Developing Hot Air-Assisted Radio Frequency Drying for In-shell Macadamia Nuts

Dehydration reduces water activity and extends shelf life of perishable agricultural products. The purpose of this research was to study the application of radio frequency (RF) energy in dehydration of in-shell Macadamia nuts and shorten the lengthy process times needed in conventional hot air drying operations. A pilot scale 27.12-MHz and 6-kW RF system was used to determine the operational parameters, the drying curve, and the quality attributes of the processed nuts. The results showed that an electrode gap of 15.5 cm and a hot air temperature of 50 °C provided an acceptable heating rate and stable sample temperatures, and were used for further drying tests. The drying curves showed an exponential decay and required 750 and 360 min to achieve the final moisture content of 0.030 kg water/kg dry solid (3.0 % dry basis) in whole nuts in hot air drying and RF heating/hot air combined drying, respectively. The drying kinetics of the nuts were described well by the Page model for hot air drying, but a logarithmic model was more suited for RF/hot air drying. Peroxide value and free fatty acid increased with the drying time both for hot air and RF drying but remained within acceptable range required by the nut industry. The RF process shows potential to provide rapid, uniform, and quality-acceptable drying technology for the nut industry.     

Dielectric Properties of Red Pepper Powder Related to Radiofrequency and Microwave Drying

To provide useful information for drying red pepper with radiofrequency or microwave energy and designing dielectric drying equipment, dielectric properties (dielectric constant ε′ and loss factor ε?″) of red pepper powder with moisture contents ranging from 10.4 to 30.8 % wet basis were measured at different temperatures (from 25 to 85 °C) over a frequency range of 20–4,500 MHz with a vector network analyzer and an open-ended coaxial-line probe. The results showed that both ε′ and ε?″ of red pepper powder were dependent on electromagnetic wave frequency, moisture content, and temperature. The value of ε′ decreased with increases in frequency over the tested range. The ε?″ decreased with increasing frequency when the frequency was below 4,000 MHz, and increased slightly when it was above 4,000 MHz. Both ε′ and ε?″ increased as either moisture content or temperature increased, and the increases were a little greater at high moisture and temperature than those at low moisture and temperature. The moisture- and temperature-dependent permittivities of red pepper powder at several frequencies of interest could be described by quadratic models. The results of variance analysis exhibited that both moisture content and temperature had significant influence (p<0.01) on permittivities of red pepper powder. The power penetration decreased as frequency, moisture content, and temperature increased. Large penetration depth at radiofrequencies below 100 MHz could be used to dry red peppers in a large scale, while microwave energy could be used for drying red peppers in a small scale.     

Development of effective drying strategy with a combination of radio frequency (RF) and convective hot-air drying for inshell hazelnuts and enhancement of nut quality

Drying characteristics of combined radio frequency (RF) and hot-air (HA) were investigated for inshell hazelnuts (Corylus avellana L.), which have air-gap between kernel and shell (shell, kernel, and air-gap between them). Inshell hazelnuts were subjected to HA, HA followed by RF (HAFRF), RF followed by HA (RFHA), and HA assisted RF (HARF) drying (simultaneous process). Fiber optic sensors were used to monitor temperature profiles for both hazelnut kernels and shells at three representative locations (center, edge, and corner) in a tray in 6-kW 27.12-MHz RF system with or without HA (~75 °C). RF heating resulted in higher kernel temperature than shell and was effective to remove kernel moisture. When RF heating was applied during or before HA drying, energy efficiency, drying efficacy, and nut quality were enhanced. This study provided a better understanding of drying characteristics of combined RF and HA process and suggested efficient RF-implemented drying strategies for inshell hazelnuts.     

Dielectric properties of ground almond shells in the development of radio frequency and microwave pasteurization

To develop pasteurization treatments based on radio frequency (RF) or microwave energy, dielectric properties of almond shells were determined using an open-ended coaxial-probe with an impedance analyzer over a frequency range of 10–1800 MHz. Both the dielectric constant and loss factor of almond shells decreased with increasing frequency, but increased with increasing temperature and moisture content. The absolute value of the slopes of log–log plots between loss factor and frequency increased with increasing temperature at low frequencies, especially at high temperatures and moisture contents. The effective electrical conductivity of shell samples was close to zero at the lowest moisture content (6% w.b.) and 3–9 times larger at 90 °C than 20 °C for the highest moisture content (36% w.b.). A good linear relationship was observed between permittivity and density at 1800 MHz. The power penetration depths at RF range (27 and 40 MHz) were about 6–24 times as deep as those for microwave frequencies (915 and 1800 MHz) at each corresponding temperature and moisture content. It is likely that RF energy may provide uniform heating and high throughput treatments for controlling Salmonella in in-shell almonds after washing.     

Compositional analysis and roasting behaviour of gevuina and macadamia nuts

This study compares the composition of macadamia and gevuina nuts following natural abscission and air-drying of intact nuts and compares chemical and sensory properties on roasting gevuina nuts using a reported macadamia roasting process. The markedly higher fat content of macadamia (75% vs. 43%) reflected a higher percentage of protein, moisture, ash and carbohydrate in gevuina nuts. Gevuina nuts also had lower energy and pH values than macadamia. Water activities were similar. Both oils were around 80% monounsaturated, but differed widely in positional isomerism. On roasting, macadamia nuts developed sweet, nutty, buttery notes along with brown colour development (measured using L *, a *, b * values) after 20 min at 135 °C while gevuina nut colour and aroma took at least 30 min, where the aroma was more hazelnut-like. Extractable volatiles were significantly higher for macadamias following roasting.     

Electromagnetic Heating for Industrial Kilning of Malt: a Feasibility Study

Industrial malting operations use ～800 kWh/t of energy to produce the heat required to kiln malt. Electromagnetic heating technologies are suggested as a way to potentially improve the energy efficiency of the kilning processing. In this work, the potential for using electromagnetic heating to dry malt to commercially acceptable moisture levels whilst preserving the activity of enzymes critical for downstream brewing processes is investigated. The 2450 MHz bulk dielectric properties of malt at moisture contents consistent with those occurring at different points in the kilning process are evaluated; 12% is shown to be a critical moisture level below which drying becomes more energy intensive. Calculated penetration depths of electromagnetic energy in malt at radio frequency are 100-fold higher than at microwave frequencies, showing a significant advantage for commercial-scale batch processing. The moisture contents and alpha and beta amylase activity of malt subjected to RF heating at different temperatures, treatment times and RF energy inputs in the intermediate and bound water drying regions were determined. It is shown for the first time that whilst significantly reduced process times are attainable, significant energy efficiency improvements compared to conventional kilning can only be achieved at higher product temperatures and thus at the expense of enzyme survival. It is suggested that RF heating may be feasible where higher bulk temperatures are not critical for downstream use of the material or when used in hybrid systems.     

Carbohydrate composition and color development during drying and roasting of macadamia nuts (Macadamia integrifolia)

Research was conducted to determine whether variability in sugar content contributes to differences in kernel browning during processing of macadamia nut (Macadamia integrifolia) cultivars, Kau (HAES 344), Keaau (HAES 660), Keauhou (HAES 246), and Kakea (HAES 508). At harvest, total sugar content of fresh macadamia kernels varied from 2.9 to 5.6 g/100 g dry weight basis (db), and the average moisture content ranged from 15.6 to 23.6 g/100 g fresh weight. Cultivars differed in kernel sucrose content, but not reducing sugar content. Reducing sugars decreased during drying, and kernel centers darkened slightly. An incremental drying process limited sucrose hydrolysis, minimizing the amount of glucose and fructose available for browning reactions. Therefore, the centers of roasted kernels were not darker than dried kernels. The variability in sugar composition in fresh kernels had a minimal impact on color quality when low-temperature drying and roasting at 125 °C were used. However, when roasted kernels received from a processor were separated based on color quality, kernels with internal or external browning had higher reducing sugar concentrations (0.24-0.27 g/100 g db) than cream-colored kernels (0.03 g/100 g db). Immature kernels had higher sucrose and reducing sugar contents and more browning than mature kernels. During commercial processing, optimal conditions may not be achieved and the presence of immature nuts can contribute to kernel browning.     

Temperature and moisture dependent dielectric properties of legume flour associated with dielectric heating

Dielectric properties data are important in developing thermal treatments using radio frequency (RF) and microwave (MW) energy and are essential in estimating heating uniformity in electromagnetic fields. Dielectric properties of flour samples from four legumes (chickpea, green pea, lentil, and soybean) at four different moisture contents were measured with an open-ended coaxial probe and impedance analyzer at frequencies of 10-1800 MHz and temperatures of 20-90 °C. The dielectric constant and loss factor of the legume samples decreased with increasing frequency but increased with increasing temperature and moisture content. At low frequencies and high temperatures and moisture contents, negative linear correlations were observed between the loss factor and frequency on a log-log plot, which was mainly caused by the ionic conductance. At 1800 MHz, the dielectric properties data could be used to estimate the legume sample density judging from high linear correlations. Loss factors for the four legume samples were similar at 27 MHz, 20 °C and low moisture contents (e.g. <15 g/100 g). At the highest moisture content (e.g. 20 g/100 g) soybean had the highest loss factor at 27 MHz and 20 °C, followed by lentil, green pea, and chickpea. The difference in loss factor among the four legumes did not show clear patterns at 915 MHz. Deep penetration depths at 27 MHz could help in developing large-scale industrial RF treatments for postharvest insect control or other applications that require bulk heating in legumes with acceptable heating uniformity and throughputs.     

Dropping macadamia nuts‐in‐shell reduces kernel roasting quality

BACKGROUND: Macadamia nuts (‘nuts‐in‐shell’) are subjected to many impacts from dropping during postharvest handling, resulting in damage to the raw kernel. The effect of dropping on roasted kernel quality is unknown. Macadamia nuts‐in‐shell were dropped in various combinations of moisture content, number of drops and receiving surface in three experiments. After dropping, samples from each treatment and undropped controls were dry oven‐roasted for 20 min at 130 °C, and kernels were assessed for colour, mottled colour and surface damage. RESULTS: Dropping nuts‐in‐shell onto a bed of nuts‐in‐shell at 3% moisture content or 20% moisture content increased the percentage of dark roasted kernels. Kernels from nuts dropped first at 20%, then 10% moisture content, onto a metal plate had increased mottled colour. Dropping nuts‐in‐shell at 3% moisture content onto nuts‐in‐shell significantly increased surface damage. Similarly, surface damage increased for kernels dropped onto a metal plate at 20%, then at 10% moisture content. CONCLUSION: Postharvest dropping of macadamia nuts‐in‐shell causes concealed cellular damage to kernels, the effects not evident until roasting. This damage provides the reagents needed for non‐enzymatic browning reactions. Improvements in handling, such as reducing the number of drops and improving handling equipment, will reduce cellular damage and after‐roast darkening. Copyright © 2010 Society of Chemical Industry     

Dielectric properties of salmon (Oncorhynchus keta) and sturgeon (Acipenser transmontanus) caviar at radio frequency (RF) and microwave (MW) pasteurization frequencies

Radio frequency (RF) and microwave (MW) heating provide an important advantage of more rapid heat penetration in pasteurization processes for heat labile high value foods, which to date, have only been pasteurized by conductive heating. The objectives of this work were to determine the dielectric constant, loss factor and power penetration depth for salmon (0.8% and 2.3% total salt) and sturgeon (0.20 and 3.3% salt) caviars at RF frequency of 27 MHz and MW frequency of 915 MHz (20–80 °C). The dielectric constant (ε′) and dielectric loss factor (ε″) for salmon and sturgeon caviar increased markedly with increasing temperature at 27 MHz but not at 915 MHz. Power penetration depth was higher at 27 MHz compared to 915 MHz, and in unsalted compared to salted roe. Power penetration depth tended to decrease as temperature increased.     

澳洲坚果仁营养成分分析与其加工副产物的综合利用研究

澳洲坚果香脆可口,营养丰富,富含多种人体生长所必需的营养物质,同时我国的澳洲坚果种植面积广。因此,该文重点对澳洲坚果仁的营养成分进行分析,并对澳洲坚果仁的加工副产物,包括澳洲坚果壳、澳洲坚果青皮以及澳洲坚果粕的综合利用进行综述,以期为澳洲坚果的市场化开发和综合利用提供理论参考。     

Evaluating performances of a small-scale 50 Ω radio frequency heating system designed for home applications

Industrial-scale radio frequency (RF) heating systems have been extensively used in processing agricultural products and foods. However, small-scale RF heating systems for household applications are yet to be realized. The purpose of this study was to develop small-scale 50 Ω RF heating systems and evaluate its heating performances with cooked rice (moisture content (MC) of 62.5 ± 0.5% wet basis (w.b.)). Two RF systems (13.56 and 27.12 MHz) were developed, and the heating rate, heating uniformity, and energy efficiency of cooked rice samples were compared between the developed RF units and a 2450 MHz microwave (MW) oven under static conditions. Results showed that the RF heating systems had smaller temperature differences and better heating uniformity than the MW oven under similar overall heating rate and the same input power (700 W) levels. The 13.56 MHz RF system performed better than the 27.12 MHz one. These findings may provide some clear performance indicators and guidelines for domestic application of small-scale 50 Ω RF heating systems.     

Dielectric Properties of Potatoes and Potato Chips

SUMMARY— Dielectric properties (dielectric constant, ɛ'_r; loss tangent, tans; and dielectric loss factor, ɛ"_r) were determined for raw potatoes and for potato chips, using the precision slotted line technique. Measurements on raw potatoes were made at 77°F (25°C) and at frequencies of 300, 1,000, and 3,000 MHz (megahertz). Measurements on potato chips were made at three moisture levels; at 77°F (25°C), 125°F (51.6°C), and 180°F (82.2°0; and at frequencies of 300, 1,000, and 3,000 MHz. Moisture, total lipids, and nitrogen contents are reported for both the raw potatoes and the potato chips.
As would be expected from their high moisture content and the presence of various dissolved salts, the raw potatoes possess extremely high dielectric values.
Potato chips show a rapidly decreasing dielectric loss as moisture content is reduced; the loss values of the chips approach those of the oil used for frying them after moisture has been reduced to approximately 3% and the oil content has been increased accordingly.
For finish drying of potato chips, a frequency of 3,000 MHz will result in 3–4.5 times greater power production in the chips than will the use of a frequency of 1,000 MHz (in the moisture and temperature range at which the data were obtained). However, this difference in power production is due almost entirely to the difference in frequency since the difference in dielectric loss values at the two frequencies is quite small.     

Radio Frequency-Vacuum Drying of Kiwifruits: Kinetics,Uniformity, and Product Quality

To overcome long drying time, low energy efficiency and poor product quality associated with conventional drying, a radio frequency (RF) vacuum technology is proposed for drying kiwifruit slices using a 27.12 MHz, 3 kW RF-vacuum drying system. The results demonstrated that the process variables, electrode gap, vacuum pressure, and sample thickness, had major effects on the RF-vacuum drying. The RF-vacuum drying was associated with internal heating and rapid drying resulting in 65% reduction of hot air drying (60 °C) time. Moreover, kiwifruits dehydrated by RF-vacuum drying were associated with better color stability, higher vitamin C retention, and higher rehydration capacity (p?<?0.05) as compared with hot-air-dried samples. Based on acceptable drying rate, stable temperature and avoiding arcing, a RF-vacuum drying protocol with the electrode gap of 60 mm, vacuum pressure of 0.02 MPa, and sample thickness of 8 mm was identified. Despite some differences observed in individual fruit slices, the RF-vacuum drying technique achieved better and more uniform drying patterns among the samples. Overall, the RF-vacuum drying process may provide a more effective and practical method for high-quality dehydration of kiwifruits.     

Temperature-Dependent Dielectric Properties of Raw Cow’s and Goat’s Milk from 10 to 4,500 MHz Relevant to Radio-frequency and Microwave Pasteurization Process

To offer useful information for milk pasteurization with radio-frequency or microwave heating, the dielectric properties (dielectric constant and dielectric loss factor) of raw cow’s milk and goat’s milk were determined over the frequency range of 10–4,500 MHz and temperature range of 25–75 °C by a vector network analyzer and an open-ended coaxial-line probe. The mathematical models describing the relationship between permittivities and temperature were built, and the power penetration depth was investigated. The results showed that both for cow’s milk and goat’s milk, the dielectric constants decreased with an increase of frequency, and the dielectric loss factor decreased with increasing frequency below 1,000 MHz and increased after that. The dielectric constants decreased with increasing temperature at a given frequency. For raw cow’s milk, the dielectric loss factor almost increased with temperature below about 800 MHz, and decreased with temperature above that. For raw goat’s milk, the loss factor decreased with temperature in whole investigated frequency range. Quadratic equations could be used to describe the relationship between permittivities and temperature at interested frequencies with coefficient of determination higher than 0.96. The penetration depth decreased with increasing frequency. Contrasted to frequency, temperature had less effect on penetration depth. Microwave heating at 915 MHz has great potential for raw cow’s milk pasteurization, while radio-frequency heating at 27.12 and 40.68 MHz and microwave heating at 915 MHz can be used for goat’s milk pasteurization.     

广西澳洲坚果果实品质分析与综合评价

为探明广西澳洲坚果果实主要品质特征,建立果实经济性状综合评价方法。对14?个广西主产地澳洲坚果果实优果判别指标以及果仁脂肪酸、氨基酸、矿质元素组成与含量等品质指标进行测定,运用因子分析、聚类分析和正交偏最小二乘判别分析对其品质进行综合评价。结果表明：广西不同产地澳洲坚果果实品质存在明显差异,42.9%的果园好果率低于97%,需要加强果园管理工作。广西澳洲坚果果仁中不饱和脂肪以油酸、棕榈油酸为主,水解氨基酸以药效氨基酸为主,磷、钙含量相对其他矿物质元素含量较多。系统聚类分析显示广西澳洲坚果可以分为3?类,好果率、脂肪、蛋白质、棕榈酸、十七烷酸、硬脂酸、花生酸、油酸、亚麻酸、二十碳三烯酸、天冬氨酸、苏氨酸、丝氨酸、谷氨酸、丙氨酸、缬氨酸、异亮氨酸、亮氨酸、酪氨酸、苯丙氨酸、赖氨酸、磷22?个指标是不同产地澳洲坚果样品间的差异指标。利用因子分析法建立澳洲坚果经济性状评价模型,逐步回归分析验证模型具有非常高的预测准确性;第3类（12、14号）品质相对最优,第1类（1、2、3、6、7、8、9、10、11、13号）次之,第2类（4、5号）再次之。该研究为准确了解广西澳洲坚果果实品质、品质评价标准建立及品质调控提供参考和依据。     

Effect of Amino Acids on Microwave Dielectric Properties of Minced Antarctic Krill (<Emphasis Type="Italic">Euphausia superba</Emphasis>)

The dielectric properties of ten solid amino acids, namely, glycine, proline, cysteine, glutamine, lysine, methionine, histidine, arginine, tyrosine, and tryptophan, and the effects of amino acid concentrations (0, 1, 3, and 5%) on the dielectric properties of minced Antarctic krill (Euphausia superba) were studied within a frequency range of 300–3000 MHz at 20.0 ± 0.5 °C. The dielectric constants and dielectric loss factor of amino acids were 2.0 ± 0.4 and 0.2 ± 0.3, respectively (moisture contents, 0.05–0.33%), except those of lysine (5.5 ± 0.5 and 1.5 ± 1.0, respectively) (moisture content, 4.5%). The dielectric properties of non-polar, neutral-polar, alkaline amino acids added to Antarctic krill were affected by the frequency and moisture contents, molecular weight, and isoelectric points (pI) of amino acids. As the molecular weight and pI values increased, the critical frequencies of aliphatic amino acid added to minced Antarctic krill decreased, whereas heterocyclic amino acid added to minced Antarctic krill increased. Quantitative relationships between parameters that define both the real and the imaginary parts of the Debye relations and the weight fraction of amino acid contents in Antarctic krill were determined. Moreover, glycine (at 5%) or lysine (at 5%) significantly influenced the dielectric constants and dielectric loss factor of minced Antarctic krill (p < 0.05) but did not have significant effects on temperature history and distribution (p < 0.05) during microwave heating at 2450 MHz.     

Dielectric properties of chestnut flour relevant to drying with radio-frequency and microwave energy

Dielectric properties of compressed chestnut flour samples with 11.6–48.0% w.b. moisture content were determined with a network analyzer and an open-ended coaxial-line probe over a frequency range from 10 to 4500 MHz and a temperature range from 20 to 60 °C. The results showed that the permittivities of chestnut flour were a function of frequency, moisture content and temperature. Both dielectric constant and loss factor decreased with increasing frequency but increased with increasing moisture content and temperature. The relationship between permittivities and moisture content and temperature at 27, 40, 915 and 2450 MHz could be described by second- or third-degree polynomial models, with the coefficients of determination higher than 0.993. The analysis of variance showed that moisture content and temperature had strong significant effects on permittivity values. The penetration depth decreased with increasing frequency, moisture content and temperature. Large penetration depth at radio frequencies below 100 MHz may provide practical large-scale dielectric drying of chestnut.     

Moisture Dependent Geometric and Mechanical Properties of Wild Pistachio (Pistacia vera L.) Nut and Kernel

In this research, wild pistachio (Pistacia vera L.) nuts and kernels were analyzed for selected geometric properties and mechanical behavior under compression loading. The average length, width and thickness arithmetic and geometric mean diameter of wild pistachio nuts at 5.83% w.b. were 13.98, 8.76, 7.25, 9.93, and 9.75 mm, while the corresponding values of kernels at 6.03% w.b. moisture content were 11.07, 5.92, 4.83, 7.21, and 6.88 mm, respectively. As the moisture content of pistachio nut increased from 5.83 to 30.73% w.b., the bulk density, apparent density and terminal velocity were found to increase from 521 to 543 kgm^?3, 809 to 829 kgm^?3, and 5.51 to 6.29 ms^?1, respectively, whereas porosity decreased from 35.14% to 34.63%. The results revealed that wild pistachio nut required higher rupture force and energy to crack wild pistachio nuts for compression along the L-axis as compared to other two axes.     

Radio frequency heating as a disinfestation method against Corcyra cephalonica and its effect on properties of milled rice

Radio frequency (RF) heating has the potential to be developed as an alternative non-chemical disinfestation method. In contrast to microwave (MW), RF exhibited higher penetration depth, which helps RF to be a useful technique in disinfesting packaging foods. A 3 kW, 27.12 MHz RF system was used to validate the practical of radio frequency technology for rice moth (Corcyra cephalonica) control in milled rice. Rice samples were placed in the polystyrene bag and moved at a speed of 0.8 m/min, and heated in the RF system with intermittent mixing. Four electrode gaps and five sample thicknesses were chosen to confirm the optimal conditions of RF treatment. The results showed that the sample thickness of 15 mm and electrode gap of 40 mm could provide the optimum heating rate for rice. Mortality of each stage (adult, larva, egg) of C. cephalonica increased with increasing heating temperature and reached 100% while RF heated 180 s (45.8 °C), 300 s (56.9 °C), and 420 s (70 °C), respectively. No C. cephalonica was determined in the samples during 45 days storage incubation period at RF treatment to 70 °C. There were no significant differences between control and RF treated samples in quality parameters (moisture, protein, fat, gelatinization, and sensory attributes). Therefore, RF treatment may provide a practical and effective method for disinfesting milled rice without affecting product quality.