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以球磨为机械活化方式,以氢氧化钠和硫酸钠为两种激发剂,通过正交试验,研究了球磨时间和激发剂用量对粉煤灰活性影响,以及活化后不同掺量的粉煤灰对胶砂试块强度的影响。XRD和粒度测试结果表明:随着球磨时间的增长,粉煤灰细度增大,降低了粉煤灰中SiO_2结晶峰的高度,从而提高粉煤灰活性;正交试验结果表明:Na_2SO_4激发效果更好,在激发剂掺量为3%,球磨时间在90 min以上时,可以有效地提高粉煤灰活性,且增加活性后的粉煤灰掺量范围可扩大至40%而保证了胶砂试块的强度损失控制在20%以内,很大程度的提高了该粉煤灰的使用率。 相似文献
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本文作者采用化学激活法,将Ⅲ级粉煤灰以不同掺量制作水泥粉煤灰胶砂,先进行FJ激发剂加入前后的对比试验;再进行加入FDN高效减水剂,FJ激发剂加入前后的对比试验,对比各龄期强度。通过对比试验探讨在FJ激发剂作用下,低品质粉煤灰在水泥胶砂中的活性变化情况,为其在混凝土中的进一步推广应用提供参考。 相似文献
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多种激发剂,在不同掺量时对粉煤灰-水泥胶砂体系抗压强度的影响.试验结果表明:掺加适量的激发剂可以提高粉煤灰的火山灰活性,不同激发剂对不同龄期粉煤灰活性的激发作用不同,以 2%掺量的氯化钙、硫酸钠、氢氧化钙的增强效果较为理想. 相似文献
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研究了60 Co-γ射线对粉煤灰活性激发的可行性、影响因素及激发机理.结果表明:在粉煤灰中加入石灰和化学激发剂,60Co-γ射线才能有效激发粉煤灰活性6;0Co-γ射线辐照对粉煤灰活性激发不受粉煤灰种类的限制,但对化学激发剂有选择性,试验条件下辐照剂量应控制在100kGre以下6;0Co-γ射线和化学激发剂共同作用对粉煤灰活性激发具有超叠加效应6,0Co-γ射线辐照提供的有效能量可使粉煤灰中玻璃体网状结构处于高能状态,与此同时该网状结构又被化学激发剂所破坏,从而加快了活性SiO2和Al2O3的反应速度,对粉煤灰早期强度的激发效果明显. 相似文献
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通过物理球磨,化学激发剂两种活化方式共同来改善新疆当地的一种矿粉活性。使用正交试验,研究了球磨时间和激发剂用量对该矿粉活性影响,以及活化后矿粉掺量对胶砂试块强度的影响。试验结果表明:Na_2SO_4对该矿粉的激发效果更好,当激发剂掺量为3%,球磨时间在90~100 min时,可以有效地提高矿粉活性,且增加活性后的矿粉掺量范围扩大40%~50%,仍可以增加胶砂试块标准及后期强度,很大程度的提高了该矿粉的使用率。微观测试表明,激活后的矿粉提高了胶砂密实度,改善了胶材对砂的包裹性能,有利于钙矾石晶体的生长,促进了水泥水化。 相似文献
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低品质活性矿物掺合料透水混凝土试验研究 总被引:2,自引:0,他引:2
通过试验研究了低品质活性矿物掺合料透水混凝土的基本性能,包括单掺低品质硅灰、单掺低品质粉煤灰、双掺低品质硅灰和粉煤灰。宏观上测试了抗压强度、抗折强度、孔隙率和透水系数;微观上用SEM观测了胶结层的微观结构、用EDS观测了胶结层的化学组成。试验结果表明:在普通透水混凝土中掺入一定量的低品质活性矿物掺合料替代部分水泥是可行的;单掺低品质硅灰效果最佳、掺量可在6%左右单掺低品质粉煤灰次之、掺量可在15%左右;单掺低品质硅灰透水混凝土和单掺低品质粉煤灰透水混凝土强度等级为C15左右,孔隙率均不低于20%,透水系数均不低于20×10~(-2)cm/s,可以满足一般轻交通路面的应用条件。 相似文献
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本文采用机械湿磨与化学激发剂的复合激发技术,制备得到高活性湿排粉煤灰料浆,并研究了不同化学激发剂、干磨和湿磨粉磨方式对湿排粉煤灰活性激发的影响以及水化产物(SEM)的变化。研究表明,复合化学激发剂Na2SO4+Ca(OH)2具有良好的活性激发效果,SEM显示7d改性湿排粉煤灰已参与二次水化反应,而激发剂Na(OH)+Ca(OH)2,水化生成大量的Ca(OH)2,对强度不利。湿磨比干磨具有更好的粉磨及活性激发效果,且湿磨对混凝土的坍落度损失影响小。通过复合激发的湿排粉煤灰料浆活性高于普通Ⅱ粉煤灰。 相似文献
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活性粉末混凝土(RPC)由于具有超高强度、韧性及耐久性而得到快速推广应用。采用0.14的极低水胶比制备200 MPa的RPC,并测试硅灰和粉煤灰对RPC强度和微结构的影响。研究结果表明:RPC的强度随着硅灰掺量的增加呈现先增大后减小的趋势,随着粉煤灰掺量的增加而减小,适量的硅灰掺量和较小的粉煤灰掺量有助于RPC获得较高的强度。硅灰和粉煤灰均具有较高的填充效应和火山灰活性,其活性二氧化硅可与氢氧化钙水化生成水化硅酸钙,尤其是颗粒极细的硅灰,可大幅改善浆体微结构,提高RPC的强度。 相似文献
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研究了不同球磨时间的粉煤灰对水泥胶砂性能的影响,结果表明:粉煤灰经过球磨后,细度增加,活性提高。在水泥中添加经过球磨的粉煤灰可以增加水泥的强度,并且安定性合格。当粉煤灰球磨时间在20 min,掺加量在20%~30%时能够显著提高水泥的强度。 相似文献
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《Construction and Building Materials》2010,24(6):1086-1093
The alkali activation of one low calcium hard coal fly ash and four high calcium lignite coal fly ashes was studied by means of conduction calorimetry, X-ray diffraction, thermogravimetric analysis and scanning electron microscopy to assess their potential for mortar and concrete production. The ashes were activated by different additions of sodium silicate with a molar SiO2/Na2O ratio of 1.0. Besides the chemical analysis of the hydrated samples, strength tests have been carried out on mortars, applying different curing regimes. The results indicate that a high content of vitreous phase and low calcium content are important factors determining the reactivity and performance of fly ashes in alkali activated systems. In the high calcium fly ashes, less alkali aluminate silicate hydrates and a much more porous microstructure are formed compared to the low calcium fly ash. Consequently, the low calcium fly ash seems to be suited best for the production of building materials. 相似文献
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基于掺加高钙粉煤灰的力学性能与抗渗性能试验,对外掺氧化镁膨胀剂普通混凝土的性能进行研究。分别加入10%、20%和30%的高钙粉煤灰,混凝土早期强度较低,后期强度增长较快,增长率大于未加掺合料的试体。加入高钙粉煤灰可大幅提升混凝土的密实度和孔隙结构,改进混凝土的抗渗性能。高钙粉煤灰的加入促进了轻集料最佳表面结构的形成,使结构更细密,是提高混凝土抗渗性的有效途径。 相似文献
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《Construction and Building Materials》2005,19(3):243-247
In present paper fly ash in wet state with low quality was used as raw material to replace clay to make fired bricks. The effect of fly ash with high replacing ratio of clay on firing parameters and properties of bricks were studied. The results indicate that the plasticity index of mixture of fly ash and clay decrease dramatically with increasing of replacing ratio of fly ash. Additive A can be chosen to improve the plasticity index of mixture to meet plastic extrusion used in most brick making factories. The sintering temperature of bricks with high replacing ratio of fly ash was about 1050 °C, which is 50–100 °C higher than that of clay bricks. The properties of fired bricks were improved by using pulverized fly ash. The fired bricks with high volume ratio of fly ash were of high compressive strength, low water absorption, no cracking due to lime, no frost and high resistance to frost-melting. 相似文献
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粉煤灰品质指标的解读与灰质评价标准的分析 总被引:5,自引:2,他引:5
本文阐述了烧失量、SO3、细度和需水量比等品质指标对粉煤灰质量的影响。烧失量与细度影响粉煤灰的需水量和活性.进而影响粉煤灰混凝土性能;SO3则对硬化混凝土体积安定性影响较大;需水量比的大小直接影响着粉煤灰混凝土的拌和用水量。品质好的粉媒灰应该是:烧失量小,SO3含量少。细度和需水量比低。通过分析我国现行灰质评价标准。认为现行标准对我国粉煤灰总体品质状况的适用性不好。为科学合理评价灰质,提高粉煤灰的利用率,提出了几点建议。 相似文献
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M. Ashraf A. Naeem Khan Qasair Ali J. Mirza A. Goyal A.M. Anwar 《Construction and Building Materials》2009,23(6):2207-2213
The research was aimed to evaluate the physico-chemical, morphological and thermal analysis of combined pozzolanic activities of minerals additives. Fly ash and ground granulated blast furnace slag were added, separately and collectively, as mineral replacement in ordinary Portland cement. Tests carried out on specimens cured at different ages were: compressive strength, ultrasonic pulse velocity, X-ray diffraction (XRD) analysis, scanning electron microscopic (SEM) studies, differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA), etc. The results indicated that the compressive strength and ultrasonic pulse velocity development rate of concrete specimens were significantly influenced by the addition of mineral additives. SEM data showed that the fly ash particles were more embedded and surrounded by slag. XRD analysis and DTA/TGA investigation have revealed different reaction kinetics of paste. The peak intensity of calcium hydroxide was significantly retarded by the addition of fly ash and slag, especially in combination, attributed to the dilution effect and calcium hydroxide consumption by pozzolanic reaction. 相似文献