Mixing characteristics of binary mixtures in a spout-fluid bed

Mixing characteristics of binary mixtures in a flat-bottom cylindrical spout-fluid bed using glass beads and air are reported in this work. Experiments were carried out to investigate the mixing characteristics for binary mixtures at three flow conditions, i.e., only spouting, only fluidization and spout-fluidization. The experiments were performed at different gas velocities, diameter ratios of binary mixtures and three different bed arrangements. Mixing index was determined for fluidized bed and static bed conditions. It was found that, in all cases, lowest-diameter ratio mixture gave good mixing index values. For all flow conditions, mixing index for large–small bed arrangement was increasing with time, whereas for small–large bed arrangement, the mixing index deteriorated with time. However, in both cases, the mixing index reached almost a constant value. For well-mixed bed arrangement and spout-fluidization flow condition, segregation and re-mixing were observed.     

Study on the flow behavior of irregular plastic particles in a spout-fluid bed with a draft tube

This work presents an experimental investigation on the hydrodynamic performance of a draft tube spout-fluid bed with irregular particles. Nonmetal particles from waste printed circuit boards (NPCBs) were used as a spouting solid, and polypropylene (PP) particles were selected as an assistant to fluidization particles. The flow pattern, minimum spouting velocity (U_ms), and minimum spout-fluidization velocity (U_msf) were investigated under different operating conditions. The irregular cohesive particles from NPCBs showed poor flowability and channeling, which restrained stable spouting in the spout-fluid bed. The quality of fluidization and spouting improved when greater than 40?wt.% PP particles were added into the NPCB/PP mixtures. The mechanism was that the PP particles accelerated the movement of NPCB particles. Meanwhile, lower density differences between NPCB and PP particles decreased the segregation of the mixtures. The minimum spouting velocity decreased with an increase in fluidization gas velocity and the ratio of NPCB particle in the NPCB/PP mixtures. Two flow patterns, unstable spouting and unstable spouting fluidization, were observed over a large range of gas velocity. The ranges of gas velocity in these two flow patterns enlarged with the increase in mass fraction of NPCB particles within the NPCB/PP mixtures.     

Fluidization behavior of binary mixtures of nanoparticles in vibro-fluidized bed

The fluidization behavior of different mixed SiO₂, TiO₂ and/or ZnO nanoparticles under the application of vibrated fields of constant vibrated frequencies (40 Hz) and amplitude (3.0 mm) is studied. The single nanoparticles experiments show that SiO₂ nanoparticles have a better fluidization quality than TiO₂ and ZnO nanoparticles. For binary mixtures of the nanoparticles, the amount of SiO₂ nanoparticles generally has a beneficial effect on the fluidization quality of the binary mixtures. Using the linear regression, the Richardson–Zaki exponents of three kinds single and their binary mixture of nanoparticles are calculated. The Richardson–Zaki analyses indicate that the particulate fluidization degree of mixed nanoparticles can be greatly improved in agglomerate particulate fluidization (APF) behavior.     

A study of gas and solid mixing behaviors in a three partitioned fluidized bed

A previously unknown partitioned fluidized bed gasifier (PtFBG) has been developed for improving coal gasification performance. The basic concept of the PtFBG is a fluidized bed divided into two parts, a gasifier and a combustor, by a partitioned wall. Char is burnt in the combustor and the generated heat is supplied to the gasifier along with the bed materials. During that time, highly concentrated CO₂ is inevitably generated in the combustor. Therefore, vigorous solid mixing is an essential precondition as well as minimizing horizontal gas mixing. In this study, gas and solid mixing behaviors were verified in a cold model three partitioned fluidized bed (3-PtFB). Glass beads with an average diameter of 150 μm and a particle density of 2500 kg/m³ were used as bed materials. For the gas mixing experiments, CO₂ and N₂ were introduced into the beds through each distributor. Then, outlet gas flow rates and concentrations were measured by gas flow meters and an IR gas analyzer respectively. The calculated gas exchange ratios ranged from 3% to 10% with varying gas flow rates. For the solid mixing experiments, 1000 μm polypropylene particles with a density of 883 kg/m³ were continuously fed into the reactor. Then, the polypropylene particles were distributed to the entire beds evenly. Solid mixing behaviors were very analogous to liquid mixing behaviors in a continuous stirred tank reactor (CSTR).     

Experimental investigation on hydrodynamic behavior in a spouted bed with longitudinal vortex generators

A spouted bed with longitudinal vortex generator (LVG) of sphere was built to enhance radial movement of particles. Particle Image Velocimetry (PIV) was applied to explore effects of longitudinal vortex flow and physical properties of particles on their radial velocity in a 152-mm-diametered spouted bed. The results show that, Compared with the conventional spouted bed, the existence of longitudinal vortex generator gives rise to a large amount of secondary fine vortex flow in the cross section of spouted bed. The enhancement factors of particles movement η with different particle densities are all greater than 1. The smaller the particle density, the more significant the effect of the longitudinal vortex on the radial velocity of the particles. The single-row LVGs can produce a good radial enhancement effect of particle movement when the particle handling capacity is small (H₀ = 165 mm). With the increase of the height of the static bed (H₀), the enhancement of the radial velocity of particles in the spouted bed by multi-row LVGs (three rows) increases gradually, which indicates that the multi-row LVGs have a better overall effect on the enhancement of particle motion in the spouted bed with more particle handling capacity (H₀ = 195 mm, 225 mm).     

Hydrodynamic behavior of binary mixture of solids in a triple-bed combined circulating fluidized bed with high mass flux

Flow behaviors of binary mixture of silica sand and nylonshot (coal char substitute) were investigated in a triple-bed circulating fluidized bed (TBCFB) as a cold model of coal gasifier. The TBCFB consisted of a downer (ϕ 0.1 m × 6.5 m), a bubbling fluidized bed (0.75 m × 0.27 m × 1.9 m), a riser (ϕ 0.1 m × 16.6 m) and a gas-sealing bed (GSB, ϕ 0.158 m × 5 m). The initial fraction of the nylonshot in the solid mixture (X_nylon,i) was 15.4 and 30% on mass and volume bases, respectively, or otherwise, 30.7 and 50%. The maximum solids mass flux (G_s) at X_nylon,i of 15.4 and 30.7 wt% were 394 and 349 kg/m² s, respectively, when the gas velocity in the riser (U_gr) was 10 m/s. Apparent solids holdups of silica sand and nylonshot were calculated separately from the static pressure gradient across the riser and the downer. The results showed possibility of large-mass-flux circulation of char in the gasifier, which plays a significant role in decomposition of tar from pyrolysis as the primary step of gasification. A newly developed pressure balance model successfully predicted G_s of the binary mixtures in TBCFB.     

Bed expansion ratio of mono-sized and binary mixtures in fluidized,spouted, and spout-fluid beds

Studies on bed expansion ratio were carried out in fluidized, spouted, and spout-fluid beds. A single column has been used to compare the characteristics of fluidized, spouted, and spout-fluid beds. Experiments were carried out using air and glass beads under fluidized, spouted, and spout-fluid bed conditions separately to study the effect of gas velocity, bed mass, and particle size on bed expansion ratio. Glass beads of different sizes (0.75, 1.2, 1.7, and 3.075?mm) have been used as solid bed material. Bed expansion ratio was determined for mono-size particles and binary mixtures (different diameter ratios and composition). It was found that the bed expansion ratio decreases with increase in bed mass for only spouting condition and spout-fluidization conditions. The bed expansion ratio increases with increase in bed mass for only fluidization condition.     

Experimental study on the discharge flow rate of binary mixture in a two-dimensional silo

In this work, the discharging process of the binary mixture composed of sphere and sphere-paired particles in a two-dimensional silo was studied. High-speed camera and self-developed particle tracking velocimetry (PTV) program were used to capture the flow behaviors of all particles. The key parameters of mixed flow, including coordination number, horizontal displacement and mechanical energy loss in the discharge process, were highlighted. It was found that the increase of sphere-paired particles can decrease the average coordination number of particles during the discharging process. The analysis about the loss of mechanical energy and the horizontal displacement of particles indicated that sphere-paired particles preferentially squeezed out sphere particles from fast flow field above the outlet. Moreover, an empirical formula was proposed to assess the influence of the proportion of sphere-paired particles on the discharge flow rate. Sphere-paired particles tended to hinder the discharging process, which was caused by the rotation around their centroids and the angular deflection close to angle of the hopper.     

鼓泡床内双组分颗粒流动行为的数值模拟

为了模拟预测粒径和密度同时存在差异的双组分颗粒体系的分级混合行为,基于欧拉-欧拉方法建立多流体模型,采用颗粒动力学理论描述颗粒相性质,分别通过Gidaspow和Syamlal曳力模型描述气-固相曳力和固-固相作用力。结果表明,模拟得到的轴向和径向颗粒浓度分布与实验数据吻合较好;当在较小气流速度下出现分级行为时,床层底部富沉积组分层中沉积组分的运动十分有限,而在较大气流速度下处于完全混合状态时,床层内部颗粒运动较为剧烈。     

Prediction of thermal diffusion in binary mixtures of nonelectrolyte liquids by the use of nonequilibrium thermodynamics

A derivation based on nonequilibrium thermodynamic leads to this expression for the thermal diffusion factor, _T=M ₂(h ₂ ^xs -h ₁ ^xs )/RT ₂, where M ₂ is the molecular weight of the lighter of the two components, h ₁ ^xs is the partial excess enthalpy of component i, J/g, R is 8.314 J · K ^–1 · mol ^–1, T is temperature in K, and ₂ is the thermodynamic correction factor (1 + d ln ₂/d ln X ₂), where ₂ is an activity coefficient and X ₂ is the mole fraction. The correctness of this theoretical prediction is verified for the liquid system ethanol-water at 298 K.Paper submitted to the Ninth Symposium on Thermophysical Properties, June 24–27, 1985, Boulder, Colorado, U.S.A.     

Correlation and extrapolation scheme for the composition and temperature dependence of viscosity of binary gaseous mixtures: Carbon dioxide + ethane

Experimental viscosity data of ethane, carbon dioxide, and three mole fractions of the binary system carbon dioxide + ethane in the temperature range 293.15<T633.15 K and in the density range 0.010.05 mol·L^–1 reported earlier were evaluated simultaneously to find out a useful correlation and extrapolation scheme for the viscosity of binary systems in the range of moderate densities. A procedure based on the ideas of the modified Enskog theory has been found to give the best results. Dependent on temperature, the collision diameters related to the equilibrium radial distribution function at contact are fitted to viscosity values of the pure substances and of at least one mixture. The results are compared with experimental data from the literature. A recommendation is given concerning the density range in which the first density contribution to the viscosity coefficient of the system carbon dioxide + ethane is sufficient to be included.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A.     

The sorption of limonene/ethyl acetate binary vapour mixtures by a biaxially oriented polypropylene film

The sorption of ethyl acetate and limonene as individual sorbates and in binary vapour mixtures by an oriented polypropylene was determined by two independent methods, namely by gravimetric and thermal stripping/thermal desorption procedures. The two methods showed excellent agreement. The solubility coefficients for the two species were found to be independent of sorbate concentration within the ranges studied, indicating that sorption followed Henry's law. Calculated and experimentally obtained sorption profile curves agreed well for both ethyl acetate and limonene at low vapour activities. At a limonene vapour activity of 0.29 there was a lack of agreement between experimental and calculated results. This was attributed to the onset of non-Fickian relaxation effects occurring within the polymer matrix at this limonene concentration. The results of sorption studies involving binary vapour mixtures indicated that at the concentration levels evaluated, the co-permeant did not effect the sorption characteristics of the other sorbate.     

Experimental study on the packing densification of mixtures of spherical and cylindrical particles subjected to 3D vibrations

To identify the dense packing of cylinder–sphere binary mixtures (spheres as filling objects), the densification process of such binary mixtures subjected to three-dimensional (3D) mechanical vibrations was experimentally studied. Various influential factors including vibration parameters (such as vibration time t, vibration amplitude A, frequency ω, vibration acceleration Γ) as well as particle size ratio r (small sphere vs. large cylinder), composition of the binary mixtures X_L (volume fraction of cylinders), and container size D (container diameter) on the packing density ρ were systematically investigated. The results show that the optimal vibration parameters for different binary cylinder–sphere mixtures are different. The smaller the size ratio, the less vibration acceleration is needed to form a stable dense packing. For each binary mixture, high packing density can be obtained when the volume fraction of large cylindrical particles is dominant. Meanwhile, increasing the container size can decrease the container wall effect and get higher packing density. The proposed analytical model has been proved to be valid in predicting the packing densification of current cylinder–sphere binary mixtures.     

用于脉动热管的二元混合工质热力特性探讨

脉动热管是一种新型传热元件。工质种类的选取影响脉动热管的运行与传热,因此应根据脉动热管的用途及相应的温度范围选择适当的工质。提出选取二元混合工作介质(简称混合工质)作为脉动热管的工作介质。分析二元混合工质的露点温度或泡点温度与工质的种类、配比、压力之间的关系,以选取适合脉动热管传热特性的二元混合工质热力参数,得到选取混合工质的相应方法及注意事项。     

Agglomerate behavior in a recirculating fluidized bed with sheds: Effect of sheds

A Radioactive Particle Tracking (RPT) technique was used to study the effects of the internal baffles in the stripping section of the Fluid Coker?, called sheds, have on the behavior of wet agglomerates that are formed when residual oil is injected into the Coker. Vapor emitted by reacting wet agglomerates below the sheds rises and causes shed fouling. The release of vapor from agglomerates can be estimated by combining the RPT results with a coking reaction model. The study found that the sheds reduce the time agglomerates spend in the shed zone, which in turn reduces the amount of organic vapor that reaches the sheds, but at the same time increase the wetness of the agglomerates that exit to the recirculation line, which results in the loss of valuable liquid. The research also found that the best type of shed, from the point of view of agglomerate motion, is the mesh-shed. Finally, experimental data indicate that reducing the cross sectional area of the sheds from 50% to 30% increases the time that the agglomerates spend above the shed zone, and thus reduces the flow of vapor emitted below the sheds.     

Experimental study and particle population modeling of coating in a jet-fluidized bed

The present work focuses on the study of a bottom-spray fluidized-bed coater in the absence of any liquid (solvent) evaporation. The main objective is to point out and model the effect of operating conditions on the coating efficiency and the coating mass content distribution of particles. A fluidized bed with a bottom-placed spraying nozzle situated in the middle of a perforated distributor plate was used. The experimental results showed that increasing the jet and fluidizing gas flow rates improve the quality of coating, but there is a limitation for the binder flow rate which is dependent on the bed size and jet gas flow rate. Based on the experimental results, an empirical function was derived to predict the coating efficiency in different operating conditions and this function was also used in the mathematical model. Furthermore, a mathematical model was derived based on the population balance equations for two different zones in the bed. The model could predict the coating mass content distribution and the effect of different operating conditions during the process.     

Critical heat flux of binary mixtures in pool boiling and its correlation in terms of Marangoni number

Critical heat flux (CHF) in nucleate pool boiling of binary mixtures was newly measured with a horizontal platinum wire, 0.5 mm in diameter, and heated by DC, over the full range of concentrations. Seven mixtures were selected with the intent to cover various types of mixtures: methanol/water, ethanol/water, methanol/ethanol, ethanol/n-butanol, methanol/benzene, benzene/n-heptane and water/ethylene glycol, each in the saturated state at atmospheric pressure. Total 311 raw CHF data were obtained at 75 concentrations including pure components.Aqueous mixtures of methanol and ethanol revealed significant increase of CHF compared to either CHF linearly interpolated between pure components or CHF predicted from a single component correlation with use of the mixture properties. Three organic mixtures showed more or less the same level as an interpolated CHF, while the remaining two mixtures of methanol/benzene and water/ethylene glycol gave the reduced CHF by 20% and 50% at most, respectively. Marangoni number was introduced as a controlling variable to explain the observed increased, invariable, or reduced CHF, and an empirical correlation was developed.     

High-throughput CW-IR laser deposition and laser microscope imaging of binary ionic liquids in vacuum

A combinatorial library of binary mixtures of ionic liquids with various mixing ratios was fabricated on a single sapphire substrate using the composition-spread technique combined with a continuous-wave infrared (CW-IR) laser deposition method; the mixtures were condensed in the form of micro-scale droplets. The mixing ratio within the droplets was examined by Raman spectroscopy. The contact angle of the droplets was found to systematically vary with the mixing ratio. Their thermal behavior was characterized with an ultrahigh-vacuum laser microscope, revealing the dependence of the evaporation rate on the mixing ratio.     

High-throughput CW-IR laser deposition and laser microscope imaging of binary ionic liquids in vacuum

Abstract

A combinatorial library of binary mixtures of ionic liquids with various mixing ratios was fabricated on a single sapphire substrate using the composition-spread technique combined with a continuous-wave infrared (CW-IR) laser deposition method; the mixtures were condensed in the form of micro-scale droplets. The mixing ratio within the droplets was examined by Raman spectroscopy. The contact angle of the droplets was found to systematically vary with the mixing ratio. Their thermal behavior was characterized with an ultrahigh-vacuum laser microscope, revealing the dependence of the evaporation rate on the mixing ratio.     

Effects of main particle diameter on improving particle flowability for compressed packing fraction in a smaller particle admixing system

Particle flowability can be improved by admixing particles smaller than the original particles (main particles). However, the mechanisms by which this technique improves flowability are not yet fully understood. In this study, we examined compressed packing in a particle bed, which is affected by particle flowability. To estimate the mechanism of improvement, we investigated the effects of the main particle diameter on the improvement of compressed packing fractions experimentally.The main particles were 397 and 1460 nm in diameter and the admixed particles were 8, 21, 62, and 104 nm in diameter. The main and admixed particles were mixed in various mass ratios, and the compressed packing fractions of the mixtures were measured. SEM images were used to analyze the coverage diameter and the surface coverage ratio of the admixed particles on the main particles. The main particle packing fraction was improved as the diameter ratio (=main particles/admixed particles) increased. This was explained by a linked rigid-3-bodies model with leverage. Furthermore, the actual surface coverage ratio at which the most improved packing fraction was obtained decreased with increasing main particle diameter. This was explained by the difference in the curvature of the main particle surface.