Converting liability into asset: novel mesoporous zeotype from fly ash using silatrane chemistry

Fly ash has become a major liability. We report here a clean technology to convert this liability into an asset. Novel mesoporous zeotype, UDCaT-8 was synthesized by using a unique process based on silatrane chemistry. Instead of costly silanes and alkoxides, fly ash was utilized as a raw material. In this process, silicon and aluminium oxide dissolutions were carried out with ethylene glycol in the presence of amines as organic bases. The silatrane and alumatrane glycolate complexes thus formed were converted to a novel mesoporous zeotype via double-stage heating process (pyrolysis followed by oxidation).     

Cost-efficient clean flotation of amorphous graphite using water-in-oil kerosene emulsion as a novel collector

Kerosene is one of the most used collectors in graphite flotation, while its consumption undergoes an enormous increase, especially in amorphous graphite flotation, imposing heavy economic burdens and raising environmental concerns. In this work, a novel water-in-oil type kerosene emulsion was prepared, and its flotation performance as a collector on an amorphous graphite ore was examined and compared to pristine kerosene. An optimized emulsification process was developed based on the roughing flotation test. Particle size distribution analysis, optical microscope, and Cryo-SEM studies indicated homogenous and fine emulsified kerosene droplets in aqueous. More importantly, the open circuit flotation test proved emulsified kerosene as a superior collector to pristine kerosene in terms of enhancing the clean flotation efficiency of amorphous graphite.     

Intelligent energy management of a fuel cell vehicle based on traffic condition recognition

Clean Technologies and Environmental Policy - This paper presents a methodological approach for intelligent control of fuel cell vehicles based on traffic condition recognition. For this purpose,...     

Formation of novel Si-fullerene compound materials using a high-density silicon-ion plasma

A Si-Ar plasma is produced using a RF discharge by an internal coil, which is accompanied by DC sputtering, for the purpose of forming novel Si-fullerene compound materials. According to the analysis of the fullerene-C₆₀ after Si-Ar plasma ion irradiation, mass peaks corresponding to Si-heterofullerenes (SiC₅₉, Si₂C₅₈ and Si₃C₅₇) are observed.It was also found that the method of introducing sublimated C₆₀ into the Si-Ar plasma using a C₆₀-oven resulted in an increase in the formation efficiency of SiC₅₉.     

In situ polymerization into porous ceramics: a novel route to tough biomimetic materials

A hydroxyapatite-based biomimetic composite, which is henceforth referred to as a synthetic bony material with high toughness characteristics, was prepared. It was obtained from a hydroxyapatite (HAp) skeleton with a relative porosity fraction of 32 vol %, prepared by cold-isostatic-press compaction, followed by a sintering process, leading to a hydroxyapatite structure containing percolated submicrometer porosity channels. The percolated pores were infiltrated with a liquid mixture of -caprolactam monomer and an initiator, before homogeneous in situ polymerization to 6-nylon within the fully percolated pore structure was induced thermally. The final composite consisted of a dense interpenetrated hydroxyapatite/6-nylon network in a fraction 68/30 vol %. The work of fracture value of the hybrid composite was found to be comparable with those found in two natural materials (bovine femur and nacre), which were also investigated under the same testing conditions.     

Remote sensing of mechanical properties of materials using a novel ultrasound transducer and signal processing

An ultrasound-based remote sensing method to evaluate the mechanical properties of materials is presented. This method consists of a disk-shaped, piezoelectric transducer, operating at its resonance frequency, and a phase-shifted, feedback circuit. Mechanical parameters are derived by analyzing the signal contained in the phase-shifted values of the reflected signal. It is concluded that, using this novel transducer system and signal processing, remote mechanical measurements can be made. Such measurements obviate the need to apply the force-deformation approach and may be used to enable stiffness imaging.     

Evaluation of water distribution in a small operating fuel cell using neutron color image intensifier

Neutron radiography is one of the useful tools for visualizing water behavior in operating fuel cells. In order to observe the detailed information about the water distribution in membrane electrode assembly (MEA) and gas diffusion layer (GDL) in fuel cells, a high performance neutron imaging system is required. A neutron color image intensifier (NCII) is a high spatial resolution and high sensitivity neutron image detector. We have developed an imaging system using an NCII for visualizing the behavior of water in fuel cells. The pixel size of the imaging system is around 4.7 μm in the small view field. By using this system, water distribution of a small sized fuel cell was observed continuously every 20 s at the Thermal Neutron Radiography Facility (TNRF). In the results, the water area appears from the GDL and MEA regions, and expanded to the cathode side channel with time. However, the voltage was gradually reduced with time, and steeply dropped. It is considered that the reduction and the drop of voltage were caused by a blockage of gas flow due to accumulation of water in the GDL and the gas flow channel in the cathode side.     

Performance evaluation of a stack cooling system using CO2 air conditioner in fuel cell vehicles

A relation between the heat release from a fuel cell stack and an air conditioning system's performance was investigated. The air conditioning system installed in a fuel cell vehicle can be used for stack cooling when additional stack heat release is required over a fixed radiator capacity during high vehicle power generation. This study investigated the performance of a stack cooling system using CO₂ air conditioner at various operating conditions. Also, the heat releasing effectiveness and mutual interference were analyzed and compared with those for the conventional radiator cooling system with/without cabin cooling. When the radiator coolant inlet temperature and flow rate were 65 °C and 80 L/min, respectively, for the outdoor air inlet speed of 5 m/s, the heat release of the stack cooling system with the aid of CO₂ air conditioner increased up to 36% more than that of the conventional radiator cooling system with cabin cooling. Furthermore, this increased by 7% versus the case without cabin cooling.     

Analysis of volatile species kinetics during typical medical waste materials pyrolysis using a distributed activation energy model

The complex reactions of typical medical waste materials pyrolysis and the evolution of different volatile species can be well represented by a Distributed Activation Energy Model (DAEM). In this study, A thermogravimetric analyser (TGA), coupled with Fourier transform infrared analysis of evolving products (TG-FTIR), were used to perform kinetic analysis of typical medical waste materials pyrolysis. A simple direct search method was used for the determination of DAEM kinetic parameters and the yield of individual pyrolysis products under any given heating condition. The agreement between the model prediction and the experimental data was generally good. The results can be used as inputs to a pyrolysis model based on first-order kinetic expression with a Gaussian Distribution of Activation Energies as a sub-model to CFD code.     

Effective transformation of the energy of high-voltage pulses into high-frequency oscillations using a saturated-ferrite-loaded transmission line

A new method of converting a high-voltage video pulse into high-frequency oscillations using a nonlinear transmission line with temporal dispersion has been studied. The dispersion was provided by pulsed magnetization reversal in a ferrite, which was initially magnetized to saturation in an external magnetic field. For a 9-ns pulse, an average energy conversion efficiency of about 10% was achieved. It is demonstrated that oscillations at frequencies within 600 MHz-1.1 GHz with a spectral width of about 15% (at a −3 dB level) can be excited using voltage pulses with an amplitude of 110–290 kV. The optimum bias magnetization fields are within 20–40 kA/m.     

A novel approach to acoustic liquid density measurements using a buffer rod based measuring cell

A new method for measuring the pressure reflection coefficient in a buffer rod configuration is presented, together with experimental results for acoustic measurements of the liquid density, based on the measurement of the liquid's acoustic impedance. The method consists of using 2 buffers enclosing the liquid in a symmetrical arrangement with a transducer fixed to each buffer. One of the transducers is used in a pulse-echo mode while the other transducer operates as a receiver. The echo amplitudes leading to the pressure reflection coefficient as found by this method possess advantages such as reduced attenuation due to a shorter liquid transmission path and reduced interference, as compared with the ABC method. Measurements with distilled water and with special density calibration oil qualities have been performed using both the new method and the ABC method and are shown for the new method to give a density span within +/- 0.15% of the reference values. A comparison of the measured densities based on both a time-domain and a l(2)-norm frequency domain integration signal processing approach is given, along with a recommendation as to how the signal processing should be performed.     

Investigation of fibroblast and keratinocyte cell-scaffold interactions using a novel 3D cell culture system

In this study we investigated the influence of fibre diameter and interfibre space in 3D scaffolds on cellular behaviour of human dermal fibroblasts and a human keratinocyte cell line (HaCaT cell). Electrospun aligned poly L-lactic acid fibres (2–10 μ m) were bound to form fibres with a broad range of diameters (2–120 μ m) and then constructed in a specifically designed 3D cell culture system. Human dermal fibroblasts were introduced to one end of the free-standing fibres using a fibrin clot and encouraged to ‘walk the plank’. Under these conditions it was observed that a minimum fibre diameter of 10 μ m for fibroblast adhesion and migration arose. A thin layer of electrospun viscose rayon scaffold fibres (diameter 30–50 μ m, pore size 50–300 μ m) was also constructed in the 3D cell culture system. After introduction to the scaffold using cells contained within a fibrin clot, fibroblasts were observed to stratify and also elongate between fibres in order to occupy voids. An interfibre span of up to 200 μ m was possible by a single fibroblast, but more commonly void distances were spanned by cellular multilayering. In contrast, HaCaT keratinocytes cultured under identical conditions using viscose rayon scaffolds occupied very much smaller void distances of 50–80 μ m predominantly by stratification.     

Heating performance enhancement of a CO2 heat pump system recovering stack exhaust thermal energy in fuel cell vehicles

A CO₂ heat pump system using recovered heat from the stack coolant was provided for use in fuel cell vehicles, where the high temperature heat source like in internal combustion engine vehicles is not available. The refrigerant loop consists of an electric drive compressor, a cabin heater, an outdoor evaporator, an internal heat exchanger, an expansion valve and an accumulator. The performance characteristics of the heat pump system were investigated and analyzed by experiments. The results of heating experiments were discussed for the purpose of the development and efficiency improvement of a CO₂ heat pump system, when recovering stack exhaust heat in fuel cell vehicles. A heater core using stack coolant was placed upstream of a cabin heater to preheat incoming air to the cabin heater. The performance of the heat pump system with heater core was compared with that of the conventional heating system with heater core and that of the heat pump system without heater core, and the heat pump system with heater core showed the best performance of the selected heating systems. Furthermore, the coolant to air heat pump system with heater core showed a significantly better performance than the air to air heat pump system with heater core.     

Efficiency of free cooling using latent heat storage integrated into the ventilation system of a low energy building

This article presents the results of an investigation into the free cooling efficiency in a heavyweight and lightweight low energy building using a mechanical ventilation system with two latent heat thermal energy storages (LHTESs), one for cooling the fresh supply air and the other for cooling the re-circulated indoor air. Both LHTESs contain sphere encapsulated PCM (paraffin RT20). Using a developed and experimentally verified numerical model of the LHTES, the temperature response functions, based on the heat storage size, the air flow rates and the PCM's thermal properties, are established in the form of a Fourier series and empirical equations and used in the TRNSYS building thermal response model. Several mechanical ventilation, night cooling and free cooling operation modes were analysed and compared. It was found that the free cooling technique enables a reduction in the size of the mechanical ventilation system, provides more favourable temperatures and therefore enables better thermal comfort conditions, and in our studied case also fresh air for the occupants.