Nb-V微合金中碳非调质钢CCT曲线的测定与分析

在Gleeble-3500热模拟机上测定了Nb-V微合化金中碳非调质钢在不同冷却速率下的膨胀曲线,并联合金相-硬度法,绘制出了Nb-V试验钢的动态CCT曲线。依据所绘试验钢动态CCT曲线,对试验钢在不同冷却速率下组织的转变转变情况进行了分析。结果表明:冷却速率低于2℃/s时,Nb-V钢的显微组织为铁素体和珠光体,冷却速率超过2℃/s时,钢中组织可以观察到贝氏体,随着冷却速率的增加贝氏体含量也明显增加;冷却速率超过10℃/s时,组织中开始出现马氏体;冷却速率超过15℃/s后Nb-V钢显微组织全部为马氏体。贝氏体转变的临界冷却速率为7~10℃/s,马氏体转变的临界冷却速率为10~15℃/s。     

V-N微合金化600 MPa高强度钢筋钢的动态连续冷却转变曲线

利用Gleeble-1500热模拟试验机测定了V-N微合金化600 MPa高强度钢筋钢在不同冷速下连续冷却转变的热膨胀曲线,结合显微组织观察,获得了该钢的动态连续冷却转变曲线。结果表明,当冷却速率小于1 ℃/s时,组织为铁素体和珠光体;当冷却速率为3 ℃/s时,出现少量贝氏体;当冷却速率为8℃/s时,珠光体消失,组织为铁素体和贝氏体;当冷却速率为10 ℃/s时,开始出现马氏体;当冷却速率在20 ℃/s以上时,组织全部转变为马氏体。     

42CrMoA钢过冷奥氏体连续冷却相转变曲线

结合膨胀法和金相-硬度法,利用Gleeble-1500D热模拟机测定了42CrMoA钢的临界点Ac1、Ac3和Ms点,测定了该钢在不同冷却速度下连续冷却时的膨胀曲线,相转变点;分析了连续冷却过程中过冷奥氏体转变过程及转变产物的组织形貌;测定了不同冷却速度下相转变后的硬度,获得了该钢过冷奥氏体连续冷却相转变曲线.结果表明,当冷却速度小于0.1℃/s时,转变产物为铁素体和珠光体组织;当冷却速度0.2～0.6℃/s时转变产物是铁素体、珠光体、贝氏体的混合组织;当冷却速度为0.7～17℃/s时,转变产物是贝氏体和马氏体的混合组织;当冷却速度大于20℃/s时,转变产物为完全马氏体,此次实验并没有获得完全贝氏体.     

65Mn钢连续冷却转变动态CCT曲线及组织

利用膨胀法结合金相-硬度法,在Gleeble-3500热模拟机上测定了65Mn钢连续冷却转变动态CCT曲线;研究了冷却速度对组织的影响。结果表明,当冷却速度小于10℃/s时,转变产物为铁素体和珠光体;当冷却速度为10～40℃/s时,转变产物是铁素体、珠光体和马氏体;当冷却速度大于40℃/s时,转变产物为完全马氏体组织。     

含Mo元素CL60钢CCT曲线的测定及分析

在Gleeble-3800热模拟机上测定了含微量Mo元素CL60钢在不同冷却速度下连续冷却时的膨胀曲线,并采用金相-硬度法,测定了该钢的连续冷却转变曲线(CCT曲线),研究了冷却速度对其显微组织演变以及硬度的影响。结果表明:当冷却速度小于1℃/s时,实验钢的转变产物为先共析铁素体和珠光体组织;当冷却速度增加到2℃/s时,开始发生贝氏体转变;当冷却速度增加到5℃/s时,开始发生马氏体转变;冷却速度在5～10℃/s的范围内时,转变产物为少量铁素体、珠光体、贝氏体和马氏体所组成的混合组织;当冷却速度为15℃/s时,先共析铁素体消失;当冷却速度为20～40℃/s时,转变产物为珠光体和马氏体混合组织;当冷却速度大于50℃/s时,转变产物全部为马氏体组织。随着冷却速度的增大,实验钢的硬度逐渐增大。尽管Mo元素的加入能细化珠光体片间距,但加Mo元素CL60钢在生产过程中得到理想组织的条件更加苛刻。为避免贝氏体、马氏体等非理想组织出现,不同部位的冷却速度须严格控制在2℃/s以下。     

42CrMo钢动态CCT曲线及组织转变

采用膨胀测量法并结合金相-硬度法测定了42CrMo钢的动态连续冷却转变曲线(CCT曲线)及组织演变。结果表明,在较低冷却速度下显微组织由铁素体、珠光体和贝氏体组成,冷却速度范围为0.2～1℃/s时,随着冷速的增加,铁素体和珠光体组织逐渐减少直至消失,当冷速增加到1℃/s时,转变组织主要由贝氏体构成。冷却速度≥3℃/s时,显微组织中开始生成马氏体,并在冷却速度≥10℃/s完全转变为马氏体组织。研究还认为马氏体组织的生成是由于大的冷速和大的变形量共同作用的结果。     

新型时效硬化塑料模具钢10Ni3Cr2MnMoCuA1的CCT曲线

使用Formaster-FⅡ型膨胀仪测定了新型时效硬化塑料模具钢10Ni3Cr2MnMoCuA1以不同冷却速度连续冷却后的相变膨胀曲线,并结合试验过程中所采集的金相照片和硬度数据,获得了该钢的连续冷却转变(CCT)曲线,研究了冷却速率对相变组织转变规律的影响。结果表明:10Ni3Cr2MnMoCuA1钢的相变主要发生在200~400℃的温度区间;贝氏体组织转变的临界冷却速度为:0.03℃/s,马氏体组织转变的临界冷却速度为:0.8℃/s;冷速为0.03℃/s时,相变组织为贝氏体(B)和少量铁素体(F);冷速为0.15℃/s时,相变组织为贝氏体(B)和马氏体(M)的混合组织;冷速为0.8℃/s时,相变组织为全马氏体组织(M)。     

海洋平台用EQ70钢的连续冷却转变

采用DIL 805A热膨胀仪测定了EQ70海洋平台用钢在不同冷速下连续冷却转变的膨胀曲线,结合组织观察和微观硬度测定,获得了该钢的连续冷却转变曲线。结果表明,冷速在0.5℃/s以下,实验用钢的组织为粒状贝氏体,冷速在0.5℃/s到2℃/s之间组织主要为粒状贝氏体和板条贝氏体,冷速为2℃/时,开始有马氏体生成,冷速在5℃/s以上,组织全部转变为马氏体。     

冷速对30MnVS6钢过冷奥氏体转变的影响

在DIL805L型膨胀仪上测定了30MnVS6钢在不同冷却速度下连续冷却时的膨胀曲线,结合金相-硬度法分析其相变规律及影响因素,获得了连续冷却转变曲线。结果表明,30MnVS6钢的临界点为:A_(c1)=629℃,A_(c3)=860℃;当冷却速度≤0.5℃/s时,转变产物为铁素体、珠光体;当冷却速度为1℃/s,转变产物开始出现少量贝氏体、马氏体;冷却速度在1~10℃/s时为铁素体、珠光体、贝氏体和马氏体;当冷却速度≥15℃/s时,转变产物为铁素体、贝氏体和马氏体,珠光体完全消失。     

EQ70海洋平台用钢动态连续冷却转变

针对EQ70海洋平台用钢实际生产条件及存在问题,采用Gleeble-1500热模拟试验机测定了EQ70海洋平台用钢动态连续冷却转变膨胀曲线,再结合金相组织观察和显微硬度测定,获得EQ70海洋平台用钢动态连续冷却转变曲线。结果表明：冷速为0.05 ℃/s时,试验用钢的组织为粒状贝氏体以及少量的铁素体;冷速在0.1 ℃/s到1 ℃/s之间组织主要为粒状贝氏体和板条贝氏体;冷速为2 ℃/s时,组织为板条贝氏体和少量马氏体;随着冷速增加,马氏体的含量逐渐增多,冷速在8 ℃/s以上时,组织全部为马氏体。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

Thermodynamics Study on the Decomposition of Chromite with KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

Influence of Heat Treatment on Damping Behaviour of the Magnesium Wrought Alloy AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Effect of Rare Earth Doping on Impedance,Modulus and Conductivity Properties of Multiferroic Composites:0.5(BiLa_xFe_(1-x)O_3)–0.5(PbTiO_3)

The Lanthanum-doped bismuth ferrite–lead titanate compositions of 0.5(Bi LaxFe1-xO3)–0.5(Pb Ti O3)(x = 0.05,0.10,0.15,0.20)(BLxF1-x-PT) were prepared by mixed oxide method.Structural characterization was performed by X-ray diffraction and shows a tetragonal structure at room temperature.The lattice parameter c/a ratio decreases with increasing of La(x = 0.05–0.20) concentration of the composites.The effect of charge carrier/ion hopping mechanism,conductivity,relaxation process and impedance parameters was studied using an impedance analyzer in a wide frequency range(102–106Hz) at different temperatures.The nature of Nyquist plot confirms the presence of bulk effects only,and non-Debye type of relaxation processes occurs in the composites.The electrical modulus exhibits an important role of the hopping mechanism in the electrical transport process of the materials.The ac conductivity and dc conductivity of the materials were studied,and the activation energy found to be 0.81,0.77,0.76 and 0.74 e V for all compositions of x = 0.05–0.20 at different temperatures(200–300 °C).     

Quantitative Analysis of the Crystallographic Orientation Relationship Between the Martensite and Austenite in Quenching–Partitioning–Tempering Steels

The orientation relationships(ORs)between the martensite and the retained austenite in low-and medium-carbon steels after quenching–partitioning–tempering process were studied in this work.The ORs in the studied steels are identified by selected-area electron diffraction(SAED)as either K–S or N–W ORs.Meanwhile,the ORs were also studied based on numerical fitting of electron backscatter diffraction data method suggested by Miyamoto.The simulated K–S and N–W ORs in the low-index directions generally do not well coincide with the experimental pole figure,which may be attributed to both the orientation spread from the ideal variant orientations and high symmetry of the low-index directions.However,the simulated results coincide well with experimental pole figures in the high-index directions{123}_(bcc).A modified method with simplicity based on Miyamoto’s work was proposed.The results indicate that the ORs determined by modified method are similar to those determined by Miyamoto’method,that is,the OR is near K–S OR for the low-carbon Q–P–T steel,and with the increase of carbon content,the OR is closer to N–W OR in medium-carbon Q–P–T steel.     

Growth Kinetics of Single Inclusion Particle in Molten Melts

On the basis of the single-particle framework, a new theory on inclusion growth in metallurgical melts is developed to study the kinetics of inclusion growth on account of reaction and collision. The studies show that the early growth of inclusion depends on reaction growth and Brawnian motion collision, and where the former is decisive, the late growth depends on turbulence collision and Stokes＇ collision, and where the former is dominant; collision growth is very quick during the smelting process, lessened in the refining process, but nearly negligible in the continuous casting process.     

Theoretical Analysis for the Motion and Temperature of Melt Droplets in Spray Degassing Process

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.     

Using Finite Element and Contour Method to Evaluate Residual Stress in Thick Ti-6Al-4V Alloy Welded by Electron Beam Welding

This work was to reveal the residual stress profile in electron beam welded Ti-6Al-4V alloy plates(50 mm thick) by using finite element and contour measurement methods.A three-dimensional finite element model of 50-mmthick titanium component was proposed,in which a column–cone combined heat source model was used to simulate the temperature field and a thermo-elastic–plastic model to analyze residual stress in a weld joint based on ABAQUS software.Considering the uncertainty of welding simulation,the computation was calibrated by experimental data of contour measurement method.Both test and simulated results show that residual stresses on the surface and inside the weld zone are significantly different and present a narrow and large gradient feature in the weld joint.The peak tensile stress exceeds the yield strength of base materials inside weld,which are distinctly different from residual stress of the thin Ti-6Al-4V alloy plates presented in references before.     

Microstructures and Tensile Properties of Ultrafine-Grained Ni–(1–3.5) wt% SiC_(NP) Composites Prepared by a Powder Metallurgy Route

Silicon carbide nanoparticle-reinforced nickel-based composites(Ni–Si CNP),with a Si CNPcontent ranged from1 to 3.5 wt%,were prepared using mechanical alloying and spark plasma sintering.In addition,unreinforced pure nickel samples were also prepared for comparative purposes.To characterize the microstructural properties of both the unreinforced pure nickel and the Ni–Si CNPcomposites transmission electron microscopy(TEM) was used,while their mechanical behavior was investigated using the Vickers pyramid method for hardness measurements and a universal tensile testing machine for tensile tests.TEM results showed an array of dislocation lines decorated in the sintered pure nickel sample,whereas,for the Ni–Si CNPcomposites,the presence of nano-dispersed Si CNPand twinning crystals was observed.These homogeneously distributed Si CNPwere found located either within the matrix,between twins or on grain boundaries.For the Ni–Si CNPcomposites,coerced coarsening of the Si CNPassembly occurred with increasing Si CNPcontent.Furthermore,the grain sizes of the Ni–Si CNPcomposites were much finer than that of the unreinforced pure nickel,which was considered to be due to the composite ball milling process.In all cases,the Ni–Si CNPcomposites showed higher strengths and hardness values than the unreinforced pure nickel,likely due to a combination of dispersion strengthening(Orowan effects) and particle strengthening(Hall–Petch effects).For the Ni–Si CNPcomposites,the strength increased initially and then decreased as a function of Si CNPcontent,whereas their elongation percentages decreased linearly.Compared to all materials tested,the Ni–Si CNPcomposite containing 1.5% Si C was found more superior considering both their strength and plastic properties.