气固流化床的离散颗粒运动-碰撞解耦模型与模拟

基于分子动力学和气固两相流体动力学，建立流化床稠密气-固两相离散颗粒运动-碰撞解耦模型，采用硬球模拟方法处理颗粒与颗粒之间的碰撞，及大涡模拟方法处理气相湍流流动．单颗粒运动满足牛顿第二定律，颗粒相和气相相间相互作用的双向耦合由牛顿第三定律确定，数值模拟二维鼓泡流化床内稠密气-固两相流动，得到了气泡的形成、发展及颗粒的流化过程，计算结果表明颗粒弹性恢复系数影响气-固两相流动特性。     

流化床密相区流动特性的数值模拟

流化床内气固两相流动一直是实验研究和数值模拟的热点。基于Eulerian双流体模型,本文建立了流化床内的气固两相流动模型,采用FLUENT软件对流化床密相区两相流动特性、床内气泡的产生运动和爆裂等特性进行了数值模拟。模型中,将颗粒相看作是连续介质,建立与气相相同形式的数学模型;采用了离散介质动力理论,引入颗粒温度来描述固相粘性应力,并用气固曳力进行气固两相耦合。模拟得到了气泡产生、运动和爆裂的变化过程,与实验结果相一致。采用不同的曳力模型对流化床稠密两相流动进行了模拟,与Kuipers实验对比,结果表明采用Gidaspow曳力模型描述流化床稠密两相流动特性更准确。     

简单射流流化床的数值模拟

以双欧拉模型及颗粒动力学理论为基础，应用Fluent软件进行了简单射流流化床的模拟．经过不同湍流模型下的二维、三维计算结果分析，并与实验值比较，初步探讨湍流模型和二维、三维模拟方法对稠密气固流动数值模拟的影响，发现RNG k-ε湍动方程较标准k-ε湍流模型提高了稠密气固两相流数值模拟的准确性，三维模拟计算的流场比二维模拟更准确．     

高通量循环流化床提升管中气固两相流动的研究

发展清洁煤炭利用、煤炭多联产和IGCC迫切需求研发先进的煤气化技术。循环流化床(CFB)提升管内的气固两相流动对循环流化床气化技术有重要影响。在f 0.187′10 m的冷态实验台上考察密相CFB提升管内气固两相流动。基于能量最小多尺度原理(EMMS)提出了改进的曳力修正系数表达式,并嵌入到双流体模型中,完成了冷态实验台的三维数值模拟。结果展现了CFB提升管内典型的环核结构和壁面颗粒返混现象,同时捕捉到了颗粒团的形成与破裂运动。通过与Gidaspow曳力模型计算结果的比较证实,提出了曳力修正系数可以较好地模拟浓相CFB提升管内的气固两相运动。     

流化床内非等密度双组分颗粒流动特性的研究

基于颗粒动力学和气固两相流体动力学,建立流化床稠密气一固两相非等密度双组分颗粒运动碰撞解耦模型,采用硬球模拟方法研究颗粒间碰撞,大涡模拟方法研究气相湍流流动。基于牛顿第二定律建立单颗粒运动方程,应用牛顿第三定律确定颗粒相和气相相间相互作用的双向耦合。数值模拟二维鼓泡流化床内非等密度双组分颗粒气一固两相流动,计算结果表明颗粒弹性恢复系数影响分层流动特性。     

燃煤循环流化床模型与试验研究

利用循环流化床内气－固两相流动等基础方面的研究成果,根据本文床内气固浓－淡流动模型,建立适用不同结构参数的循环流化床燃烧模型,考虑了床内气体、固体颗粒的返混、循环过程,以及煤燃烧、ＮＯ的生成和分解、颗粒磨损等因素。在循环流化床燃烧试验台上进行实验研究,模型仿真结果和实验数据吻合良好,表明气固两相浓－淡流动模型所建立的循环流化床燃烧系统模型可以正确地模拟循环流化床的燃烧过程。     

基于修正的颗粒动理学模型超细颗粒聚团流动模拟研究

为解决超细颗粒多尺度气固两相聚团流动问题,对颗粒弹性模量和颗粒粘度经验公式进行修正。采用修正的周涛-力平衡模型来描述颗粒间的微观聚团过程,得到改进的颗粒动理学模型(KTGF),并结合气相方程,建立适合超细颗粒气固两相聚团流动的数学模型。对流化床和聚并器内的超细颗粒聚团气固两相流动过程进行数值模拟。结果表明:采用改进模型后计算误差减少了64. 8%,与实验结果更接近。在聚并器中,肋片间距和布置对团聚效果有很大影响,当扰流圆柱和肋片间距为325 mm,相邻肋片间距为200 mm,肋片旋转30°布置时,可提升聚团效果。     

循环流化床中的气固两相传热模型

循环流化床中存在着分散固体颗粒的连续上升气相和相对紧密的颗粒团两部分,颗粒团聚物对气固两相传热有着重要的影响。采用拟Boltzmann动力学方法描述循环流化床中颗粒团的动力学行为,建立了循环流化床中气固两相间传热过程的理论模型,对气体表观流速、固体颗粒循环率等对气固传热系数沿床高分布规律的影响进行了分析和讨论。模型计算结果与参考文献中的实验数据进行了比较,两者符合较好。     

300 MW循环流化床锅炉气固流动特性的CPFD模拟

采用计算颗粒流体力学（CPFD）的方法对300 MW循环流化床锅炉内的气固两相流体动力学参数进行全床数值模拟研究,重点分析了循环流化床锅炉炉膛以及回料阀的气固流动特性,获得固相颗粒浓度和速度场在炉膛内的分布以及固体循环流量、系统压力平衡、回料阀的运行情况等锅炉关键参数。结果表明：颗粒浓度的轴向分布呈现明显的密相区和稀相区两部分,模拟得到的轴向压力分布与实际工况吻合较好,验证了CPFD方法模拟循环流化床锅炉的准确性;锅炉回料阀内压降最大,这与床料分布相符;回料阀返料室流化程度较高,而输运室流化程度较小,呈现鼓泡床状态,气泡大都贴壁逃逸。     

矩形平壁循环流化床冷态流动特性研究

在循环流化床冷态试验台架上,以空气为流化介质,砂子（０．１￣０．４５ｍｍ）为床料,采用反射式光导纤维探针,分别测定了铅轴向和径向的颗粒浓度分布,特别是考察了矩形截面循环床边角对气固两相流动的影响,对径向颗粒浓度分布的影响,考察了壁面附近的气固流动。引入了时序分析方法对采样数据建立了参数模型。实验结果对加深循环流化床内气固两相流动的理解具有重要意义。     

Ash-forming elements in four Scandinavian wood species. Part 1: Summer harvest

Woody biomass in Finland and Sweden comprises mainly four wood species: spruce, pine, birch and aspen. To study the ash, which may cause problems for the combustion device, one tree of each species were cut down and prepared for comparisons with fuel samples. Well-defined samples of wood, bark and foliage were analyzed on 11 ash-forming elements: Si, Al, Fe, Ca, Mg, Mn, Na, K, P, S and Cl. The ash content in the wood tissues (0.2–0.7%) was low compared to the ash content in the bark tissues (1.9–6.4%) and the foliage (2.4–7.7%). The woods’ content of ash-forming elements was consequently low; the highest contents were of Ca (410–1340 ppm) and K (200–1310), followed by Mg (70–290), Mn (15–240) and P (0–350). Present in the wood was also Si (50–190), S (50–200) and Cl (30–110). The bark tissues showed much higher element contents; Ca (4800–19,100 ppm) and K (1600–6400) were the dominating elements, followed by Mg (210–2400), P (210–1200), Mn (110–1100) and S (310–750), but the Cl contents (40–330) were only moderately higher in the bark than in the wood. The young foliage (shoots and deciduous leaves) had the highest K (7100–25,000 ppm), P (1600–5300) and S (1100–2600) contents of all tissues, while the shoots of spruce had the highest Cl contents (820–1360) and its needles the highest Si content (5000–11,300). This paper presented a new approach in fuel characterization: the method excludes the presence of impurities, and focus on different categories of plant tissues. This made it possible to discuss the contents of ash element in a wide spectrum of fuel-types, which are of large importance for the energy production in Finland and Sweden.     

NEXT GENERATION ENGINEERED MATERIALS FOR ULTRA SUPERCRITICAL STEAM TURBINES

正1 ABSTRACT To reduce the effect of global warming on our climate,the levels of CO2emissions should be reduced.One way to do this is to increase the efficiency of electricity production from fossil fuels.This will in turn reduce the amount of CO2emissions for a given power output.Using US practice for efficiency calculations,then a move from a typical US plant running at 37%efficiency to a 760℃/38.5 MPa(1 400/5 580 psi)plant running at 48%efficiency would reduce CO2emissions by 170kg/MW.hr or 25%.     

Contents in Volume 23,2014

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Aerodynamic performance effects of leading-edge geometry in gas-turbine blades

The purpose of this paper is to illustrate the advantages of the direct surface-curvature distribution blade-design method, originally proposed by Korakianitis, for the leading-edge design of turbine blades, and by extension for other types of airfoil shapes. The leading edge shape is critical in the blade design process, and it is quite difficult to completely control with inverse, semi-inverse or other direct-design methods. The blade-design method is briefly reviewed, and then the effort is concentrated on smoothly blending the leading edge shape (circle or ellipse, etc.) with the main part of the blade surface, in a manner that avoids leading-edge flow-disturbance and flow-separation regions. Specifically in the leading edge region we return to the second-order (parabolic) construction line coupled with a revised smoothing equation between the leading-edge shape and the main part of the blade. The Hodson–Dominy blade has been used as an example to show the ability of this blade-design method to remove leading-edge separation bubbles in gas turbine blades and other airfoil shapes that have very sharp changes in curvature near the leading edge. An additional gas turbine blade example has been used to illustrate the ability of this method to design leading edge shapes that avoid leading-edge separation bubbles at off-design conditions. This gas turbine blade example has inlet flow angle 0°, outlet flow angle −64.3°, and tangential lift coefficient 1.045, in a region of parameters where the leading edge shape is critical for the overall blade performance. Computed results at incidences of −10°,   −5°,   +5°,   +10° are used to illustrate the complete removal of leading edge flow-disturbance regions, thus minimizing the possibility of leading-edge separation bubbles, while concurrently minimizing the stagnation pressure drop from inlet to outlet. These results using two difficult example cases of leading edge geometries illustrate the superiority and utility of this blade-design method when compared with other direct or inverse blade-design methods.     

Hydrogen production by steam-gasification of carbonaceous materials using concentrated solar energy – V. Reactor modeling,optimization, and scale-up

A chemical reactor for the steam-gasification of carbonaceous particles (e.g. coal, coke) is considered for using concentrated solar radiation as the energy source of high-temperature process heat. A two-phase reactor model that couples radiative, convective, and conductive heat transfer to the chemical kinetics is applied to optimize the reactor geometrical configuration and operational parameters (feedstock's initial particle size, feeding rates, and solar power input) for maximum reaction extent and solar-to-chemical energy conversion efficiency of a 5 kW prototype reactor and its scale-up to 300 kW. For the 300 kW reactor, complete reaction extent is predicted for an initial feedstock particle size up to 35 μm at residence times of less than 10 s and peak temperatures of 1818 K, yielding high-quality syngas with a calorific content that has been solar-upgraded by 19% over that of the petcoke gasified.     

汽轮机数字电液调节系统挂闸异常的技术完善

分析了200MW汽轮机数字电液调节系统在运行中存在的挂闸异常问题,采取了相应的技术处理措施,且运行实践效果良好。     

新型高压共轨ECU升压模块的数字化开发与优化

为了提高喷油器电磁阀的响应速率,提出了一种基于CPLD(复杂可编程逻辑器件)应用于高压共轨ECU的数字升压模块。鉴于该升压电路结构参数多,其升压电压的恢复响应要求高等特征,基于Pspice建立了升压电路的仿真模型,研究了不同电路参数下升压模块的输出特性,全面优化了该升压模块的性能。结果显示,该升压模块的最大转换效率可以达90%以上。在柴油发动机上对ECU的试验表明,升压电压最大波动不超过10%,其恢复时间仅为1.3ms,功率管最大温升仅为41℃,满足整机运行范围内ECU的需求。     

Trace metal chemistry and silicification of microorganisms in geothermal sinter, Taupo Volcanic Zone, New Zealand

As part of a pilot study investigating the role of microorganisms in the immobilisation of As, Sb, B, Tl and Hg, the inorganic geochemistry of seven different active sinter deposits and their contact fluids were characterised. A comprehensive series of sequential extractions for a suite of trace elements was carried out on siliceous sinter and a mixed silica-carbonate sinter. The extractions showed whether metals were loosely exchangeable or bound to carbonate, oxide, organic or crystalline fractions. Hyperthermophilic microbial communities associated with sinters deposited from high temperature (92–94°C) fluids at a variety of geothermal sources were investigated using SEM. The rapidity and style of silicification of the hyperthermophiles can be correlated with the dissolved silica content of the fluid. Although high concentrations of Hg and Tl were found associated with the organic fraction of the sinters, there was no evidence to suggest that any of the heavy metals were associated preferentially with the hyperthermophiles at the high temperature (92–94°C) ends of the terrestrial thermal spring ecosystems studied.     

Assessment methods of material ageing using Sdobyrev''s creep rupture model

The physical aspects of the activation energy, in higher and high temperatures, of the metal creep process were examined. The research results of creep-rupture in a uniaxial stress state and the criterion of creep-rupture in biaxial stress states, at two temperatures, are then presented. For these studies creep-rupture, taking case iron as an example the energy and pseudoenergy activation was determined. For complex stress states the criterion of creep-rupture was taken to be Sdobyrev's, i.e. σ_red = σ₁ β + (1 − β)σ_i, where: σ₁-maximal principal stress, σ_i-stress intensity, β-material constant (at variable temperature β = β(T)). The methods of assessment of the material ageing grade are given in percentages of ageing of new material in the following mechanical properties: 1) creep strength in uniaxial stress state, 2) activation energy in uniaxial stress state, 3) criterion creep strength in complex stress states, 4) activation pseudoenergy in complex stress states. The methods 1) and 3) are the relatively simplest because they result from experimental investigations only at nominal temperature of the structure work, however, for methods 2) and 4) it is necessary to perform the experimental investigations at least at two temperatures.     

Production of hydrogen from sewage biosolids in a continuously fed bioreactor: Effect of hydraulic retention time and sparging

Hydrogen was produced from primary sewage biosolids via mesophilic anaerobic fermentation in a continuously fed bioreactor. Prior to fermentation the sewage biosolids were heated to 70 °C for 1 h to inactivate methanogens and during fermentation a cellulose degrading enzyme was added to improve substrate availability. Hydraulic retention times (HRT) of 18, 24, 36 and 48 h were evaluated for the duration of hydrogen production. Without sparging a hydraulic retention time of 24 h resulted in the longest period of hydrogen production (3 days), during which a hydrogen yield of 21.9 L H₂ kg⁻¹ VS added to the bioreactor was achieved. Methods of preventing the decline of hydrogen production during continuous fermentation were evaluated. Of the techniques evaluated using nitrogen gas to sparge the bioreactor contents proved to be more effective than flushing just the headspace of the bioreactor. Sparging at 0.06 L L min⁻¹ successfully prevented a decline in hydrogen production and resulted in a yield of 27.0  L H₂ kg⁻¹ VS added, over a period of greater than 12 days or 12 HRT. The use of sparging also delayed the build up of acetic acid in the bioreactor, suggesting that it serves to inhibit homoacetogenesis and thus maintain hydrogen production.