共查询到20条相似文献,搜索用时 281 毫秒
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《中国无线电电子学文摘》2004,(2)
TM53 2004020521碳纳米管超电容器组装工艺的初步探讨/王晓峰,王大志,梁吉(清华大学)11电源技术一2003,27(5)一451一454通过催化裂解法制备了碳纳米管并采用超声震荡的方法制备成板式碳纳米管电极碳纳米管材料比容量为39F·g一1,并表现出良好的功率特性.阻抗测试表明球模处理可以较明显地降低碳纳米管材料的电阻.采用多种研究方法对基于该种材料的超电容器的电化学特性进行了详细研究,并采用“Transmission line model’,模型对电极的多孔结构进行了模拟还介绍了两种超电容器组装工艺并根据该工艺制备了工型和H型碳纳米管超电容器,两种超… 相似文献
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A novel strategy based on titanate nanotubes (TNTs) for developing an electrochemical biosensor is proposed. Stable TNT films are fabricated on glassy carbon (GC) electrodes by a casting technique. Cyclic voltammetry, electrochemical impedance spectrometry, and linear‐sweep voltammetry are used to characterize the TNT membrane‐covered GC electrodes (TNT/GCs). The TNT film is shown to demonstrate selectivity by charge exclusion. The TNT film is also shown to be capable of improving the mass transport to the electrode surface and electron transfer between dopamine (DA) and the electrode. Therefore, DA exhibits a quasireversible electrochemical reaction at the TNT/GC electrode. The voltammetric signal of DA is well resolved from those of ascorbate (AA) and uric acid (UA) at the TNT/GC electrode; therefore, DA can be selectively detected in the presence of a large excess of AA and UA at physiological pH. The linear calibration curve for DA is obtained over the concentration range 0.1–30 μM in a physiological solution that contains 0.1 mM AA and 0.3 mM UA. 相似文献
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用化学方法对碳纳米管进行表面处理 ,用红外谱对处理后的碳纳米管进行表征 ,处理后的碳纳米管表面出现了活性功能团羧基。用这些碳纳米管制成电极 ,对Cd离子在硫酸钠中的电化学行为进行了分析。结果表明 ,从碳纳米管电极上可以观察到很好的、准可逆循环伏安图 ;在扫描速度为 10 0mV·s- 1时 ,氧化还原峰电位分别出现在 - 0 .6 5V和 - 0 .95V对照饱和甘汞电极(SCE)。峰电流与扫描速度的平方根成良好的线性关系 ,说明反应过程是由镉离子的扩散控制的。由循环伏安图相关的电位与扫描速度关系 ,我们导出了电子转移动力学速度参数。由于碳纳米管电极有很好的电化学活性和可重复性 ,它可以成为一种新型的分析电极材料 相似文献
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An Integrated Free‐Standing Flexible Electrode with Holey‐Structured 2D Bimetallic Phosphide Nanosheets for Sodium‐Ion Batteries
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Xiao‐Wei Wang Hai‐Peng Guo Ji Liang Jia‐Feng Zhang Bao Zhang Jia‐Zhao Wang Wen‐Bin Luo Hua‐Kun Liu Shi‐Xue Dou 《Advanced functional materials》2018,28(26)
An integrated, free‐standing, and binder‐free type of flexible anode electrode is fabricated from numerous holey‐structured, 2D nickel‐based phosphide nanosheets connected with carbon nanotubes. This electrode architecture can not only uniformly disperse the nanosheets throughout the whole electrode to avoid aggregation or detachment, but also provide an ideal sodium ion and electrolyte diffusion and penetration network with high electronic conductivity. Meanwhile, bimetallic phosphide formation by introducing secondary metal species will lead to a synergistic effect to modify the electrochemical properties. Due to the excellent compositional and structural characteristics of this electrode, it delivers superior performance. This designed flexible anode with Ni1.5Co0.5Px nanosheets demonstrates a reversible capacity of 496.4 mAh g?1 at 0.5 C and a good rate capacity of 276.1 mAh g?1 at 8 C. Meanwhile, this connected integrated network woven from carbon nanotubes can effectively restrain volumetric expansion and shrinkage, and affect the conversion reaction products formation as well, from large‐sized microspheres to film structure, which is primarily credited with the improvement in electrochemical performance. This work may open up a new path for the synthesis of morphology‐controlled phosphides and promote the further development of flexible devices. 相似文献
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Hongyu Liu Zheng-Ze Pan Alex Aziz Rui Tang Wei Lv Hirotomo Nishihara 《Advanced functional materials》2023,33(40):2303730
This study proposes a next-generation model membrane electrode for fundamental electrochemical research of amorphous-based porous carbon materials. This novel electrode is fabricated by the uniform carbon coating of anodic aluminum oxide formed on an Al substrate and free from a barrier layer. The conformally carbon-coated layer forms vertically aligned giant carbon nanotubes, and their walls comprise low-crystalline stacked graphene sheets. The diameter and the length of the nanopores can be tuned over a broad range of between 10 to 200 nm and 2 to 90 µm, respectively. Moreover, unlike composite electrodes made from other ordered nanoporous carbons, this model electrode exhibits an absence of inter-particle spacing and hence no contact resistance between particles. Thus, this model electrode provides representative nanopores of low-crystalline carbon materials. An atomic-scale structural model of the low-crystalline carbon walls is built with the aid of an in-house temperature-programmed desorption system to enable theoretical simulations to be performed. Using this model electrode, the electrical conductivity of low-crystalline carbon walls and mass transportation in an electric double-layer system are elucidated. This representative model electrode is expected to help clarify the complex electrochemical processes in porous carbon electrodes. 相似文献
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In this work, we demonstrate flexible solution processed light emitting electrochemical cells (LECs) which use single-walled carbon nanotubes (SWCNTs) films as the substrate. The SWCNTs were synthesized by an integrated aerosol method and dry-transferred on the plastic substrates at room temperature. The addition of a screen printed poly (3,4-ethylene dioxythiophene) doped with poly (styrene sulfonate) (PEDOT:PSS) film onto the nanostructured electrode further homogenizes the surface and enlarges the work function, enhancing the hole injection into the active layer. By using an efficient phosphorescent ionic transition metal complex (iTMC) as the active material, efficacies up to 9 cd/A have been obtained. These values are among the highest reported so far for light-emitting diodes employing CNTs as transparent electrode. 相似文献
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Changzhou Yuan Long Yang Linrui Hou Jiaoyang Li Yaxin Sun Xiaogang Zhang Laifa Shen Xiangjun Lu Shenglin Xiong Xiong Wen Lou 《Advanced functional materials》2012,22(12):2560-2566
A facile one‐step hydrothermal method is developed for large‐scale production of well‐designed flexible and free‐standing Co3O4/reduced graphene oxide (rGO)/carbon nanotubes (CNTs) hybrid paper as an electrode for electrochemical capacitors. Densely packed unique Co3O4 monolayer microsphere arrays uniformly cover the surface of the rGO/CNTs film. The alkaline hydrothermal treatment leads to not only the deposition of Co3O4 microspheres array, but also the reduction of the GO sheets at the same time. The unique hybrid paper is evaluated as an electrode for electrochemical capacitors without any ancillary materials. It is found that the obtained hybrid flexible paper, composed of Co3O4 microsphere array anchored to the underling conductive rGO/CNTs substrate with robust adhesion, is able to deliver high specific capacitance with excellent electrochemical stability even at high current densities, suggesting its promising application as an efficient electrode material for electrochemical capacitors. 相似文献
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Neural electrodes are designed to interface with the nervous system and provide control signals for neural prostheses. However, robust and reliable chronic recording and stimulation remains a challenge for neural electrodes. Here, a novel method for the fabrication of soft, low impedance, high charge density, and controlled releasing nanobiomaterials that can be used for the surface modification of neural microelectrodes to stabilize the electrode/tissue interface is reported. The fabrication process includes electrospinning of anti‐inflammatory drug‐incorporated biodegradable nanofibers, encapsulation of these nanofibers by an alginate hydrogel layer, followed by electrochemical polymerization of conducting polymers around the electrospun drug‐loaded nanofibers to form nanotubes and within the alginate hydrogel scaffold to form cloud‐like nanostructures. The three‐dimensional conducting polymer nanostructures significantly decrease the electrode impedance and increase the charge capacity density. Dexamethasone release profiles show that the alginate hydrogel coating slows down the release of the drug, significantly reducing the burst effect. These multifunctional materials are expected to be of interest for a variety of electrode/tissue interfaces in biomedical devices. 相似文献
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Min‐Sik Park Yong‐Mook Kang Gou‐Xiu Wang Shi‐Xue Dou Hua‐Kun Liu 《Advanced functional materials》2008,18(3):455-461
The electrochemical performances of 1D SnO2 nanomaterials, nanotubes, nanowires, and nanopowders, are compared to define the most favorable morphology when SnO2 nanomaterials are adopted as the electrode material for lithium‐ion batteries. Changes in the morphology of SnO2 are closely related with its electrochemical performance. Some SnO2 nanomaterials feature not only an increased energy density but also enhanced Li+ transfer. The correlation between the morphological characteristics and the electrochemical properties of SnO2 nanomaterials is discussed. The interesting electrochemical results obtained here on SnO2 nanomaterials indicate the possibility of designing and fabricating attractive nanostructured materials for lithium‐ion batteries. 相似文献
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Mohammadjavad Eslamian Fereshtehsadat Mirab Vijay Krishna Raghunathan Sheereen Majd Mohammad Reza Abidian 《Advanced functional materials》2021,31(49):2105358
Electrochemical devices that transform electrical energy to mechanical energy through an electrochemical process have numerous applications ranging from robotics and micropumps to microlenses and bioelectronics. To date, achievement of large deformation strains and fast responses remains challenging for electrochemical actuators wherein drag forces restrict the device motion and electrode materials/structures limit the ion transportation. Results for electrochemical actuators, electrochemical mass transfers, and electrochemical dynamics made from organic semiconductors (OSNTs) are reported. The OSNTs device exhibits high-performance with fast ion transport and accumulation in liquid and gel-polymer electrolytes. This device demonstrates an impressive performance, including low power consumption/strain, a large deformation, fast response, and excellent actuation stability. This outstanding performance stems from the enormous effective surface area of nanotubes that facilitates ion transport and accumulation resulting in high electroactivity and durability. Experimental studies of motion and mass transport are utilized along with the theoretical analysis for a variable–mass system to establish the dynamics of the device and to introduce a modified form of Euler-Bernoulli's equation for the OSNTs. Ultimately, a state-of-the-art miniaturized device composed of multiple microactuators for potential biomedical applications is demonstrated. This work provides new opportunities for next-generation actuators that can be utilized in artificial muscles and biomedical devices. 相似文献
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Patzer J.F. II Yao S.J. Wolfson S.K. Jr. 《IEEE transactions on bio-medical engineering》1991,38(11):1157-1161
Voltage polarity relay (VPR) is shown to optimize the urea oxidation rate and urea current utilization under constant current conditions in direct electrochemical urea oxidation. Direct electrochemical urea oxidation is characterized by reversible deactivation of the working electrode due to oxidation products remaining on the surface and the requirement that the working electrode potential remain below about 1.1 V relative to Ag/AgCl in order to prevent undesirable secondary electrochemical oxidations. The VPR method monitors the potential of the working electrode relative to a suitable reference and changes system polarity when the upper potential set limit is reached. Thus, what was the working electrode becomes the counter electrode and vice versa. Since urea oxidation products are desorbed from the counter electrode when its potential drops below about -0.6 V relative to Ag/AgCl, alternating electrode functions between working and counter provides cyclic electrode regeneration and continuous urea oxidation. VPR is believed to optimize constant current control for any electrochemical system that exhibits behavior similar to direct electrochemical urea oxidation. 相似文献