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典型方法和材料对水玻璃的改性效果与机制 总被引:1,自引:0,他引:1
研究比较了超声处理、纳米粉末改性、复合材料改性等水玻璃粘结剂改性方法及材料对水玻璃粘结剂的改性效果;分析了水玻璃的改性机制。试验结果表明,超声处理虽然提高了水玻璃砂的常温强度,却也恶化了溃散性;水玻璃经过纳米氧化物粉末改性后,适量纳米氧化物粉末可以在一定程度上改善水玻璃砂的溃散性,但常温强度却不能得到较大幅度的提高,作者开发的复合改性剂,既可提高水玻璃砂的常温强度,又可改善水玻璃砂的溃散性。借助XPS和SEM微观分析的方法,探讨了水玻璃粘结剂改性方法及材料对水玻璃粘结剂的改性机理。 相似文献
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近年来,铸造生产上自硬砂发展很快,应用越来越广泛。无论是以有机物为粘结剂或是以无机物为粘结剂的自硬砂,均较粘土砂(或称烘模砂、干模砂)有它独特的优点。如型砂有良好的流动性,易成型,型芯轮廓清晰;强度高便于装配组芯;溃散性好,出砂方便,减轻劳动强度等等。在铸造工艺 相似文献
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水玻璃粘结剂改性技术的现状及发展趋势 总被引:2,自引:0,他引:2
结合酯硬化水玻璃砂应用特点,介绍了水玻璃粘结剂改性技术的现状及发展方向.水玻璃粘结剂改性的本质可概括为提高纯净度(降低杂质含量)、减少老化现象(加入抗老化物质)、提高水玻璃砂的强度、溃散性、抗湿性、操作性等.水玻璃的模数是水玻璃砂性能的主要性能控制指标,调整水玻璃的模数是调整水玻璃砂硬化速度和强度的主要手段.普通干法再生砂能实现循环使用的关键技术之一是采用模数为1.6~2.0的超低模数的水玻璃.目前,水玻璃砂的抗湿性问题、干法再生砂循环使用后溃散性快速恶化问题、酯硬化水玻璃砂厚大砂型的硬透性问题等还有待进一步解决,这些问题的深入研究及其实用技术的开发是水玻璃粘结剂改性技术的发展方向. 相似文献
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本文研究了一种新型液体溃散剂,该列加入到水玻璃粘结剂中,可以和水玻璃无限互溶,提高水玻璃砂的粘结强度,减少型砂中水玻璃的加入量。加入该剂的水玻璃砂,可加热硬化,也可吹C02气硬化,不降低使用强度,但却极大地降低水玻璃砂浇注后的残留强度,从而改善其溃散性。 相似文献
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本文研究了一种新型液体溃散剂,该剂加入到水玻璃粘结剂中,可以和水玻璃无限互溶,提高水玻璃砂的粘结强度,减少型砂中水玻璃的加入量。加入该剂的水玻璃砂,可加热硬化,也可吹CO2气硬化,不降低使用强度,但却极大地降低水玻璃砂浇注后的残留强度,从而改善其溃散性。 相似文献
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本文研究了BY粘结剂对水玻璃砂工艺性能和不同温度下残留强度的影响。通过差热分析和扫描电镜断口分析,证实了BY粘结剂在其分解温度区间255~565℃,由于析出大量气体,在连接桥上形成大大小小的孔洞,严重破坏其残留强度,显著改善水玻璃砂的溃散性。 相似文献
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铸铝件造型制芯技术的现状与发展 总被引:5,自引:0,他引:5
游敏 《特种铸造及有色合金》1997,(3):44-46
综述了铝合金铸件生产工艺的现状与发展,指出随着汽车工业对高质量铝铸件的需求日益增加,铝合金铸造技术将得到很快的发展。开发铸铝件专用粘结剂、改善型芯砂的溃散性、防止环境污染等将成为今后铸铝件生产技术发展的主要方向。 相似文献
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Xia Zhou Jinzong Yang Depeng Su Guohui Qu 《Journal of Materials Processing Technology》2009,209(14):5394-5398
A new binder composed of α-starch, kaolin, sodium silicate, dextrin, phosphate and water in proportions 2.5–4.0%, 1.5–3.0%, 0.55%, 0.35%, 0.04% and 2.5–3.5% by weight percent respectively has been developed. The high-temperature resistant mechanism of the mold and core sand bonded with α-starch composite binder was studied by way of differential scanning calorimetry (DSC), X-ray diffraction (XRD), infrared (IR) spectra and scanning electron microscopy (SEM) analyses without sand or on a sand base. It is believed that the high-temperature strength of the sand mold or sand core is mainly dependent on the cohesive strength of the adhesive membrane between sand grains. When the binder was heated over 600 °C, the kaolin in it reacted with the sodium silicate and phosphate separately, forming Al–O–Si three-dimensional skeleton and heat-resistant AlPO4, thus, the binder is provided with higher high-temperature resistant strength. This conclusion is also confirmed by the experimental research on the high-temperature mechanical properties of the binder bonded sand and the microstructure observation of the binding film. The research on the high-temperature resistant mechanism of the starch binder bonded sand is helpful to its high-temperature performance optimization and its application in the foundry industry. 相似文献
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Two important factors affecting the performance of sand mold/core generated by 3D printing (3DP) are strength and dimensional accuracy,which are not only closely related to the reactivity of furan resin and the phase transition of silica sand,but also the curing agent system of furan resin.This paper studies the influence of gel time on the strength and dimensional accuracy of a 3DP sand mold/core,taking the furan resin system as an example and using a sand specimen generated by a 3DP inkjet molding machine.The experiment demonstrates that the gel time of 3 to 6 min for the sand mixture suits 3DP core-making most under the experimental condition.However,it should be noted that under the same resin condition,the strength of a no-bake sand mold/core is higher than that of a 3DP sand mold/core.The dimensional accuracy of the sand mold/core does not change significantly when the gel time is less than 15 min.Improving the activity of binder and developing ultra-strong acid with low corrosion shall be an effective way to improve the quality of the mold/core by 3D printing. 相似文献