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热障涂层技术是提升航空发动机性能的关键因素之一,随着航空发动机技术的发展,对热障涂层也提出了更高的要求。为适应镍基合金涡轮叶片热胀涂层的使用要求,热胀涂层的陶瓷面层发展出(YSZ+A2B2O7)结构涂层。热障涂层陶瓷面层常用的制备方法包括等离子喷涂技术和电子束物理气相沉积技术,金属粘结层常用的制备方法包括真空电弧镀技术和化学气相沉积技术。热障涂层低膨胀系数金属粘结层技术、热障涂层修复技术、新一代热障涂层材料、建立科学的热障涂层性能评价体系等是未来热障涂层的主要发展方向。 相似文献
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提高等离子喷涂热障涂层隔热性能的方法 总被引:1,自引:0,他引:1
为进一步提高等离子喷涂热障涂层的隔热性能,对陶瓷材料的导热理论及热障涂层的热导率进行了研究.提出了包括寻求新型热障涂层陶瓷材料、添加掺杂剂、制备纳米涂层及双陶瓷层热障涂层等能够改善等离子喷涂涂层隔热性能的方法;并指出,采用等离子喷涂技术制备带颜色的稀土锆酸盐纳米双陶瓷层热障涂层,将会进一步改善热障涂层的隔热性能. 相似文献
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国际公认的重型燃气轮机制造尖端技术之一—热障涂层技术,高温下通常面临CMAS(CaO-MgO-Al2O3-SiO2)腐蚀、氧化、相变与烧结等问题,其抗CMAS腐蚀性等关键性能极大地影响涂层寿命,提高热障涂层的性能刻不容缓。对重型燃气轮机用热障涂层的研究进展与发展趋势进行全面总结与分析。首先介绍国内外重型燃气轮机的现状及发展趋势、热障涂层的系统结构、材料和几种典型的制备工艺,然后针对高温下燃气轮机热障涂层遇到的一些问题,对其隔热性、抗氧化性及抗热震性等关键性能的研究进展进行综述,最后分类详述热障涂层的CMAS腐蚀机理及其防护研究进展。综述热障涂层的几种关键性能,提出热障涂层的性能与其材料、结构及制备工艺密切相关,据此总结归纳提高热障涂层性能的方法,为热障涂层性能的提高提供参考依据,以弥补燃气轮机热障涂层领域目前缺乏这类综述文章的不足。 相似文献
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高温防护涂层研究进展 总被引:6,自引:0,他引:6
简要介绍了高温防护涂层的发展进程,特别关注航空航天领域中几种常用的高温涂层,包括扩散涂层、MCrAlY包覆涂层和热障涂层;介绍了新概念涂层和玻璃基复合涂层等特色高温防护涂层;综述了国内外关于包括抗氧化或耐腐蚀涂层、热障涂层和扩散阻挡层等高温涂层的最新研究进展;还讨论了高温涂层未来的发展。 相似文献
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等离子喷涂陶瓷热障涂层是近年来极为引人注目的研究领域。本文介绍了热障喷涂层的材料、涂层结构和涂层的工艺技术,阐述了涂层的技术性能和损毁机理。本文报告了热障涂层在大功率柴油机上的应用研究进展和经过三千多小时在机车柴油机上运行试验的结果,并就今后进一步的发展提出了意见。 相似文献
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热障涂层(TBCs)具有优异的高温抗氧化、高温力学和抗热腐蚀性能而备受关注,广泛应用于航空发动机和燃气轮机热端部件中。热障涂层服役环境的恶劣和涂层体系结构的复杂,极易导致涂层发生界面分层或剥落失效,因此通过对热障涂层的裂纹萌生和扩展问题进行实时监测,对于失效机理研究显得尤为重要。简述光激发荧光压电光谱(PLPS)、红外热成像(IRT)、阻抗谱(IS)的原理及其在热障涂层失效行为研究中的应用,重点介绍声发射技术在热障涂层失效机理方面的研究成果。基于声发射的热障涂层失效过程的信号分析和深度处理,结合声发射技术在热障涂层中的参数分析和波形分析,对热障涂层失效过程及失效形态进行模式识别,通过损伤程度的定量评估来进行热障涂层的寿命预测。对声发射技术在热障涂层失效预测及寿命评估指明了方向,并创新性地对未来声发射技术在热障涂层的疲劳损伤方面研究趋势提出展望。 相似文献
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热障涂层材料与技术的研究进展 总被引:1,自引:0,他引:1
热障涂层具有良好的隔热效果和抗高温性能,应用于涡轮发动机的热端部件,能显著提高使用温度,延长使用寿命。本文对热障涂层的材料、制备技术的新进展进行了综述,展望了热障涂层的发展趋势。 相似文献
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为了更好的理解热障涂层的失效机理,文中运用ABAQUS有限元软件来分析热障涂层的失效情况,使用内聚力单元和扩展有限元(XFEM)两种方法研究热障涂层TGO界面开裂与陶瓷涂层(TC)和氧化层(TGO)内随机裂纹的萌生与扩展,研究竖直裂纹与水平裂纹的关系.结果表明,热障涂层TGO界面的开裂首先出现在TGO/TBC波谷处.陶瓷涂层和氧化层内随机裂纹的萌生同样发生在TGO/TBC波谷处.竖直裂纹的存在可以抑制水平裂纹的萌生与扩展,且其在TGO/TBC波谷处的扩展长度比在TGO/TBC波峰处的扩展长度更长,说明TGO/TBC波谷区域是个危险区域,在此区域容易引发裂纹的萌生与扩展. 相似文献
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Microstructural features and properties of plasma sprayed YPSZ/NiCrAlY thermal barrier coating (TBC)
0 IntroductionThermalbarriercoatings(TBCs)arewidelyusedontheturbinebladesforaircraftpropulsionorpowergenerationtoreducethemetallicsubstratetemperature,whichleadstoincreasingengineefficiencyandloweringpollutantemissionsresultingfromallowableincreaseofoperationtemperature[1,2].Today,TBCsareattractingmoreattentionandhavewiderpotentialapplicationstoprotecthightemperaturecomponents.However,thermalbarriercoatingshaveatendencytocrackandspallinserviceduetothermalshockandthermalcyclingbetweenambient… 相似文献
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目的采用低温超音速等离子喷涂(LT-HVOF)在镍基高温合金基体(K417)上制备了NiCoCrAlYTa粘结层,使用大气等离子喷涂(APS)在粘结层上制备了纳米7%Y_2O_3-ZrO_2(7YSZ)陶瓷涂层,以获得温度梯度热循环下纳米陶瓷层的结构演变机制。方法通过燃气热冲击实验仪对热障涂层模拟真实服役条件下温度梯度热循环的工作环境,采用一维稳态热传导模型计算了热障涂层中各涂层界面的温度,探讨了在热驱动作用下等径晶粒和非等径晶粒的扩散长大机制。结果热循环次数为40次时,涂层近表面出现了烧结致密化现象,而陶瓷层底部涂层保持原来的结构。热循环次数增加到460次时,整个陶瓷层断面都发生了烧结致密化现象。结论温度是涂层烧结致密化的主导因素。涂层中当等大晶粒接触形成弯曲颈时,由于弯曲颈只受水平方向静压力作用,晶粒中原子扩散速率慢,导致晶粒长大速率较慢;而当非等大晶粒接触形成弯曲颈时,在晶粒接触弯曲颈处存在一偏大晶粒方向的剪切力,其导致晶粒向弯曲颈扩散速率增加,晶粒长大速率较快。 相似文献
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M. Tamura M. Takahashi J. Ishii K. Suzuki M. Sato K. Shimomura 《Journal of Thermal Spray Technology》1999,8(1):68-72
Multilayered thermal barrier coatings (TBC) with different functions were proposed for the hot section components of land-based
gas turbines. This article describes a multilayered TBC with an oxidation resistant layer. A conventional duplex TBC and a
triplex TBC, in which an aluminized layer was added to the conventional duplex TBC to increase oxidation resistance, were
prepared. It was confirmed by a burner rig test that the triplex TBC with the aluminized layer is resistant to oxidation and
shows high durability in a thermal cycle test, compared with the conventional duplex TBC. The spalling in the thermal cycle
test of each TBC specimen occurred at the same position, when the thickness of the oxidation layer was 11 to 13 μm. The mechanism
of spalling of the coating in the thermal cycle test was discussed in terms of stress in the coating. Stress in the direction
of spalling occurred by an uneven interface between the bond and top coat and increased with growth of the oxidation layer.
It is thought that the high durability of the triplex TBC in the thermal cycle test is derived from suppressing the growth
of the oxidation layer and decreasing the stress due to the addition of the aluminized layer. 相似文献
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采用等离子喷涂技术制备了三种不同材料的热障涂层(TBC),对涂层进行了组织性能的分析比较.结果表明,Al-1075的TBC结合强度最高,为 24.66 MPa,具有良好的抗热震性能;KF-230的TBC结合强度最低,为 16.06 MPa;LG-210的TBC结合强度居中,抗热震性能最差.分析认为,氧化物层(TGO)在热障涂层中的失效起至关重要的作用,TGO是裂纹的产生源,是裂纹扩展的通道,是热障涂层系统中的最薄弱环节.因此抑制TGO是提高涂层结合强度、改善涂层抗热震性能的重要措施. 相似文献
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Ann Bolcavage Albert Feuerstein John Foster Peter Moore 《Journal of Materials Engineering and Performance》2004,13(4):389-397
Various methods of thermal shock testing are used by aircraft and industrial gas turbine engine (IGT) manufacturers to characterize
new thermal barrier coating systems in the development stage as well as for quality control. The cyclic furnace oxidation
test (FCT), widely used in aircraft applications, stresses the ceramic/bondcoat interface, predominantly through thermally
grown oxide (TGO) growth stress. The jet engine thermal shock (JETS) test, derived from a burner rig test, creates a large
thermal gradient across the thermal barrier coating (TBC), as well as thermomechanical stress at the interface. For IGT applications
with long high-temperature exposure times, a combination of isothermal preoxidation and thermal shock testing in a fluidized
bed reactor may better represent the actual engine conditions while both types of stress are present. A comparative evaluation
of FCT, JETS, and a combined isothermal oxidation and fluidized bed thermal shock test has been conducted for selected ceramic/bondcoat
systems. The results and the failure mechanisms as they relate to the TBC system are discussed. A recommendation on the test
method of choice providing best discrimination between the thermal shock resistance of the ceramic layer, the ceramic/bondcoat
interface, and even substrate related effects, is given.
This paper was presented at the 2nd International Surface Engineering Congress sponsored by ASM International, on September
15–17, 2003, in Indianapolis, Indiana, and appeared on pp. 520–29. 相似文献
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New material concepts for the next generation of plasma-sprayed thermal barrier coatings 总被引:1,自引:0,他引:1
D. Stöver G. Pracht H. Lehmann M. Dietrich J -E. Döring R. Vaßen 《Journal of Thermal Spray Technology》2004,13(1):76-83
In application as a thermal barrier coating (TBC), partially stabilized zirconia (Zr) approaches some limits of performance.
To further enhance the efficiency of gas turbines, higher temperature capability and a longer lifetime of the coating are
needed for the next generation of TBCs. This paper presents the development of new materials and concepts for application
as TBC. Materials whose compositions have the pyrochlore structure or doped Zr are presented in contrast with new concepts
like nanolayers between the top and bond coat, metal-glass composites, and double-layer structures. In the last concept, the
new compositions are used in a combination with Zr, as a double, multi, or graded layer coating. In this case, the benefits
of Zr will be combined with the promising properties of the new top coating. In the case of metal-glass composites, the paper
will be focused on the influences of different plasma spraying processes on the microstructure. The performance of all these
different coating systems has been evaluated by burner rig tests. The results will be presented and discussed. 相似文献
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The stiffness of air plasma sprayed (APS) thermal barrier coatings (TBCs) was determined from bending experiments combining
strain analysis on a microstructural level with macroscopic mechanical parameters. Tests were performed with freestanding
and attached TBCs, the latter either loaded in tension or in compression. Relationships are derived, which describe the TBC
stiffness in a multilayer composite (attached TBC) and for a bimodular material that possess a lower stiffness in tension
than in compression (stand-alone TBC). The increase of in-plane stiffness with increasing compressive stress emphasizes the
importance of the spraying defects for the elastic response of the coating. 相似文献
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