共查询到20条相似文献,搜索用时 62 毫秒
1.
《材料保护》2016,(Z1)
溶剂萃取技术已被广泛应用于回收和分离提纯铂族金属。磷酸三丁酯(TBP)萃取分离铂成功地应用于失效汽车催化剂富集精矿溶解液中铂的萃取分离。分别用N-正丁基异辛酰胺(BiOA)和磷酸三丁酯(TBP)作为萃取剂,研究了对铂废料电解液中铂的萃取性能。N-正丁基异辛酰胺(BiOA)的一级萃取率高达99.85%、萃取容量达20.1 g/L、用水作反萃剂的累计二级反萃率达99.5%;磷酸三丁酯(TBP)的一级萃取率达99.2%、萃取容量达16.5 g/L、用水作反萃剂的累计二级反萃率在50%左右。BiOA萃铂体系在以上3方面的性能优于TBP萃铂体系,但还需进一步做更多更深入的研究,探寻BiOA萃铂体系的工业化应用可能。 相似文献
2.
3.
溶剂萃取技术已被广泛应用于回收和分离提纯铂族金属。随着新萃取剂和新萃取体系的研究开发,贵金属萃取技术研究不断取得新的进展。用N-正丁基异辛酰胺(BiOA)作为萃取剂,研究对铂废料电解液中铂的萃取性能。在合适的萃取条件下,即酸度为4 mol/L、萃取剂浓度为2 mol/L,相改善剂磷酸三丁酯(TBP)的加入量为3vol%,萃取率达99.5%以上;用水作反萃剂,反萃率达99.2%以上。铂反萃液,通过常规的水合肼还原的方法,即可获得99.95%纯度的海绵铂。该萃取体系高效、环保,具有工业化的应用价值。 相似文献
4.
色氨酸是人体内的必需氨基酸之一。针对色氨酸的分离纯化,提出一种基于CTAB为表面活性剂的反胶团法分离纯化方法。结果表明,CTAB浓度为40mol/L;以正丁醇作为有机溶剂;异辛烷作为助表面活性剂,二者之比为1:1(V:V);萃取PH为12;萃取离子选择氯化钾;萃取浓度为0.3mol/L;反萃PH为4;反萃离子为氯化钾;萃取浓度为2mol/L,萃取时间为15min;水浴振荡250r/min;反萃时间为20min;水浴振荡250r/min;萃取温度为室温;回收率最高可以达到60%左右。 相似文献
5.
6.
钴离子在P507—CCl4液膜体系中的活性迁移 总被引:1,自引:1,他引:0
研究了在P507-CCl4大块液膜体系中,载体P507浓度、反萃液硫酸的浓度、料液pH、醋酸根浓度等因素对Co2+的活性迁移的影响.实验结果表明,载体浓度增加,Co2+的迁移通量增加.反萃液硫酸浓度增加,料液pH及醋酸根浓度适度增加均有利于Co2+的迁移.实验中观察到Co2+在膜迁移中的滞留现象,并在支撑液膜实验中测定了较大的P507浓度时Co2+的渗透系数P. 相似文献
7.
三正辛胺—二甲苯支撑液膜萃取Cd(Ⅱ)的研究 总被引:3,自引:1,他引:2
研究了Cd(Ⅱ)在三正辛胺-二甲苯支撑液膜体系中的迁移规律.结果表明,载体三正辛胺浓度显著影响Cd(Ⅱ)的渗透系数P.料液中H+浓度、Cd(Ⅱ)浓度和膜溶剂对Cd(Ⅱ)的迁移有影响.在此液膜体系中反萃剂醋酸铵比氢氧化钠好,温度升高能提高Cd(Ⅱ)的迁移速率. 相似文献
8.
以聚丙烯(PP)中空纤维膜为支撑体,二(2-乙基己基)磷酸(简称D2EHPA)为载体,煤油为膜溶剂,探讨D2EHPA-煤油-H2SO4中空纤维支撑液膜(SLM)体系对水中氨氮的传质行为.以去除率为指标,考察了料液初始氨氮浓度及pH值、载体浓度、反萃剂浓度对传质效果的影响;并通过对比实验分析了导致传质速率降低的主要原因.结果表明:在反萃剂H2SO4浓度为2 mol/L,料液相pH值在8~13范围内,提高料液pH值、增大膜相中载体浓度,均能提高氨氮的去除率.D2EHPA-煤油-H2SO4体系对氨氮的传质能力随氨氮浓度降低而下降.料液中氨氮浓度下降和pH值降低是导致氨氮传质速率降低的主要原因,调节料液pH值可调控和提高氨氮的去除与传质效果. 相似文献
9.
10.
11.
《International journal for numerical methods in engineering》2018,113(9):1488-1506
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method. 相似文献
12.
13.
Standards are the basis for production enterprises to organize production ex-factory inspection trade 《中国标准化(英文版)》2008,25(1):24-25
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.…… 相似文献
14.
Steffen Müller-Probandt 《材料科学与工程:中英文B版...》2018,(4):161-177
We associate a variety of innovations with the term "Industry 4.0". The pioneer of many 4.0 modifications forms the basisfor the trend towards the integrated di... 相似文献
15.
A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa. 相似文献
16.
On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.…… 相似文献
17.
Janet Lang 《Materials and Manufacturing Processes》2017,32(7-8):857-866
ABSTRACTThe production of ferrous metal increased during the Roman Late Republican period, Principate and Empire. The direct bloomery process was used to extract the metal from its ores using slag-tapping and slag-pit furnaces. The fuel was charcoal and an air blast was introduced by bellows-operated tuyères. Iron formed as a bloom, often as a spongy mass of metal, which contained impurities from the smelting process, including unreacted ore, fuel, slag and fragments from the furnace walls, while the metal was often inhomogeneous with varied carbon contents. Blooms were either smithed directly into bars or ingots or they were broken up, which also allowed the removal of gross impurities and a selection of pieces with similar properties to be made. These could then be forge-welded together and formed into characteristically shaped ingots. Making steel in the furnace seems to have been achieved: it depended on the ore and the furnace and conditions within it. Surface carburization was also carried out. Iron and steel were used extensively in construction and for tools and weapons. Fire welding was often used to add pieces of steel to make the edges of tools and weapons, which could be heat-treated by quenching to harden them. 相似文献
18.
Zusammenfassung Bei der Gestaltung von Ernteprozessen — beispielsweise des Prozesses Mähdrusch, Körnertransport und -abnahme — als transportverbundene Fließarbeitsverfahren mit mindestens zwei verschiedenen Arbeitsmitteln gibt es einen großen Optimierungsspielraum. Solche Prozesse sind mehrstufige Bedienungsprozesse mit gemischter Anordnung der Bedienungseinrichtungen. Außerdem besitzen sie stark ausgeprägte räumliche Aspekte. Es wird vor allem gezeigt, welche Merkmale solcher Prozesse in Simulationsmodellen abgebildet sein müssen, welche Zielgrößen in Abhängigkeit von welchen Einflußgrößen unter Berücksichtigung welcher Prozeßbedingungen ermittelt werden sollten und wie der Bewertungsprozeß zur Ermittlung der gewünschten Informationen gestaltet werden muß. 相似文献
19.
C. Qihong W. Zhan‐Wen J. Yi J. Yehua L. Fei F. Hanguang 《Materialwissenschaft und Werkstofftechnik》2014,45(7):582-590
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill. 相似文献
20.
Dimiter Hadjistamov 《材料科学与工程:中英文B版...》2019,(2):56-65
The definition of the thixotropy is a decrease in viscosity with time in shear and a subsequent recovery of viscosity after the shear deformation is removed.We ... 相似文献