机械合金化制备金属难熔化合金

在介绍机械合金化特点的同时，重点研究和讨论了机械合金化制备金属难熔化合物的过程及机理，并认为机械合金化是制备难熔化合物及其材料的一种行之有效的方法。     

机械合金化纳米晶材料研究进展

综述了机械合金化制备纳米晶材料的研究进展，重点介绍了高强度铝合金，铜合金，难熔金属化合物，金属储氢材料，复相烯土永磁材料等几类机械合金化纳米晶材料的制备与组织性能，指出了机械合金化技术在纳米晶材料制备方面的优势及应用前景。     

金属间化合物的机械合金化制备

综述了机械合金化制备金属间化合物的研究进展，指出了机械合金化技术在金属问化合物制备方面的优势。简述了机械合金化形成金属问化合物的机理，重点介绍了平衡相金属间化合物、弥散强化金属问化合物、过饱和金属问化合物，非晶合金、纳米晶材料等几类机械合金化金属间化合物的制备与组织性能。并针对目前研究的不足以及该研究领域的发展方向提出了加强MA过程热力学和动力学的基础理论研究、改良MA工艺等建议．     

机械合金化金属间化合物Ni3Al研究现状

本文综述了用机械合金化法制备金属间化合物Ni3AI的研究现状和发展情况。介绍了Ni3AI的机械合金化过程和影响因素，以及Ni3AI机械合金化后粉体的成形烧结工艺及性能。展望了金属间化合物Ni3Al机械合金化的发展前景。     

机械合金化(MA)技术的新进展

论述了机械合金化技术的基本原理，介绍了机械合金化技术在弥散强化超合金、非晶态合金、磁性材料、超导合金、高熔点金属间化合物制备中应用的新进展。     

机械合金化结合激光熔覆技术制备CoCrMoNbTi难熔高熵合金

采用机械合金化方法制备CoCrMoNbTi难熔高熵合金粉末，并通过激光熔覆技术成功制备出CoCrMoNbTi高熵合金涂层。研究了球磨时间对合金粉末组织形貌的影响，并利用X射线衍射仪、扫描电子显微镜和能谱仪等分析了高熵合金粉末和涂层的微观结构。结果表明，随着球磨时间的增加，单质金属的衍射峰按其熔点由低到高陆续消失。粉末微观形貌随球磨时间变化明显，粉末由原始状态被挤压成片状，片状粉末逐渐焊合在一起形成扁平状粉末颗粒。在球磨时间达到40 h时，粉末实现完全合金化，此时粉末形貌趋于球形且得到了极大的细化，粉末中各元素分布均匀，形成了稳定的单相体心立方固溶体结构。CoCrMoNbTi难熔高熵合金激光熔覆层成形质量良好，主要由体心立方固溶体和少量Cr₂Nb、Co₂Ti化合物组成，树枝晶组织细小致密。     

机械合金化——一种生产弥散强化合金的新工艺

概述 机械合金化是用高能球磨法制取弥散强化合金粉末的新工艺。利用该工艺能够生产各种类型的、含有弥散难熔化合物粒子和铬、铝等活性合金元素的复杂弥散强化合金粉末,这种粉末经通普粉末冶金方法或其他加工方法进一步处理,可制成机械合金化合金     

机械合金化在Fe-Si合金制备中的应用

机械合金化是一种新的材料制备方法, 近年来在功能材料的制备中得到了广泛的应用. 该文简要回顾了机械合金化的发展历史, 阐述了机械合金化的原理及反应机制, 介绍了机械合金化技术在过饱和固溶体、非晶、纳米晶及金属间化合物等领域的应用状况. 指出机械合金化过程的热力学和动力学研究及合金相结构、性能与球磨工艺条件之间的规律是今后研究的重点, 后续处理工艺的改进是产品实现从实验室向工业应用转变的重要保证.     

机械合金化制备金属间化合物

机械合金化制备金属间化合物机械合金化是一种用来制备过饱和固溶体、金属间化合物和非晶材料各种合金相的固态粉末工艺。该工艺减少了因两种金属熔点不同造成化合物成份分布不均匀现象。本实验用该种工艺合成了Ｔｉ－Ａｌ、Ｆｅ－Ａｌ、Ｎｂ－Ａｌ合金。用等静压方法加工...     

方钴矿热电材料的研究进展

回顾了熔融法、固相反应法、机械合金化和放电等离子烧结技术等方钴矿热电材料的制备方法及其特点，重点阐述了在方钴矿化合物中固溶F2，Ni等元素，以及在方钴矿化合物中填充碱土或稀土元素对热电性能的改进；同时介绍了低维化对方钴矿化合物的热电传输特性的影响。提出了优化方钴矿化合物热电性能的途径。     

Titanium microalloyed steels

Compared with niobium and vanadium, titanium has been regarded as a relative minor element in microalloyed (MA) steels. More recently, titanium compounds in MA steels have been recognised as having a wider role than just involved in austenite grain refinement. A brief history is followed by considering the physical state of titanium and its compounds characterized in MA steels. Their solubility in iron and the morphology of the precipitates they form, lead to their functions in controlling mechanical and toughness properties of MA steels often involving the multiple alloying with niobium, vanadium, carbon and nitrogen. Titanium has become an important element in the development of linepipe steels, which can develop bainite/acicular ferrite (AF) microstructures. The influence of Ti on nucleation of AF is an active research area, particularly in welding of MA steels. Finally, the influence of titanium on hot ductility, continuous casting and thin slab direct-charging processes is discussed.     

Prospects of utilizing refractory compounds for manufacture of hig h-temperature thermocouples

Summary The author discusses the prospects of utilizing refractory compounds as thermoelectrode material. Some questions concerning the manufacture of thermoelectrodes of homogeneous length from refractory compounds are discussed.On the basis of an analysis of the stability of the thermoelectric characteristics and resistance of refractory compounds in some aggressive media (air, Co, CO + N₂, fused metals), the conclusion is drawn that it is possible to manufacture high-temperature thermocouples from refractory compounds with a single calibration curve for a batch of material.     

Relationship of the Yttrium Compounds with the Alloying Method in ODS Ferritic Stainless Steel

ＲｅｌａｔｉｏｎｓｈｉｐｏｆｔｈｅＹｔｔｒｉｕｍＣｏｍｐｏｕｎｄｓｗｉｔｈｔｈｅ　ＡｌｌｏｙｉｎｇＭｅｔｈｏｄｉｎＯＤＳＦｅｒｒｉｔｉｃＳｔａｉｎｌｅｓｓＳｔｅｅｌＺｈａｎｇＹｏｎｇ（张勇）；ＣｈｅｎＭｉｎｇｂｉａｏ（陈明彪）；ＷｕＣｈｅｎｇＪｉａｎ...     

The preparation and properties of spherical powders of refractory compounds

Summary A study was made of the manufacture of spherical powders from refractory compounds by the method of granulating fine starting powders with a binder and subsequent sintering. Several physical and technological properties of spheroidized powders of refractory compounds were investigated.     

Corrosion of Refractory Alloys in Molten Lithium and Lithium Chloride

Several refractory materials have been considered over the years as containment material for lithium and lithium halides. Surface modified refractory metals are being extensively investigated for containment of reactive metals, radionuclides and their compounds. An overview of experimental observations and results of liquid lithium corrosion of selected engineering refractory materials are presented. The nature of the degradation and its mechanism has been explained. The influence of temperature, microstructure, stress, impurities and service time on the corrosion behavior for various refractory alloys have been discussed. Selection rules for materials of containment for liquid lithium and lithium compounds have been suggested. Recent experimental observations on the behavior of tantalum and niobium-based refractory metal alloys in a specific molten salt environment comprising LiCl/Li₂O/Li/Li₃N at 725°C have been included in an effort to select suitable materials for molten salt equipment. It has been observed that oxygen contamination is particularly harmful for the refractory metal alloys where as nitrogen is deleterious to iron-based alloys.     

The Role of Refractory Metals in the Development of Structural Intermetallic Compounds

The role of refractory metals in high temperature applications is discussed in the context of structural intermetallic compounds. The use of refractory metals in the elemental form as well as its use as alloying additions is first discussed. A catalogue of refractory metal based structural intermetallics is then itemised. Two examples, a niobium-based structural intermetallic compound and the role of the refractory metal W in improving the thermal stability of TiAl-based intermetallics are then discussed.     

Computerized System for the Sintering of Nanoceramics at High Pressures

A computerized system of apparatuses for the sintering at high pressure of nanoceramics based on refractory compounds was developed. It allows for carrying out the sintering process according to a given program with rapid and accurate regulation of the P-T parameters. Information on the sintering process is stored in an internal data base with the possibility of export. The system can also be used as part of a shop local computing network. The properties of nanoceramics based on various refractory compounds produced with use of the system is given.     

The Role of Refractory Metals in the Development of Structural Intermetallic Compounds

Abstract

The role of refractory metals in high temperature applications is discussed in the context of structural intermetallic compounds. The use of refractory metals in the elemental form as well as its use as alloying additions is first discussed. A catalogue of refractory metal based structural interrnetallics is then itemised. Two examples, a niobium-based structural intermetallic compound and the role of the refractory metal W in improving the thermal stability of TiAI-based interrnetallics are then discussed.     

钢水温度和碳对镁铝尖晶石质耐火材料侵蚀的影响

根据热力学分析和热态实验研究了钢水温度及其碳质量分数对镁铝尖晶石质耐火材料侵蚀的影响，并探讨了耐火材料的侵蚀机理。研究表明，提高温度将加剧钢水对耐火材料的侵蚀，随钢水中碳质量分数的增加，耐火材料的侵蚀指数先增加后减小。侵蚀机理包括：一是钢水中碳与耐火材料组分氧化镁反应化学侵蚀耐火材料；二是钢水向耐火材料内部的渗入以及低熔点物相在耐火材料颗粒界面的析出，降低了耐火材料颗粒间的结合力，加剧了钢水冲刷对耐火材料的损毁程度。