Effect of Bio-Lubricant and Biodiesel-Contaminated Lubricant on Tribological Behavior of Cylinder Liner–Piston Ring Combination

This article addresses the issue of friction and wear characteristics of diesel engine cylinder liner–piston ring combinations under different lubricating conditions using a pin-on-disc wear tribometer. The discs were made out of actual engine cylinder liner material using a casting process. Pins were made out of top compression ring material. The tests were conducted on a pin-on-disc tribometer for wear and friction characteristics of the cylinder liner and piston ring combination with diesel-contaminated rapeseed oil–based bio-lubricant, diesel-contaminated commercial synthetic lubrication oil (SAE 20W40), biodiesel-contaminated commercial synthetic lubrication oil (SAE 20W40), and used (150 h) commercial synthetic lubrication oil (SAE 20W40). Experimental results demonstrated that the rapeseed oil–based bio-lubricant and biodiesel-contaminated synthetic lubricant exhibited better performance in terms of wear, friction, and frictional force under similar operating conditions. Thus, usage of newly formulated bio-lubricant and biodiesel in the long run may have a positive impact on engine life.     

Study on Influence of Cylinder Liner Surface Texture on Lubrication Performance for Cylinder Liner–Piston Ring Components

A marine diesel engine, where the cylinder liner–piston ring (CLPR) pair is one of the most important rubbing pairs, is the heart of a marine system. Studying the lubrication characteristics of the CLPR will provide a guide for rational design of the CLPR to reduce wear and prolong its service life. The surface texture features have a significant impact on the lubricating performance of the CLPR. In this study, the tribological system of the CLPR was investigated. Different surface textures (such as different sizes of surface concaves and grooves, etc.) were designed and produced on the cylinder liners using surface treatment. A series of experimental tests were then carried out in a specially designed diesel engine tester to investigate the tribological characteristics of the treated CLPR pairs. The comparison analyses of the worn surface texture features, element content of the lubrication oil, and abrasive particle characteristics were conducted under different wear surface texture features and cylinder liner speeds. The analysis results showed that there were significant differences in the tribological and lubrication properties of the rubbing pairs in different wear surface texture features. The wear performance of the CLPR pair with a regular concave texture was superior to that of the concave and groove, and regular groove textures. In addition, the regular concave with a depth-diameter ratio of 0.1 was the most effective surface texture to improve the lubrication and wear properties of the CLPR pairs. It is believed that the knowledge obtained in this study provides the real practical basis for tribological design and manufacturing of CLPR pair in marine diesel engines.     

Recent research on tribology in Japan

Recent research on tribology in Japan is outlined. There have been many papers on the following problems.

In fluid film lubrication, the effects of surface irregularities on the lubricating performance and increase in friction in high speed bearings due to turbulent flow are highlighted to date. Elastohydrodynamic lubrication and its related problems such as traction play an important role in the lubrication of cams and followers, rolling contact bearings and traction drives. The rheology of lubricants at high pressures is one of the most important properties governing lubricated concentrated contacts. Regarding basic studies on wear, the mechanism of the adhesive wear process is being studied. It is interesting to investigate the deformation behaviours of materials and structures by finite element methods. The friction and wear characteristics of plastics and their composites have been studied in basic terms.

The chemical reactions of lubricating oil additives with frictional surfaces play important roles in lubricated concentrated contacts. Recently there have been many studies on the correlation between the lubricating properties and the chemical reactivity of lubricant additives. It is very interesting that there are many papers on the mutual effects between lubricant additives.     

Comparison of friction and lubrication of different hip prostheses

It is well documented that an important cause of osteolysis and subsequent loosening of replacement hip joints is polyethylene wear debris. To avoid this, interest has been renewed in metal-on-metal and ceramic-on-ceramic prostheses. Various workers have assessed the lubrication modes of different joints by measuring the friction at the bearing surfaces, using different lubricants. Measurements of friction factors of a series of hip prostheses were undertaken using carboxymethyl cellulose (CMC) fluids, silicone fluids, synovial fluid and different concentrations of bovine serum as the lubricant. The experimental results were compared with theoretical predictions of film thicknesses and lubrication modes. A strong correlation was observed between experiment and theory when employing CMC fluids or silicone fluids as the lubricant. Mixed lubrication was found to occur in the metal-on-metal (CoCrMo/CoCrMo) joints with all lubricants at a viscosity within the physiological range. This was also the case for the metal-on-plastic (CoCrMo/ultra-high molecular weight polyethylene) joints. The ceramic-on-ceramic (Al2O3/Al2O3) joints, however, exhibited full fluid film lubrication with the synthetic lubricants but mixed lubrication with the biological lubricants. Employing a biological fluid as the lubricant affected the friction to varying degrees when compared with the synthetic lubricants. In the case of the ceramic-on-ceramic joints it acted to increase the friction factor tenfold; however, for the metal-on-metal joints, biological fluids gave slightly lower friction than the synthetic lubricants did. This suggests that, when measuring friction and wear of artificial joints, a standard lubricant should be used.     

A New Approach Using Palm Olein,Palm Kernel Oil,and Palm Fatty Acid Distillate as Alternative Biolubricants: Improving Tribology in Metal-on-Metal Contact

Metal-on-metal (MoM) hip replacements are commonly used hip implants. However, one of the issues under debate is the interference of friction and wear. The purpose of this feasibility study is to elucidate the performance of palm lubrication between the femoral head and the acetabular cup. In the tribology of hip implants, the use of palm olein, palm kernel oil, and palm fatty acid distillate as synthetic lubricants for human joints has shown tremendous potential. A modified pin-on-disc as hip screening has been used to evaluate the friction and wear on an acetabular cup with an inner diameter of 28 mm. The wear debris was then observed with microscopy image analysis. This study revealed that the physical and unique chemical properties in palm oil can optimize the rate of friction and wear on the metal acetabular cup and thus allow for a stable implant of MoM.     

Suitability of vegetable oils as industrial lubricants

This paper reports on the application‐relevant properties of sixteen commercially available vegetable oils tested without additives in accordance with established standards. Their performance was compared with each other and with that of mineral oil and synthetic esters. The basic characteristics of all the oils (density, viscosity, pour point, cloud point, flash point and fire point) were initially determined. A chemical analysis of the vegetable oils was carried out to determine the acid value, saponification and iodine numbers. Additionally, the oxidative stability of all the oils was tested. The tribological performance, lubrication, and wear protection of the oils were judged under abrasive as well as adhesive conditions. The comparative study of the test vegetable oils showed great differences in the properties of the oils. All the vegetable oils tested revealed weak points during testing, including rape seed and castor oils, which have established uses in industry. This study shows that certain vegetable oils, such as sesame oil and wheatgerm oil, may have potential for use in selected technical applications. The mineral oil and synthetic esters showed markedly superior performance when tested under adhesive conditions, but comparable behaviour to the other oils under abrasive conditions.     

添加剂对聚氨酯材料摩擦性能的影响

为改善聚氨酯水润滑轴承材料的性能,在聚氨酯预聚体中分别添加不同含量的润滑脂、消泡剂和合成蜡,制备3种聚氨酯复合材料;利用CBZ-1型船舶轴系摩擦磨损试验机测试复合材料在不同工况下的摩擦学性能,利用激光干涉位移表面轮廓仪和超景深显微镜观察不同聚氨酯复合材料对摩副的表面形貌,探讨材料在水润滑条件下的磨损机制。结果表明:润滑脂和消泡剂的添加提高了聚氨酯材料的稳定性,再添加合成蜡有效地改善其在高压工况下的润滑状态;在高压工况下,与纯聚氨酯材料对摩的铸铜盘磨损后出现犁沟现象,表现出磨粒磨损的特征并伴随着黏着磨损,而与复合聚氨酯材料对摩的铸铜盘磨损后仅出现黏着磨损的特征。润滑脂、消泡剂和合成蜡能有效提高聚氨酯材料的耐磨性以及降低对摩副的磨损损耗,从而提高了聚氨酯材料作为水润滑轴承的安全性和可靠性。     

自乳化酯在全合成切削液中的性能研究

为探讨自乳化酯作为全合成切削液主润滑剂的可能性,以聚醚、四聚蓖麻油酸酯、自乳化酯为润滑剂调配了不同的合成切削液;采用四球抗磨试验机以及攻丝扭矩试验机、液体循环泡沫试验机,考察3种润滑剂在全合成切削液中的润滑性能、抗磨性能及抗泡性能.结果 表明:自乳化酯能有效提高全合成切削液的润滑性能和抗磨性能,其润滑性能及抗磨性能与四...     

润滑条件对纳米SiO2填充尼龙复合材料摩擦学性能的影响

利用MM-200磨损实验机在干摩擦、水润滑和油润滑等条件下，研究了润滑条件对含量为10％的纳米SiO2填充尼龙1010复合材料与45^#钢对磨时的摩擦学性能的影响，并利用扫描电子显微镜对纳米SiO2-PA1010复合材料的磨损表面和磨损机理进行了观察和分析。结果表明水润滑时，纳米SiO2-PA1010复合材料的摩擦因数比在干摩擦时有一定程度的降低，但磨损量却比干摩擦时增加了很多；而在油润滑时，摩擦因数和磨损量均比干摩擦和水润滑时降低了许多；复合材料的磨损机制也随着润滑条件的不同发生了相应的变化。     

Temperature—friction characteristics of cylinder lubrication in large,slow, cross‐head marine diesel engines under boundary lubrication conditions

In large, slow, cross‐head marine diesel engines research has increasingly shown that the lubrication regime between piston rings and cylinder liner at top dead centre is of the boundary lubrication type due to the high gas pressure, low sliding speed, and high temperature. This means that the tribological properties of piston ring, cylinder liner, and cylinder lubricant in these types of engine under boundary lubrication conditions should be considered simultaneously when friction and wear between the piston ring and cylinder liner are studied. Until now there has been no standard method to evaluate boundary lubrication performance. There are a few traditional methods used in lubricant research, but their results are not correlated with service conditions. It is important to find a suitable method to evaluate the boundary lubrication performance of lubricants at the laboratory testing stage or before the engine testing stage. The important parameters, such as sliding speed, normal load, materials of the contacting pairs, and lubricant, need all to be controlled. In this paper a systematic experimental procedure, the ‘five times heating and cooling test’, is introduced to assess lubricant properties under boundary lubrication conditions. Most of the parameters mentioned above are controlled. The model contact, of pin‐on‐plate form, is made from the actual piston and liner materials used in a large‐bore, slow, cross‐head marine diesel engine. The temperature characteristics of different blends of lubricants are investigated under boundary lubrication conditions using a pin‐on‐plate reciprocating test rig. These blends of lubricants have the same additives but different base fluids; they nevertheless fulfil the physical and chemical requirements of a real marine diesel engine. The test temperature range is from room temperature to the working temperature of the top piston ring. The experiments show that there are different temperature—friction characteristics for lubricants with different bases and the same additive package and there are also different temperature—friction characteristics during heating up and cooling down for each blend. Single‐base lubricants have more promising temperature—friction characteristics than those of a blend of a high‐viscosity base and a low‐viscosity base at high temperature.     

Effect of Metallic-Coating Properties on the Tribology of Coated and Oil-Lubricated Ceramics

Friction and wear behavior was determined for zirconia ceramics lubricated with solid coatings (Ag, Au, and Nb) deposited by ion-beam-assisted-deposition (IBAD) techniques, and a polyol-ester-based synthetic oil. Although the use of soft Ag and Au coatings as solid lubricants in conjunction with the synthetic oil significantly reduced the fiction and wear under boundary lubrication at temperatures up to 250°C, these films had poor durability. In contrast, the Nb coating was more durable in terms of chemical reactivity and adhesion during the tribo-tests than were the Ag or Au films. However, the friction and wear behavior of the Nb-coated zirconia was poorer than that of the ceramics coated with Ag or Au.     

二种锌铝合金润滑时摩擦磨损特性的研究

对二种锌铝合金ＺＡ－ＳｉＴ ＨＤＺＡ在２０号机油润滑条件下的摩擦磨损特性进行了研究。研究发现：该摩擦－润滑系统以边界润滑为主，且伴随有断续的、短暂的混合润滑或弹性流体润滑；磨擦磨损过程中存在着磨粒磨损、接触疲劳和粘着磨损３个磨损机制；二种锌合金在一定条件下具有优良的耐磨性能和减摩性能。研究结果还初步解释了这些试验现象。     

Concept of molecular design towards additive technology for advanced lubricants

A simple model to develop novel friction modifiers and anti‐wear agents for synthetic oils was studied. Our attention was focused on the construction of additive molecules to meet the requirement for synthetic oils, which possess a different polarity and solvency from mineral oils. The relation between the molecular structure of additives and their tribological properties were elucidated prior to the preparation of the substance and estimation of its tribological properties. Computer‐assisted chemistry was partly applied to predict the properties of the designed molecules. The adsorptive activity of the conventional fatty acids is insufficient to reduce friction when they were dissolved in polar synthetic oils such as polyethers. Introduction of another carboxyl group into the fatty acid, especially at the carbon atom next to the original carboxyl group, makes the molecule polar; resulting in friction modifiers for polyethers. Conversion of the carboxyl groups into trimethylsilyl esters provides soluble friction modifiers for poly(dimethylsilicone)‐type synthetic oils. A unique lubrication mechanism based on in situ regeneration of the original molecule was proposed for synthetic oils with poor solvency. Importance of adsorptive activity of additive molecule was also pointed out in phosphate‐type anti‐wear additives for polar synthetic oils. We found that both the polarity of additives and that of base oils have to be taken into account in lubricant design. Too much adsorption activity of the molecule caused corrosive wear. Hydrolytic stable compounds reduces corrosive wear to a considerable extent. Introduction of a hydroxyl group into the alkyl moiety of the phosphate ester provides polar molecule with low acidity. The additives reduce wear in synthetic esters even at low concentrations of phosphorus. The lubrication mechanism was also discussed; the novel additives provide a thick boundary film composed of iron phosphate on rubbing surfaces. Moreover, an acceleration of the kinetics of the film formation by the hydroxyl group was observed. Copyright © 2007 John Wiley & Sons, Ltd.     

Lubrication and wear modelling of artificial hip joints: A review

The tribological performance of artificial hip joints is a critical issue for their success, because adverse tissue reaction to wear debris causes loosening and failure. Many studies on wear and lubrication of hip prostheses have been published in the last 10 years, mostly on experimental tests. Theoretical/numerical models have been proposed for investigating geometrical and material parameters also. This paper reviews recent literature on lubrication and wear models, stressing simplifying hypotheses, input data, methods and results. It is pointed out that actually lubrication and wear are described neglecting each other while new advanced models including both aspects could be helpful.     

水凝胶/热塑性聚氨酯复合材料在水润滑条件下的摩擦学性能

为提高水润滑轴承的承载能力，利用水凝胶在水润滑条件下的水合作用来改善热塑性聚氨酯（TPU）轴承材料的摩擦学性能。利用聚乙烯醇、海藻酸钠、壳聚糖等材料制备水凝胶颗粒，并通过熔融共混法制备水凝胶/TPU复合材料；在0.3和0.5 MPa的载荷下测试复合材料的摩擦磨损性能，利用激光干涉表面轮廓仪和扫描电子显微镜观察其磨损表面形貌，分析其磨损机制。结果表明：水凝胶微粒可以通过水合润滑改善摩擦副的润滑条件，从而降低摩擦因数和磨损量，提高复合材料的摩擦性能；水凝胶质量分数4%时复合材料具有最佳的摩擦磨损性能，其在0.3和0.5 MPa工况下相对于TPU试样的平均摩擦因数减少率分别为52.31%和43.94%。研究结果为开发高性能水润滑轴承材料提供了一种方法。     

人工关节材料的表面润滑设计与应用

人工关节的摩擦磨损问题仍然是基础研究中最重要的问题,借助表面改性技术改善假体的摩擦学性能是人工关节未来发展的必经之路。从润滑角度考虑,对假体关节材料摩擦性能的研究主要集中在表面功能化润滑结构设计以及新型仿生润滑剂研究两方面。针对功能化润滑结构,介绍表面织构设计以及聚合物刷的应用,分析表面织构参数对不同运动工况下摩擦副摩擦性能的影响,阐述表面织构的润滑机制;总结不同种类的聚合物刷结构对摩擦体系耐磨性能的调控,阐明"刷型"结构在摩擦界面的水润滑特点,提出环境介质对聚合物刷结构及性质的影响作用。针对关节润滑剂,介绍传统的关节滑液组分向聚合物仿生润滑剂的拓展。指出微/纳结构的嵌套设计与协同润滑以及润滑剂结构仿生与功能仿生的结合,将是未来的重要发展方向。     

Tribotechnical properties of thin-film coatings obtained by the tribomodifcation of crankshaft pins for ship diesel engines

The tribotechnical properties of thin-film coatings obtained as a result of the tribomodification of 40Kh steel by various organic-inorganic tribotechnical materials (natural inorganic and synthetic polymers), as well as the compositions and composites created based on vermiculite are considered in the work. Comparative tribotechnical tests have made it possible to establish that the most promising materials for the tribomodification of the friction surfaces of steels are nanostructured composites based on vermiculite, which make it possible to get the minimum coefficient of friction and high wear resistance of the conjugation under the friction condition at boundary lubrication.     

Mechanical testing of hydraulic fluids

The antiwear properties of hydraulic fluids are important because hydraulic pump and motor wear is costly. While international hydraulic fluid performance standards continue to be developed, e. g., the ISO/TC28/SC4 committee's draft ISO DIS 11158 ‘Specifications for mineral oil hydraulic fluids’, the normal hydraulic fluid performance specifications represent minimum requirements. Performance specifications for nonmineral oil hydraulic fluids are also being developed. Typically, both the user and the fluid manufacturer possess insufficient objective information about the antiwear properties of special fluids, e. g., environmentally acceptable hydraulic fluids (EAHF) or fire‐resistant hydraulic fluids (FRHF) for use in hydraulic equipment such as axial‐piston pumps, vane pumps or radial‐piston motors. Manufacturer's specifications must therefore be determined. The required lubrication properties can be determined by either laboratory pump tests or a field trial, often at the customer's expense. The lubrication properties of a hydraulic fluid should ideally be determined under conditions that are equivalent to field practice. This paper will discuss the use of the vane pump test and the FZG gear test to gauge ‘recommended’ hydraulic fluid performance; many non‐mineral hydraulic fluids, such as environmentally acceptable hydraulic fluids, fire‐resistant fluids or synthetic hydraulic fluids, cannot be used in axial‐piston systems based only on results obtained with these tests, and additional testing is always required. Proposals are made for testing of such fluids on a variable‐load test rig. These tests are done with axial‐piston pumps, or other similar displacement systems, and are intended to determine the industrial suitability of non‐mineral hydraulic fluids.     

Fretting wear of carburized titanium alloy against ZrO2 under serum lubrication

Fretting wear of carburized titanium alloys was investigated on the universal multifunctional tester (UMT) with the ball-on-flat fretting style under bovine serum lubrication. The tangential load and friction coefficient during the fretting process were analyzed, and the evolution of fretting log during the fretting process was investigated to understand the wear mechanism of the titanium alloy and carburized titanium alloy. Furthermore, the wear scar was examined using a SEM and three-dimension surface profiler. It was found that the friction coefficient of the titanium alloy increased faster than that of carburized titanium alloy in the first stage under serum lubrication, and then remained steady with a similar value in the second stage. The Ft-D curve indicated that there was wear mechanism transition from gross slip to mixed stick and slip. Finally, it was observed that there was a slight damage of the titanium alloy and carburized titanium alloy showed excellent performance during the fretting wear process under serum lubrication. All of the results suggested that carburized titanium alloy was a potential candidate for the stem material in artificial joints.     

多因素影响的格莱圈材料摩擦磨损试验研究*

格莱圈由聚四氟乙烯(PTFE)矩形滑环和丁腈橡胶(NBR)O形圈组成。为了研究不同因素对于格莱圈密封材料摩擦磨损性能的影响,利用UMT-3多功能摩擦磨损试验机,通过改变往复频率、粗糙度、润滑状态研究格莱圈材料与45钢配副时的摩擦磨损性能,利用SEM对试块试验前后表面形貌进行观测,并对摩擦磨损机制进行分析。试验结果表明:在干摩擦和滴油润滑条件下PTFE材料相比NBR材料具有更为优异的摩擦磨损性能;NBR材料表面粗糙度过高或过低都会导致摩擦因数升高,表面粗糙度对具有自润滑性能的PTFE材料的摩擦因数影响不大;高往复频率会使NBR材料摩擦因数降低,过高或过低的往复频率都会使PTFE材料摩擦因数降低;NBR材料的磨损形式以磨粒磨损和黏着磨损为主,PTFE材料以黏着磨损和疲劳磨损为主。