Forced convection adsorption cycle with packed bed heat regeneration: Cycle à adsorption à convection forcée avec régénération thermique du lit fixe

The convective thermal wave is part of a patented cycle which uses heat transfer intensification to achieve both high efficiency and small size from a solid adsorption cycle. Such cycles normally suffer from low power density because of poor heat transfer through the adsorbent bed. Rather than attempting to heat the bed directly, it is possible to heat the refrigerant gas outside the bed and to circulate it through the bed in order to heat the sorbent. The high surface area of the grains leads to very effective heat transfer with only low levels of parasitic power needed for pumping. The new cycle presented here also utilises a packed bed of inert material to store heat between the adsorption and desorption phases of the cycle. The high degree of regeneration possible leads to good coefficients of performance (COPs). Thermodynamic modelling, based on measured heat transfer data, predicts a COP (for a specific carbon) of 0.90 when evaporating at 5°C and condensing at 40°C, with a generating temperature of 200°C and a modest system regenerator effectiveness of 0.8. Further improvement is possible. Experimental heat transfer measurements and cycle simulations are presented which show the potential of the concept to provide the basis of a gas-fired air conditioner in the range 10–100 kW cooling. A research project to build a 10-kW water chiller is underway. The laboratory system, which should be operational by June 1997, is described.     

Experimental correlation of combined heat and mass transfer for NH3–H2O falling film absorptionCorrélation expérimentale entre le transfert de chaleur et de masse pour de l'absorption au NH3–H2O à film tombant

In this article, experimental analysis was performed for ammonia–water falling film absorption process in a plate heat exchanger with enhanced surfaces such as offset strip fin. This article examined the effects of liquid and vapor flow characteristics, inlet subcooling of the liquid flow and inlet concentration difference on heat and mass transfer performance. The inlet liquid concentration was selected as 5%, 10% and 15% of ammonia by mass while the inlet vapor concentration was varied from 64.7% to 79.7%. It was found that before absorption started, there was a rectification process at the top of the test section by the inlet subcooling effect. Water desorption phenomenon was found near the bottom of the test section. It was found that the lower inlet liquid temperature and the higher inlet vapor temperature, the higher Nusselt and Sherwood numbers are obtained. Nusselt and Sherwood number correlations were developed as functions of falling film Reynolds Re₁, vapor Reynolds number Re_v, inlet subcooling and inlet concentration difference with ±15% and ±20% error bands, respectively.     

Effect of vapor flow on the falling-film heat and mass transfer of the ammonia/water absorber

Falling-film heat and mass transfer in an absorber can be influenced by the motion of the surrounding refrigerant vapor. In this study, the effect of the vapor flow direction on the absorption heat and mass transfer has been investigated for a falling-film helical coil absorber which is frequently used in the ammonia/water absorption refrigerators. The heat and mass transfer performance was measured for both parallel and countercurrent flow. The experiments were carried out for three different solution concentrations (3, 14, and 30%). The vapor in equilibrium with the solution is supplied to the test section. It is found that the falling-film heat and mass transfer is deteriorated in the countercurrent flow if the specific volume of the vapor solution is large. For the countercurrent flow, the high velocity of the vapor due to large specific volume seems to cause the unfavorable distribution of falling-film and reduce the heat and mass transfer performance of the ammonia absorber. The effect of vapor flow direction decreased with increasing concentration of ammonia solution since the specific volume of the ammonia vapor which is in equilibrium with the solution becomes smaller and the vapor velocity becomes lower.     

Condensation heat transfer and flow pattern inside a herringbone-type micro-fin tubeTransfert de chaleur lors de la condensation et configuration de l'écoulement à l'intérieur d'un tube à microailettes à chevrons

Condensation heat transfer and pressure drop of R410A and R22 in a newly proposed herringbone-type micro-fin tube are measured and compared to those of a helical micro-fin tube and a smooth tube. The heat transfer coefficient of the herringbone micro-fin tube is higher than that of the helical micro-fin tube in the high mass velocity region, while it has slightly lower value in the low mass velocity region. Pressure drop of the herringbone micro-fin tube is, however, higher than that of the helical micro-fin tube. Flow patterns of the herringbone micro-fin tube are observed and the heat transfer enhancement mechanism is discussed. The heat transfer coefficient and pressure drop of the helical micro-fin tube is predicted well with previously proposed correlations, while those of the herringbone-type micro-fin tube has higher value than the predicted values. Preliminary correlations for the pressure drop and the heat transfer coefficient are proposed for the herringbone micro-fin tube.     

Performance of a packed bed absorber for aqua ammonia absorption refrigeration systemPerformance d''un matelas dispersant dans un système frigorifique à absorption à ammoniac/eau

A mathematical model of a packed bed absorber for aqua-ammonia absorption refrigeration system is presented. The model is used to predict the performance of the bed at various design and operating conditions. The governing equations and the boundary conditions are derived to predict the bed performance. A numerical integral method and an iteration scheme are used to solve the governing one dimensional, non-linear simultaneous differential equations which are subjected to three point boundary value problem. A computer program is prepared and carefully debugged to solve the governing equations with the help of some supporting equations to describe the properties of the working fluids and the heat and mass transfer coefficients in the bed. The analysis show that the absorption process is affected by the following parameters: the volumetric heat rejection model, bed height, vapor and solution flow rates to the bed and the inlet conditions; and packing material type. The effect of changing each of those parameters on the performance of the bed is studied after suggesting a model for the volumetric heat rejection from the bed. The results showed that changing the bed pressure and/or the vapor inlet temperature have negligible effect on the performance of the bed. Changing other parameters are found to affect the performance of the bed by different degrees. Also, the results show that within the present range of parameters, a bed height less than 0.7 m guarantees an absorption efficiency better than 91%.

Résumé

On présente un modèle mathématique d'un matelas dispersant dans un système frigorifique à absorption à ammoniac/eau. On utilise ce modèle pour prévoir la performance du matelas utilisant diverses conceptions et sous diverses conditions de fonctionnement. On établit des équations qui décrivent ce processus et les conditions limites afin de prévoir la performance du matelas. On utilise une méthode numérique intégrale et un schéma d'itération afin de résoudre les équations unidimensionnelles, non-linéaires, simultanées et différentielles, qui sont soumises au problème des limites à trois points. Un programme informatique est préparé et débogué afin de résoudre les équations qui gouvernent le processus étudié, avec l'aide de quelques équations supplémentaires qui décrivent les caractéristiques des fluides actifs et les coefficients de transmission thermique et de transfert d'énergie massique du matelas. L'analyse montre que le processus d'absorption est influencé par des paramètres suivants: le modèle de rejet de chaleur volumétrique, la hauteur du matelas, les débits d'écoulement de la vapeur et de la solution vers le matelas, les conditions d'entrée et le matériau dispersant utilisé. On étudie également l'influence de la variation de chacun de ces paramètres sur la performance du matelas apres avoir proposé un modèle de rejet de chaleur volumétrique par le matelas. Les résultats montrent que si on change la pression dans le matelas et/ou la température de la vapeur à l'arrivée, de tels changements ont un effet negligeable sur le matelas. Suite au changement d'autres paramètres, la performance du matelas a été modifée de diverses façons. Les résultats montrent également qu'avec les paramètres adoptés ici, une hauteur du matelas inférieure à 0,7 m assure un taux d'absorption supérieur à 91%.     

Evaluation of heat and mass transfer coefficients in a gauze-type structured packing air dehumidifier operating with liquid desiccant

In this paper, high performance packing, namely, structured packing that has good heat and mass transfer characteristics, is proposed for dehumidification of air using liquid desiccants and for regeneration of liquid desiccants. In order to design a structured packing tower for liquid desiccant — air contacting operations, heat and mass transfer coefficients for each phase are required. This paper is concerned with the interface transfer of heat and mass when air is brought into contact with the liquid desiccant solution. A theoretical study of evaluating heat and mass coefficients in an air-desiccant contact system employing three liquid desiccants, namely calcium chloride, lithium chloride, and a mixture of 50% calcium chloride and 50% lithium chloride (called cost effective liquid desiccant, CELD) is investigated. Moreover, air phase transfer coefficients are correlated with flow rates of air and liquid and the temperature of air, whereas liquid phase coefficients are correlated with rates of air and liquid flow, and the temperature and concentration of the liquid. The findings for the three liquid desiccants are compared and discussed.     

Prediction of in-tube condensation heat transfer characteristics of binary refrigerant mixtures

This study presents a prediction model for the condensation heat transfer characteristics of binary zeotropic refrigerant mixtures inside horizontal smooth tubes. In this model, both the vapor-side and liquid-side mass transfers are considered, and the high flux mass transfer correction factor is used to evaluate mass transfer coefficients. The model was applied to the binary zeotropic refrigerant mixture R134a/R123, which has a large temperature glide. Calculation results showed that the heat transfer degradation of R134a/R123 due to gradients in the mass fraction and temperature is considerable, and depends on the mass fraction of the more volatile component and the vapor mass quality of the refrigerant mixture. By comparison with experimental data, incorporating the present finite mass transfer model for the liquid film side into the calculation algorithm was shown to reasonably well predict the condensation heat transfer coefficients of binary refrigerant mixtures with the mean deviation of about 10.3%. In the present calculations, however, it was also found that the high flux mass transfer correction factor had only a slight effect on the condensation heat transfer.     

The influence of a low viscosity oil on the pool boiling heat transfer of the refrigerant R507Influence d'une huile à faible viscosité sur le transfert de chaleur lors de l'ébullition libre du frigorigène R507

This paper describes the influence of a low viscosity polyolester based lubricating oil on the pool boiling heat transfer of the refrigerant R507. The pool boiling heat transfer coefficients for this refrigerant–oil mixture are measured on a smooth tube and on an enhanced tube. The investigation is made for oil mass fractions up to 10% and for saturation temperatures between −28.6°C and +20.1°C. For the smooth tube the heat transfer increases for increasing oil mass fractions up to 3% at lower saturation temperatures. At higher saturation temperatures the heat transfer decreases for increasing oil mass fractions for both tubes. For oil mass fractions greater than 1% at the higher saturation temperatures a range of decreasing heat transfer coefficient is found for increasing heat flux. The effect is caused by the different miscibility of the oil and the components of the refrigerant mixture.     

Development of a slug flow absorber working with ammonia–water mixture: part II—data reduction model for local heat and mass transfer characterization

This study deals with a data reduction model for clarifying experimental results of a counter-current slug flow absorber, working with ammonia–water mixture, for significantly low solution flow rate conditions. The data reduction model to obtain the local heat and mass transfer coefficient on the liquid side is proposed by using the drift flux model to analyze the flow characteristics. The control volume method and heat and mass transfer analogy are employed to solve the combined heat and mass transfer problem. As a result, it is found that the local heat and mass transfer coefficient on the liquid side of the absorber is greatly influenced by the flow pattern. The heat and mass transfer coefficient at the frost flow region is higher than that at the slug flow region due to flow disturbance and random fluctuation. The solution flow rate and gas flow rate have influence on the local heat and mass transfer coefficient at the frost flow region. However, it is insignificant at the slug flow region.     

大压差下静止氨水表面吸收特性研究

基于对大压差下静止氨水溶液表面吸收氨蒸气过程中热质传递现象的分析,建立了该吸收过程传热传质相互耦合的数学物理模型。在氨蒸气压力不变的情况下,推导出氨水溶液温度场、浓度场以及表征相界面传质的无量纲准则数的理论表达式,结果证明:相界面处氨浓度、温度均为定值,该值只取决于吸收的初始条件。在引入氨水相平衡方程的前提下,拟合出了传质准则数与初始压差、氨水溶液初始参数的半经验关联式,获得了一定初始条件下时均传质量随时间的变化曲线。曲线显示:在吸收开始时,时均传质量最大,随着吸收时间的增加,时均传质量迅速下降。     

Experimental measurements for condensation of downward-flowing R123/R134a in a staggered bundle of horizontal low-finned tubes with four fin geometriesMesures expérimentales de la condensation lors de l'éoulement vertical d'un mélange de R123 et de R134a sur un faisceau de tubes en quinconce munis de quatre types d'ailettes

Experiments were conducted to obtain row-by-row heat and mass transfer data during condensation of downward-flowing zeotropic mixture R123/R134a in a staggered bundle of horizontal low-finned tubes. The vapor temperature and the mass fraction of R134a at the tube bundle inlet were about 50°C and 14%, respectively. The refrigerant mass velocity ranged from 9 to 34 kg m⁻² s⁻¹, and the condensation temperature difference from 1.9 to 12 K. Four kinds of low-finned tubes with different fin geometry were tested. The highest heat transfer coefficient was obtained with a tube which showed the highest performance for R123. However, the diference among the tubes was much smaller for the mixture than for R123. The heat transfer coefficient and the vapor-phase mass transfer coefficient decreased significantly with decreasing mass velocity. The mass transfer coefficient increased with condensation temperature difference, which was due to the effect of suction associated with condensation. On the basis of the analogy between heat and mass transfer, a dimensionless correlation of the mass transfer coefficient was developed for each tube.     

Experimental investigations on boiling of n-pentane across a horizontal tube bundle: two-phase flow and heat transfer characteristicsEtude expérimentale de l'ébullition de n-pentane à travers un faisceau de tubes horizontal: écoulement diphasique et caractéristiques de transfert de chaleur

This paper presents the heat transfer characteristics obtained from an experimental investigation on flow boiling of n-pentane across a horizontal tube bundle. The tubes are plain with an outside diameter of 19.05 mm and the bundle arrangement is inverse staggered with a pitch to diameter ratio of 1.33. The test conditions consist of reduced pressure between 0.006 and 0.015, mass velocity from 14 to 44 kg/m²s, heat flux up to 60 kW/m² and vapor quality up to 60%. The convective evaporation is found to have a significant effect on the heat transfer coefficient, coexisting with nucleate boiling. An asymptotic model allows the prediction of the heat transfer data with a fitted value of n=1.5. A strong mass velocity effect is observed for the enhancement factor, implying that the correlations available from the literature for the convective evaporation will fail in predicting the present data. This effect decreases as the mass velocity increases.     

Research on the condensation of the ammonia–water mixture on a horizontal smooth tube

This paper reports on the experimental research and the theoretical analysis conducted to study the condensation of the ammonia–water mixture on a horizontal smooth tube. Experiments were carried out with ammonia concentrations and wall subcoolings ranging from 62% to 95% and from 45 °C to 90 °C, respectively. Experimental results of the overall condensation heat transfer coefficients (HTCs) are reported and discussed. A theoretical model based on the analytical method proposed by Colburn and Drew was developed. The model was able to predict the trends of the experimental HTCs for the ranges of concentrations and wall subcoolings considered in the experiments. The heat flow and the overall condensation HTCs were slightly overestimated with mean errors of 9.3% and 11.2%, respectively. The theoretical results revealed that the ammonia mass transfer in the vapour phase has a significant effect on the heat and mass transfer coefficients and, consequently, on the overall condensation HTCs. Finally, a calculation procedure was established to estimate the vapour mass and heat transfer coefficients from experimental data. The results are shown as dimensionless correlations.     

Evaluation of heat and mass transfer coefficients for falling-films on tubular absorbers

A coupled heat and mass transfer model is developed to extract the transfer coefficients for falling-films from the measurements on a tubular absorber. The mass transfer coefficients obtained from the coupled model and the log-mean-difference approach agree within about 10%. For the heat transfer coefficient, the values given by the two models can differ quite significantly. The cooling water temperature distribution predicted by the coupled model agrees well with measurements. The transfer coefficients obtained from experimental measurements using the various methods reported in the literature show wide variations.     

A dynamic model of heat and mass transfer in a double-bed adsorption machine with internal heat recovery

This paper presents the results of a predictive two-dimensional mathematical model of an adsorption cooling machine consisting of a double consolidated adsorbent bed with internal heat recovery. The results of a base-case, taken as a reference, demonstrated that the COP of the double bed adsorption refrigeration cycle increases with respect to the single bed configuration. However, it was verified that, in order to maximize also the specific power of the machine, the adsorbent beds must have proper thermo-physical properties.Consequently, a sensitivity analysis was carried out, studying the influence of the main heat and mass transfer parameters on the performance of the machine. The results obtained allowed us to define the adsorbent bed design that maximizes its heat and mass transfer properties, as well as the most profitable heat recovery conditions.     

Evaporation heat transfer for R-22 and R-407C refrigerant–oil mixture in a microfin tube with a U-bendTransfert de chaleur lors de l'évaporation de R-22 et de R-407C mélangés avec de l'huile dans un tube à micro-ailettes avec un coude en U

Evaporation heat transfer experiments for two refrigerants, R-407C and R-22, mixed with polyol ester and mineral oils were performed in straight and U-bend sections of a microfin tube. Experimental parameters include an oil concentration varied from 0 to 5%, an inlet quality varied from 0.1 to 0.5, two mass fluxes of 219 and 400 kg m⁻²s⁻¹ and two heat fluxes of 10 and 20 kW m⁻². Pressure drop in the test section increased by approximately 20% as the oil concentration increased from 0 to 5%. Enhancement factors decreased as oil concentration increased under inlet quality of 0.5, mass flux of 219 kg m⁻² s⁻¹, and heat flux of 10 kW m⁻², whereas they increased under inlet quality of 0.1, mass flux of 400 kg m⁻² s⁻¹, and heat flux of 20 kW m⁻². The local heat transfer coefficient at the outside curvature of an U-bend was larger than that at the inside curvature of a U-bend, and the maximum value occurred at the 90° position of the U-bend. The heat transfer coefficient was larger in a region of 30 tube diameter length at the second straight section than that at the first straight section.     

Local boiling heat transfer characteristics of ammonia/water binary mixture in a vertical plate evaporator

The next-generation energy production systems are expected to be based on ocean thermal energy conversion (OTEC) and discharged thermal energy conversion (DTEC). These systems use a plate-type evaporator and ammonia or an ammonia/water mixture as a working fluid. It is important to clarify heat transfer characteristics for designing efficient power generation systems. Measurements of local boiling heat transfer coefficients and visualizations were performed for an ammonia/water mixture (z = 0.9) on a vertical flat plate heat exchanger at a range of mass fluxes (7.5-15 kg m⁻² s⁻¹), heat fluxes (15-23 kW m⁻²), and pressures (0.7-0.9 MPa). The results show that in the case of an ammonia/water mixture, the local heat transfer coefficients increase with an increase in the vapor quality and mass flux and decrease with an increase in the heat flux. The influence of the flow pattern on the local heat transfer coefficient is also observed.     

CO2 flow condensation heat transfer and pressure drop in multi-port microchannels at low temperatures

CO₂ flow condensation heat transfer coefficients and pressure drop are investigated for 0.89 mm microchannels at horizontal flow conditions. They were measured at saturation temperatures of −15 and −25 °C, mass fluxes from 200 to 800 kg m⁻² s⁻¹, and wall subcooling temperatures from 2 to 4 °C. Flow patterns for experimental conditions were predicted by two flow pattern maps, and it could be predicted that annular flow patterns could exist in most of flow conditions except low mass flux and low vapor quality conditions. Measured heat transfer coefficients increased with the increase of mass fluxes and vapor qualities, whereas they were almost independent of wall subcooling temperature changes. Several correlations could predict heat transfer coefficients within acceptable error range, and from this comparison, it could be inferred that the flow condensation mechanism in 0.89 mm channels should be similar to that in large tubes. CO₂ two-phase pressure drop, measured in adiabatic conditions, increased with the increase of mass flux and vapor quality, and it decreased with the increase of saturation temperature. By comparing measured pressure drop with calculated values, it was shown that several correlations could predict the measured values relatively well.     

Boiling of ammonia/lubricant mixture on a horizontal enhanced tube in a flooded evaporator with inlet vapor quality

In a flooded evaporator of an ammonia vapor-compression refrigeration system, boiling commonly takes place with ammonia mixed with compressor lubricant and subjected to a vapor quality at the inlet of the evaporator. In the present study, flooded boiling tests of ammonia on an enhanced tube under simultaneous influence of a miscible lubricant and inlet quality were conducted. The results suggest that the boiling heat transfer coefficient increases with both saturation temperature and heat flux. The coefficient slightly increases or does not significantly vary with the inlet quality. The coefficient in general is decreased by adding lubricant to the refrigerant, but the coefficient does not necessarily decrease as the lubricant concentration increases. The lubricant effect is generally more significant than the inlet quality effect. A correlation was developed based on the present data for flooded boiling of lubricant/ammonia mixture on an enhanced horizontal tube under the influence of inlet quality.     

Heat and mass transfer enhancement of binary nanofluids for H2O/LiBr falling film absorption process

The objectives of this study are to measure the vapor absorption rate and heat transfer rate for falling film flow of binary nanofluids, and to compare the enhancement of heat transfer and mass transfer under the same conditions of nanofluids. The key parameters are the base fluid concentration of LiBr, the concentration of nanoparticles in weight %, and nanoparticle constituents. The binary nanofluids are H₂O/LiBr solution with nanoparticles of Fe and Carbon nanotubes (CNT) with the concentrations of 0.0, 0.01 and 0.1 wt %. The vapor absorption rate increases with increasing the solution mass flow rate and the concentration of Fe and CNT nanoparticles. It is found that the mass transfer enhancement is much more significant than the heat transfer enhancement in the binary nanofluids with Fe and CNT. It is also found that the mass transfer enhancement from the CNT nanoparticles becomes higher than that from the Fe nanoparticles. Therefore, the CNT is a better candidate than Fe nanoparticles for absorption performance enhancement in H₂O/LiBr absorption system.