Testing the robustness of CIECAM02

CIE TC8‐01 has adopted a new color appearance model: CIECAM02¹ replaces the CIECAM97s.² The new model consists of a number of refinements and simplifications of the CIECAM97s color appearance model. This article describes further tests to the robustness of the forward and reverse modes. © 2005 Wiley Periodicals, Inc. Col Res Appl, 30, 99–106, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20087     

Refined CIECAM02 for bright surround conditions

Displays such as mobile phones are viewed under surround conditions that vary from dark night to bright sunlight. The overall goal of this study is to test the appropriateness of CIECAM02 for mobile displays, and modify it according to any insufficiency found. Firstly, the testing of CIECAM02 is described using the visual data from 2‐inch display of three achromatic backgrounds (gray, black, and white), and three surround conditions (dark, dim, and average). Secondly, CIECAM02 was tested under four surround conditions (dark, dim, average, and bright), and three displays (2‐, 4‐, and 7‐inch), with only the gray background used, to focus more on the surround conditions. Those twelve experimental phases were used to refine CIECAM02, considering the surround factors. The surround parameters (c, F, and N_C) were optimized, and N_cb was modified from the CIECAM02; the modified model is named MobileCAM‐v1. Colourfulness prediction by MobileCAM‐v1 has been improved, especially for a black background under average surround condition. A further refined version of CIECAM02, MobileCAM‐v2, was developed, for mobile displays viewed under different surround conditions. A set of equations based on surrounding conditions was first derived, to be able to accurately define surround parameters. The MobileCAM‐v2 model gave the largest improvement in brightness, followed by lightness, and with colourfulness the smallest. The improvement is significant for bright surround conditions, improving the performance of CIECAM02 in predicting the visual results. © 2014 Wiley Periodicals, Inc. Col Res Appl, 40, 114–124, 2015     

The structure of the CIE 1997 Colour Appearance Model (CIECAM97s)

The components comprising the CIE 1997 Colour Appearance Model, CIECAM97s, are described, and the steps needed to implement it in both forward and reverse modes are listed. A worked example is also given. © 1998 John Wiley & Sons, Inc. Col Res Appl, 23, 138–146, 1998     

CMC 2000 chromatic adaptation transform: CMCCAT2000

CMCCAT97 is a chromatic adaptation transform included in CIECAM97s, the CIE 1997 colour appearance model, for describing colour appearance under different viewing conditions and is recommended by the Colour Measurement Committee of the Society of Dyers and Colourists for predicting the degree of colour inconstancy of surface colours. Among the many transforms tested, this transform gave the most accurate predictions to a number of experimental data sets. However, the structure of CMCCAT97 is considered complicated and causes problems when applications require the use of its reverse mode. This article describes a simplified version of CMCCAT97— CMCCAT2000—which not only is significantly simpler and eliminates the problems of reversibility, but also gives a more accurate prediction to almost all experimental data sets than does the original transform. © 2002 John Wiley & Sons, Inc. Col Res Appl, 27, 49–58, 2002     

Image color-appearance specification through extension of CIELAB

An extension of the CIE 1976 (L*, a*, b*) color space, CIELAB is described for applications in color reproduction. This extension incorporates a more accurate model of chromatic adaptation, capability to distinguish between the modes of appearance of reflective and self-luminous stimuli, and adjustments to account for changes in surround. The extension of CIELAB is referred to as the RLAB color space. This color space can be used for calculating metrics of lightness, chroma, hue, and color difference. It can also be used to determine the required colors for reproduction across changes in media and viewing conditions. A pilot experiment testing the RLAB model for cross-media color reproduction is also described.     

Sorption and transport of CO2 above and below the glass transition of poly(ethylene terephthalate)

At temperatures at least 30°C above the glass transition (T_g) the sorption and transport of carbon dioxide in poly(ethylene terephthalate) (PET) can be described conveniently using Henry's law and Fick's law with a constant diffusion coefficient. Below T_g Fick's law with a concentration- dependent diffusion coefficient, coupled with a sorption isotherm which is concave toward the pressure axis adequately describes the observed sorption and transport data. Physical interpretations of the quantitative deviations from Henry's law and the form of the concentration dependence of the diffusion coefficient is provided by a model which hypothesizes dual modes of sorption and separate non zero mobilities of two populations of sorbed species in local equilibrium. The implications of the observed temperature variations of the phenomenological model parameters are discussed. Dilatometric parameters for PET, polycarbonate, and poly(acrylonitrile) (PAN) are shown to correlate well with a simple. relationship developed to explain the existence of the “extra” mode of sorption responsible for deviations from Henry's law for CO in glassy polymers. In the temperature range from T_g to + 20°C, deviations from Fickian behavior are also apparent. These effects are consistent with a transition in the nature of the polymer from an elastic solid below T_g to a viscous liquid above T_g In the narrow temperature range slightly above T the time scale for chain rearrangements apparently approaches that for the diffusion process. The polymer's viscoelastic response to the probing molecule, therefore, causes deviations from the classical time lag predictions. These deviations disappear 30°C above T_g.     

Extraction of aminoglycoside antibiotics with reverse micelles

The reverse micelle system of sodium di-2-ethylhexyl phosphate was used to extract aminoglycoside antibiotics, neomycin and gentamicin. The aminoglycosides can be efficiently extracted into a reverse micelle solution, and the antibiotics extracted into the micelle phase can readily be recovered back to a divalent cation aqueous solution, such as Ca²⁺. The transfer efficiency, %E, is heavily dependent on pH and salt concentration in the aqueous feed solution. %E decreases drastically with pH in the pH range 8·5–11, and declines with increasing (NH₄)₂SO₄ concentration. A simple transfer mechanism was proposed which suggests that the antibiotic molecules were extracted into the inner water cores of reverse micelles through attractive electrostatic interaction during forward transfer. In backward transfer, the antibiotics loaded in the micelle phase are released back to an aqueous phase through breaking up of the reverse micelles by using divalent cation solutions. The model is supported by the results of dynamic light scattering and infra-red spectroscopy study.     

Further investigation on the modified hyperbolic function in the CAM16 color appearance model

In the International Commission on Illumination (CIE) color appearance model CIECAM02, a modified hyperbolic function is used to represent luminance adaptation. The same nonlinear function is also used in the new color appearance model CAM16 [Color Res Appl., 2017;42:703‐718]. Although the modified hyperbolic function seems reasonable based on physiological evidence, it has an infinite slope at the origin, which causes instability for both the forward and inverse modes of the CIECAM02/CAM16 models. In this article, various possible extensions to the nonlinear luminance adaptation function in CIECAM02/CAM16 are reviewed and evaluated. Based on these investigations, the Gill extension to the hyperbolic function that is used to represent luminance adaptation [Proceedings of 16th Color and Imaging Conference, pp. 327‐331, 2008], is recommended at both the lower end (q < q_L ) and the upper end (q > q_U ), where q is the appropriate R_c , G_c , B_c (or R_wc , G_wc , B_wc ) response. In addition, the new recommended function can be readily inverted for use in the appropriate inverse appearance model. From an extensive analysis using available experimental data sets, we also propose that, for the lower and upper limits of the luminance range in the extended model, the values q_L = 0.26 and q_U = 150 be used, respectively.     

Cracking energy density for rubber materials: Computation and implementation in multiaxial fatigue design

This article proposes a heuristic model to predict the fatigue life of rubber parts. The developed model is mainly based on the Cracking Energy Density (CED), originally developed by Mars, for the study of rubber parts fatigue. The main contribution consists in the integration of the theoretical framework of the critical plane analysis proposed by Mars with Saintier's experimental research carried out in tension and torsion modes. The CED parameter, derived from the Strain Energy Density (SED), can predict the occurrence of the first crack and its possible orientation depending on the type of loading path. In this context, an analytical analysis of this parameter is carried out for typical loading cases. Furthermore, the variation of CED by SED ratio (W_C/W), as a function of the probable crack angle θ and the principal stretch λ₁ is investigated. A finite element (FE) model is, then, developed to measure the performance and efficiency for some basic criteria used to investigate rubber fatigue life in literature. The pertinence of such criteria is evaluated in terms of a determination coefficient. The CED parameter can be considered as the most effective criterion for describing the multiaxial fatigue life of rubbers.     

A dissolution—precipitation model for metal passivation

Kinetic equations for the passivation of metals are developed under the activation and diffusion controlled conditions. In various activation conditions, four Tafel slopes have been derived theoretically. In The diffusion controlled reaction, the kinetics depended on the rate constants for the forward and backward directions in the passive film growth process. If the forward rate constant is much smaller than the backward rate constant, the log of current was linearly related to the log of(time)^?1/2, and the current approached zero after a long anodizing time. However, in the reverse case, the log of current was proportional to the log of (time + constant)^?1/2 in a short passivation time; however, current did not approach zero but a constant after a long anodizing time.     

Vector-based modelling of colour difference: a pilot study of the DE2000 colour difference model

A novel approach to colour difference modelling is presented whereby for any given CMC (1:1) or CIE DE2000 ∆E, ∆C, ∆H, and ∆L colour difference, the equivalent CIE XYZ, L*a*b*, and L*C*h coordinate changes are derived by optimising the input RGB stimuli from which they are all calculated. Single-dimension L or C or H difference loci expressed in DE2000 difference units are thus generated, and the additive equivalence of tristimulus values is likewise projected forward onto each locus and also onto a set of CIE DE2000 three-unit ellipse boundaries. Using the datasets thus generated, it is then shown firstly that the derived ellipses have well-defined semi-axes, which explain the detailed orientation of the MacAdam ellipses in x,y,Y space. Unit CIE DE2000 difference is confirmed as a successful quantifying constant of visual difference over a wide range of chroma, hue, and lightness differences. As a constant, CIE DE2000 unit difference is shown to have a significantly variable value at high and low chroma: evidence is established for systematic changes in both chroma and hue difference sensitivity. A hitherto unresolved non-linearity is revealed in the C* dimension of L*C*h space that is not replicated in the CIE DE2000 model. The derived difference loci appear to specify physically reproducible experimental stimuli that could be used in the estimation of visual difference magnitude. Overall, the data derived by the new approach and presented in this paper increase the probability that a true vector model of the visual difference response may eventually be derived.     

Simplified theory for linear rheology of monodisperse linear polymers

A new version of the tube theory based on the de Gennes–Doi–Edwards reptation concept (reported in Likhtman and McLeish's work published in 2002) is evaluated, modified to allow for simplified computations, and used to study the relationship between zero‐shear viscosity and molecular weight for monodisperse entangled linear homopolymers. The Likhtman–McLeish model combines self‐consistent theories for contour length fluctuations and constraint release with reptation theory for monodisperse linear polymers. Because of the nature of the Rubinstein and Colby approach used for the treatment of constraint release, the related term is probabilistic and requires stochastic simulations for the calculation of the relaxation modulus G(t). This makes the Likhtman–McLeish model computationally difficult to use. In this work we solve this problem by generating an approximate closed‐form solution for the stochastic term. Then analytical integration of the relaxation modulus function G(t) provides an expression for the zero‐shear viscosity (η₀). Results of the computations of the zero‐shear viscosity and of the slope of η₀ versus molecular weight are compared with available experimental data for monodisperse entangled linear polystyrene and polyethylene (hydrogenated polybutadiene). The model is a major improvement over previous theoretical models, even if there is still some disagreement between the predictions and experimental data of the slope of η₀ versus molecular weight. The possibility of inferring monomer chemistry–dependent parameters from the zero‐shear viscosity remains a difficult task because of the introduction of a constraint‐release parameter. Nevertheless, the model is a useful tool for the prediction of linear viscoelasticity data. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 569–586, 2004     

Color discrimination results from a CRT device: Influence of luminance

In this article, we report new color discrimination ellipsoids calculated from two normal observers, using a CRT device and five values of luminance at each of the five centers recommended by the CIE in 1978 (Col Res Appl 1978;3:149–151). Our main goal was to test the weighting function for lightness adopted by the CIE94 color‐difference model (CIE Publication 116, 1995). Although some of the experimental conditions employed here (CRT monitor, small size of the visual field, and controlled exposure time) did not fit those recommended by this model, our results support the weighting function for lightness proposed by CIE94. The only robust trends observed in the ellipsoids obtained were a confirmation of Weber's law and a decrease in the area of the x, y chromaticity ellipses, when the luminance of each reference stimulus increased towards the one of the surround. © 1999 John Wiley & Sons, Inc. Col Res Appl, 24, 38–44, 1999     

Copolycondensation of IPA/TPA,BPA, and 4,4′‐dihydroxydipehnylsulfone and 4,4′‐dicarboxydiphenylsulfone

Copolycondensations of IPA, TPA, bisphenol A (BPA), and several cimonomers were carried out to improve thermal properties, such as, the glass transition temperature (T_g) of the IPA/TPA (50/50)–BPA polyester. Among the comonomers examined, 4,4′‐Dihydroxydiphenylsulfone (BPS) and 4,4′‐Dicarboxydiphenylsulfone (DCDPS) having a strongly dipolar sulfonyl group in the chain were significantly effective. The favorable effect upon the T_gs was studied by varying the amounts of BPS and DCDPS incorporated into the copolymers. In the copolycondensation with BPS, two‐stage copolycondensation of BPA first and then BPS, the reverse order of reaction, and their spontaneous addition were examined to investigate the effect of distribution of the BPS unit segments in the copolymer upon the T_gs of the resulted copolymers. The distribution was briefly studied from distribution of the IPA/TPA‐BPA oligomers in the initial reaction using GPC. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 875–879, 2000     

Glass‐transition temperature–conversion relationship for an epoxy–hexahydro‐4‐methylphthalic anhydride system

The DGEBA–MHHPA epoxy system has found increasing applications in microelectronics packaging, making crucial the ability to understand and model the cure kinetics mechanism accurately. The present article reports on work done to elucidate an appropriate model, modified from the empirical DiBenedetto's equation, to relate the glass‐transition temperature (T_g) to the degree of conversion for a DGEBA–MHHPA epoxy system. This model employs the ratio of segmental mobility for crosslinked and uncrosslinked polymers, λ, to fit the model curve to the data obtained. A higher ratio value was shown to indicate a more consistent rate of increase of T_g in relation to the degree of conversion, while a lower value indicated that the rate of T_g increase was disproportionately higher at higher degrees of conversion. The best fit value of λ determined by regression analysis for the DGEBA–MHHPA epoxy system was 0.64, which appeared to be higher than for those previously obtained for other epoxy systems, which ranged from 0.43–0.58. The highest T_g value obtained experimentally, T_{g max}, was 146°C, which is significantly below the derived theoretical maximum T_g∞ value of 170. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 511–516, 2000     

Theoretical Vibrational Spectra of Carbon Fullerenes

This article investigates the stretching vibrational modes of carbon fullerenes (C₂₄, C₂₈, C₃₂, and C₅₀) by using one-dimensional U(2) algebra. Considering the molecular symmetry, the model Hamiltonian is constructed which is able to describe the fundamental “stretching modes” of the physical system with less number of algebraic parameters. The calculated energies find an excellent agreement with the theoretical data of harmonic force constant calculation.     

Asymptotics for stationary very nearly unit root processes

Abstract. This article considers a mean zero stationary first‐order autoregressive (AR) model. It is shown that the least squares estimator and t statistic have Cauchy and standard normal asymptotic distributions, respectively, when the AR parameter ρ_n is very near to one in the sense that 1 ? ρ_n = o(n^?1).     

Kinetics of Pressure Cycling Extraction of Solute from Leaves of Mate (Ilex paraguariensis) Dispersed in Water

A set of seven extraction experiments was performed to investigate the influence of pressure cycles on the kinetics of solute removal from leaves of mate dispersed in water. The mass ratio of liquid to dry solid (40), the temperature (32°C), and time of extraction (3600?s) were not varied. Five extraction runs were under cyclic pressurization (1?cycle?=?300?s at 91.4?kPa?+?300?s at 182.8?kPa) and stirring speeds (S) of 0, 150, 500, 1500, and 2000?rpm, while the two other ones were at constant pressure (182.8?kPa) and S close to 1500 and 2000?rpm. Based on seven pairs of parameters of a reliable second-order kinetic model (R²?≥?0.967), cyclic pressurization had no effect on equilibrium and kinetics of extraction (p?>?0.05) when the role of convection on solute transfer was negligible (S?≥?500?rpm). In the stirring speed range from 500 to 2000?rpm, the operation was controlled by diffusion (Bi >?1.7?×?10³), so a transient two-dimensional diffusion model was able to describe correctly the changes of solute concentration with time. Below 500?rpm, solute transfer was governed by a combination of diffusion and convection with the external resistance to mass transfer as a function of S (16?≤?Bi?≤?28).     

Technical Analysis of an Eco‐Friendly Hybrid Plant With a Microgas Turbine and an MCFC System

This article refers to a Molten Carbonate Fuel Cell (MCFC) system coupled to a plant with a microgas turbine and a heat recovery system for obtaining a small sized hybrid system in co‐generative arrangement. MCFC are devices capable of concentrating carbon dioxide (CO₂) produced in anode exhaust gases. If they are handled conveniently, it is possible to separate and store the surplus CO₂ produced by the plant instead of emitting it into the atmosphere. From the simulation model of the MCFC system, previously developed by the authors, a zero‐dimensional and stationary simulation model for the whole hybrid system was formulated and implemented in the same language. By the simulation model of the MCFC system it has been possible to make a parametric analysis of the hybrid plant to find some optimal operating conditions of the fuel cell(s) that maximise the performance of the entire hybrid plant. In addition, the separation of the CO₂ surplus produced by the hybrid plant was simulated by the model and then the emissions of carbon monoxide (CO) and nitrogen oxides (NO_x) from the same plant were evaluated.