An investigation of fretting behaviour of several metallic materials under grease lubrication

Fretting wear tests under grease lubrication have been carried out on an aluminium alloy, 52100 steel and low-alloy steel. The sphere–flat contact configuration is used. The influence of the displacement amplitude and normal load is investigated. Comparison between dry and lubricated contact of aluminium alloy, between 52100/52100 steel and 52100/low-alloy steel contact with grease lubrication has been carried out. Results show that grease lubrication strongly affects fretting behaviour. Base oil that separated from the grease during friction may result in accelerated contact wear by fretting.     

Subsurface damage development during fretting fatigue of high strength steel

The results of fretting fatigue experiments performed on two high-strength structural steels, PH 13-8 Mo stainless steel and quenched and tempered 4340 steel, are evaluated. Observations regarding the subsurface deformation and cracking behavior of the steels are compared and contrasted. It was found that the fretting stresses influenced early crack growth to a greater depth in PH 13-8 Mo stainless steel than in 4340 steel. In addition, experiments on PH 13-8 Mo led to the development of a region below the fretting scar that underwent a microstructural transformation, while experiments on 4340 steel did not. Likely reasons for this discrepancy are suggested. Differences in the formation of oxide layers and the occurrence of adhesion between the two materials are also discussed.     

Impact Fretting Wear Behavior of Alloy 690 Tubes in Dry and Deionized Water Conditions

The impact fretting wear has largely occurred at nuclear power device induced by the flow-induced vibration, and it will take potential hazards to the service of the equipment. However, the present study focuses on the tangential fretting wear of alloy 690 tubes. Research on impact fretting wear of alloy 690 tubes is limited and the related research is imminent. Therefore, impact fretting wear behavior of alloy 690 tubes against 304 stainless steels is investigated. Deionized water is used to simulate the flow environment of the equipment, and the dry environment is used for comparison. Varied analytical techniques are employed to characterize the wear and tribochemical behavior during impact fretting wear. Characterization results indicate that cracks occur at high impact load in both water and dry equipment; however, the water as a medium can significantly delay the cracking time. The crack propagation behavior shows a jagged shape in the water, but crack extended disorderly in dry equipment because the water changed the stress distribution and retarded the friction heat during the wear process. The SEM and XPS analysis shows that the main failure mechanisms of the tube under impact fretting are fatigue wear and friction oxidation. The effect of medium(water) on fretting wear is revealed, which plays a potential and promising role in the service of nuclear power device and other flow equipments.     

Dry sliding wear of Cu–15Ni–8Sn alloy

Using a pin-on-disc apparatus, the wear behavior of Cu–15Ni–8Sn alloy aged for different periods of time at 400 °C was investigated under dry condition. The results showed the wear rate was inversely proportional to the hardness of the alloy, but the maximum wear resistance was not consistent with maximum hardness. The alloy contained about 10% (volume) cells precipitated along grain boundaries had the lowest wear rate. The friction coefficient was constant for different hardness. SEM micrographs of the debris and pin revealed that the removal process of surface material involved subsurface deformation, crack nucleation, crack propagation and delamination of the material.     

2.25Cr1Mo传热管切向微动磨损性能研究

钠冷快堆换热器中的冷却剂与构件之间的流致振动会导致传热管发生微动磨损。以钠冷快堆换热器传热管候选材料2.25Cr1Mo钢为研究对象，研究其在不同法向载荷(10、20、30 N)下的切向微动磨损行为和损伤演变规律；采用光学显微镜(OM)、扫描电镜(SEM)及EDS对磨痕的形貌及摩擦化学反应进行分析；通过白光干涉仪获得传热管的磨损量。结果表明：随着法向载荷的增加，2.25Cr1Mo钢的微动模式由完全滑移转变为部分滑移，摩擦因数、磨损体积随着法向载荷的增加先增加后减小；当载荷为10～20 N时，2.25Cr1Mo钢的主要磨损机制为磨粒磨损、分层剥落以及氧化磨损，当载荷为30 N时，主要磨损机制为黏着磨损、塑性变形和氧化磨损。     

Effect of alloying additives on impact-abrasive wear of manual arc welded hadfield steel hardfacings

The results of studying the impact-abrasive wear of manual arc welded Hadfield steel hardfacings and this steel alloyed with Cr, Ni, Mo, B, Cu, and Si, both without and with coarse-grained tungsten carbide reinforcement, are presented. It has been found that under conditions of impactless wear the presence of the hardening phase in the Hadfield steel increases its wear by 40% on average compared to the wear of the base and alloyed Hadfield steels. With an increase in the impact energy from 2.8 to 5.6 J, the wear of the reinforced Hadfield steels decreases and becomes comparable with the wear of the base and alloyed Hadfield steels. Under the conditions of erosion by coarse particles, layers of the Hadfield steel reinforced by tungsten carbide have slightly lower wear rate than unreinforced ones.     

An experimental study torsional fretting behaviors of LZ50 steel

Four simple fretting modes are defined according to relative motion: tangential, radial, rotational, and torsional fretting. This paper presents a new test rig that was developed from a low-speed reciprocating rotary system to show torsional fretting wear under ball-on-flat contact. Torsional fretting behavior was investigated for LZ50 steel flats against AISI52100 steel balls under various angular displacement amplitudes and normal loads. The friction torques and dissipation energy were analyzed in detail. Two types of T–θ curves in the shape of quasi-parallelograms and ellipticals were found that correspond to gross and partial slips, respectively. The experimental results showed that the dynamic behavior and damage processes depend strongly on the normal loads, angular displacement amplitudes, and cycles. In this paper, the debris and oxidation behaviors and detachment of particles in partial and gross slip regimes are also discussed. Debris and oxidation are shown to have important roles during the torsional fretting processes. The wear mechanism of torsional fretting was a combination of abrasive and oxidative wear and delamination before third-body bed formation. The mechanism was then transformed into third-body wear after a great amount of debris formed.     

Slurry abrasion response of surface engineered Ti6Al4VELI

Titanium alloys, by virtue of their outstanding combination of properties, continue to evolve as direct replacements for steels in offshore production systems to meet the challenging offshore application conditions. However, the wider use of titanium and its alloys is frequently retarded by their reputation for poor tribological behaviour. It is because of this simple engineering scenario that comparative tribological behaviour of surface engineered Ti6Al4VELI in abrasive slurry has been evaluated to identify treatments capable of improving its wear behaviour. To best simulate potential application conditions, sliding wear tests were carried out using a block-on-wheel test configuration in abrasive mud slurry. The wear volumes lost from the surface engineered Ti6Al4VELI test blocks ranged from negligibly small for substrates plasma sprayed with either WC–Co, Ni–Cr or Mo, to approximately twice that measured for a steel test block in the cases of untreated, shot peened, electroless Ni plated and anodised Ti6Al4VELI. Hard chrome plated material and thermochemically treated material demonstrated a certain degree of wear, which however, was significantly less than that found for the steel block.     

硬质合金刀具车削Cr12Mn5Ni4Mo3Al不锈钢的试验研究

使用硬质合金刀具YW2进行Cr12Mn5Ni4Mo3Al不锈钢的干车削试验。分析了切削速度对车削力及表面粗糙度的影响,并采用扫描电子显微镜(SEM)观察刀具的磨损形貌。研究结果表明:使用硬质合金刀具YW2干车削Cr12Mn5Ni4Mo3Al不锈钢时,在小进给量和小背吃刀量切削的条件下,车削三向力的大小顺序为:径向力轴向力切向力;受积屑瘤的影响,表面粗糙度呈现出随车削速度的变化先减小后增大的变化趋势;硬质合金刀具后刀面磨损较轻微,而沿刀尖周围出现了较严重的粘结现象,前刀面上出现了较严重的划痕现象,低速时,前刀面还出现了贝壳状的剥落现象。     

Cavitation erosion-corrosion behaviour of CrMnB stainless overlay and 0Cr13Ni5Mo stainless steel in 0.5 M NaCl and 0.5 M HCL solutions

The cavitation erosion-corrosion behaviour of CrMnB overlay was investigated in comparison with 0Cr13Ni5Mo stainless steel in 0.5 M NaCl and 0.5 M HCl solutions by using a magnetostrictive-induced cavitation facility. The micrographs of damaged surfaces were observed by scanning electron microscope (SEM), and the polarization curves were measured under quiescent and cavitating condition. The results showed that the cavitation erosion-corrosion resistance of CrMnB overlay was 14 times higher than that of 0Cr13Ni5Mo steel in NaCl solution, but, the cavitation erosion-corrosion resistance was 5.7 times lower in HCl solution. For CrMnB overlay in NaCl solution, the excellent cavitation erosion-corrosion resistance could be attributed to strain-induced martensite transformation and its “skeleton” structure of borides. For CrMnB overlay in HCl solution, the electrochemical dissolution promoted the borides to drop out. The martensite transformation was retarded by cushion effect of H₂ gas. Material removal in massive chunks (independent on the microstructural features) was accelerated by connection of cavitation cracks, which was enhanced by hydrogen embrittlement. These results suggested that developing steels with high martensite transformability and boride strengthening is an important method to design coatings or steels used in neutral cavitation environments, but which is not suitable for acidic environments.     

Micro-scale abrasive wear testing of duplex and non-duplex (single-layered) PVD (Ti,Al)N, TiN and Cr–N coatings

A micro-scale abrasive wear test, based on ball-cratering, has been used to evaluate the wear resistance of duplex and non-duplex (Ti,Al)N, TiN and Cr–N coatings. The term duplex is used here when plasma nitriding is followed by PVD coating. Coatings without the plasma nitriding stage are termed single-layered. Coating properties were evaluated by surface profilometry, hardness and scratch testing. All duplex coatings showed higher micro-abrasive wear resistance than their single-layered counterparts, with the duplex (Ti,Al)N coating achieving the best performance. After a certain number of ball revolutions, the coating material became worn through, exposing the substrate material. After this point, the presence of a hard nitrided case diminished the scratching action of the SiC abrasive particles. The experimental results also indicate that the choice of the PVD coating plays an important role in improving the micro-abrasive wear resistance. Apart from single-layered and duplex Cr–N coatings, all the other coating systems provided a higher micro-abrasive wear resistance than the uncoated substrate (hardened AISI H13 steel). The poor abrasive wear resistance recorded for the single-layered and duplex Cr–N coatings could be attributed to the hardness of the Cr–N being much lower than that of the SiC abrasive particles, which caused tearing of the coating with subsequent delamination. The wear pattern observed was found to change from surfaces characterised by grooves (uncoated substrate, single-layered TiN and Cr–N systems and duplex Cr–N system) to surfaces which exhibited multiply indented surfaces (single-layered and duplex (Ti,Al)N systems), indicating a transition between wear mechanisms. This transition was found to be dependent on the ratio between the hardness of the SiC abrasive particles and surface (coating) or subsurface hardness. By decreasing this ratio, the ability of the SiC abrasive particles to scratch the composite surface was reduced and the resistance to micro-scale abrasion was improved.     

An investigation of fretting behaviour of several synthetic base oils

The chemical and physical properties are quite different for mineral oil and synthetic oil. Compared to the investigation of mineral oil, less work on fretting behaviour of synthetic oils was reported. In this paper, a study of typical synthetic base oils such as polyalkylene glycol (PAG), polyalphaolefin (PAO) and silicone oil has been conducted. The contact consisted of a fixed flat specimen (GCr15 steel and 45 steel) opposite to a moving ball specimen (GCr15 steel) with a diameter of 12.3 mm. Other main parameters were as follows: the slip amplitude was ranged from 5 to 80 μm, the frequency was varied from 2 to 5 Hz; the normal load, temperature and relative humidity were respectively 100 N, 23 °C and 60%. Variations in the tangential force versus the displacement as a function of the fretting cycles were recorded. For comparison, fretting tests under dry condition have also been performed. The fretting scars were examined after tests. The evolution of coefficient of friction and wear volume were analyzed and compared at different fretting regimes for different synthetic base oils. The competitions between oil penetration into the interface and self-cleaning by fretting in different fretting regimes, the effect of physical properties such as surface tension, pressure–viscosity coefficient and compressibility on fretting behaviour have been particularly discussed.     

Delamination wear of metal injection moulded 316L stainless steel

The wear behavior of metal injection moulded (MIM) stainless steels was studied using a pin-on-disc apparatus under dry sliding conditions. Pin specimens were MIM 316L stainless steel, while disc specimens were wrought 316L stainless steel. At low sliding speeds (0.2–0.6 m/s), the wear rates gradually decreased with increasing sliding speed, but then increased at high sliding speeds (0.6–2 m/s). The adhesive-induced delamination wear dominated at low sliding speeds, while abrasive-induced delamination wear dominated at high sliding speeds. At low sliding speeds, the surface densification occurred on the worn surface of pin specimens, hence no difference was found between the wear resistances of MIM pins containing 2% and 6% porosity. In contrast, the abrasive-induced delamination wear at high sliding speeds was enhanced by porosity; therefore the wear rates of MIM pins containing 6% porosity were higher than those of MIM pins containing 2% porosity.     

Friction and wear behaviour of sintered steels submitted to sliding and abrasion tests

Fe–C–Mo and Fe–C–Cr steels were sintered by PM processes carried out using different values of temperature and pressure, leading to different microstructures and density values. Flat specimens were submitted to tribological tests in order to evaluate their behaviour under both dry sliding and abrasive wear conditions. A flat-on-cylinder tribometer was used for the sliding tests, while a micro-scale ball cratering device was used for the abrasion tests. The dry sliding wear resistance of the PM steels was mainly influenced by the composition and sintering conditions. In this regard, the best behavior was observed for the more hardenable Fe–C–Mo steels with higher Mo content, sintered under conditions giving rise to bainitic microstructures. A determining role was also played by the porosity content and pore shape: reduction in porosity (obtained by increasing the sintering temperature and the compacting pressure), as well as an increase in pore roundness, led to a significant improvement in the resistance to sliding wear. A mild oxidative wear regime were observed for all the sintered steels under relatively low values of the applied load, while an increase of the applied load led to a delamination wear regime. The resistance to abrasive wear was low for all the tested steels, irrespective of composition and sintering cycle.     

Wear analysis of Cu–Al coating on Ti–6Al–4V substrate under fretting condition

Fretting behavior of Cu–Al coating on Ti–6Al–4V substrate was investigated with and without fatigue load. Soft and rough Cu–Al coating resulted in abrasive wear and a large amount of debris remained at the contact surface, which caused an increase in tangential force during the fretting test under gross slip condition. Fretting in the partial slip condition also showed the wear of coating. To characterize wear, dissipated energies during fretting were calculated from fretting loops and wear volumes were obtained from worn surface profiles. Energy approach of wear analysis showed a linear relationship between wear volume and accumulated dissipated energy. This relationship was independent of fatigue loading condition and extended from partial slip to gross slip regimes. As an alternate but simple approach for wear analysis, accumulated relative displacement range was correlated with the wear volume. This also resulted in a linear relationship as in the case of accumulated dissipated energy suggesting that the accumulated relative displacement range can be used as an alternative parameter for dissipated energy to characterize the wear. When the maximum wear depth was equal to the thickness of Cu–Al coating, harder Ti–6Al–4V substrate inhibited further increase in wear depth. Only when a considerable energy was supplied through a large value of the applied displacement, wear in the substrate material could occur beyond the thickness of coating.     

Erosive wear of hardfaced Fe–Cr–C alloys at elevated temperature

Many engineering components are subjected to erosive wear at elevated temperature. As erosive wear at elevated temperature is governed by the synergistic effect of erosive wear and oxidation, it is possible to modify surfaces of the components in order to achieve improved performances. In view of the above, two different types of hardfacing alloys of Fe–Cr–C were designed incorporating Nb, Mo and B to ensure improved performances at elevated temperature. In order to achieve the above objective, mild steel was hardfaced with these alloys under optimised gas metal arc welding (GMAW) condition. The microstructures of the hardfaced coating was characterised with the help of optical microscopy (OM) and scanning electron microscopy (SEM). The mechanical properties of these coatings were obtained by means of micro indenter. Erosive wear of these coatings was evaluated for four different temperatures, for two different impact angles and at one impact velocity. The morphologies and the transverse sections of the worn surfaces are examined with SEM. The erosive wear of these coatings were compared with conventional M2 tool steel. Results indicate that erosion rate of these coatings increases with increase of test temperature and impact angles. Among various coatings, Fe–Cr–C coating containing higher amount of Nb, Mo and B exhibits best erosion resistance particularly at elevated temperature.     

The effect of boron on the abrasive wear behavior of austenitic Fe-based hardfacing alloys

The effect of boron on the abrasive wear behavior of the austenitic Fe–Cr–C–Si–B hardfacing alloys was investigated with varying boron concentration. It was found that the abrasive wear resistance of the hardfacing alloys increased up to 50% compared to that of boron-free alloys with increasing boron concentration. The mechanism of the abrasive wear resistance changed at 0.6 wt.% boron. Below 0.6 wt.% boron concentration, the abrasive wear resistance was improved almost linearly and strain-induced martensitic transformation was considered as the controlling factor for improving the resistance. Above 0.6 wt.% boron, it was observed that the primary borides started to precipitate. Further increase in boron concentration was not able to enhance the resistance due to the negligible change of primary borides’ size and volume fraction. With these results, it was concluded that two different effects of boron on the wear resistance of the austenitic Fe–Cr–C–Si–B hardfacing alloys existed depending on the boron concentration.     

Characterization of fretting wear behavior of Cu–Al coating on Ti–6Al–4V substrate

Fretting wear and fretting fatigue are two commonly observed material damages when two contacting bodies with a clamping load are under the oscillatory motion. In this study, fretting wear damage of Cu–Al coating on titanium alloy, Ti–6Al–4V substrate was investigated using the dissipated energy approach. Fretting tests were conducted with either no fatigue load or the maximum fatigue load of 300 MPa and stress ratio of 0.1 on the substrate (specimen). In order to investigate the effect of contact load and contact size, different pad sizes and contact loads were used in the tests. Accumulated dissipated energy versus wear volume data showed a linear relationship regardless of fatigue loading condition on specimen with the smaller pad size. However, two separate linear relationships were observed based on the fatigue loading condition with the larger pad size, such that a relatively more dissipated energy was required for a certain amount of wear with fatigue load on the specimen. The linear relationship between the accumulated dissipated energy and wear volume for both pad sizes extended from partial to gross slip regimes and was not affected by the applied contact load. Further, fretting tests with and without fatigue load resulted in different shapes of fretting loops when the larger pad size was used.     

Fretting Wear Behavior of Cu–Al Coating on Ti-6Al-4V Substrate under Dry and Wet (Lubricated) Contact Condition

The fretting wear behavior of Cu–Al coating was investigated with and without fatigue load under the dry and wet (lubricated) contact conditions. The Cu–Al coating was plasma deposited on titanium alloy, Ti-6Al-4V. Fretting regime was determined from the shape of fretting hysteresis loop. Fretting regime changed from partial slip to total (gross) slip at ∼15 μm of the applied relative displacement, and this transition point was independent of fatigue loading and contact surface (lubricated versus dry) conditions. Wet contact condition reduced frictional force during cycling, as evidenced by the lower-tangential force. Wear analysis using the accumulated dissipated energy approach did not show any effect of contact surface condition. In other words, the relationship between the accumulated dissipated energy and wear volume showed a linear relationship, and it was independent of loading and contact surface conditions, as well as of the fretting regime. Further, the relationship between the wear depth and accumulated dissipated energy did not show any effect of loading and contact surface conditions, as well as of the fretting regime up to instant when the maximum wear depth was equal to the coating thickness. The views expressed in this article are those of the authors and do not reflect the official policy or position of the United State Air Force, Department of Defense, or the U.S. Government.     

Fretting fatigue strength estimation considering the fretting wear process

In fretting fatigue process the wear of contact surfaces near contact edges occur in accordance with the reciprocal micro-slippages on these contact surfaces. These fretting wear change the contact pressure near the contact edges. To estimate the fretting fatigue strength and life it is indispensable to analyze the accurate contact pressure distributions near the contact edges in each fretting fatigue process.So, in this paper we present the estimation methods of fretting wear process and fretting fatigue life using this wear process. Firstly the fretting-wear process was estimated using contact pressure and relative slippage as follows:

W=K×P×S,