包裹型缓／控释肥对冬小麦产量、土壤无机氮和氮肥利用效率的影响

采用超大区田间试验,以不施氮、传统氯素管理方式和优化氮素管理方式为对照,研究冬小麦施用包裹型缓／控释肥（包裹肥料）对产量、土壤无机氮和氮肥利用效率的影响,并对冬小麦施用包裹型缓／控释肥效果进行评价,结果表明：与传统氮素管理方式相比,优化氮素管理方式和包裹肥料处理在分别节省了78％和67％的氮肥的条件下,获得了和传统氮素管理方式相似的冬小麦子粒产量;采用氮素优化管理模式和施用包裹肥料显著降低了土壤无机氮残留和氮素表观损失,从而显著提高了氮肥利用率;与优化氮素管理方式相比,施用包裹肥料可一次性基施,省时省力,提高了经济效益。     

Comparative response of bread and durum wheat cultivars to nitrogen fertilizer in a rainfed Mediterranean environment: soil nitrate and N uptake and efficiency

A 3-year multi-site study was carried out on rainfed Vertisols under Mediterranean conditions in southern Europe to determine the influence of the N fertilizer rate on soil nitrates, N uptake and N use efficiency in bread wheat (Triticum aestivum L.) and durum wheat (Triticum turgidum L. var. Durum Desf.) in rotation with sunflower (Heliathus annuus L.). Nitrogen fertilizer rates were 0, 100, 150 and 200 kg N ha⁻¹ applied in equal proportions at sowing, tillering and stem elongation. The experiment was designed as a randomized complete block with a split plot arrangement and four replications. Nitrogen harvest index (NHI), N uptake/grain yield (NUp/GY), N use efficiency (NUE), N utilization efficiency (NUtE), N uptake efficiency (NUpE) and N apparent recovery fraction (NRF) were calculated. Differences were observed in N use efficiency between the two modern bread wheat and durum wheat cultivars studied. In comparison to durum, bread wheat displayed greater N accumulation capacity and a more efficient use of N for grain production. While under N-limiting conditions, the behavior was similar for both wheat types. No difference was noted between wheat types with regard to changes in soil residual levels over the study period at the various sites. The 100-kg ha⁻¹ N fertilizer rate kept soil nitrates stable at a moderate level in plots where both wheat types were sown.     

Nitrogen use efficiency by maize as affected by a mucuna short fallow and P application in the coastal savanna of West Africa

Maize is the primary food crop grown by farmers in the coastal savanna region of Togo and Benin on degraded (rhodic ferralsols), low in soil K-supplying capacity, and non-degraded (plinthic acrisols) soils. Agronomic trials were conducted during 1999–2002 in southern Togo on both soil types to investigate the impact of N and P fertilization and the introduction of a mucuna short fallow (MSF) on yield, indigenous N supply of the soil, N recovery fraction and internal efficiency of maize. In all plots, an annual basal dose of 100 kg K ha^–1 was applied to the maize crop. Maize and mucuna crop residues were incorporated into the soil during land preparation. Treatment yields were primarily below 80% of CERES-MAIZE simulated weather-defined maize yield potentials, indicating that nutrients were more limiting than weather conditions. On degraded soil (DS), maize yields increased from 0.4 t ha^–1 to 2.8 t ha^–1 from 1999 to 2001, without N or P application, in the absence of MSF, with annual K application and incorporation of maize crop residues. Application of N and P mineral fertilizer resulted in yield gains of 1–1.5 t ha^–1. With MSF, additional yield gains of between 0.5 and 1.0 t ha^–1 were obtained at low N application rates. N supply of the soil increased from 10 to 42 kg ha^–1 from 1999 to 2001 and to 58 kg N ha^–1 with MSF. Application of P resulted in significant improvements in N recovery fraction, and greatest gains were obtained with MSF and P application. MSF did not significantly affect internal N efficiency, which averaged 45 kg grain (kg N uptake)^–1. On non-degraded soils (NDS) and without N or P application, in the absence of MSF, maize yields were about 3 t ha^–1 from 1999 to 2001, with N supply of the soil ranging from 55 to 110 kg N ha^–1. Application of 40 kg P ha^–1 alone resulted in significant maize yield gains of between 1.0 (1999) and 1.5 (2001) t ha^–1. Inclusion of MSF did not significantly improve maize yields and even reduced N recovery fraction as determined in the third cropping year (2001). Results illustrate the importance of site-specific integrated soil fertility management recommendations for the southern regions of Togo and Benin that consider indigenous soil nutrient-supplying capacity and yield potential. On DS, the main nutrients limiting maize growth were N and probably K. On NDS, nutrients limiting growth were mainly N and P. Even on DS rapid gains in productivity can be obtained, with MSF serving as a means to allow farmers with limited financial means to restore the fertility of such soils. MSF cannot be recommended on relatively fertile NDS.     

黄河流域产粮地区推广粮食干燥机的前景分析

黄河流域是我国主要粮食产区，但农业机械化水平很低，粮食干燥机械化水平更低。结合目前该地区的农业生产条件，对比分析了影响黄河流域粮食干燥机发展的主要原因。对几种实现粮食干燥机械化的模式进行了比较，并研讨了实现这几种模式的操作方法。回顾了我国近年来的农业政策，并展望了未来的农业政策。虽然目前的粮食干燥机械化程度不蓉乐观，但在国家政策的支持下，各级政府的努力下，在不远的将来实现粮食干燥机械化的目标是不容质疑的，但需要投资，需要做大量的宣传、引导工作。     

Characteristics of the fate and efficiency of nitrogen in supergranules of urea

Using¹⁵ N tracer technique, the fate and efficiency of nitrogen in supergranules of urea as compared with that in powdered urea were studied in rice fields. The results obtained show that supergranules of urea were characterized by the slight N loss and high N recovery as well as by delayed but long lasting fertilization effects. It follows that the supergranules should be applied earlier and at a lower rate as compared with powdered urea.     

Quantifying the effect of soil organic matter on indigenous soil N supply and wheat productivity in semiarid sub-tropical India

A field experiment was conducted on a loamy sand soil for six years to quantify the effect of soil organic matter on indigenous soil N supply and productivity of irrigated wheat in semiarid sub-tropical India. The experiment was conducted by applying different combinations of fertilizer N (0–180 kg N ha⁻¹), P (0–39 kg P ha⁻¹) and K (0–60 kg K ha⁻¹) to wheat each year. For the data pooled over years, fertilizer N together with soil organic carbon (SOC) and their interaction accounted for 75% variation in wheat yield. The amount of fertilizer N required to attain a yield goal decreased as the SOC concentration increased indicating enhanced indigenous soil N supply with an increase in SOC concentration. Besides SOC concentration, the soil N supply also depended on yield goal. For a yield goal of 4 tons ha⁻¹, each ton of SOC in the 15 cm plough layer contributed 4.75 kg N ha⁻¹ towards indigenous soil N supply. An increase in the soil N supply with increase in SOC resulted in enhanced wheat productivity. The contribution of 1 ton SOC ha⁻¹ to wheat productivity ranged from 15 to 33 kg ha⁻¹ across SOC concentration ranging from 3 to 9 g kg^-1 soil. The wheat productivity per ton of organic carbon declined curvilinearly as the native SOC concentration increased. The change in wheat productivity with SOC concentration shows that the effect of additional C sequestration on wheat productivity will depend on the existing SOC concentration, being higher in low SOC soils. Therefore, it will be more beneficial to sequester C in soils with low SOC than with relatively greater SOC concentration. In situations where the availability of organic resources for recycling is limited, their application may be preferred in soils with low SOC concentration. The results show that an increase in C sequestration will result in enhanced wheat productivity but the increase will depend on the amount of fertilizer applied and the existing fertility level of the soil.     

Effect of lime nitrogen on the efficiency of urea and other ammonium nitrogen fertilizers

Five pot experiments were conducted with wheat and rice in a net house to study the effect of lime nitrogen (LN, contains about 55% calcium cyanamide) amendment rates on the efficiency of urea, the recovery urea-¹⁵N, the efficiency of the three nitrogen fertilizers(NF), on the efficiency of urea in the three soils, and on NO ₃ ^- -N leaching from a flooded soil. A rate of LN-N of 5–8% of applied fertilizer N increased the recovery of labeled urea-N by 9.42%. The effect of LN on the efficiency of NF was urea > ammonium sulfate > ammonium chloride. Under flooded conditions, LN decreased NO ₃ ^- formation and leaching.Responses of several crops to LN amended fertilizers were also studied in field experiments. At equal NPK applications, the efficiency of basal applications to rice, wheat, corn, potatoes, soybean, peanut, grapes, peaches, melon and watermelon were bette r with LN than without. Efficiency with a basal fertilizer for rice or wheat with LN were the same as with the same fertilizer without LN applied in split applications.     

Millet nutrient use efficiency as affected by natural soil fertility,mineral fertilizer use and rainfall in the West African Sahel

Field experiments were designed to investigate the effectiveness of integrated soil fertility management (ISFM), comparing fertilizer use efficiency and its impact on millet, cultivated close to the homestead (“infields”) and away from the homestead (“outfields”). Millet yields and response to N (0, 30, and 60 kg ha⁻¹) and P (0, 15, and 30 kg ha⁻¹) were determined on nine infields and nine outfields over a period of 3 years (from 1999 to 2001) in the southern Sahel of Niger. Rainfall was 650, 470, and 370 mm during the three successive years, interaction between decreasing rainfall and millet yield performance was also analyzed. While soil organic carbon (1.5 g kg⁻¹ on outfields and 1.6 g kg⁻¹ on infields) and pH-H₂O (4.8 on outfields and 5.1 on infields) were comparable, total-N, plant available P (measured as P-Olsen and P-Bray), and exchangeable Ca, K, and Mg levels were higher on infields as compared to outfields. Without fertilizer, average grain yield (GY) and stover yield obtained on infields were three times as high as on outfields. GY across years and fertilizer treatments was higher on infields as compared to outfields (P < 0.001). Average yield was 800 kg ha⁻¹ on outfields and 1,360 kg ha⁻¹ on infields (P < 0.001). On outfields, average GY was stagnant over the 3-year experimental period. Despite declining rainfall, millet GY across all treatments gradually increased over time on infields (P < 0.001). P fertilization alone resulted on both field types to steadily and substantial yield increases while yield response to N fertilization was only obvious when fertilizer P was applied. With no fertilizer applied, N uptake on infields (19 kg N ha⁻¹) was more than twice as high as on outfields (7 kg ha⁻¹), and P uptake was four times higher on infields (3 kg ha⁻¹) than on outfields (0.8 kg ha⁻¹). Indigenous soil N supply was on average 24 kg N ha⁻¹ on outfields and 46 kg N ha⁻¹ on infields. Average value for indigenous soil P supply was 4 kg P ha⁻¹ on infields and 2 kg ha⁻¹ on outfields. Apparent recovery of fertilizer N applied varied considerably among treatments and ranged from 17 to 23% on outfields and 34 to 37% on infields (P < 0.001). Average apparent recovery of fertilizer P applied was significantly higher (P < 0.001) on infields (31%) than on outfields (18%) over the 3-year growing period, illustrating ISFM-induced positive effect on millet nutrient N and P use. Results indicate higher inherent soil fertility, underline ISFM-induced drought tolerance of soils on infields as compared to outfields, and highlight the crucial role of fertilizer P (especially on outfields) for millet production. These call for site-specific nutrient management and support, even under low rainfall conditions, the potential value of fertile infields for efficient and productive external input use and sustainable millet production in West African Sahel.     

Evaluation of compacted urea fertilizers prepared with acid and non-acid producing chemical additives in three soils varying in pH and cation exchange capacity; II. Yield and N use efficiency by rice

With a view to evaluate the effect of different chemical additives on the efficacy of urea, a green house study was conducted with wet season rice (Oryza sativa L.) as test crop. The results showed that compaction of phosphogypsum (PG), diammonium phosphate (DAP), ZnSO₄, NH₄Cl or KCl with urea increased the rice yield and N use efficiency as compared to that obtained with straight urea. A significant positive correlation between potential N loss (measured by soluble N in floodwater) and NH₃ volatilization (measured by forced air draft system) was observed. The results clearly indicate that N use efficiency can be increased through suitable modification of urea by compacting it with acid and non-acid producing fertilizers such as NH₄Cl, KCl, ZnSO₄ and DAP or industrial byproduct like phosphogypsum.     

Initial and residual effects of nitrogen fertilizers on grain yield of a maize/bean intercrop grown on a Humic Nitosol and the fate and efficiency of the applied nitrogen

Initial and residual effects of nitrogen (N) fertilizers on grain yield of a maize/bean intercrop grown on a deep, well-drained Humic Nitosol (66% clay, 3% organic carbon) were evaluated. Enriched (¹⁵N) N fertilizer was used to study the fate of applied N in two seasons: using urea (banded) at 50 kg N ha^–1 in one season, and¹⁵N-enriched urea (banded), calcium ammonium nitrate (CAN, banded), and urea supergranules (USG, point placement) were applied in the other season (different field) at 100 kg N ha^–1. Nitrogen fertilizer significantly (P = 0.05) increased equivalent maize grain yield in each season of application with no significant differences between N sources, i.e., urea, CAN, and USG. Profitmaximizing rates ranged from 75 to 97 kg N ha^–1 and value: cost ratios ranged from 3.0 to 4.8. Urea gave the highest value: cost ratio in each season. Most (lowest measurement 81%) of the applied N was accounted for by analyzing the soil (to 150 cm depth) and plant material. Measurements for urea, CAN, and USG were not significantly different. The high N measurements suggest low losses of applied N fertilizer under the conditions of the study. Maize plant recovery ranged from 35 to 55%; most of this N (51–65%) was in the grain. Bean plant recovery ranged from 8 to 20%. About 34–43% of the applied N fertilizer remained in the soil, and most of it (about 70%) was within the top soil layer (0–30 cm). However, there were no significant equivalent maize grain increases in seasons following N application indicating no beneficial residual effect of the applied fertilizers.     

N fertilisation,soil type and cultivars effects on N use efficiency in tef [<Emphasis Type="Italic">Eragrostis tef (Zucc.) Trotte</Emphasis>]

Tef [Eragrostis tef (Zucc.) Trotte] is a major staple crop in Ethiopia and a large proportion of the imported fertiliser is being applied to tef fields. However, since the 1980s the yield on farmers fields has stagnated. Response of the crop to applied fertiliser is influenced by several factors. We aimed to study the fertiliser N use efficiency (FNUE) of four tef varieties from ammonium sulphate and urea on different soil types with the help of the ¹⁵N isotopic dilution technique. Three experiments were conducted under greenhouse and field conditions. On a typic Eutrocrept soil, higher percent N derived from fertiliser (% Ndff) and % FNUE were obtained for all the tested tef varieties when the N source was urea, while percent N derived from soil (% Ndfs) was higher for ammonium sulphate. The mean % FNUE for urea and ammonium sulphate was 49 and 34%, respectively. When the varieties were grown on a Nitosol or a Vertisol and ammonium sulphate was applied, the % Ndff, the total and fertiliser N yield and % FNUE of the tef varieties were higher on a eutric Nitosol compared to the Vertisol. The mean % FNUE was 61.3 for the Nitosol and 27.8 for the Vertisol. In an on farm experiment, relatively higher FNUE (33.3%) was obtained on an Andosol compared to Vertisols (17 and 27%). The tested varieties showed no difference in FNUE. As tef is the most important crop grown on Vertisols in Ethiopia, the low FNUE has a direct negative implication for the livelihood of the farmers and the environment.     

Nitrogen use efficiency of <Superscript>15</Superscript>N-labelled sheep manure and mineral fertiliser applied to microplots in long-term organic and conventional cropping systems

Nitrogen (N) utilisation by crops has to be improved to minimize losses to the environment. We investigated N use efficiency of animal manure and mineral fertiliser and fate of fertiliser N not taken up by crops in a conventional (CONMIN) and a bio-organic (BIOORG) cropping system of a long-term field experiment over three vegetation periods (winter wheat–soybean–maize). Microplots planted with wheat received a single application of ¹⁵N-labelled slurries (either urine or faeces labelled) or mineral fertiliser. At the end of each vegetation period we tested whether higher microbial activity and larger microbial biomass in BIOORG than CONMIN soils, and lower long-term N input level in BIOORG, affected use efficiency and fate of fertiliser N not taken up by crops. Recovery of ¹⁵N in wheat was 37%, 10% and 47% from urine, faeces and mineral fertiliser, respectively, and decreased strongly in the residual years. In total 41%, 15% and 50% of ¹⁵N applied as urine, faeces and mineral fertiliser was recovered by the three crops. ¹⁵N recovered from originally applied urine, faeces and mineral fertiliser in the topsoil (0–18 cm) at the end of the third vegetation period was 19%, 25% and 20%, respectively. Of urine-, faeces- and mineral fertiliser-¹⁵N, 40%, 61% and 29%, respectively, was not recovered by the three crops and in topsoil suggesting significant transport of ¹⁵N-labelled components to deeper soil layers. CONMIN and BIOORG differed neither in fertiliser N use efficiency by crops nor in ¹⁵N recovery in soil indicating insignificant difference in the turnover and utilization of the applied manure nitrogen in the conventional and the bio-organic cropping systems.     

Using mucuna and P fertilizer to increase maize grain yield and N fertilizer use efficiency in the coastal savanna of Togo

To reduce severe soil degradation associated with agriculture an intensified land-use system is being promoted in West African countries. Most soils of the West African savanna zones are so poor that the efficiency of mineral fertilizers, if applied, is very low. For this reason and because of their high cost and unavailability, many small-scale farmers are reluctant to apply fertilizer. This work investigates a fertilizer management strategy using integrated soil fertility management with a leguminous cover crop (mucuna) so as to improve the soil fertility and increase the use efficiency of fertilizer. The experiment was conducted in the coastal savanna of Togo at Djaka Kopé. The aim was to evaluate the effectiveness of mucuna short fallow (MSF) in increasing maize grain yield through an improved use efficiency of mineral fertilizer. A 2-year maize–mucuna relay intercropping system was compared with continuous sole maize cropping. Fertilizer treatments were factorial combinations of 0, 50 and 100 kg nitrogen (N) ha^–1 and 0, 20 and 40 kg phosphorus (P) ha^–1. While maize grain yield was significantly increased by N fertilization, P did not show any important effect on grain yield. With no N and P applied, grain yield after MSF was on average 40% (572 kg ha^–1) higher than without. The response to N was much greater than the response to MSF, indicating that N was undoubtedly the key element for maize yield building. P fertilization and MSF together positively influenced the apparent N recovery fraction (NRF). N uptake alone did not reflect on its own the yield obtained, and the relationship between grain yield and N uptake is shifted by MSF, with the grain yield increase per unit of N uptake being higher with than without MSF. Combining MSF and P fertilization may therefore lead to improved N use efficiency, making the application of fertilizer N (lower rates) more attractive to small-scale farmers.     

Processes during the Hypergolic Ignition between Monomethylhydrazine (MMH) and Dinitrogen Tetroxide (N2O4) in Rocket Engines

Two potential sources for engine complications with methylhydrazine/nitrogen tetroxide rocket engines were examined. The products formed during a cold pre‐reaction before the actual ignition of the rocket engine and their later behavior were investigated with Car‐Parrinello molecular dynamics simulations. It was found that methyldiazene is the main product of the cold pre‐reaction. As a side product, especially in the presence of an excess of methylhydrazine, dimethyltetrazanes are formed. These may be responsible for violent side reactions.     

长江下游原水臭氧-生物活性炭深度处理效果及有机物特性变化

以长江下游镇江征润洲段为原水,利用中试装置研究臭氧-生物活性炭(O3-BAC)组合工艺优化运行及其对有机物特性变化的影响。结果表明:当调整主臭氧投加量为2.5 mg/L时,深度处理工艺对CODMn、NH4^+-N和两类消毒副产物前体物(TTHMFP、THAAFP)的去除率分别为68.5%、86.7%、57.3%和48.9%;同时,从净水过程中有机物特性变化对消毒副产物影响的角度,提出应将强疏水性小分子有机物作为镇江市饮用水处理的控制主体。     

Association between Changes in the Patterns of Antinuclear Autoantibodies during Immune Checkpoint Inhibition Therapy and the Development of Severe Immune Related Adverse Events

Immune-related adverse events (irAEs) are unpredictable autoimmune-like toxicities induced by immune checkpoint inhibitors (ICI). irAEs are a consequence of a breakdown in self-tolerance. ICIs can induce autoantibody formation, and the presence of antinuclear autoantibodies (ANAs) has been reported in patients who developed irAEs. Our goal was to compare ANA patterns by indirect immunofluorescence at different timepoints before (baseline) and after the initiation of ICI treatment and to analyze the role of ANA pattern changes as predictors of irAEs. This is a 2-year-follow-up prospective study of 152 consecutive patients with solid tumors treated with anti-PD-(L)1 blockade agents. They were included from September 2018 until March 2020 in the Hospital de la Santa Creu I Sant Pau (Barcelona, Spain). We grouped patients into three groups: ANA de novo (patients who showed new ANA patterns at any time after ICI initiation), ANA (ANA positive at baseline without changes in the ANA patterns after initiation of treatment) and non-ANA (ANA negative at baseline and after ICI initiation). We did not find any association between the appearance of ANAs and irAE rates or the number and types of irAEs. However, patients in the ANA de novo group showed higher severe irAE rates (grade ≥ 3) than the other groups. Additionally, in most of the patients with severe irAEs (83.3%), changes in ANA patterns preceded irAE onset. In conclusion, we found ANA induction during ICI therapies in 22 patients and our results suggest that the appearance of ANAs may predict the severity of the irAE.