye

It is experimentally shown that both two- and three-photon absorption in a high-molar-concentration chromophore system can be more efficiently utilized to accomplish optical power limiting and stabilization at laser wavelengths of 1.064 and /spl sim/1.3 /spl mu/m, respectively. The nonlinear absorbing medium is a novel liquid dye system, trans-4-[4-(dihexylamino)styryl]-N-(2-{2-[2-(2-hydroxy-ethoxy) -ethoxy]-ethoxy}ethyl)-pyridini um p-tosylate (abbreviated as ASEPT), consisting of chromophore molecules capable of multiphoton absorption in the near IR range. The nonlinear transmission property and output/input characteristics have been studied based on this liquid dye system, using nanoseconds 1.064-/spl mu/m laser pulses for two-photon excitation and /spl sim/1.3-/spl mu/m subpicoseconds laser pulses for three-photon excitation. A fairly good optical stabilization capability of this new material has been demonstrated at both laser wavelengths. The relative intensity fluctuation of the laser pulses can be remarkably reduced by simply passing through this multiphoton absorbing medium.     

One-, two-, and three-photon pumped lasing in a novel liquid dye salt system

We report the observation of one-, two-, and three-photon pumped lasing in the same medium, a novel liquid dye salt system when excited by pulsed 0.532-, 1.06-, and /spl sim/1.49-/spl mu/m coherent radiation pulses, respectively. Since the gain medium is a liquid and not a solution, it contains a significantly higher effective dye concentration and, therefore, is highly suitable for multiphoton pumped lasing and optical power limiting applications. The lasing spectra, temporal waveforms, near- and far-field intensity distributions, and output/input efficiency were measured under the conditions of one-, two-, and three-photon pump configurations.     

不同激光脉冲作用下ZnS晶体非线性光学特性

用Z-scan技术在532 nm的皮秒激光脉冲和800 nm飞秒激光脉冲作用下分别研究了ZnS晶体的非线性吸收及非线性折射特性。实验结果表明,ZnS晶体在532 nm的皮秒激光脉冲作用下非线性吸收为双光子吸收,其非线性吸收系数为5.310-11 m/W,在800 nm的飞秒激光脉冲作用下非线性吸收为三光子吸收,非线性吸收系数为0.5910-21 m2/W2;在532 nm皮秒激光脉冲作用下,ZnS晶体的非线性折射率符号为负,自由载流子产生的非线性折射率的改变占主导,而800 nm飞秒激光脉冲作用下,ZnS晶体的非线性折射率符号为正,束缚电子产生的非线性折射率的改变为主要因素。     

The nonlinear optical properties of AlGaAs at the half band gap

We report experimental values for the nonlinear optical coefficients of AlGaAs, in the half-band-gap spectral region. The dispersion of the nonlinear refractive-index coefficient, n₂, is measured for both TE- and TM-polarized light. We observe n₂(TE)>n₂(TM) and a ratio of cross-phase modulation to self-phase modulation (TE) of ~0.95, as predicted from band structure calculations. The spectral dependence of the two- and three-photon absorption coefficients are also measured. Finally, the implications for all-optical switching and spatial soliton propagation are discussed     

Multiphoton excitation processes between vibrational states of molecules

An approximation method has been developed to evaluate the perturbation theory expressions for the probabilities of two- and three-photon transitions among vibrational-rotational levels of diatomic and polyatomic molecules. The sum over intermediate rotational states and the degenerate quantum numberMis evaluated for a general case, and the sum over intermediate vibrational states for particular cases. The molecule is taken to be a rotating anharmonic oscillator. The electrical anharmonicity and the effects of the electronic states of the molecule are considered. Two- and three-photon processes, with or without the presence of near-resonant intermediate states, should be observable with available infrared lasers. However, the intensities predicted for the observation of three-photon excitation would result in more dominant effects such as dissociation or gas breakdown.     

用于超快宽带激光防护的共轭扭曲并苯高性能光限幅材料

高性能的光限幅对激光防护应用来说非常重要。虽然光限幅相关的研究持续了几十年,但是绝大多数的已知光限幅材料无法兼顾低限幅阈值、高线性透过率和宽带、超快响应。从实验和理论上报道一种基于共轭扭曲并苯分子的多功能光限幅材料。研究结果显示,借助等效三光子吸收,该材料能够在480~700 nm的光谱范围内实现光限幅并具备快速的响应能力。此外,样品还同时具备低限幅阈值（0.15 J/cm2）和极高的线性透过率（532 nm时92%）。该光限幅材料集以上所有优点于一身,在用于人眼和光子器件的超快激光防护领域具有巨大的前景。     

Saturable absorbers based on impurity and defect centers incrystals

Saturation of near-infrared absorption and transmission dynamics are investigated in tetravalent-chromium-doped Gd₃Sc₂ Ga₃O₁₂, Gd₃Sc₂Al₃ O₁₂, and Mg₂SiO₄ crystals, as well as in reduced SrTiO₃ using 20 ps 1.08 μm laser pulses. An absorption cross section of (5±0.5)×10^-18 cm² in garnets and (2.3±0.3)×10^-18 cm² in forsterite is estimated for the ³A ₂-³T₂ transition of tetrahedral Cr⁴⁺. Q-switched and ultra-short pulses are realized in neodymium lasers using chromium-doped crystals as the saturable absorbers. Saturation of free-carrier absorption with ultra-short relaxation time is observed in SrTiO₃ at 10⁸-10 ¹⁰ W/cm² pump intensities, while at 10¹⁰-10¹¹ W/cm² three-photon interband transitions predominate. The free-carrier absorption cross section is estimated to be (2.7±0.3)×10^-18 cm²     

二维有机-无机杂化钙钛矿非线性光学研究进展（特邀）

自从钙钛矿材料问世以来,有机-无机杂化钙钛矿材料在近数十年的时间得到了蓬勃发展。二维（2D）有机-无机杂化钙钛矿是由典型的无机八面体框架以及不同的有机阳离子构成,其具有本征的量子阱结构和有趣的光电特性,也因此在发光、传感器、调谐、光伏体系以及通讯设备等领域引起了人们的密切关注。低成本、可溶液法制备、以及可替换的有机阳离子等特性使二维杂化钙钛矿在光学和光子应用中具有灵活的层间距,层数和可变的晶格扭曲,从而实现可调节的框架以及在光学和光子学应用中的高调节度。尤其地,它们也表现出突出的二阶、三阶和高阶非线性光学特性,例如在激光脉冲激发下的二次谐波产生（SHG）、太赫兹 、双光子吸收（2PA）和饱和吸收（SA）和三光子吸收（3PA）等。讨论了具有不同结构特点的二维杂化钙钛矿的构建,并重点介绍了这些二维杂化钙钛矿在线性和非线性光学领域地特性和应用。最后,对二维杂化钙钛矿的研究现状进行了评估,并对其未来发展进行了展望。