A review of hydrogen as a compression ignition engine fuel

Diesel fuelled engines emit higher levels of carbon dioxide and other harmful air pollutants (such as noxious gases and particulates) per litre of fuel than gasoline engines. This fact, combined with the recent diesel emission scandal and the rumours of more widespread cheating by automotive manufacturers have initiated a long discussion about the future and sustainability of diesel engines.Improving the compression ignition engine is a direct way of going green. Reducing the harmful emissions can be achieved by future developments in the engine technology but also the implementation of alternative fuels. Hydrogen is a renewable, high-efficient and clean fuel that can potentially save the future of diesel-type engines. The evolution of high-efficiency renewable hydrogen production methods is the most important path for the start of a new hydrogen era for the compression ignition engine that can improve its sustainability and maximum efficiency.This paper provides a detailed overview of hydrogen as a fuel for compression ignition engines. A comprehensive review of the past and recent research activities on the topic is documented. The review focuses on the in-cylinder combustion of hydrogen either as a primary fuel or in dual fuel operation. The effects of injection strategies, compression ratio and exhaust gas recirculation on the combustion and emission characteristics of the hydrogen fuelled engine are fully analysed. The main limitations, challenges and perspectives are presented.     

Theoretical modeling and experimental studies on biodiesel-fueled engine

In recent years, much research has been carried out to find suitable alternative fuel to petroleum products. The use of renewable fuels like ethanol, biogas and biodiesel in diesel engines is significant in this context. The properties of biodiesel depend on the type of the vegetable oil used for the trans-esterification process. Experimental analysis of the engine with various biodiesel and its blends requires much effort and time. Hence, a theoretical model is developed to analyze the performance characteristics of the compression ignition engine fueled by biodiesel and its blends. In the present investigation, biodiesel is produced using unrefined rubber seed oil. A two-step trans-esterification process (i.e. acid–alkaline trans-esterification) is developed for the production of methyl-esters of rubber seed oil. The properties of this biodiesel are closely matched with those of diesel fuel. The performance tests are carried out on a C.I. engine using biodiesel and its blends with diesel (B20 and B100) as fuel. The effects of relative air-fuel ratio and compression ratio on the engine performance for different fuels are also analyzed using this model. The comparison of theoretical and experimental results are presented.     

Effect of ethanol–gasoline blends on engine performance and exhaust emissions in different compression ratios

Renewable energy sources for the gasoline engines alcohols gain importance recently. These renewable energy sources have attracted the attention of researchers as alternative fuel due to their high octane number. In addition, these are also clean energy sources and can be obtained from the biomass alcohols with low carbon like ethanol. In this study, the effect of compression ratio on engine performance and exhaust emissions was examined at stoichiometric air/fuel ratio, full load and minimum advanced timing for the best torque MBT in a single cylinder, four stroke, with variable compression ratio and spark ignition engine.     

燃氢发动机的爆震燃烧问题

随着经济和社会的高速发展,车辆的有害排放物给环境造成了严重的危害.氢气是可再生能源,作为车用发动机的替代燃料,排放的唯一有害气体是NO.但是,氢气的燃烧扩散速度太快,形成爆震燃烧的几率比汽油大得多,爆震问题是设计氢气燃料发动机要考虑的最重要的因素之一,在分析和试验的基础上,为控制氢发动机的爆震提供了参考条件.     

Influence of the equivalence ratio on the knock and performance of a hydrogen direct injection internal combustion engine under different compression ratios

Hydrogen has become an ideal alternative fuel for internal combustion engines. However, with an increase in the equivalence ratio and compression ratio, knock combustion is more likely to occur, which limits its engineering application. In this study, the effects of the equivalence ratio on the knock under different compression ratios were studied through numerical simulation. The signal energy ratio (SER) were used to evaluate the knock onset (KO). The knock intensity (KI) and engine performance were compared and analyzed under different equivalence ratios and compression ratios. The results revealed that a high compression ratio can significantly amplify the effect of the equivalence ratio on combustion and knock. Under the compression ratio of 17.5, KI increases more quickly, with the constant equivalence ratio rise and is more sensitive to ignition timing with equivalence ratio increasing. For the compression ratio of 11, the ignition timing limited by knock is about 4°CA earlier than that of compression ratio of 17.5, and the engine performance is more stable in the low-knock zone. However, when KI exceeds 1 MPa, the power and ITE decreases 20.6% and 20.9% respectively.     

Study on combustion and emission characteristics of a n-butanol engine with hydrogen direct injection under lean burn conditions

The n-butanol fuel, as a renewable and clean biofuel, could ease the energy crisis and decrease the harmful emissions. As another clean and renewable energy, hydrogen properly offset the high HC emissions and the insufficient of dynamic property of pure n-butanol fuel in SI engines, because of the high diffusion coefficient, high adiabatic flame velocity and low heat value. Hydrogen direct injection not only avoids backfire and lower intake efficiency but also promotes to form in-cylinder stratified mixture, which is helpful to enhance combustion and reduce emissions. This experimental study focused on the combustion and emissions characteristics of a hydrogen direct injection stratified n-butanol engine. Three different hydrogen addition fractions (0%, 2.5%, 5%) were used under five different spark timing (10° ,15° ,20° ,25° ,30° CA BTDC). Engine speed and excess air ratio stabled at 1500 rpm and 1.2 respectively. The direct injection timing of the hydrogen was optimized to form a beter stratified mixture. The obtained results demonstrated that brake power and brake thermal efficiency are increased by addition hydrogen directly injected. The BSFC is decreased with the addition of hydrogen. The peak cylinder pressure and the instantaneous heat release rate raises with the increase of the hydrogen addition fraction. In addition, the HC and CO emissions drop while the NOx emissions sharply rise with the addition of hydrogen. As a whole, with hydrogen direct injection, the power and fuel economy performance of n-butanol engine are markedly improved, harmful emissions are partly decreased.     

Examination of the effect of combustion chamber geometry and mixing ratio on engine performance and emissions in a hydrogen-diesel dual-fuel compression-ignition engine

The fact that fossil fuels, which supply a large amount of the energy need, are limited in the world and can be only found in certain regions, have led humankind to seek alternatives. In addition, the use of fossil fuels generates wastes detrimental to humans and nature, which has led this search to alternative, clean and renewable energy sources. The use of hydrogen, which is a clean energy source, in internal combustion engines is very important in terms of reducing emission values as well as providing an alternative to petroleum-derived fuels. This study presents a literature review on the effect of the hydrogen ratio and combustion chamber geometry on the engine performance and emissions in a compression-ignition engine operating in the hydrogen diesel bi-fuel mode. As a result of the study, it was concluded that the hydrogen energy ratio should be between 5 and 20% and the combustion chamber should be designed by considering the combustion characteristics. The main purpose of the study is to highlight the functionality of the use of hydrogen in dual fuel mode in compression ignition engines and to be a resource for researchers who will work on this subject.     

Experimental study of engine performance and emissions for hydrogen diesel dual fuel engine with exhaust gas recirculation

With an alarming enlargement in vehicular density, there is a threat to the environment due to toxic emissions and depleting fossil fuel reserves across the globe. This has led to the perpetual exploration of clean energy resources to establish sustainable transportation. Researchers are continuously looking for the fuels with clean emission without compromising much on vehicular performance characteristics which has already been set by efficient diesel engines. Hydrogen seems to be a promising alternative fuel for its clean combustion, recyclability and enhanced engine performance. However, problems like high NOx emissions is seen as an exclusive threat to hydrogen fuelled engines. Exhaust gas recirculation (EGR), on the other hand, is known to overcome the aforementioned problem. Therefore, this study is conducted to study the combined effect of hydrogen addition and EGR on the dual fuelled compression ignition engine on a single cylinder diesel engine modified to incorporate manifold hydrogen injection and controlled EGR. The experiments are conducted for 25%, 50%, 75% and 100% loads with the hydrogen energy share (HES) of 0%, 10% and 30%. The EGR rate is controlled between 0%, 5% and 10%. With no substantial decrement in engine's brake thermal efficiency, high gains in terms of emissions are observed due to synergy between hydrogen addition and EGR. The cumulative reduction of 38.4%, 27.4%, 33.4%, 32.3% and 20% with 30% HES and 10% EGR is observed for NOx, CO2, CO, THC and PM, respectively. Hence, the combination of hydrogen addition and EGR is observed to be advantageous for overall emission reduction.     

The potential role of hydrogen as a sustainable transportation fuel to combat global warming

Hydrogen is recognized as a key source of the sustainable energy solutions. The transportation sector is known as one of the largest fuel consumers of the global energy market. Hydrogen can become a promising fuel for sustainable transportation by providing clean, reliable, safe, convenient, customer friendly, and affordable energy. In this study, the possibility of hydrogen as the major fuel for transportation systems is investigated comprehensively based on the recent data published in the literature. Due to its several characteristic advantages, such as energy density, abundance, ease of transportation, a wide variety of production methods from clean and renewable fuels with zero or minimal emissions; hydrogen appears to be a great chemical fuel which can potentially replace fossil fuel use in internal combustion engines. In order to take advantage of hydrogen as an internal combustion engine fuel, existing engines should be redesigned to avoid abnormal combustion. Hydrogen use in internal combustion engines could enhance system efficiencies, offer higher power outputs per vehicle, and emit lower amounts of greenhouse gases. Even though hydrogen-powered fuel cells have lower emissions than internal combustion engines, they require additional space and weight and they are generally more expensive. Therefore, the scope of this study is hydrogen-fueled internal combustion engines. It is also highlighted that in order to become a truly sustainable and clean fuel, hydrogen should be produced from renewable energy and material resources with zero or minimal emissions at high efficiencies. In addition, in this study, conventional, hybrid, electric, biofuel, fuel cell, and hydrogen fueled ICE vehicles are comparatively assessed based on their CO₂ and SO₂ emissions, social cost of carbon, energy and exergy efficiencies, fuel consumption, fuel price, and driving range. The results show that when all of these criteria are taken into account, fuel cell vehicles have the highest average performance ranking (4.97/10), followed by hydrogen fueled ICEs (4.81/10) and biofuel vehicles (4.71/10). On the other hand, conventional vehicles have the lowest average performance ranking (1.21/10), followed by electric vehicles (4.24/10) and hybrid vehicles (4.53/10).     

Thermodynamic analysis of combustion and pollutants formation in a wood-gas spark-ignited heavy-duty engine

Awareness of limitations of petroleum based liquid fuels as for example used in spark-ignited heavy-duty engines for power generation, has led engineers to propose various solutions such as the use of alternative/renewable energy sources. Wood-gas is an alternative gaseous fuel generated from the gasification of wood, which could be used as a full supplement fuel in conventional heavy-duty spark-ignited engines fuelled with natural gas. Previous related research studies have shown that the main disadvantage of the wood-gas combustion is its negative impact on brake engine efficiency compared to the normal natural gas operation, while NO and CO emissions are also increased. Compression ratio and spark timing are some of the engine parameters, which influence significantly the combustion mechanism inside the combustion chamber of a wood-gas powered spark-ignited engine. In order to examine the effect of these parameters on the performance and exhaust emissions of a heavy-duty, turbocharged, spark-ignited engine fuelled with wood-gas, a theoretical investigation is conducted in this work by using a numerical simulation. The results concern engine performance characteristics, NO and CO emissions for various engine operating conditions (i.e. air to fuel excess ratios), by using a comprehensive two-zone phenomenological model. The predictive ability of the thermodynamic model was tested against experimental measurements, which were obtained from the operation of a multi-cylinder, four-stroke, turbocharged, spark-ignited engine fuelled with wood-gas fuel at various loads. The experimental results are found to be in good agreement with the respective computed ones obtained from the simulation model. The main objective of the comparative assessment shown in the present work is to record and comparatively evaluate the relative impact of each one of the above mentioned parameters (compression ratio and spark timing) on the engine performance characteristics and emitted pollutants. Furthermore, an effort is made to determine the optimum combinations between these parameters, since at high engine load conditions their simultaneous increase may lead in undesirable results concerning the engine performance characteristics. The conclusions from the present investigation are valuable for the use of wood-gas as a full supplement energy source in conventional, natural gas fuelled, heavy-duty, spark-ignited engines used for electric power generation.     

Experimental investigation of combustion characteristics and NOx emission of a turbocharged hydrogen internal combustion engine

In order to alleviate the contradictions of increasingly prominent environmental pollution, greenhouse gas emissions and oil resource security issues, the search for renewable and clean alternative energy sources is getting more and more attention. Hydrogen energy is known as a future energy source because of its safety, reliability, wide range of resources and non-polluting products. Hydrogen internal combustion engine combines the technical advantages of traditional internal combustion engines and has comprehensive comparative advantages in terms of manufacturing cost, fuel adaptability and reliability. It is one of the practical ways to realize hydrogen energy utilization. In this paper, the combustion characteristics and NOx emission of a turbocharged hydrogen engine were investigated using the test data. The results showed the combustion duration (the crank angle of 10%–90% fuel burned) at 1500 rpm and 2000 rpm was equal and the combustion duration is much bigger than the other loads when the BMEP is 0.27 MPa. The reason is the effect of the turbocharger on the gas exchange process, which will influence the combustion process. The cylinder pressure and pressure rise rate were also investigated and the peak pressure rise rate was lower than 0.25 MPa/°CA at all working conditions. Moreover, the NOx emission changed from 300 ppm to 1200 ppm with engine speed increasing and the maximum value can reach to 7000 ppm when the equivalence ratio is 0.88 at 2500 rpm, maximum brake torque. The NOx emission shows different changing tendencies with different working conditions. Finally, these conclusions can be used to develop controlling strategies to solve the contradictions among power, brake thermal efficiency and NOx emission for the turbocharged hydrogen internal combustion engines.     

The effects of ethanol–unleaded gasoline blends on engine performance and exhaust emissions in a spark-ignition engine

Alcohols have been used as a fuel for engines since 19th century. Among the various alcohols, ethanol is known as the most suited renewable, bio-based and ecofriendly fuel for spark-ignition (SI) engines. The most attractive properties of ethanol as an SI engine fuel are that it can be produced from renewable energy sources such as sugar, cane, cassava, many types of waste biomass materials, corn and barley. In addition, ethanol has higher evaporation heat, octane number and flammability temperature therefore it has positive influence on engine performance and reduces exhaust emissions. In this study, the effects of unleaded gasoline (E0) and unleaded gasoline–ethanol blends (E50 and E85) on engine performance and pollutant emissions were investigated experimentally in a single cylinder four-stroke spark-ignition engine at two compression ratios (10:1 and 11:1). The engine speed was changed from 1500 to 5000 rpm at wide open throttle (WOT). The results of the engine test showed that ethanol addition to unleaded gasoline increase the engine torque, power and fuel consumption and reduce carbon monoxide (CO), nitrogen oxides (NO_x) and hydrocarbon (HC) emissions. It was also found that ethanol–gasoline blends allow increasing compression ratio (CR) without knock occurrence.     

Combustion and emission characteristics of a hydrogen-diesel dual-fuel engine

Hydrogen generated from renewable sources is an eco-friendly fuel that can be used in automotive industry or for energy generation purposes. Hydrogen is a high-energy content gas and its carbonless chemical structure can provide significant benefits of high thermal efficiency and near zero or very low carbon emissions when combusted with other fuels.In this study, the implementation of hydrogen fuel was tested at low and medium operating loads in a heavy-duty hydrogen-diesel dual-fuel engine. The paper provides a detailed experimental analysis of the effects of hydrogen energy share ratio and various combustion strategies such as exhaust gas recirculation, diesel injection pressure and diesel injection patterns.At low load conditions, engine operation with an H₂ energy share ratio of up to 98% was achieved without any engine operation implications. This condition provided a simultaneous reduction of carbon and NOx emission of over 90% while soot emissions were dropped by 85% compared to the conventional diesel-only operation. At medium load, the increased NOx emission due to the high energy content of hydrogen fuel was found to be the primary challenge.     

Using HHO (Hydroxy) and hydrogen enriched castor oil biodiesel in compression ignition engine

Hydrogen and HHO enriched biodiesel fuels have not been investigated extensively for compression ignition engine. This study investigated the performance and emissions characteristics of a diesel engine fueled with hydrogen or HHO enriched Castor oil methyl ester (CME)-diesel blends. The production and blending of CME was carried out with a 20% volumetric ratio (CME20) using diesel fuel. In addition, the enrichment of intake air was carried out using pure HHO or hydrogen through the intake manifold with no structural changes – with the exception of the reduction of the amount of diesel fuel – for a naturally aspirated, four cylinder diesel engine with a volume of 3.6 L. Hydrogen amount was kept constant with a ratio of 10 L/min throughout the experiments. Engine performance parameters, including Brake Power, Brake Torque, Brake Specific Fuel Consumption and exhaust emissions – including NOx and CO, – were tested at engine speeds between 1200 and 2600 rpm. It is seen that HHO enriched CME has better results compared to pure hydrogen enrichment to CME. An average improvement of 4.3% with HHO enriched CME20 was found compared to diesel fuel results while pure hydrogen enriched CME20 fuel resulted with an average increase of 2.6%. Also, it was found that the addition of pure hydrogen to CME had a positive effect on exhaust gas emissions compared to that adding HHO. The effects of both enriched fuels on the engine performance were minimal compared to that of diesel fuel. However, the improvements on exhaust gas emissions were significant.     

Improving the performance of dual fuel engines running on natural gas/LPG by using pilot fuel derived from jojoba seeds

The use of jojoba methyl ester as a pilot fuel was investigated for almost the first time as a way to improve the performance of dual fuel engine running on natural gas or liquefied petroleum gas (LPG) at part load. The dual fuel engine used was Ricardo E6 variable compression diesel engine and it used either compressed natural gas (CNG) or LPG as the main fuel and jojoba methyl ester as a pilot fuel. Diesel fuel was used as a reference fuel for the dual fuel engine results. During the experimental tests, the following have been measured: engine efficiency in terms of specific fuel consumption, brake power output, combustion noise in terms of maximum pressure rise rate and maximum pressure, exhaust emissions in terms of carbon monoxide and hydrocarbons, knocking limits in terms of maximum torque at onset of knocking, and cyclic variability data of 100 engine cycles in terms of maximum pressure and its pressure rise rate average and standard deviation. The tests examined the following engine parameters: gaseous fuel type, engine speed and load, pilot fuel injection timing, pilot fuel mass and compression ratio. Results showed that using the jojoba fuel with its improved properties has improved the dual fuel engine performance, reduced the combustion noise, extended knocking limits and reduced the cyclic variability of the combustion.     

氢存储技术

日益严峻的能源危机和环境污染，使得发展清洁的可再生能源成为各个国家的重要议题。氢能源以其可再生性和良好的环保效应成为未来最具发展潜力的能源载体。氢的储存是发展氢能技术的难点之一。文章介绍了高压、液化、金属氢化物和碳质吸附等储氢技术的研究现状，并对储氢技术的发展趋势进行了讨论。     

Simulation of the combustion process for a CI hydrogen engine in an argon-oxygen atmosphere

Hydrogen combustion in a noble gas atmosphere increases the combustion chamber temperature, and the high specific heat ratio of the gas increases the thermal efficiency. In this study, nitrogen was replaced by argon as the intake air along with pure oxygen to supply the engine. The objectives of this study are to determine the effects of different engine parameters on combustion and to analyse the emissions from hydrogen combustion in an argon-oxygen atmosphere. This research was conducted through simulations using CONVERGE 2.2.0 software, and the YANMAR engine NF19SK model was used to determine the basic parameters. Changing the injector location affects the pressure and temperature in the combustion chamber. With increasing compression ratio, the pressure increases more rapidly than the temperature. However, combustion at high compression ratios decreases the maximum heat release rate and increases the combustion duration. Hydrogen combustion at ambient temperatures below 1200 K follows the Arrhenius equation.     

Performance and emission studies of direct injection C.I. engine in duel fuel mode (hydrogen-diesel) with EGR

Presently majority of the world’s energy demand is met by fossil fuels. These fuels are depleting at an alarming rate. Thus in future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. Among the various alternative fuels, hydrogen is a long-term renewable and least polluting fuel (produced from renewable energy sources). Its clean burning characteristics help to meet the stringent emission norms. Majority of the work using hydrogen as a fuel is being done in spark ignition engine, however, in this experimental investigation efforts have been made to utilize it in compression ignition engine.     

Artificial Neural Network based prediction of performance and emission characteristics of a variable compression ratio CI engine using WCO as a biodiesel at different injection timings

Due to the increasing demand for fossil fuels and environmental threat due to pollution a number renewable sources of energy have been studied worldwide. In the present investigation influence of injection timing on the performance and emissions of a single cylinder, four stroke stationary, variable compression ratio, diesel engine was studied using waste cooking oil (WCO) as the biodiesel blended with diesel. The tests were performed at three different injection timings (24°, 27°, 30° CA BTDC) by changing the thickness of the advance shim. The experimental results showed that brake thermal efficiency for the advanced as well as the retarded injection timing was lesser than that for the normal injection timing (27° BTDC) for all sets of compression ratios. Smoke, un-burnt hydrocarbon (UBHC) emissions were reduced for advanced injection timings where as NO_x emissions increased. Artificial Neural Networks (ANN) was used to predict the engine performance and emission characteristics of the engine. Separate models were developed for performance parameters as well as emission characteristics. To train the network, compression ratio, injection timing, blend percentage, percentage load, were used as the input parameters where as engine performance parameters like brake thermal efficiency (BTE), brake specific energy consumption (BSEC), exhaust gas temperature (T_exh) were used as the output parameters for the performance model and engine exhaust emissions such as NO_x, smoke and (UBHC) values were used as the output parameters for the emission model. ANN results showed that there is a good correlation between the ANN predicted values and the experimental values for various engine performance parameters and exhaust emission characteristics and the relative mean error values (MRE) were within 8%, which is acceptable.     

Combustion,performances, and emissions characteristics of Hermetia illucens larvae oil in a direct injection compression ignition engine

Hermetia illucens larvae oil (HILO) is among biofuel feedstock from insects that has high potential to reduce dependency on petroleum resources. The present paper is motivated by the need to critically examine the effect of HILO mixed with diesel fuel (DF) on combustion, engine performance, and emission characteristics of a single cylinder direct injection (DI) compression ignition (CI) engine. The experiment was performed at a constant speed of 1500 rpm under various engine loads. The results revealed that the in-cylinder pressure, heat release rate (HRR), and the ignition delay (ID) were reduced by an average of 3.32%, 12.89%, and 4.36%, respectively. The brake specific fuel consumption (BSFC) and exhaust gas temperature (EGT) increased considerably at all engine loads. The brake thermal efficiency (BTE) was discovered to be lower by 11.47% compared to DF. The finding also shows that carbon monoxide (CO), carbon dioxide (CO₂), and unburned hydrocarbon (UHC) emissions increased with the addition of HILO. The nitrogen oxides (NO_x) emission reduced by 19.80% compared to DF at all the engine loads. Overall, this study concluded the potential of HILO in CI engine as a promising renewable and environmentally friendly resource for the better earth.