Purification of undergound waters of manganese compounds using a natural sorbent-catalyst

Natural underground waters often contain manganese ions in such amount that the water becomes hazardous for human health. We have developed the technology of obtaining sorbent-catalyst based on oxide-carbonate ore of the Nikopol Deposit (Ukraine). We have also determined conditions for using the given material for purification of underground water with a high content of manganese.     

Uranium (VI) in natural waters: Study of occurrence forms

A comparative study of U(VI) occurrence forms in natural waters has been conducted on the basis of experimental determination of the faction of U(VI) soluble and colloidal forms and the calculation of the specified forms by using the known stability constants. It was shown that the forms of U(VI) radionuclide in aqueous media could considerably change depending on the concentration of U(VI), carbonate ions, and suspended particles of different nature. It has been found out that uranium U(VI) at the level of its typical concentrations (several micrograms and less) occurs in natural waters in soluble different-metal and carbonate forms.     

一座传统村落的前世今生——新技术、保护概念与乐清南阁村保护规划的关联性

本文简要回顾了南阁村保护规划过程中所思考的一些具有普遍意义的问题,以及由于应用数字技术而出现的对传统空间认知与分析方法方面所作的一些改进。传统文化遗产的保护与传承是一件十分复杂的工作。保护不是简单地守成,而是在一个已经发生巨变了的社会经济环境中对中断的历史进行重新疏理,并将其融入新的社会环境中。     

Permeation liquid membrane as a tool for monitoring bioavailable Pb in natural waters

In order to predict metal bioavailability by microorganisms in natural waters, analytical speciation techniques such as the permeation liquid membrane (PLM) are required. A planar sheet PLM has been characterized by measuring Pb fluxes in the absence and presence of tiron and nitrilotriacetic, iminodiacetic, malonic, citric, polyacrylic and fulvic (Suwannee River fulvic, SRFA) acids. Important parameters such as the diffusion coefficient in the membrane phase and the effective distribution coefficient between the solution and membrane were evaluated in order to determine limiting conditions for the overall transport flux through the membrane. Subsequently, the PLM was tested for its ability to predict bioavailability by the freshwater alga, Chlorella kesslerii by comparing Pb PLM fluxes (JPLM) to Pb biouptake fluxes (Jint) in the absence and presence of the synthetic ligands and SRFA. The capability of the PLM to mimic transport across biological membranes was demonstrated, in particular, from the similarity between the accumulated (PLM, algal) Pb vs. time plots under the different conditions. Under membrane transport limiting conditions, fluxes across both the PLM and biological membranes were proportional to the free metal ion and directly correlated to each other in the zone below saturation of the biological metal uptake sites. The correlation between the different fluxes may be used to predict Pb uptake by C. kesslerii in the presence of the synthetic ligands. However, in the presence of SRFA, the observed Jint was much higher than predicted by results obtained either in the absence or presence of the synthetic ligands.     

走绿色低碳地产发展之路

房地产处于国民经济各产业链的中游,与20余个产业相关,在房地产领域推广绿色低碳战略,将拉动上游的绿色生产,拉动下游的绿色消费。如采用大量的可再生能源、低碳技术及绿色建材产品,势必带动相关行业的发展,为我国产业结构调整和产能过剩提供一条十分重要的途径。     

F-specific RNA coliphages: occurrence,types, and survival in natural waters

A small, well-defined watershed was investigated over a 2-year period to determine the prevalence of F-specific RNA coliphage (F + RNA) serotypes as indicators of animal fecal contamination. Sampling sites collected runoff from areas of urban and agricultural land use patterns. F-specific coliphages were concentrated from 2-L freshwater samples by polyethylene glycol precipitation, isolated using the double agar layer (DAL) method, confirmed as F + RNA by RNAse suppression, and serotyped. A subset of serotyped F + RNA were confirmed by genotyping. To determine relative survival, 10 confirmed F + RNA field isolates and 5 prototypic F + RNA were spiked into surface water and incubated at 25 degrees C for 36 days. F-specific coliphage isolation was strongly associated with rainfall events and was infrequent from primarily animal impacted surface waters. Field isolates were predoffiinantly Type I F + RNA (81%) and raw sewage isolates were predominantly Type III F + RNA (57%). Genotyping from either the watershed or raw sewage samples never positively identified Type IV F + RNA. Results from laboratory studies showed that F + RNA differ in their survival in water and that Type IV strains were the least persistent. Type III F + RNA were found to be reliably related to the release of uncontrolled human fecal material in the watershed, but the results of this study suggest that further study is required before utilizing for fecal source identification in natural waters.     

Numerical study of flow anisotropy within a single natural rock joint

The paper investigates the flow anisotropy within a natural joint subjected to mechanical shear. The cubic law is the simplest way to describe fluid flow through rock joints but because of rock wall roughness, deviations from this model have been observed. The Reynolds equation usually gives better results. In this study, micro-scale roughness is taken into account to define a reduced coefficient of permeability. Numerical simulations have been carried out by applying Darcy's law to the rock joint, described as an equivalent porous medium. The numerical simulations are based on experimental data obtained by Hans (PhD, Grenoble, 2002) from a series of hydromechanical shear tests on a rock joint replica. The numerical results have been compared to the experimental ones, and to the results obtained by applying the Reynolds equation, to assess the relevance of the simulations. For the fracture studied, the approach proposed herein can reproduce relatively well the experimental flow anisotropy, and provides consistent values of flow rates, whereas the Reynolds equation tends to give higher flow rates.     

Decay of intestinal enterococci concentrations in high-energy estuarine and coastal waters: towards real-time T90 values for modelling faecal indicators in recreational waters

Intestinal enterococci are the principal 'health-evidence-based' parameter recommended by WHO for the assessment of marine recreational water compliance. Understanding the survival characteristics of these organisms in nearshore waters is central to public health protection using robust modelling to effect real-time prediction of water quality at recreation sites as recently suggested by WHO and the Commission of the European Communities Previous models have more often focused on the coliform parameters and assumed two static day-time and night-time T90 values to characterise the decay process. The principal driver for enterococci survival is the received dose of irradiance from sunlight. In the water column, transmission of irradiance is determined by turbidity produced by suspended material. This paper reports the results of irradiated microcosm experiments using simulated sunlight to investigate the decay of intestinal enterococci in relatively turbid estuarine and coastal waters collected from the Severn Estuary and Bristol Channel, UK. High-turbidity estuarine waters produced a T90 value of 39.5 h. Low-turbidity coastal waters produced a much shorter T90 value of 6.6 h. In experiments receiving no irradiation, high-turbidity estuarine waters also produced a longer T90 of 65.1 h compared with corresponding low-turbidity coastal waters, T90 24.8 h. Irradiated T90 values were correlated with salinity, turbidity and suspended solids (r>0.8, p<0.001). The results suggest that enterococci decay in irradiated experiments with turbidity >200 NTU is similar to decay observed under dark conditions. Most significantly, these results suggest that modelling turbidity and or suspended solids offers a potential means of predicting T90 values in 'real-time' for discrete cells of a hydrodynamic model.     

Photochemistry of excited-state species in natural waters: A role for particulate organic matter

Laser flash photolysis (LFP) was used to characterize a triplet excited state species isolated from Black River and San Joaquin wetlands particulate organic matter (POM). The solubilized organic matter, isolated from POM by pH-independent diffusion in distilled water, was named PdOM. UV–visible absorption spectroscopy, excitation–emission matrix spectroscopy (EEMs), and ¹H NMR were used to characterize the PdOM. While LFP of dissolved organic matter (DOM) is known to generate the solvated electron, LFP of the PdOM transient in argon-, air-, and nitrous oxide-saturated solutions indicated that this was a triplet excited state species (³PdOM*). The lifetime and the reactivity of ³PdOM* with sorbic acid, a triplet state quencher, were compared with that of the triplet excited state of benzophenone, a DOM proxy. A second excited state species (designated DOM*), with a longer lifetime, was reported in a number of previous studies but not characterized. The lifetime of DOM*, measured for seventeen organic matter isolates, lignin, tannic acid, and three wetlands plant extracts, was shown to differentiate allochthonous from autochthonous DOM. ³POM* and DOM* were also observed in lake water and a constructed wetlands' water. Aqueous extracts of fresh and aged plant material from the same wetland were shown to be one source of these excited state species. This study provides evidence of a role for POM in the photochemistry of natural and constructed wetland waters.     

Results of a simple intercomparison of natural radioactivity measurements using a 'blue concrete' sample

A simple intercomparison of natural radioactivity and radon emanation factor measurements co-ordinated by the Medical Physics Department of the University of Cantabria UC, Spain, has been carried out during 1998 in the framework of the EU Concerted Action ERRICCA (European Research into Radon in Construction Concerted Action). All the measurements have been made on a 'blue concrete' sample kindly donated by Dr G. Akerblom from the Swedish Radiation Protection Institute. In addition to UC, two other participant laboratories, STUK from Finland and ZVD from the Republic of Slovenia, have contributed to the development of the intercomparison exercise. Considering the uncertainties of the measurements, a good agreement between the results obtained by the three participating laboratories has been ascertained. However, in accordance with experimental results obtained by other authors, data reported by UC show a significant decrease of the radon emanation factor as moisture content of the sample decreases below 5% (per weight).     

Formation of a test system and the choice of test criteria when biotesting natural waters

Described are main problems of biotesting natural water. Defined are principles for formation of a test system and factors influencing it. Proposed are main areas for the choice of sensitive test reaction of organisms and test criteria for assessing the quality of natural water by the results of their biotesting.     

Characterization of isolated fractions of dissolved organic matter from natural waters and a wastewater effluent

Dissolved organic matter (DOM) was concentrated from natural waters and the effluent of a wastewater treatment plant using a portable reverse osmosis (RO) system. The humic acid (HA), fulvic acid (FA) and hydrophilic (HyI) fractions were isolated and purified by the XAD-8 resin combined with the cation exchange resin method. The FA fractions predominated in natural waters and accounted for 54-68% of the total amount of dissolved organic carbon (DOC), whereas the HA and HyI fractions constituted, respectively, 13-29 and 9-30% of the total DOC. The effluent of wastewater was almost devoid of HA and the HyI fraction exceeded FA. The elemental compositions of HA and FA were in the ranges typical for natural humic materials, but the HyI fractions did not exhibit humic character. 1H NMR spectra revealed that the HyI fractions were almost devoid of aromatic protons and the aliphatic region featured more sharp signals than HA and FA fractions, indicating that HyI fractions were consisted of more simple compounds and less complex mixtures. The aliphatic functional groups in these fractions of DOM samples followed the order HA < FA HyI. The rate of Cu complexation with the HyI fraction was faster than the rate with the HA or FA fraction of the Suwannee River DOM, implying that copper reacted with relatively weak ligands faster than with strong ligands.     

Aluminum speciation in natural waters: measurement using Donnan membrane technique and modeling using NICA-Donnan

The study of Al speciation is of interest for the assessment of soil and water quality. For the measurement of "free" aluminum (Al3+), a recently developed Donnan membrane technique was tested by measuring Al3+ in aluminum-fluoride solutions and gibbsite suspensions. It shows that the Donnan membrane technique can measure free Al3+ reliably up to 10(-9) M and the equilibration takes 3-4 days. Next, Al binding to humic acid (HA) purified from a forest soil was measured using either the Donnan membrane technique or gibbsite suspension. Results were compared with those predicted with the non-ideal consistent competitive adsorption (NICA)-Donnan model. The predictions using the generic parameters without fitting were in reasonable agreement with the measured data. Finally, the Donnan membrane technique was used to determine Al binding to dissolved organic matter (DOM) in the solutions of 24 soil samples at pH interval of 3-7. Measurements agree well with the predictions using the NICA-Donnan model assuming 30% of DOM is HA and 30% is fulvic acid. With this model, the effects of pH and DOM changes on the concentration of Al in 81 soil solutions were predicted reasonably without adjustment of model parameters. The comparison between the results of analysis and the modeling provides a mutual validation for the two methods.     

Sorption-membrane removal of boron compounds from natural and waste waters: Ecological and economic aspects

The paper demonstrated the importance of research into the development of the methods for the removal of boron from aqueous solutions determined both by ecological and economic reasons. The paper has investigated the possibilities of the electrodialysis method and reverse osmosis in terms of separation or concentration of boron-containing solutions obtained in the course of regenerating boron-selective sorbents with the aim of creating the sorption-membrane “green” technology of removing boron from natural and waste waters. We have developed a general technological flowchart of sorption-membrane utilization of boron from the waters in question.     

Durability of concrete containing a natural pozzolan as defined by a performance-based approach

This paper deals with the application of a performance-based approach on the durability of concrete made with an Algerian natural pozzolan. The evaluation of the durability of concrete was based on the comparison of durability indicators with a reference concrete usually found in Algeria. The properties measured included general indicators (water porosity, gas permeability, capillary absorption and Portlandite content) and specific indicators related to degradation phenomena that might occur in Algeria: corrosion induced by carbonation and chlorides, and chemical attacks by sulphates and acids. For the specific degradations, the indicators measured included carbonation depths, chloride diffusion coefficients, chloride permeability, expansion and sulphate profiles, and depth of leaching due to ammonium nitrate attack. The results showed that general durability indicators were almost equivalent for all the types of concrete tested, highlighting the importance of using specific indicators for each type of exposure. The results of specific indicators for corrosion and acid attacks showed that increasing the pozzolan content led to higher resistance of the concrete. Thus, it is possible to improve the durability of typical concretes currently made in Algeria by using local materials.     

Determination of the natural stress state in a Brazilian rock mass by back analysing excavation measurements: a case study

The Serra da Mesa Hydroelectric Power Plant, located in the Tocantins river, 210 km north of Brasilia, Brazil, has been completed and power (1200 MW) has been generated since 1998. This project includes one of the largest underground structures in Brazil, totalling 550,000 m³ of underground excavations in rock for the hydraulic circuit which was excavated in very high quality granite. Geotechnical investigations, laboratory tests and geological mapping showed that the rock mass could be considered as a continuous, homogeneous, isotropic and linearly elastic (CHILE) material.

In situ tests, for obtaining the natural stress tensor, namely hydraulic fracturing and small flat jack tests (SFJ), were executed. The hydraulic fracturing tests were performed in two boreholes, at the planned position of the future underground structures. SFJ were executed in a test gallery especially constructed for the purpose. These latter tests confirmed the in situ rock stress data obtained from the hydraulic fracturing tests.

This paper presents a new technique for interpretation of the SFJ results. This is achieved by inputting the SFJ measurements into a 3D program that compiles the influence matrix of the excavated rock mass domain and then, via the least square technique, the determination of the stress tensor. All the equations are fully developed and the methodology is presented in its entirety. The successful application of the methodology is also presented, with comparisons between the results obtained and the in situ stress tensor determined by other methods.     

Priority pollutants in surface waters and settleable particles within a densely urbanised area: Case study of Paris (France)

Implementation of the European Water Framework Directive 2000/60/EC (WFD) requires Member States to expand their collective knowledge of priority pollutants (PPs) within receiving waters. To achieve this objective, information on the occurrence of PPs in surface waters and, more specifically, within densely urbanised areas needs to be collected. This study has therefore been designed to provide information on both PP occurrence and concentration build-up along a heavily urbanised transect of the Seine River in the Paris region (France). A large range of PPs were observed in settleable particles and, to a lesser extent, in the waters surveyed. In surface waters, a total of 18 PPs, including 15 priority hazardous substances?, were indeed detected, yet concentrations rarely exceeded the limit of quantification. In fact, only diuron?, DEHP?, fluoranthene and para-tert-octylphenol? are observed on a frequent basis, with concentrations ranging from < 0.01 to 1.0 µg l^− 1. As regards the Environmental Quality Standards (EQS), 10 substances or groups of substances were found in surface waters to exhibit concentrations above the annual average value, while only the benzo(a)pyrene? concentration exceed the maximum allowable level. As for the Canadian Sediment Quality Guidelines, settleable particles collected in the Seine River appear to be heavily contaminated since most samples contain PP levels above the guideline values (18 PPs) and, in many cases, above the probable effect levels (15 PPs), which underscores that the levels of metals, PAHs and PCBs in settleable particles constitute a potential risk to freshwater organisms.     

Silo-quake—measurements, a numerical approach and a way for its suppression

Silo-quake can be observed in granular bodies during silo emptying in the form of dynamic effects as pulsations or shocks. Measurements were carried out in full-scale aluminium silos containing potato powder and polymer granulates, and in a model perspex silo containing different fills to investigate this phenomenon. Theoretically, dynamic effects in silos were analysed with a finite element method developed in the frame of a polar (Cosserat) continuum using an elastoplastic and a hypoplastic approach. The onset of a dynamic silo flow with controlled and free outlet velocity in a plane strain model silo was simulated. A reliable, practical method to significantly reduce dynamic effects and to suppress resonance effects in mass flow during silo emptying was proposed. It was verified with experiments and FE-calculations.