Streamwise interaction of burning drops

The spatial distribution of drops and their interactions are influential parameters in spray combustion. Most available researches on this subject were about lateral spacing or were performed in micro-gravity. Studies about upstream/downstream convective interaction of burning drops are scarce. In this study, drop strings of different spacing were investigated in a high-temperature oxidizing environment for their flame transition, flame width variation and drop evaporation rate. The flame transition showed that along the flow direction, the drop flame initially located ahead of the drop, became a spherical envelope flame, then moved behind the drop, and finally burned as a wake flame. It was found that a drop string with an initial drop spacing (S_i) of 2.5 or 5 was surrounded by a bulk flame tube, exhibited local group burning and soot layer. In addition, for S_i = 2.5, spacing instability and collision merging of the burning drops occurred; the wake flame stretched away from the drop could attach to and stabilize on the rear drop. In the experiment, for all cases, most of drops in the string were not surrounded by the flame. For S_i < 30, the drop evaporation rate was lower than that of a single drop. For 30 < S_i < 75, the drop evaporation rate was higher than that of a single drop. The interaction of drops diminished if S_i was more than 75.     

Micro-alumina particle volatilization temperature measurements in a heterogeneous shock tube

Peak flame temperatures in aluminum particle combustion should approach the volatilization temperature of the product alumina. References are divided in assigning this temperature anywhere between 3200 and 4000 K, which can provide significant uncertainty not only in numerical models for combustion but also in the interpretation of flame structure from temperature measurements. We present results in the controlled conditions of the UIUC heterogeneous shock tube of volatilization temperature, made by measuring the extinction of light by nano- and micro-alumina particles at non-resonant wavelengths at different ambient temperatures. At 10 atm, there is a sharp cutoff at 3860 K beyond which nano-particles volatilize and stop extinguishing within the shock tube test time. Numerical modeling of the evaporation rate of these particles is used to assign a volatilization temperature of 4340 K at 10 atm. Similarly, a volatilization temperature of 4260 K at 3 atm is measured. From our analysis, the best estimate for the volatilization temperature at 1 atm was 4189 ± 200 K, which is consistent with the high range of volatilization temperature reported in the literature.     

Combustion of micro aluminum–water mixtures

An experimental investigation on the combustion behavior of micro-sized aluminum (μAl)–water mixtures was conducted. It was easily ignited and self-deflagrated on μAl and liquid water when using a paper shell tube. Linear burning rates of quasi-homogeneous mixtures of μAl and liquid water as a function of pressure, mixture composition, density and environment gas medium were measured. Steady-state burning rates were obtained at room temperature using a windowed vessel for a pressure range of 1–80 bar in a nitrogen atmosphere, particle size of 0.5 × 30 × 30 μm and overall mixture equivalence ratios from 0.67 to 2.0. The pressure exponent was obtained as 0.47 at room temperature and compared to the case of nano-sized aluminum (nAl) and liquid water. When a wire was inserted into the sample, for increasing local heat transfer, burning rates were found to be faster.     

Ag–Al based air braze for high temperature electrochemical devices

Silver–aluminum based air brazing was attempted using an in situ alloying and brazing process. In this process, layers of foils of aluminum and silver were laid up between alumina plates in alternating fashion to achieve three target compositions representing Ag, Ag₃Al, and Ag₂Al phases. Each alloy composition revealed different microstructure, mechanical properties and fracture mechanisms. Joints brazed with foils containing 9.8 at% Al formed a long continuous layer parallel to the direction of the original aluminum foil. The fracture occurred at low bend strength (6–12 MPa) mainly through the interface between this newly formed long alumina layer and the braze filler. Joints containing 26.5 at% Al in the braze filler metal experienced the series of phase transformations, leading to cracks in as-brazed specimens. The fracture initiated through these pre-existing cracks, thus the joint strength observed in these specimens was extremely low. The joints prepared using foils with 35.1 at% Al exhibited a good interface even though interfacial alumina particles formed during air brazing. Crack propagation occurred along the interface between the alumina substrate and in situ formed interfacial alumina particles or directly through these particles. Due to the good interface, the best bend strength (46–52 MPa) was achieved for the braze filler containing 35 at% Al.     

Preparation and characterization of activated carbon from rubber-seed shell by physical activation with steam

The use of rubber-seed shell as a raw material for the production of activated carbon with physical activation was investigated. The produced activated carbons were characterized by Nitrogen adsorption isotherms, Scanning electron microscope, Thermo-gravimetric and Differential scanning calorimetric in order to understand the rubber-seed shell activated carbon. The results showed that rubber-seed shell is a good precursor for activated carbon. The optimal activation condition is: temperature 880 °C, steam flow 6 kg h^?1, residence time 60 min. Characteristics of activated carbon with a high yield (30.5%) are: specific surface area (S_BET) 948 m² g^?1, total volume 0.988 m³ kg^?1, iodine number of adsorbent (q_iodine) 1.326 g g^?1, amount of methylene blue adsorption of adsorbent (q_mb) 265 mg g^?1, hardness 94.7%. It is demonstrated that rubber-seed shell is an attractive source of raw material for producing high capacity activated carbon by physical activation with steam.     

The effect of porous media particle size on forced convection from a circular cylinder without assuming local thermal equilibrium between phases

A detail numerical analysis of the effect of particle diameter of a packed bed of spherical particles on forced convection about an embedded circular cylinder is presented. This parametric study focusses on the two-phase energy (LTNE—local thermal non-equilibrium) model, which does not assume local thermal equilibrium (LTE) between the solid medium and the fluid. The investigation is performed for a cylinder-to-particle diameter ratio D_cy/d_p = 10–100, at a wide ranges of Reynolds number Re_D = 1–250 and solid-to-fluid thermal conductivity ratio k_r = 0.01–1000. A comparison of predictions from the LTNE and LTE energy models is also made. This paper quantifies the influence of the key non-dimensional parameters on the heat transfer rate. It is also shown that although the presence of the porous materials around the heated cylinder enhances the overall heat transfer and increases the pressure drop in the bed compared to an empty channel, using a porous medium with large particle diameters increases considerably this enhancement in heat transfer and decreases significantly the unfavorable pressure drop.     

Effect of magnetic obstacle on fluid flow and heat transfer in a rectangular duct

The vortex dynamics behind various magnetic obstacles and characteristics of heat transfer are investigated using a three-dimensional model. In the numerical study, the magnet width (M_y) is alterable to investigate the instability, Strouhal number, wake structure behind various magnetic obstacles and percentage increment of the overall heat transfer for a wide range of constrainment factors (0.08 ≤ κ ≤ 0.26), Reynolds numbers (400 ≤ Re ≤ 900) and interaction parameters (9 ≤ N ≤ 15). For all constrainment factors, the fundamental frequency (f) is uniform for a particular value of Reynolds number. Downstream cross-stream mixing due to vortex shedding enhances the wall-heat transfer and the maximum value of percentage increment of the overall heat transfer (HI) is about 20.2%. However, the pressure drop penalty (ΔP_penalty) is not increasingly dependent on interaction parameter when Re and κ remain constant.     

Momentum and heat transfer phenomena of spheroid particles at moderate Reynolds and Prandtl numbers

The momentum and heat transfer phenomena of spheroid particles in an unbounded Newtonian fluid have been numerically investigated by solving governing conservation equations of the mass, the momentum and the energy. The numerical solution methodology has been benchmarked by performing comparisons between present results with those reported in the literature. Further, extensive new results have been obtained to elucidate effects of pertinent dimensionless parameters such as the Reynolds number (Re), the Prandtl number (Pr) and the aspect ratio (e) on the flow and heat transfer behaviour of spheroid particles in the range of parameters: 1 ? Re ? 200; 1 ? Pr ? 1000 and 0.25 ? e ? 2.5. Regardless of the value of the Reynolds number, the total and individual drag coefficients of oblate spheroids (e < 1) are smaller than those of spheres (e = 1) and opposite trend has been observed for prolate spheroids (e > 1). Irrespective of values of Reynolds and Peclet numbers, the average Nusselt number is large for prolate particles as compared to spheres and opposite trend has been observed for the case of oblate particles. Major contribution of this work is the development of simple correlations for the total drag coefficient and the average Nusselt number of unconfined isolated spheroid particles based on present numerical results which can be used in new applications.     

Study of interaction of entrained coal dust particles in lean methane–air premixed flames

This study investigates the interaction of micron-sized coal particles entrained into lean methane–air premixed flames. In a typical axisymmetric burner, coal particles are made to naturally entrain into a stream of the premixed reactants using an orifice plate and a conical feeder setup. Pittsburgh seam coal dust, with particle sizes in the ranges of 0–25 μm, 53–63 μm, and 75–90 μm, is used. The effects of different coal dust concentrations (10–300 g/m³) entrained into the mixture of methane–air at three lean equivalence ratios, ?, of 0.75, 0.80 and 0.85, on the laminar burning velocity are studied experimentally. The laminar burning velocity of the coal dust–methane–air mixture is determined by taking high quality shadowgraph images of the resulting flames and processing them using the cone-angle method. The results show that the laminar burning velocity reduces with the addition of coal dust having particle sizes in the ranges of 53–63 μm and 75–90 μm, irrespective of the equivalence ratio values. However, burning velocity promotion is observed for one case with particle size in the range of 0–25 μm at an equivalence ratio of 0.75. Two competing effects are considered to explain these trends. The first effect is due to volatile release, which increases the overall equivalence ratio and thus, the flame temperature and burning velocity. The second is the heat sink effect that the coal particles take up to release the volatiles. This process reduces the flame temperature and accordingly the burning velocity also. A mathematical model is developed considering these effects and it is seen to successfully predict the change of laminar burning velocity for various cases with different dust concentrations and equivalence ratios of the gas mixture. Furthermore, the implication of this study to coal mine safety is discussed.     

Layered Li(Ni0.5−xMn0.5−xM2x′)O2 (M′=Co,Al, Ti; x=0, 0.025) cathode materials for Li-ion rechargeable batteries

Layered Li(Ni_0.5−xMn_0.5−xM_2x′)O₂ materials (M′=Co, Al, Ti; x=0, 0.025) were synthesized using a manganese-nickel hydroxide precursor, and the effect of dopants on the electrochemical properties was investigated. Li(Ni_0.5Mn_0.5)O₂ exhibited a discharge capacity of 120 mAh/g in the voltage range of 2.8–4.3 V with a slight capacity fade up to 40 cycles (0.09% per cycle); by doping of 5 mol% Co, Al, and Ti, the discharge capacities increased to 140, 142, and 132 mAh/g, respectively, and almost no capacity fading was observed. The cathode material containing 5 mol% Co had the lowest impedance, 47 Ω cm², while undoped, Ti-doped, and Al-doped materials had impedance of 64, 62, and 99 Ω cm², respectively. Unlike the other dopants, cobalt was found to improve the electronic conductivity of the material. Further improvement in the impedance of these materials is needed to meet the requirement for powering hybrid electric vehicle (HEV, <35 Ω cm²). In all materials, structural transformation from a layered to a spinel structure was not observed during electrochemical cycling. Cyclic voltammetry and X-ray photoelectron spectroscopy (XPS) data suggested that Ni and Mn exist as Ni²⁺ and Mn⁴⁺ in the layered structure. Differential scanning calorimetry (DSC) data showed that exothermic peaks of fully charged Li_1−y(Ni_0.5−xMn_0.5−xM_2x′)O₂ appeared at higher temperature (270–290 °C) than LiNiO₂-based cathode materials, which indicates that the thermal stability of Li(Ni_0.5−xMn_0.5−xM_2x′)O₂ is better than those of LiNiO₂-based cathode materials.     

Creep behavior of Ni-12 wt.% Al anodes for molten carbonate fuel cells

Ni-12 wt.% Al anodes are fabricated for use in molten carbon fuel cells by tape casting and sintering. Sintering is performed in three steps, first at 1200 °C for 10 min in argon, then at 700 °C for 2.5 h in a partial oxidation atmosphere (P_H2/P_H2O=10⁻²), and finally at 950 °C for 5 min, 30 min or 1.5 h in hydrogen. Three anodes with different phases or microstructures are produced at different reduction times. One anode contains three phases, namely Ni–Al solid solution, Ni₃Al, and Al₂O₃. The amount of Al₂O₃ is extremely small at 5 min. A second anode also contains the three phases with the amount of Al₂O₃ comparable with that of Ni₃Al at 30 min. Third anode contains two phases, i.e. Ni–Al solid solution and Al₂O₃ formed at 1.5 h. The creep strains measured for the three anodes after a 100-h creep test are practically the same with an average value of 0.85%.     

Transient flame spread during convective ignition of solid fuel in a sudden-expansion combustor

The convective ignition of solid fuel (PMMA) in a sudden-expansion combustor (Re_h = 6200, u₀ = 22 m/s, [O₂] ～ 11.7%, T₀ = 810 °C) is investigated from the perspective of flame–vortex interactions. Three phases of the transient flame spread are identified via the diagnostics of flow visualization and particle image velocimetry (PIV). The dominance of small/large vortices is revealed, respectively, in the pre-/post-ignition regimes, which demonstrates the small-to-large vortex transformation due to heat release. Attributed to the decreased characteristic reaction time and enhanced mixing, the first ignition is observed at the downstream end of the fuel, after which a primitive flame is formed and initiates the opposed flame spread. During the spread, the rolling behavior of flame kernels are considered to be dominated by the small eddies. The combined effects of broken vortices and continuing pyrolysis introduce the periodical extinction–reignition around the reattachment region. At the final phase, the entrainment of flame kernels into the shear layer is facilitated by the large shedding vortices, and a sustained diffusion flame is established. The study not only provides novel insights into the convective ignition of solid fuel in the separation–reattachment flow, but also serves as a basis for the advancement of ignition control.     

Swirl effects on harmonically excited,premixed flame kinematics

This paper describes the response of a swirling premixed flame with constant burning velocity to non-axisymmetric harmonic excitation. This work extends prior studies of axisymmetric forcing, which have shown that wrinkles are excited on the flame that propagate downstream along the mean flame surface at a speed given by U_o cos ψ, where U_o is the mean flow velocity and ψ is the flame angle. The swirl component in the flow field introduces an azimuthal transport mechanism for disturbances on the flame. As such, the flame response at any given position is a superposition of flame wrinkles excited at earlier times, upstream axial locations, and different azimuthal positions. These swirl transport effects do not arise in problems where axisymmetric flames are subjected to axisymmetric excitation, but enter quite prominently in the presence of non-axisymmetries, such as when the flame is subjected to transverse excitation. The solution characteristics are strongly dependent upon the ratio of angular rotation rate to excitation frequency, denoted by σ = Ω/ω, which describes the fraction of azimuthal rotation a disturbance makes in one acoustic period. When σ ? 1 and σ ? 1, the axial wavelength of flame wrinkles scales with the convective wavelength, λ_c, but becomes much longer for σ ～ O(1). The spatial variation in phase of flame wrinkling is also strongly dependent upon σ. Regardless of swirl number, flame wrinkles propagate in helical spirals along the solution characteristics at a phase speed equal to the local tangential velocity. The axial phase characteristics of flame wrinkling at a fixed azimuthal location, as would be measured by laser sheet imaging, are much more complex. For σ < 1, the wrinkles exhibit the familiar negative roll-off character for the phase with axial downstream distance, indicative of an axially convecting disturbance. The slope of this phase roll-off decreases with increasing σ, however, and becomes zero at σ = 1 for a compact flame. For σ > 1, the wrinkles actually have a positive roll-off character for the phase with axial downstream distance, indicating a flame wrinkle with a negative trace velocity, but whose actual propagation velocity is positive. Finally, these results show that while the flame response to transverse acoustic excitation is quite strong locally, its spatially integrated effect is much smaller for acoustically compact flames. This suggests that the dominant mechanism through which the flame responds globally to transverse excitation is the induced vortical and longitudinal acoustic fluctuations.     

Two-phase flow pattern and frictional performance across small rectangular channels

This study presents flow visualizations and two-phase frictional pressure drop data for three rectangular channels with channel height of 3, 6 and 9 mm, and a fixed width of 3 mm. It is found that the stratified flow pattern still exists for an aspect ratio of unity at a low mass flux of 100 kg/m² s but it completely vanishes when G > 200 kg/m²s. For the same plug flow of intermittent flow pattern, the number of plug increases whereas its length decreases when the aspect ratio is increased. This is especially pronounced when the mass flux is further increased over 500 kg/m² s. The major departure of the observed flow pattern relative to the conventional Mandhane flow map is the transition boundary for slug/annular had been moved to a much lower superficial vapor velocity. The two-phase frictional pressure drop data are compared to homogeneous and Chisholm method, Wambsganss and Ide-Fukano correlations. It is found that none of the existing methods or correlations can satisfactorily predict the two-phase pressure gradient in rectangular channels. A modified C factor of Chisholm method considering the effect of aspect ratio was proposed from the empirical fit with the data sets of Wambsganss et al., Ide-Fukano, and this study. The corresponding mean deviations of the proposed correlation against the datasets are 24.99%, 10.83% and 10.73%, respectively. This correlation is applicable in wide rages of mass flux (50 < G < 700 kg/m² s), vapor quality (0.001 < x < 0.95), Martinelli parameter (0.05 < X < 20) and aspect ratio (0.1 < A < 1.0).     

Biodiesel production from jatropha oil (Jatropha curcas) with high free fatty acids: An optimized process

Response surface methodology (RSM) based on central composite rotatable design (CCRD) was used to optimize the three important reaction variables—methanol quantity (M), acid concentration (C) and reaction time (T) for reduction of free fatty acid (FFA) content of the oil to around 1% as compared to methanol quantity (M′) and reaction time (T′) and for carrying out transesterification of the pretreated oil. Using RSM, quadratic polynomial equations were obtained for predicting acid value and transesterification. Verification experiments confirmed the validity of both the predicted models. The optimum combination for reducing the FFA of Jatropha curcas oil from 14% to less than 1% was found to be 1.43% v/v H₂SO₄ acid catalyst, 0.28 v/v methanol-to-oil ratio and 88-min reaction time at a reaction temperature of 60 °C as compared to 0.16 v/v methanol-to-pretreated oil ratio and 24 min of reaction time at a reaction temperature of 60 °C for producing biodiesel. This process gave an average yield of biodiesel more than 99%. The fuel properties of jatropha biodiesel so obtained were found to be comparable to those of diesel and confirming to the American and European standards.     

Transient thermal-fluid flow characteristics of vascular networks

Here we develop new vascular designs for the volumetric bathing of smart structures under time-varying conditions. The three flow configurations described in this paper are the first, second, and third constructal structures with optimized hydraulic diameters (D₁ and D₂) and non-optimized hydraulic diameter (D) for one system size, 20 × 20. The main objective was to determine the longest permissible time delay so that the maximum temperatures do not exceed the maximum allowable limit. It is the best to cool with the first construct in the optimized constructal configurations when pressure drop number (Be) is lower than 1 × 10¹¹ and the best structure is the second constructal structure when pressure drop number (Be) is greater than 2 × 10¹¹, whereas the best structure in the non-optimized constructal configurations is the third construct. It is also shown that the most attractive configurations have larger allowable delay times: in both the optimized and non-optimized constructal structures, the best configuration is the second construct where the pressure drop is fixed at about 1 kPa.     

Influence of fuel fraction gradient on triple flame velocity in plain and axis-symmetrical channels

Dynamics of laminar triple flame investigated numerically for the different mixture degrees. One-step methane–air chemistry adequate to reach and lean mixture combustion was accepted. Velocity of triple flame is determined as a function of methane concentration logarithm gradients μ = d(ln Y₁)/dx (characterizing mixing degree). It is found that maximum velocity of the triple flames correspond to the value of the methane concentration logarithm gradients μ ≈ 1000 m^?1 for plain and μ ≈ 2000 m^?1 for axis-symmetrical channels. The maximum velocity of triple flame in plain and axis-symmetrical channels in the case of non-gradient incoming gas flow is about twice bigger than normal laminar flame velocity S_f ≈ 2.1S_l.     

Electrophoretic deposition of binary energetic composites

This work utilizes electrophoretic deposition (EPD) as a facile and effective method to deposit binary energetic composites. In particular, micron-scale aluminum and nano-scale copper oxide were co-deposited as a thin film onto a conductive substrate without the use of surfactants. For comparative purposes, films of this energetic mixture were also prepared by drop-casting (DC) the premixed suspension directly onto the substrate, then allowing the liquid to dry. The structure and microscopic features of the two types of films were compared using optical and electron microscopies. The films prepared using EPD had an appreciable density of 2.6 g/cm³, or 51% the theoretical maximum density, which was achieved without any further processing. According to the electron microscopy analysis, the EPD films exhibited much more uniformity in composition and film thickness than those produced by DC. Upon ignition, the EPD films resulted in a smoother and faster combustion event compared to the DC films. The dispersion stability was improved by adding water and decreasing the particle concentration, resulting in dispersions stable for >30 min, an ample amount of time for EPD. Patterned electrodes with fine feature sizes (20 × 0.25 mm) were then combined with EPD to deposit thin films of thermite for flame propagation velocity studies. The fastest velocity (1.7 m/s) was observed for an equivalence ratio of 1.6 ± 0.2 (Al fuel rich composition). This peak value was used to investigate the effect of film mass/thickness on propagation velocity. The deposition mass was varied from 20 to 213 μg/mm², corresponding to a calculated range of film thicknesses from 9.8 to 104 μm. At lower masses, a flame did not propagate, indicating a critical mass (20 μg/mm²) or thickness (9.8 μm). Over the range of thicknesses, in which self-propagating combustion was observed, the flame velocity was found to be independent of sample thickness. The lack of a thickness dependence suggests that under these particular conditions heat losses are negligible, and thus the velocity is predominantly governed by the intrinsic reactivity and heat transfer through the material.     

Flame stabilization between two beds of alumina balls in a porous burner

Conditions for flame stabilization in a porous media combustor formed by two beds of different sizes of alumina balls were studied. Premixed combustion of lean methane–air mixtures were used as variables. Measurements performed included temperature profiles and chemical products compositions. Stabilized flames were observed in the range of volumetric flow rate from 7.01 l/min to 19.00 l/min at equivalence ratio of ? = 0.6 and ? = 0.7. Low pollutants emissions were found in the entire operation range.     

Effect of (Al,Mg) substitution in LiNiO2 electrode for lithium batteries

Stabilized lithium nickelate is receiving increased attention as a low-cost alternative to the LiCoO₂ cathode now used in rechargeable lithium batteries. Layered LiNi_1−x−yM_xM_yO₂ samples (M_x = Al³⁺ and M_y = Mg²⁺, where x = 0.05, 0.10 and y = 0.02, 0.05) are prepared by the refluxing method using acetic acid at 750 °C under an oxygen stream, and are subsequently subjected to powder X-ray diffraction analysis and coin-cell tests. The co-doped LiNi_1−x−yAl_xMg_yO₂ samples show good structural stability and electrochemical performance. The LiNiAl_0.05Mg_0.05O₂, cathode material exhibits a reversible capacity of 180 mA h g⁻¹ after extended cycling. These results suggest that the threshold concentration for aluminum and magnesium substitution is of the order of 5%. The co-substitution of magnesium and aluminium into lithium nickelate is considered to yield a promising cathode material.