Effect of freezing on quality of sea bass and gilthead sea bream

Freezing is an efficient method of fish preservation. The aim of the present work was to examine the impact of freezing in fatty acid composition and in the in vitro inhibitory activity of sea bass (Dicentrarchus labrax) and gilthead sea bream (Sparus aurata) fillet lipids against platelet activating factor (PAF). The Bligh and Dyer extraction method and the counter‐current distribution method were used to obtain total, polar and neutral lipids. The fatty acid analysis conducted using the internal standard method and the biological assay on washed rabbit platelets took place calculating the in vitro inhibitory activity of fish lipids against 2.5 × 10^?11 M of PAF. No statistical changes (p<0.05) occurred in fatty acid content of fresh and thawed gilthead sea bream, while fatty acid amount in thawed sea bass was significantly higher (p<0.05) compared to fresh fish. Total lipids of both thawed fish species exhibited stronger anti‐thrombotic activity compared to fresh fish. Freezing preserved fish quality and reinforced the anti‐thrombotic properties of fish oils, since even after 6 months of freezing, fish oils preserve their nutritional value in terms of protecting against cardiovascular diseases. Practical applications: Fish fillets contain high amount of unsaturated lipids that may easily undergo lipid oxidation. Freezing and frozen storage prevent such oxidative changes so fish quality is retained. Fatty acids and PAF‐antagonists in fish are of major importance since they contribute to the nutritional value of fish. The practical application of this work lies on the evaluation of the nutritional value of fish in terms of cardio protection by examining the impact of freezing on the levels of fatty acids and PAF‐antagonists in aquacultured fish fillets.     

Comparison of Water Blanching and High Hydrostatic Pressure Effects on Drying Kinetics and Quality of Potato

Abstract

Drying kinetics and quality parameters of potato cubes were evaluated as affected by high pressure processing and hot water blanching. The potato cubes in 1% citric acid solution as immersion medium were pressure treated at 400 MPa for 15 min. Hot water blanching was conducted in boiling water for 3 min. Drying kinetics and quality parameters (i.e., rehydrability, texture, color and apparent density) were assessed for the high pressure–treated and water-blanched samples and for dehydrated and rehydrated samples. Drying rates were found to be higher (p < 0.05) in the initial period of drying for the pressure treated samples. The Page model was found to better fit drying data of the thermally treated samples, and the two-terms model better described the drying behavior of high pressure–treated samples. High pressure–treated samples had a similar rehydrability to thermally treated samples. It was found that pressure–treated samples had a hardness value close to that of fresh samples, whereas thermal treatment resulted in a softer texture. After rehydration, samples of both treatments returned their texture before drying. The total color difference for the thermally blanched samples was higher (p < 0.05) than for pressure–treated samples before drying and after drying. High pressure–treated and dried potato cubes had a color close to that of fresh potato cubes. High pressure–treated and air-dried samples were found to have higher (p < 0.05) apparent density than thermally treated samples.     

Ultrasound- and microwave-assisted intermittent drying of red beetroot

Abstract

A drying technique using a combination of high power airborne ultrasound, microwaves and hot air was applied to investigate the effect of intermittent drying on the process kinetics and several quality indicators of red beetroot. An innovative hybrid dryer was used in drying experiments. Six sets of drying programs were carried out. Ultrasound and microwaves were applied in convective drying continuously (hybrid processes) or periodically (hybrid intermittent processes). The drying processes were assessed in terms of drying time, drying rate, and energy consumption. Moreover, the total color change, retention of natural dye (betanin), water activity, texture, and microstructure of dry product were examined. The drying kinetics was well-fitted with the use of the Midilli-Kucuk model. It was found that hybrid intermittent drying reduces the total drying time and energy consumption, enhances both the drying rate and product quality. Furthermore, it was demonstrated that the hybrid intermittent drying can serve as an alternative to traditional hot air drying that could produce a more porous, nice color, and crispy vegetable product.     

Effects of Microwave-Assisted Hot Air Drying and Conventional Hot Air Drying on the Drying Kinetics,Color, Rehydration,and Volatiles of Moringa oleifera

In this study, the fresh Moringa oleifera pods (Drumsticks) were dehydrated by microwave-assisted hot air drying (MAHD) and conventional hot air drying methods. The samples were dried at three different temperatures, viz. 50, 60, and 70°C, with and without the application of microwaves. Microwave power density of 1 W/g was used for the MAHD. The final moisture content was targeted as 13% wb. The drying curves and drying rate curves were plotted and compared. The kinetics of drying obtained experimentally were correlated with the Page equation. The constants K and N of the Page equation were determined to predict the drying kinetics for varying conditions. The quality attributes, namely, color, rehydration ratio, and volatile compounds, were analyzed and compared with that of the fresh Moringa pods. The volatile compounds were analyzed using z-Nose (an electronic nose; Electronic Sensor Technology, Newbury Park, CA) and bioactive molecules were analyzed using gas chromatography–mass spectrometry. The results showed that the MAHD method had significantly (P < 0.05) reduced the loss of volatiles during drying. Also, MAHD preserved most of the bioactive molecules when compared to the conventional hot air drying method. The samples dried at 50°C using MAHD were the best in terms of all of the quality attributes tested in this study. Also, the results established that the z-Nose can be used as a quick and inexpensive means to assess the effect of different process parameters on the aromatic quality of the product and quantitatively classify quality based on aroma.     

Pulsed vacuum drying (PVD) of wolfberry: Drying kinetics and quality attributes

The effects of drying temperature (50, 53, 56, 59, 62, and 65°C) and pulsed vacuum ratio defined as the vacuum pressure duration versus atmosphere pressure duration (3:3, 6:6, 9:2, 12:5, 15:1, 18:4?min/min) on pulsed vacuum drying (PVD) characteristics and quality attributes of wolfberry in terms of polysaccharide content, color parameters (L^*, a^*, b^*, ΔE, and C), rehydration ratio and microstructure were investigated. Results revealed that appropriate PVD can reduce drying time by 73.2% compared to hot air drying at the same drying temperature. The moisture effective diffusivity (D_eff) ranged from 5.23?×?10^?10 to 9.73?×?10^?10?m²/s, calculated using the Weibull distribution model. The polysaccharide content, L^* (lightness), a^* (redness/greenness) of the PVD products were higher than those of the hot air-dried samples at the same drying temperature. The total color difference (ΔE) and color intensity (C) of PVD samples were close to those of the fresh ones. The retention rate of total polysaccharide content of PVD samples was about 49–77%, which was significantly higher than 30% of the hot air-dried samples. The surface of PVD wolfberry was highly porous, which may enhance moisture transfer during drying as well as rehydration processes. The results of current work indicate that PVD is a promising technology for wolfberry process, for the reason that PVD can reduce drying time significantly as well as enhance the quality attributes in terms of the total polysaccharide content, color parameters and rehydration ratio.     

ON THE STUDY OF TIME-VARYING TEMPERATURE DRYING—EFFECT ON DRYING KINETICS AND PRODUCT QUALITY

ABSTRACT

The ability of heat pump dryer to produce controlled transient drying conditions, in terms of temperature, humidity and air velocity, has given it an edge over other drying systems. Exploiting this characteristic, we studied and compared the effect of different temperature-time profiles on the quality of agricultural products in a tunnel heat pump dryer capable of providing up to 14.6 kW of cooling capacity. The product quality refers to the color change of the products. Samples of banana and guava were dried in batches in a two-stage heat pump dryer. The effects of the starting temperature of a selected profile and the cycle time on both drying kinetics and product quality were studied. It was observed that by employing a step change in drying air temperature with the appropriate starting temperature and cycle time, it was possible to reduce significantly the drying time to reach the desired moisture content with improved product color.     

Impact of initial moisture content levels,freezing rate and instant controlled pressure drop treatment (DIC) on dehydrofreezing process and quality attributes of quince fruits

Dehydrofreezing process involves water partial removal before freezing. This treatment has been proposed in order to reduce the negative impacts of conventional or even accelerated freezing, especially on the textural quality of high water content fruits and vegetables. Indeed, in such cases, freezing and thawing processes result in severe damage of the integrity of product’s cell structure due to the formation of ice crystals. For this purpose, quince fruits (7?g H₂O/g db) were subjected to convective air drying of 40?°C and 3m/s to reach different water content levels of 2, 1, and 0.3?g H₂O/g db. Freezing profiles obtained at various freezing rates (V₁, V₂, and V₃) for different water contents allowed the main freezing characteristics such as the Initial Freezing Temperature (IFT), the Practical Freezing time (PFt), and the Specific Freezing time (SFt) to be assessed. The impact of freezing rate was important on PFt and SFt, and more pronounced for high water contents (W between 7 and 2?g H₂O/g db (dry basis)). Furthermore, IFT decreased sharply when initial sample water content decreased. Indeed, it started at ?0.8?°C for W?=?7g H₂O/g db, while it reached a value of ?8.2?°C for samples of W?=?1g H₂O/g db. Since convective air drying normally triggers shrinkage which causes a detrimental deformation of fruit structures, instant controlled pressure drop (DIC) treatment was used to improve the texture and enhance the whole dehydrofreezing performance and the final frozen-thawed product quality. Moreover, DIC implied a slight increase of PFt compared to untreated ones. On the other hand, quality attributes were estimated through the assessment of thawed water exudate (TWE g H₂O/100?g db), color and texture (maximum puncture force as index of firmness): freezing rate and water content had great impacts on TWE. Hence, the lower the water content, the weaker the TWE. Furthermore, the TWE of the pre-dried quince (0.3?g H₂O/g db) had higher value for DIC-textured samples than for the un-treated ones. Indeed, DIC-texturing leads to a well-controlled structure expansion of the cell wall. These textural changes resulted in more lixiviation of residual water. Consequently, water becomes more available, hence more releasable after thawing. Finally, the partial removal of water by air drying before freezing remarkably reduced the negative impact of freezing/thawing processes on final quince color. Decisively, the firmness of quince fruit increased with the decrease of water content level.

Abbreviations: DMC: Dry Matter Concentration (%); DIC: Instant controlled pressure drop; W: Water content dry basis (g H₂O/g db); IFT: Initial Freezing Temperature (°C); PFt: Practical Freezing time (min); SFt: Specific Freezing time (min); TWE: Thawed Water Exudate (g H₂O/100?g db); L, a, and b: Color coordinates; (L): The degrees of lightness; (a) and (–a): The redness (a) or greenness (?a), respectively; (b) and (?b): The yellowness (b) or blueness (?b), respectively; ΔE*_ab: Total color difference; L₀, a₀, and b₀: Color coordinates of fresh or dried quince samples; SD: Standard Deviation; ANOVA: Analysis of variances; LSD: Least Significant Differences; cp: Specific Heat of the product depending on composition (dry material and water content)(KJ/kg K); cp_d: Specific Heat of the dry material (KJ/kg K); cp_W: Specific Heat of water (KJ/kg K); V₁: Freezing rate without insulation; V₂: Freezing rate with a food stretch film insulation with thickness e2?=?3?mm and thermal conductivity λ₂?=?0.17 W/m K; V₃: Freezing rate with a versatile flexible insulation (Armacell) with thickness e3?=?13mm and weak thermal conductivity λ₃?=?0.036 W/m K; v_d: Volume of dry material of quince sample (mm³); v_H2O: Volume of quince sample water (mm³); v_t: Total volume of quince sample (mm³); e₀: Quince sample thickness (mm); e₂: Insulation thickness in the case V2; = 3?mm; ; e₃: Insulation thickness in the case V3; = 13?mm; ; λ₀: Quince sample conductivity (W/m K); λ₂: Insulation conductivity in the case V2;?=?0.17 W/m K; ; λ₃: Insulation conductivity in the case V3;?=?0.036 W/m K; λ_d: Conductivity of quince sample dry material (W/m K); λ_H2O: Conductivity of water (W/m K); λ_equiv: Equivalent conductivity of quince sample versus water content (W/m K); m_i and m_f: Weights of the frozen and thawed samples, respectively     

NMR imaging and differential scanning calorimetry study on drying of pine,birch, and reed pulps and their mixtures

Drying, water fractions, and water distribution were investigated for pine, birch, and reed pulps and pine–birch, pine–reed, and pine–birch–reed pulp mixtures. Gravimetrically determined drying times showed that the drying rates of the pulps decreased at two to four inflection points. Characterizations of the dried pulps by differential scanning calorimetry (DSC) showed a faster removal of free water than freezing and nonfreezing bound waters; all decreased simultaneously, however. DSC also revealed the critical water contents at which the free water and freezing bound water disappeared. The gravimetrically determined inflection points of the drying curves corresponded with the critical points determined by DSC. NMR line widths and images produced by ¹H‐NMR imaging revealed the nature and regions of the pulp drying. The constant growth rate of the NMR line widths with decreasing water content appeared to change at two inflection points, which fell approximately in the same water content regions as the inflection points of the drying curves. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 937–945, 2006     

Study on quality attributes and drying kinetics of instant parboiled rice fortified with turmeric using hot air and microwave-assisted hot air drying

Abstract

This study investigated the quality and drying kinetics of instant parboiled rice fortified with turmeric (IPRFT) by using hot air (HA) and microwave-assisted hot air (MWHA) drying. The cooked long grain parboiled rice (LGPR) fortified with turmeric was dried with HA at temperatures of 65, 80, 95, and 110?°C. The microwave power density of 0.588 Wg^?1 was incorporated for drying with MWHA. Drying was performed until the dried IPRFT reached 16% (d.b.) of moisture content. The quality of the dried IPRFT was evaluated in terms of color, total phenolics content (TPC), total antioxidant capacity (TAC), rehydration ratio, volume expansion ratio, texture and microstructure. The results showed that the incorporation of microwave power with HA drying helped to reduce the drying time by 50% compared to conventional HA drying. A prediction of the moisture ratio by using the Page model provided the best R² and RMSE in drying kinetics. The drying conditions had small effects on the color, TPC, TAC, and microstructure of the dried IPFRT. The rehydration ratio, volume expansion ratio and texture of the rehydrated IPFRT showed minimal variations from changes in the drying conditions. The TPC and TAC of the dried IPRFT clearly increased compared to the TPC and TAC of the initial LGPR.     

Relationship of Product Structure,Sorption Characteristics,and Freezing Point of Atmospheric Freeze-Dried Foods

Drying is an important unit operation in processing of foods with a long shelf life. The drying process influences product properties and quality; the products may shrink, break, or undergo rheological, physical, and biochemical changes. Important parameters responsible for product quality changes during drying are temperature, relative humidity, and residence time. Studies of thermal and mass transfer properties during drying are essential for understanding the changes in product quality and for designing and dimensionalizing the drying process.

Drying kinetics, sorption properties, shrinkage, and freezing point depression were determined during atmospheric freeze drying (AFD) of pieces of apple, turnip cabbage, and cod. Adsorption rate and sorption isotherms were determined in the end product. The drying temperature affected the physical properties. Drying at ?5°C resulted in a larger shrinkage than drying at ?11°C. GAB modeling was used to characterize the sorption properties of the products. No typical sigmoidal shape was found of the moisture sorption isotherms of the products, which is in accordance with the Guggenheim constant found from the same results. Experimental data on freezing point depression were used to find product constants E and b in the Schwartzberg equation for the freezing point depression. Freezing point depression, as a function of the dry matter content, was determined using Schwartzberg's equation and a component composition model (CCM). The result indicates an influence of structural effects on freezing point depression.     

Drying Kinetics,Texture, Color,and Determination of Effective Diffusivities During Sun Drying of Chempedak

Sun drying of chempedak (Artocarpus integer) was carried out on different sample sizes to investigate the effects on product quality. Fick's second law model was used to determine the effective diffusivities of sun–dried chempedak slabs based on the drying rate versus moisture content plots. In addition, texture degradation and total color changes were investigated. The texture and color changes of dried chempedak were relatively significant (p < 0.05) compared to fresh chempedak. There was an increase in dried fruit hardness and chewiness but a decrease in springiness and cohesiveness during drying.     

Mathematical Modeling of the Coupled Transport Phenomena and Color Development: Finish Drying of Trellis-Dried Sultanas

A mathematical model for simulation of simultaneous heat and mass transport was developed to describe the drying kinetics during finish drying of trellis-dried sultanas. In this model, the governing partial differential equations for heat and mass transfer for a solid spherical body were numerically solved using a finite difference technique. In addition, a kinetic model was coupled to the heat and mass transfer calculations to simultaneously predict the evolution of product color during the drying process. This allows predictions of moisture content, temperature, and color profiles of the product in a space–time domain during the drying process as a function of various operating conditions.

Predictions compared well with the experimental values, implying that the proposed numerical model can be used with confidence for the simulation of the important transport phenomena in optimizing the design and operation of a drying system for sultanas that maximizes the retention of the desired product color. The work has demonstrated the importance of establishing optimal and closely controlled drying conditions because significant effects of the key operational parameters on drying kinetics and the associated changes of product color were found. The modeling approach proposed here can be extended to other products and for incorporation of other product quality indices.     

Development of a Microwave–Vacuum-Based Dehydration Technique for Fresh and Microwave–Osmotic (MWODS) Pretreated Whole Cranberries (Vaccinium macrocarpon)

A bench scale microwave–vacuum (MWV) dryer was developed using a modified consumer-grade microwave oven. MWV dehydration was first tested as a standalone method on whole frozen–thawed berries. Subsequently, a new combination drying technique was developed employing microwave osmotic dehydration under continuous-flow medium-spray (MWODS) conditions together with MWV as a secondary drying operation. Fresh (frozen–thawed) and MWODS pretreated berries were dried under a range of MWV treatments employing continuous and decreasing microwave power settings (duty cycles). Initial microwave power density for all treatments was approximately 10.2 W/g and magnetron power-on and power-off times varied from 3 to 15 s and 27 to 15 s, respectively. Drying times to 20% (db) were recorded and energy consumption was calculated according to the total magnetron power-on time where overall it was found that drying times and energy consumption decreased with increasing MWV process intensity, where drying times for all MWV treatments were significantly shorter than those of conventional air drying. Drying kinetics were fit using two models (exponential and Page's empirical model), where Page's model better fit the experimental data. The quality of the berries was monitored visually through evidence of scorching in order to screen treatments and establish upper limits of treatment intensity for further studies.     

Peppermint Drying Performance of Contact Dryer in Terms of Product Quality,Energy Consumption,and Drying Duration

Drying is a commonly used postharvest operation for medicinal and aromatic plants. Their high initial moisture contents, requirement of moderate drying temperatures, and quick deterioration of their quality attributes make their drying processes energy intensive and time consuming. These properties may also cause the dried product to be of heterogeneous quality. A contact dryer that transferred energy to drying plants mainly by heat conduction was developed and tested by mixing or not mixing batches of 15 kg of chopped peppermint plants. The contact dryer had three main operational units: a drying table, a mobile mixing/aeration car, and a control panel. The contact dryer was operated with one of four drying programs. All programs affected the completion duration of drying, essential oil content, and dried product color differently. The shortest drying time (15 h) was obtained using the drying program of gradually increased water temperature from 55–60 to 75–80°C in 6 h and mixing/aeration. However, mixing and aeration changed the product color slightly more and partially increased essential oil loss. These drawbacks can be alleviated by selecting the appropriate duration of mixing and aeration. The menthol and menthone percentages of fresh peppermint essential oil ranged from 31.02 to 34.02% (average value: 32.52%) and 23.23 to 26.47% (average value: 24.85%), respectively. The menthol and menthone percentages of dried peppermint essential oil ranged from 22.74 to 42.07% and from 8.95 to 21.76%, respectively. The significant variations in the essential oil composition of dried peppermint leaves within replications were possibly caused by the variations associated with the age and cutting order of fresh peppermint plants at harvest.     

Non-Isothermal Drying of Medicinal Plants

An intelligent system for non-isothermal drying of medicinal plants, based on machine vision, sensor fusion, and neural network, was developed. Air temperature, velocity, and humidity, along with material size and moisture content were inputs to the neural model for diffusivity. Temperature, time, mass, volume, and color were inputs to the neural model for quality. Isothermal low-temperature drying of ginseng root and blueberry showed extremely low effective diffusivity (0.2–0.75)*10^?10 m²/s. In contrast, non-isothermal drying demonstrated a potential to increase diffusivity and prevent quality losses. Testing of the intelligent drying system showed reduced drying time from 240 to 60 hours for ginseng, and from 110 to 30 hours for blueberry with desired product quality.     

Drying behavior and quality parameters of dried beef (biltong) subjected to different pre-treatments and maturation stages

The drying behavior of fresh, matured, and frozen beef, marinated with 0.5% salt, 1% salt, salt and vinegar, and blind samples, dried at 70°C, was investigated. Weight and color (CIELAB) were measured and images of the samples were created with a hyperspectral imaging camera. Results show that the marinade and the type of beef influences the drying behavior of beef, but not the final color. Results from the hyperspectral imaging show that it is possible to build good fitting prediction models resulting in high R² (min. 0.81, max. 0.98) and low RMSE (min. 0.08, max. 2.35) for moisture content, a^* and b^* values.     

Convective-intermittent drying of cherries preceded by ultrasonic assisted osmotic dehydration

This paper presents the results of experimental studies on convective drying of cherries (Prunus cerasus L.) in stationary and intermittent conditions, previously pretreated with ultrasonic assisted osmotic dehydration. The effect of a stepwise changing air temperature and osmotic pretreatment on drying kinetics and the biomaterial quality were investigated. The main aim of the studies was to find the possibly best drying conditions, by which the drying time was shortened and the product quality degradation was minimized. Except drying kinetics and total color and water activity changes, the effect of osmotic pretreatment expressed by such parameters as the Solid Gain and the Water Loss were examined. It was proved that intermittent drying of cherries preceded by ultrasonic assisted osmotic dehydration contributes to shorter drying time, better color preservation and smaller water activity.     

On-Line Determination of Water Activity at the Lean Surface of Meat Products During Drying and Its Relationship with the Crusting Development

Abstract

One of the main problems in drying of meat products is the surface hardening or crusting. The crusted surface layer is harder and less permeable than the inner part of the product. A dramatic increase of hardness during drying in dry-cured meat products has been found when the water content reaches a critical value. The water content can be related with the water activity by sorption isotherms. Therefore, an on-line measurement of the water activity at the surface (a_ws) could be used by the control system in order to avoid the crusting problem. The aim of this study was to evaluate a methodology for the on-line water activity determination at the lean surface of raw or salted meat during drying and relate this determination with the crusting development. Water activity at the surface was estimated from the heat balance (a_ws ^h) in salted meat slices and in unsalted and in salted loin samples. The proposed methodology was able to monitor the a_ws in both products. The estimated a_ws ^h was related with the crusting development in loin samples, showing its potential application in control systems for avoiding the crusting development during the drying of meat products.     

Comparison of Drying Characteristics and Quality of Shiitake Mushrooms (Lentinus edodes) Using Different Drying Methods

The objective of this study was to compare the drying characteristics and the quality of dried Shiitake mushroom (Lentinus edodes) cubes obtained by hot-air drying (HAD), intermediate-infrared drying (IIRD), and vacuum microwave spouted-bed drying (VMSD). Several quality parameters of products, including color, texture, and rehydration capacity, were investigated. Compared to IIRD and VMSD, HAD turn out to be the most undesirable method due to its longer drying time and poor product quality. With similar rehydration capacity, the color of the VMSD product was closest to the original material. In terms of texture, total sugar content, and sensory evaluation, the VMSD product has the best quality.     

冷冻干燥过程强化中冷冻阶段优化的研究进展

冷冻干燥产品质量高,但时间长、能耗高。本文综述了冷冻干燥过程强化中冷冻阶段的优化方法,控制冷冻速率、调节冰晶成核和退火处理可以获得大而均匀的冰晶从而提高升华干燥阶段速率,但物料内部比表面积的减小会降低解吸干燥阶段速率,这类常规的冷冻阶段优化方法对弱吸湿性的物料有一定的强化效果。有机溶剂具有较高的蒸气压,作为共溶剂时可以增加传质推动力,但较低的有机溶剂残留量要求阻碍了其进一步应用。“初始非饱和多孔介质冷冻干燥”的技术思想是将液体物料首先制备成具有一定初始孔隙的冷冻物料,然后再进行冷冻干燥。物料具有的初始孔隙为水蒸气的迁移提供了便捷的通道,而且纤薄的固体基质也有利于结合水的解吸,可以同时强化升华干燥阶段和解吸干燥阶段。该技术思想是过程低消耗和产品高质量的完美结合,为解决冷冻干燥过程速率低的问题提供了新的方案。