Mechanical properties and microstructure of ZrO2–SiO2 composite

ZrO2–SiO2 composite powder has been prepared by a wet chemical route using zirconyl chloride and fumed silica as starting materials and subsequently sintered by the hot-pressing method to obtain a ZrO2–SiO2 ceramic. The mechanical properties of the silica matrix have been much increased by the addition of 20 vol% zirconia. The microstructural features of the composite are observed by transmission electron microscopy (TEM) and high-resolution electron microscopy (HREM). The stabilibity of tetragonal zirconia in the matrix is attributed to the particle-size effect, and to the constraint effect of the silica matrix and that of the interphasic reaction layer. The increase in mechanical properties is discussed in relation to the residual stress and the enhanced elastic modulus caused by the incorporated ZrO2 particles.     

Synthesis and characterization of chitosan–carbon nanotube composites

Acid functionalized single walled carbon nanotubes were covalently grafted to chitosan by first reacting the oxidized carbon nanotubes with thionyl chloride to form acyl-chlorinated carbon nanotubes which are subsequently dispersed in chitosan and covalently grated to form composite material, CNT–chitosan, 1, which was washed several times to remove un-reacted materials. This composite has been characterized by FTIR, 13C NMR, TGA, SEM and TEM and has been shown to exhibit enhanced thermal stability. The reaction of 1, with poly lactic acid has also been accomplished to yield CNTchitosan–g-poly(LA), 2 and fully characterized by the above techniques. Results showed covalent attachment of chitosan and chitosan–poly lactic acid to the carbon nanotubes.     

Synthesis,structure, and optical properties of Au–TiO2 composite thin films

Titanium dioxide (TiO₂) films with varying concentrations of gold particles were synthesized using pulsed DC magnetron sputtering, with the intent to develop infrared reflecting films for use on cars and planes to reduce solar heat load. Under our deposition conditions, the films are smooth (RMS roughness on the order of 1.0–2.0 nm) and consist of rutile TiO₂ with embedded gold. The average gold particle diameter on the sample surface was found to change from 60 to 200 nm as the volume fraction of gold in the films increased from 1.9 to 4.3% (3.5 to 7.9 mol% Au). The maximum reflectance of these films in the infrared region (800–2500 nm) is > 50%, compared with 30% for pure TiO₂. The Maxwell–Garnett equation does not model the reflectance data very well, due to the relatively large gold particle size. Instead, by assuming that the contribution of gold particles to the reflectance response is proportional to their projected areal fraction in an effective medium approximation, we were able to fit the observed reflectance data quite well.     

Synthesis and properties of electrodeposited Ni–B–CeO2 composite coatings

Ni–B coatings are extremely hard and wear resistant with decent anticorrosion properties which make them suitable for automotive, aerospace, petrochemical, plastic, optics, nuclear, electronics, computer, textile, paper, food and printing industries. However, further improvement in properties is essential to address more challenging requirements and new developments. In the present study, Ni–B and novel Ni–B–CeO₂ composite coatings were electrodeposited (ED) on mild steel substrates using dimethylamine borane (DMAB) as a reducing agent. A comparison of properties of Ni–B and Ni–B–CeO₂ coatings is presented to elucidate the useful role of CeO₂ addition. The structural analyses indicate that Ni–B coatings are amorphous in their as deposited state. However, addition of CeO₂ into Ni–B matrix considerably improves the crystallinity of the deposit. The surface morphology study reveals the formation of uniform, dense and fine-grained deposit in both Ni–B and Ni–B–CeO₂ composite coatings. However, Ni–B–CeO₂ composite coatings exhibit high surface roughness. The nano mechanical properties show that the addition of CeO₂ particles into Ni–B matrix results in remarkable improvement in mechanical properties (hardness and modulus of elasticity) which may be attributed to dispersion hardening of Ni–B matrix by CeO₂ particles. The electrochemical polarization tests confirm that the addition of CeO₂ improves the corrosion resistance of Ni–B coatings. This improvement in corrosion behavior may be ascribed to the reduction in active area of Ni–B coatings by the presence of inactive CeO₂ particles into Ni–B matrix.     

Joining of C/C–SiC using boron-modified phenolic resin with SiO2 and B4C additives

Abstract

Joining of carbon fibre reinforced C– SiC dual matrix composite has been realized through a reaction joining process using boron-modified phenolic resin with B₄C and SiO₂ additives. The effect of the technological parameters on the strength of joints was investigated. The optimized technological parameters are the curing temperature of 200°C, the curing time of 2 hours and the curing pressure of 30 kPa, under which conditions, the obtained strength of the joint is equal to 82.6% of that of the substrate. The interlayer composed of Si, C, B and O is basically uniform and dense. There are no obvious cracks nor pores at the interfaces. The elements migrate across the interfaces, contributing to the enhancement of the joint strength. The results of heat treatment at 1500°C show good heat resistance of the joints. The B₄C and SiO₂ additives contribute to the densification of the interlayer and the adhesion at the interfaces.     

Synthesis and characterization of gold–polypyrrole film composite

Polypyrrole (PPy) coatings have potential applications in batteries, fuel cells, sensors, anti-corrosion coatings, and drug delivery systems. In this article, PPy film coating on the electrode of quartz crystal microbalance (QCM) was exposed to acidic aqueous HAuCl₄ solution. The reduction for gold ions took place and gold particles were produced at the film surface. The gold content at the PPy film was monitored by using QCM. The concentration of gold uptake increases as the original concentration of HAuCl₄ solution increases. The morphology of the film before and after the deposition of the gold particles was studied by the scanning electron microscopy coupled with energy dispersive X-ray spectrometry. The gold particles are of undefined shape and have diameters around 200–600 nm. However, the image of the composite powder shows that gold particles of sizes 100–120 nm are distributed over the surface of the polymer particles with some aggregation. Infrared spectroscopy and X-ray diffraction were used to characterize the composite.     

Photocatalytic degradation of gaseous toluene over TiO2–SiO2 composite nanotubes synthesized by sol–gel with template technique

TiO₂–SiO₂ composite nanotubes were successfully synthesized by a facile sol–gel technique utilizing ZnO nanowires as template. The nanotubes were well characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, N₂ adsorption–desorption analysis and UV–vis diffuse reflectance spectroscopy. The nanotubular TiO₂–SiO₂ composite photocatalysts showed diameter of 300–325 nm, fine mesoporous structure and high specific surface area. The results indicated that the degradation efficiency of gaseous toluene could get 65% after 4 h reaction using the TiO₂–SiO₂ composite as the photocatalyst under UV light illumination, which was higher than that of P25.     

Design,preparation and properties of online-joints of C/SiC–C/SiC with pins

This work is aimed at providing a new joining technology for C/SiC composites and investigating the influence of drilling holes, hole distribution (including ratios of edge distance to diameter (E/D), width to diameter (W/D) and hole distance to diameter (H/D)) and the number of applied pins on the mechanical properties of C/SiC substrates and joints. The mechanical testing results show that drilling holes and hole distribution greatly affects the mechanical properties of C/SiC substrates but when adopting an optimized design principle (E/D ⩾ 3, W/D ⩾ 3 and H/D ⩾ 3) the effect could be neglected. 1D C/SiC pins with higher shearing strength (107.2 MPa) are more suitable to join the substrates. With the increase of pins (1, 2 and 4), the bearing loads of the joints increase almost linearly, and the reliability of joints is also improved in that the fracture mode changes from the interlayer damage to the substrate rupture. Besides, the joining process generates uniform and dense joining layer (composition of ZrC and SiC) and a strong bonding without obvious interface.     

Properties of a composite multilayered hard coating Zr–ZrN

Mechanical and tribotechnical characteristics of composite multilayered coatings Zr–ZrN in air at temperatures from 20 to 900°C have been determined. The coefficient of friction of the Zr–ZrN coating against steel 65G has been found to exhibit a tendency toward decreasing as the velocity is lowered and the load is raised from 10 to 30 kgf. A study of properties of the coatings in the range between 20 and 900°C has demonstrated that hardness under a load of 1 kgf goes down gradually from 19 to 3.2 GPa. Hardness along the friction trace has been found to grow from 23 to 25 MPa, while hardness of the counterbody has increased twofold (from 4.5 to 9.0 GPa). The coefficient of friction of the composite multilayered coating Zr–ZrN against diamond at a velocity of 16 mm/s has been determined to range between 0.26 and 0.28.     

Synthesis and properties of light weight magnesium–cenosphere composite

Significantly light weight magnesium composite foams are synthesised by addition of fly ash cenosphere particles (waste from coal-fired power plants) in biocompatible pure magnesium using solidification-based disintegrated melt deposition technique. The density of the composite foams synthesised in this study approaches that of plastics- and polymer-based composites. Microstructure development of Mg/cenosphere composite foams was favourable as they exhibited better dimensional stability (reduced coefficient of thermal expansion) and remarkable improvements in tensile strengths, compressive strengths, compressive total strain and microhardness. The present study highlights the processing, microstructure and mechanical properties of Mg/cenosphere composite foams which hold great potential as light weight metal-based green materials for diverse weight critical applications spanning from engineering to biomedical sector.     

Synthesis of clay–carbon nanotube hybrids: Growth of carbon nanotubes in different types of iron modified montmorillonite

In the present study, montmorillonite–carbon nanotube hybrids were synthesized by catalytic decomposition of ethylene over iron montmorillonite surfaces modified by different experimental procedures. SEM and STEM analyses reveal the presence of carbon nanotubes attached to the clay layers and X-ray diffraction results indicate that sodium montmorillonite layers were intercalated with iron species during the ion-exchange processes and further delaminated due to the growth of carbon nanotubes. It is expected that montmorillonite–carbon nanotube hybrids will be beneficiary for improvement of mechanical properties in polymer nanocomposites due to their pre-exfoliated internal structure and the presence of surface carbon nanotubes which may significantly enhance reinforcing effect.     

The effect of additives on Al2O3–SiO2–SiC–C ramming monolithic refractories

Abstract

The aim of this study is to describe the effect of containing additives on increasing cold crushing strength (CCS) and bulk density (BD) of Al₂O₃–SiO₂–SiC–C monolithic refractories. Two series of carbon containing monolithics were prepared from Iranian chamotte (Samples A) and Chinese bauxite (Samples B), as 65 wt.% in each case together with, 15wt.% SiC-containing material regenerates (crushed sagger), 10 wt.% fine coke (a total of 90% aggregate) and 10 wt.% resole (phenol formaldehyde resin) as a binder. Different types of additives (such as silicon and ferrosilicon metal) are added to a batch of 100 g of mixture and the physical and mechanical properties (such as BD, apparent porosity and CCS) are measured after tempering at 200°C for 2 h and firing at 1100°C and 1400°C for 2h. After low temperature tempering at 200°C, silicon and ferrosilicon contribute to the formation of stronger cross linking in the resulting structure and provides CCS values as high as 65 MPa. After high temperature sintering, at 1400°C, SiC whiskers of nano sized diameter are formed due to the presence of Si and FeSi₂ and increases the CCS values of the refractories as high as 3–4 times in sample containing 6wt.% ferrosilicon metal as additive, compared to the material without additive. The temperature of 1100°C is a transient temperature, used in high temperature sintering.     

Synthesis,characterization and in vitro bioactivity of sol-gel-derived SiO2–CaO–P2O5–MgO bioglass

In this study, the synthesis of SiO₂–CaO–P₂O₅–MgO bioactive glass was performed by the sol-gel method. Sol-gel-derived bioglass material was produced both in powder and in discs form by uniaxial pressing, followed by sintering at 700 °C. The obtained material was evaluated by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), thermal gravimetric analysis (TGA) and differential scanning caloremetry (DSC) analyses. The biocompatibility evaluation of the formed glass was assessed through in vitro cell culture [alkaline phosphatase (AP) activity of osteoblasts] experiments and immersion studies in simulated body fluid (SBF) for different time intervals while monitoring the pH changes and the concentration of calcium, phosphorus and magnesium in the SBF medium. The SEM, XRD and FTIR studies were conducted before and after soaking of the material in SBF. At first, an amorphous calcium phosphate was formed; after 7 days this surface consisted of deposited crystalline apatite. The present investigation also revealed that the sol-gel derived quaternary bioglass system has the ability to support the growth of human fetal osteoblastic cells (hFOB 1.19). Finally, this material proved to be non-toxic and compatible for the proposed work in segmental defects in the goat model in vivo.     

Tension–compression fatigue of a SiC/SiC ceramic matrix composite at 1200 °C in air and in steam

Tension–compression fatigue behavior of a non-oxide ceramic composite with a multilayered matrix was investigated at 1200 °C in laboratory air and in steam. The composite was produced via chemical vapor infiltration (CVI). The composite had an oxidation inhibited matrix, which consisted of alternating layers of silicon carbide and boron carbide and was reinforced with laminated woven Hi-Nicalon™ fibers. Fiber preforms had pyrolytic carbon fiber coating with boron carbide overlay applied. Tension–compression fatigue behavior was studied for fatigue stresses ranging from 80 to 200 MPa at a frequency of 1.0 Hz. Presence of steam significantly degraded the fatigue performance. Specimens that achieved fatigue run-out were subjected to tensile tests to failure to characterize the retained tensile properties. The material retained 100% of its tensile strength. Composite microstructure, as well as damage and failure mechanisms were investigated.     

Investigation of corrosion and mechanical properties of Al–Cu–SiC–xNi composite alloys

In this study, dry sliding wear behavior and corrosion resistance of Al–Cu–SiC–xNi (x: 0, 0.5, 1, 1.5 wt.%) composites were investigated. Effect of nickel content on the microstructure and hardness of the alloys was also studied. Wear tests were conducted using a ball on disc wear test device. Corrosion behavior of Al–Cu–SiC–xNi composite alloys in 3.5% NaCl solution was investigated by using potentiodynamic polarization, impedance spectroscopy and cronoamperometric methods. The results showed that the hardness of the composite alloy increases with increasing nickel content. Maximum wear resistance is reported with the addition of 1 wt.%Ni. It was determined that corrosion resistance of Al–Cu–SiC composite alloys improved with increasing nickel content in the alloy.     

Synthesis and some properties of Ti3SiC2 by hot pressing of Ti,Si and C powders Part 2 – Mechanical and other properties of Ti3SiC2

Abstract

Some properties of the remarkable Ti₃SiC₂ based ceramic synthesised by hot pressing of elemental Ti, Si, and C powders have been investigated. Its flexural strength by using three point bending tests and fracture toughness by using single edge notched beam tests were measured at room temperature to be in the range 310–427 MPa and about 7·MPa m^1/2, respectively. This material is a relative 'soft' ceramic with a low hardness of 4 GPa. Ti₃SiC₂ is similar to the soft metals and is a damage tolerant material that is able to contain the extent of microdamage. An oxidation test has been performed in the temperature range 1000–1400°C in air for 20 h. The oxidation resistance below 1100°C was good. Two oxidized layers were formed, the outer layer consisting of pure rutile-type TiO₂, and the inner layer a mixture of SiO₂ and TiO₂. The average coefficient of thermal expansion (CTE) of Ti₃SiC₂ was measured to be 9·29 × 10^?6 K^?1 in the temperature range 25–1400°C. The thermal shock resistance of Ti₃SiC₂ was evaluated by quenching the samples from 800°C, 1200°C, and 1400°C, respectively. The retained flexural strength drops dramatically at quenching temperature, but shows a slight increase after quenching from 1400°C compared with quenching from 800°C and 1200°C.