连续碳纤维增强尼龙复合材料的研究

研究了碳纤维对CCF／MCPA力学性能的影响以及CCF／MCPA的摩擦学性能和磨损机制。结果表明，CCF／MCPA的弯曲强度，弯曲弹性模量，冲击强度和平面剪切强度随碳纤维含量的增加而提高；CCF／MCPA的摩擦数和磨损量随着载荷的增加而降低。其磨损机制主要是磨粒磨损和粘着磨损特征。     

碳纤维/环氧树脂复合材料摩擦性能研究

采用液相氧化法合成氧化碳纤维,制备碳纤维/环氧树脂复合材料,研究了复合材料的力学性能和摩擦性能。结果表明,碳纤维经液相氧化后,复合材料的力学强度有所降低,但模量均有明显提高;碳纤维和氧化碳纤维能改善环氧树脂复合材料的摩擦性能,降低摩擦系数和减少磨损率,提高复合材料的耐磨性;复合材料的摩擦系数和磨损率均随着载荷和时间的增加而增大。由材料磨损表面的扫描电镜可知碳纤维/环氧树脂复合材料以磨粒磨损与粘着磨损为主,氧化碳纤维/环氧树脂复合材料以疲劳磨损和磨粒磨损为主。碳纤维和氧化碳纤维可以作为环氧基摩擦材料的增强材料,这一研究对于拓宽摩擦材料领域的研究发展具有重要意义和促进作用。     

RTM工艺制备碳纤维复合材料的力学性能

本文选用树脂传递模塑成型(RTM)工艺制备(3K-T300,3312)碳纤维/环氧树脂复合材料,分别采用拉伸实验和弯曲实验研究复合材料的力学性能;并对样件的拉伸断口进行SEM观察,分析其失效形式。结果表明:碳纤维/环氧树脂复合材料的拉伸强度和弯曲强度分别为459.17MPa和576.82MPa;断口微观形貌表明环氧树脂充分浸润到碳纤维编织布层状界面和丝束之间的界面中,断口中碳纤维和环氧树脂脆性断裂以及碳纤维与环氧树脂界面裂纹萌生扩展并断裂是试样失效的机制,说明RTM具有较好的工艺应用性。     

Si的质量分数对C/C-SiC摩擦材料摩擦磨损性能的影响

以PAN基碳纤维针刺整体毡为预制体,经化学气相渗透法制得C/C多孔坯体,采用反应熔体浸渗法制备了C/C-Si C摩擦材料。用XD-MSM型定速摩擦试验机测定摩擦磨损性能,研究了不同Si含量对C/C-Si C摩擦材料摩擦磨损性能的影响。利用VK-X200三维激光扫描显微镜观察了摩擦材料磨损后表面的微观形貌并探讨其磨损机制。结果表明:随着Si质量分数的增加,摩擦材料的硬度和冲击强度逐渐增大,开孔率逐渐降低,摩擦材料的磨损形式由单一的磨粒磨损转变为磨粒磨损和黏着磨损的混合磨损机制。3种摩擦材料中,Si质量分数为28.42%的C/C-Si C摩擦材料物理和力学性能均较好,摩擦系数较大,磨损率较小,摩擦磨损性能较好。 更多还原     

混合纤维对尼龙66的增刚研究

以尼龙66（PA66）为基体,研究和分析玻璃纤维和碳纤维混杂对尼龙66增刚的影响.固定玻璃纤维质量分数为24.6%,改变碳纤维的质量分数,将玻璃纤维（GF）、碳纤维（CF）先用硅烷偶联剂KH550进行表面处理,用双螺杆挤出造粒和注塑成型方式制备GF/CF增刚PA66复合材料,对试样进行拉伸模量、拉伸强度、弯曲模量、弯曲强度、缺口冲击强度等性能测试,并利用扫描电镜分析复合体系的冲击断面特征.研究结果表明：GF/CF混合纤维对PA66具有很好的增刚效果.     

碳纤维/环氧复合材料弯曲模量影响因素的研究

就环氧树脂固化条件、碳纤维体积比、加载环境温度对碳纤维 /环氧复合材料弯曲模量的影响作了系统研究 .试验结果表明 ,弯曲模量与碳纤维的体积比基本上呈线性关系 ,充分固化有利于提高碳纤维/环氧复合材料弯曲模量的稳定性 .     

温湿场交变环境下外加载荷对不同孔隙率CFRP弯曲力学性能影响

为探究不同孔隙率碳纤维/环氧树脂层合板在仿超音速飞行的高低温湿热老化环境及外加载荷作用对弯曲力学性能的影响规律,基于材料服役期间的吸湿状态和内应力状态,对T700CF/3234EP进行模拟超音速飞机服役环境的高低温交变加速湿热循环试验.通过控制模压压力,制备3种孔隙率分别为0.04、0.08和0.11的层合板,将3种孔隙率的层合板进行加载,加载载荷为层合板最大弯曲载荷的0、30%、40%和60%,然后将其置于高低温环境模拟试验箱中,分别测量不同循环周期复合材料层合板的弯曲强度变化,并采用ABAQUS软件对其弯曲力学性能进行有限元模拟.试验结果表明:温湿场交变环境下,外加载荷和孔隙率加速层合板弯曲强度的下降,在高低温湿热循环4~6周期时,随着载荷的增大,二次固化现象越明显,层合板的弯曲强度变化比较平缓.使用ABAQUS软件建立有限元模型,计算得到的弯曲力学强度变化趋势与试验结果相一致,说明高低温湿热老化环境和外加载荷对复合材料弯曲性能的影响,对不同孔隙率的碳纤维/环氧树脂层合板弯曲性能进行较为准确的预测.     

基于纤维包覆法制备碳纤维增强热塑性复合材料

采用热塑性长丝包覆碳纤维束和热压法制备单向碳纤维增强复合材料,测试了试样的拉伸和冲击性能,研究了长丝包覆在树脂浸润过程中缩短流程的作用。同时,采用了多向包覆法制备了聚酯/芳纶长丝包覆碳纤维束并得到单向碳纤维增强复合材料,包覆芳纶进一步提高了热塑性复合材料的力学性能,结果表明:和碳纤维增强聚酯复合材料相比,芳纶/碳纤维增强聚酯复合材料拉伸强度增加了22.8%和49.5%,冲击强度增加了65.8%和45.6%。     

玄武岩短纤维增强环氧树脂复合材料的研究

以环氧树脂为基体、玄武岩短纤维为增强材料,制备了玄武岩短纤维/环氧树脂复合材料.研究了不同玄武岩短纤维含量对复合材料拉伸强度和耐磨性能的影响,采用扫描电子显微镜（SEM）观察了复合材料的断面形貌和磨损表面形貌,分析了磨损机制.结果表明,玄武岩短纤维/环氧树脂复合材料的抗拉强度和耐磨性能与纯环氧树脂相比均有不同程度的改善和提高,当玄武岩短纤维的含量为8%时,复合材料的拉伸强度最大;当玄武岩短纤维的含量为6%时,磨损率最低.随着玄武岩短纤维含量的增加,复合材料的磨损机制由黏着磨损向磨粒磨损转化.     

纤维切削角对CFRP加工缺陷的影响规律

为研究碳纤维增强复合材料(CFRP)在加工中出现毛刺、崩边等缺陷,提出基于纤维切削角的碳纤维每齿切削长度计算方法,分析毛刺缺陷的形成机制和发展规律.计算结果和验证试验表明:纤维切削角决定碳纤维每齿切削长度和受到作用的切削刃总数,随着纤维切削角增大,碳纤维每齿切削长度增大,而受到切削刃的作用频率降低.产生毛刺的主要原因是碳纤维实际弯曲半径大于理论最小弯曲半径,碳纤维仅仅发生弯曲并没有断裂.当纤维切削角在0°~90°时,缺陷形式为崩边;当纤维切削角在90°~180°时,出现毛刺缺陷,且毛刺长度随纤维切削角的增大而不断增大.     

碳纤维对增强的摩阻材料的摩擦磨损特性的影响

利用Ｄ－ＭＳ摩擦磨损试验机，用自制的碳纤维增强摩阻材料中碳纤维含量、表面状态、强度和长度对摩擦磨损性能的影响进行了试验研究。     

Influence of surface state on moisture sensitivity of carbon fiber and its composite interfacial properties

The influence of surface state on the moisture sensitivity of carbon fiber was analyzed by applying a T800 grade carbon fiber with five different surface conditions, namely, with and without surface oxidation, in the presence or absence of sizing agent. The interfacial properties of their composites in the presence of two epoxy matrices (respectively EP07 and EP10) were also characterized by micro-droplet tests. The overall results show that both oxidized and sizing-coated fibers have higher moisture equilibrium content than that of the pristine unsurface-treated fiber, due to higher amount of activated carbon groups. After moisture absorption of the carbon fibers, almost all the fiber/epoxy systems show decrease in the interfacial shear strength and the unsurface-treated fiber system exhibits the largest decline. Moreover, both interfacial shear strength and interlaminar shear strength of carbon fiber/EP10 composite demonstrate better water resistance performance than that of the carbon fiber/EP07 composite, consistent with DSC results of the two resins.     

填充聚四氟乙烯的某些性能研究

对9种成分的填充聚四氟乙烯进行了机械性能和热性能的测试。结果表明:与纯聚四氟乙烯相比,填充聚四氟乙烯的抗压、抗弯强度和硬度增高;抗拉强度、断裂伸长率和线膨胀系数则降低;摩擦磨损性能明显改善.填充聚四氟乙烯的性能改变与填充剂的成分配比及其结晶度有关。X射线结晶度的测量结果表明,填充聚四氟乙烯的结晶度亦随填充剂的結晶性质不同而变化.     

Effect of Carbon Nanotube on the Oscillating Wear Behaviour of Metal-PTFE Multilayer Composites

Two kinds of metal-PTFE multilayer composites, which were composed of a steel backing, a middle layer of sintered porous bronze and a surface layer of polytetrafluoroethylene(PTFE) filled by carbon nanotubes(CNTs) or not, were prepared. The wear properties of metal-PTFE multilayer composites oscillating against 45 carbon steel under dry condition were evaluated on an oscillating wear tester, and the effect of CNTs on wear behaviour of metal-PTFE multilayer composites was studied. The results showed that the worn surface of metal-PTFE multilayer composites was characterized by adhesive wear, abrasive wear and fatigue wear. The CNTs greatly increased the adhesion strength of PTFE in the metal-PTFE composites and thereby greatly reduced puck, ploughing, and fatigue failure of PTFE during wearing. The PTFE filled with CNTs prevented direct contact between the mating surfaces and served as fine self-lubricating film, in which the oscillating wear mechanism of the composites was changed to a slightly adhesive wear. Therefore, the CNTs significantly decreased the weight loss and obviously increased the wear resistance of metal-PTFE multilayer composites.     

Preparation and properties of C/C-SiC brake composites fabricated by warm compacted-in situ reaction

Carbon fibre reinforced carbon and silicon carbide dual matrix composites(C/C-SiC) were fabricated by the warm compacted-in situ reaction.The microstructure,mechanical properties,tribological properties,and wear mechanism of C/C-SiC composites at different brake speeds were investigated.The results indicate that the composites are composed of 58wt%C,37wt%SiC,and 5wt%Si.The density and open porosity are 2.0 g.cm~(-3) and 10%,respectively.The C/C-SiC brake composites exhibit good mechanical properties.The ...     

固化剂用量对SF/UF共混复合材料力学性能的影响

剑麻纤维(SF)经碱处理后与自制的低毒改性脲醛树脂(UF)、固化剂等原料进行捏合、模压成型,制成SF/UF共混复合材料,研究了不同固化剂用量对复合材料力学性能的影响:并用DSC对树脂进行了固化分析,采用扫描电镜(SEM)对材料的微观形貌进行了观察.结果表明,固化剂用量对复合材料的力学性能有较大影响:用量为1.0%时,复合材料的冲击强度达到12.39 kJ/m2,磨损体积仅为1.47×10 mm3,弯曲强度达到了55.24 MPa.     

丙烯酸在碳纤维表面的电聚合改性

为了提高碳纤维与树脂基体之间的粘结性能,采用循环伏安法,以丙烯酸为聚合单体对碳纤维进行了电聚合改性.利用傅里叶红外光谱仪和扫描电子显微镜研究了改性前后碳纤维表面的结构变化,并利用电脑伺服控制材料试验机对复合材料进行了力学性能测试.结果表明:当丙烯酸浓度为0.3 mol/L、循环次数为10次时,碳纤维的改性效果最佳;改性后的碳纤维在红外光谱的2 680 cm-1附近出现了—OH特征吸收峰;复合材料的层间剪切强度由10.50 MPa增加到了23.44 MPa,提高了123.21%;改性后碳纤维表面出现了圆片状丙烯酸聚合物层,且可与环氧树脂基体紧密结合.     

High temperature behaviors of high velocity arc sprayed Fe-Al/Cr3C2 composite coatings

Fe-Al/Cr3C2 composite coatings were manufactured using high velocity arc spraying （HVAS） technology. The high temperature erosion, wear and corrosion resistance of the coatings were investigated. The coating properties such as bonding strength, porosity, hardness as well as microstructures were characterized. The results show that the coatings have relatively high heat tremble bond strength, hardness, and typical layer-shaped coatings＇ microstructures. With the rise of temperature, the coating erosion resistance increases too; the impingement angel does effects on erosion properties, and the erosion mechanism changes from ductile to brittle behaviors at 450℃. The coatings have good room temperature wear resistance and relatively good high temperature resistance. The wear mechanism of the coatings is peeling wear behavior. The coatings have excellent high temperature corrosion resistance because of the produce of oxides during corrosion.     

填料特性对尼龙摩擦学性能的影响及作用机理

在尼龙１０１０（ＰＡ１０１０）中分别添加颗粒状、层状、纤维状填料,制备出系尼龙基复合材料,利用环块磨损实验机研究了填料的形态,性质对尼龙基复合材料干摩擦条件下摩擦学性能的影响。结果表明,当填料的质量分数为３０％时,玻璃纤维、高岭土、铝粉、二氧化硅以及氧化铜均能改善ＰＡ１０１０的摩擦学性能,其中以玻璃纤维（ＧＦ）最为显著,层状结构的高岭土也有较好的效果,其他３种各向同性填料的改性效果差别较小,利用高倍显微镜对尼龙及其复合材料的转移行为,磨损机理以及填料减磨机理进行了研究,分析表明,填料的加匀不同程度的促进了复合材料向对介副表面的转移、改善了材料的摩擦学性能,而各种填料的减磨机理也不一样,尼龙基复合材料的磨损形式以粘着磨损,疲劳磨损为主,此外还有磨粒磨损,在给定实验条件下,ＰＡ１０１０复合材料含有质量分数为３０％的