Preparation of Ni60-WC coating by plasma spraying, plasma re-melting and plasma spray welding on surface of hot forging die

In order to produce the hear-resistant inner layer of hot-forging die, the plasma spraying and plasma re-melting and plasma spray welding were adopted. Substrate material was W6Mo5Cr4V2, including 10%, 20%, 30% tungsten carbide (WC) ceramic powder used as coating material to obtain different Nickel-based WC alloys coating. Micro-structure and micro-hardness analysis of the coating layer are conducted, as well as thermophysical properties for the coating layer were measured. The experimental results show that the coating prepared with 70%Ni60, 30%WC powder has the best properties with plasma spray welding, in which the micro-hardness can achieve 900HV, meanwhile it can improve the thermal property of hot-forging die dramatically.     

Preparation of Ni60-Cr3C2 coating by plasma spraying, plasma re-melting and plasma spray welding on W6Mo5Cr4V2

In order to prepare heat-resistant inner layer of hot-forging die,plasma spraying,plasma re-melting and plasma spray welding were adopted.Cr₃C₂ coatings of Ni-Based were prepared respectively with 10%,20% and 30% Cr₃C₂ powder and W6Mo5Cr4V2 substrate.The coating microstructure analysis,the micro-hardness test,and the measurement of thermal parameters of coating were conducted.The experimental results show that the coating has the better thermo-physical property by using plasma spray welding method with the powder ratio of 90% Ni60 and 10% Cr₃C₂,and by this way the micro-hardness of coating can achieve 1100 HV.     

平行闸板阀阀座等离子弧喷焊工艺对喷焊层组织及性能的影响

试验研究了平行闸板阀阀座35CrMo等离子喷焊Ni60A合金粉末试样的组织与性能。试验分析结果表明,等离子弧喷焊层冶金结合较好,焊层组织致密、稀释率低;喷焊层是由各种化合物硬质相和基体组成,形成的合金涂层具有良好的耐磨损性能。     

Wear-resistance Performance of Spray-welding Coating by Plasma Weld-surfacing

Alloy powders including Ni60, WC, Cr_3C_2, and TiC with different mass ratios were deposited on medium carbon low alloy steel by plasma welding. Through the experiments, the optimal alloy powder reinforcing cutter tool surface properties were discovered. The wear resistance properties were investigated on the impact abrasive wear tester. The experimental results show that in terms of microstructure, there exists the shape of herringbone, spider mesh, broken flower structures in coatings. In addition, fusion area of four specimens surfacing welding layer displays a large number of acicular martensite with a small amount of austenite. The coating mainly consists of Ni-Cr-Fe austenitic phase and the other precipitates. TiC density is smaller, its content is less in alloy powder, in the process of surfacing welding, TiC is melted fully, which is mainly distributed in surface layer and middle layer of hard facing layer. The content of TiC gradually reduces from surface layer of hard facing layer to the fusion area. Compared to TiC, the density of tungsten carbide and chromium carbide is larger, there exist tungsten carbide and chromium carbide particles, which are not completely melted near the fusion area. The micro-hardness presents gradient change from the fusion area to the surface layer of hard facing layer, and the hardness of the middle layer is slightly lower than that of the fusion area, and the hardness increases near the surface layer.     

等离子喷焊铁/镍混合基喷焊层Q345复合板的制备

通过在铁合金粉末中加入5%质量分数的镍合金粉末来制备铁镍合金粉末。使用等离子喷焊技术在以Q345为基体的低合金钢表面制备铁/镍混合基喷焊层。通过设计正交实验,使用金相显微镜,物相显微镜以及扫描电镜,来研究铁/镍混合基喷焊层的物相以及微观组织,判断其基体和喷焊层的结合性是否良好以及对基体,融合线,喷焊层的金相组织进行观察与分析。在判断喷焊层显微硬度时,使用维氏显微硬度计,对试样的喷焊层,融合线以及基体进行测试,并对其数据进行分析。使用软件对试样的金相图进行晶粒分析,通过对试样的硬度,成型系数,焊缝宏观样貌,裂纹等数据进行分析,优化出具有高性能的铁/镍混合基Q345复合板工艺参数。     

等离子喷涂参数对镍基合金涂层组织及冲蚀磨损性能的影响

采用SEM、XRD、LSCM和冲蚀磨损试验机研究了等离子喷涂参数(氢气流量HFR、喷涂电流I)对Ni60涂层组织与冲蚀磨损性能的影响。结果表明,Ni60涂层主要由γ-Ni、Ni3B、Cr2B、CrB、M7C3、M23C6相构成;增加HFR、I有利于减小涂层中层片厚度,增加涂层结晶度、平均晶粒尺寸、微观应变量及残余应力,提高涂层显微硬度及抗冲蚀磨损性能。但过大的HFR、I(15ft3/h、600A)导致涂层孔隙率增加,显微硬度及抗冲蚀磨损性能降低。等离子喷涂参数HFR=12.5ft3/h、I=500A时,在小角度冲蚀条件下,Ni60涂层具有更高的抗冲蚀磨损性能。     

等离子喷焊ZrC增强铁基喷焊层Q345复合板的制备

对Q345钢板进行等离子喷焊表面处理,通过正交实验优化了Q345表面处理的最佳工艺参数,优化的喷焊工艺为电流60 A、焊枪行走速度20 mm/min、送粉量为35％、离子气流量为1.2～1.4 L/min、保护气流量为10～12 L/min.结果表明,Q345基板的组织正常,为珠光体+铁素体组织,热影响区处金相组织仍为...     

铸铁等离子喷焊Stellite6钴基合金涂层的组织与性能

以Steilite6钴基合金粉末为原料,采用等离子喷焊技术,选择合适的工艺参数,在HT250基体上制备具有冶金结合的耐磨、耐热合金涂层．借助于OM、SEM、XRD观察分析涂层的组织,利用显微硬度计测试涂层的显微硬度分布,在磨损试验机上通过环一块磨损试验评估涂层的耐磨性能．结果表明：等离子喷焊涂层组织均匀细小,主要由γ-Co、（Cr,Fe）,C2相组成;涂层的显微硬度可达590～680HV。;在室温干滑动磨损条件下,基体试样的失重量约为涂层的5．5倍,表明涂层的耐滑动磨损性能明显提高．     

大气压下等离子体喷涂制备Cu/W涂层性能研究(英文)

采用大气压等离子体喷涂和高速大气压等离子体喷涂技术制备Cu/W涂层,分别对该涂层断面的表面形貌、孔隙率、氧含量和结合强度进行测试分析.结果表明,高速大气压等离子体喷涂技术制备的Cu/W涂层在孔隙率和氧含量方面突显优势.采用高速大气压等离子体喷涂技术制备的Cu/W涂层孔隙率低于3%,且大部分孔径均小于1μm,利用EDS测得的W涂层氧含量为w(O)=0.41%,该值与真空等离子体喷涂制备的W涂层含氧量接近.与真空等离子体喷涂技术相比,高速大气压等离子体喷涂制备W涂层技术的复杂性和制作成本显著降低,在工程应用中实用可行.     

电渣重熔双金属热锻模的研究

电渣重熔双金属模块具有钢质纯洁、成分均匀、组织致密、各向异性小、良好综合性能等特点。研究和应用表明:平均使用寿命比德国进口和国产5CrNiMo、5CrMnMo锻制模块提高30～80％,而材料成本却降低30％左右。这不仅有效地节约原材料,完满地完成以铸代锻,而且省去了锻造镦拔及专门对燕尾回火两道工序,取得显著经济效益。     

Microstructure and Tribological Properties of Fe-Cr-B-Si-based Alloy Coating on the Surface of Scraper Conveyor Middle Trough NM450

This paper aims to develop a surface modification process to improve the surface properties of the middle trough.The coatings were prepared by plasma cladding with Fe-Cr-B-Si-based alloy powders (Ig 6 and Ig7).The organizational structure and micro-hardness of the coatings were analyzed by laboratory equipments.The friction and wear tests were performed to investigate the friction-wear properties of middle trough.The coatings have higher hardness and good friction-wear properties than the substrate.The hardness and friction wear properties of the coating with Ig7 powder are better than those with Ig6 powder.The experimental results show that the surface properties of the middle trough are improved by Fe-Cr-B-Si-based alloy coating,which can improve the middle trough service life.The plasma cladding can be widely used in the surface-modification of middle trough to reduce the waste of resources.     

等离子弧喷焊Mo/Ni60合金复合涂层的研究

采用等离子弧喷焊法制备了Mo/Ni60复合涂层.测定了喷焊层的耐磨性,并用光学显微镜对覆层进行了金相组织观察,利用X射线衍射分析了覆层的相结构.结果表明:加入Mo的镍基等离子喷焊层组织得到均匀化,共晶体细化,耐滑动磨损性能得到改善.     

Propagation properties of overmoded plasma circular waveguide

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等离子喷焊层NiCrBSi+WC/Co的组织与性能

利用等离子喷焊技术在H13模具钢表面制备NiCrBSi+20%WC/Co喷焊层。研究表明,基体与喷焊层之间存在明显的分界面,与传统焊接接头的微观组织类似,喷焊层中出现垂直于界面结合方向的柱状晶,这种组织形态在等离子喷涂涂层中从未观察到,说明喷焊层NiCrBSi+20%WC/Co与H13钢基体之间的结合为冶金结合。XRD分析表明,喷焊层中的主要相为γ-(Fe,Ni),Cr7BC4,Ni4B3,Cr7C3和Co7W6,并且由于这些相的存在,使得表面喷焊层比H13钢基体具有更高的强度和硬度。     

SiC／Cu粉团聚状态对SiC沉积率的影响

采用亚音速火焰喷涂技术制备了SiC／Cu金属基复合材料,研究了碳化硅与铜喷涂前团聚状态对碳化硅沉积率的影响．与未经团聚处理粉相比,SiC／Cu经团聚处理后沉积层中碳化硅沉积率高出1倍多．     

精铸模具钢热锻模的应用及寿命的提高

为了稳定和提高精铸热锻的使用寿命,研究了其失效形式和机理。研究结果表明:材质及工艺决定了精铸热锻模具呈现不同的失效形式和寿命。不恰当的材质及工艺导致热锻模具出现早期断裂失效,失效形式不合理,寿命较低。经改进材质及工艺后,热磨损、塑性变形为主要失效形式,而未出现早期断裂失效,寿命得到明显提高,稳定在6000~7000件,高于锻造模具钢80%以上。     

Investigation on plasma-sprayed ZrO_2 thermal barrier coating on nickel alloy substrate

1　ＩＮＴＲＯＤＵＣＴＩＯＮＺｒＯ2 ｔｈｅｒｍａｌｂａｒｒｉｅｒｃｏａｔｉｎｇｓａｒｅｍａｉｎｌｙｕｓｅｄａｓｈｅａｔ ｉｎｓｕｌａｔｉｎｇｌａｙｅｒｏｎｔｈｅｓｕｒｆａｃｅｏｆｈｉｇｈｔｅｍ ｐｅｒａｔｕｒｅｃｏｍｐｏｎｅｎｔｓｉｎｔｈｅｆｉｅｌｄｏｆｄｉｅｓｅｌ,ｔｕｒ ｂｉｎｅ ,ａｎｄｊｅｔｅｎｇｉｎｅｓ.Ｔｈｅｓｕｒｆａｃｅｔｅｍｐｅｒａｔｕｒｅｏｆｔｈｅｈｏｔｃｏｍｐｏｎｅｎｔｓｃａｎｇｒｅａｔｌｙｂｅｒｅｄｕｃｅｄｕｓｉｎｇｔｈｅｈｅａｔ ｉｎｓｕｌａｔｉｎｇｌａｙｅｒ,ｗｈｉｃｈｒｅｓｕｌ…     

植物甾醇微胶囊的制备

研究了乳化温度、乳化剂用量、助乳化剂用量、壁材和高速剪切时间对粉末稳定性的影响。采用O/W微乳液法对植物甾醇乳化,进行喷雾干燥得到植物甾醇微胶囊粉末。结果表明,乳化剂蔗糖脂肪酸酯(HLB 16)质量分数为12%、助乳化剂蔗糖质量分数为12.5%、壁材为酪蛋白酸钠,在60℃水浴中乳化,高速剪切30 min得到的植物甾醇粉末在水性材料中分散稳定、均一。     

用喷焊合金粉Fe55熔铸制造耐磨复合层

给出利用熔铸法，即利用铸件浇铸时的热量直接将喷焊合金粉末Ｆｅ５５熔融于铸件表面，形成厚度为３．０－３．５ｍｍ耐磨复合层的试验过程及结果，经金相和能谱分析，合金层与铸铁基体之间为冶金结合，其耐磨性能达到Ｆｅ５５粉末原设计要求。     

STRESS ANALYSIS OF ALUMINA COATINGS ON SILICON CARBIDE BASED REFRACTORIES DURING THERMAL CYCLING

It is possible to enhance the high tempera-ture oxidation resistance and thus prolong the life time of non-oxide refractories by the application of oxide coating. In this -work, silicon nitride bonded silicon carbide refractories were coated with alumina using the plasma spraying technique. X-ray diffraction shouted r-Al2O3 to be the dominent phase in the as-sprayed alumina coatings. The stresses developed in the coating layer during post-spray heat-treatment have been analysed. It was found that the coating-was under a compressive stress below,but when heated above 1100C , the r-Al2O3 phase transformed into a-Al2O3 and this led to the formation of a destructive tensile stress(up to 1700 MPa) which caused cracks to form in and along the iveak bond between the alumina coating and SiC grains. The coatings then delaminated and of fered little protection to the refractory substrate from oxidation. Future research will be directed on the avoidance oj metastable phase formation in the plasma sprayed coating a