Bonding of Silicon Nitride Ceramic Composite with RE_2O_3Al_2O_3SiO_2 Glass Solders

Ｓｉｌｉｃｏｎｎｉｔｒｉｄｅｃｅｒａｍｉｃｈａｓａｓｅｒｉｅｓｏｆｅｘｃｅｌｌｅｎｔｐｒｏｐｅｒｔｉｅｓ,ｆｏｒｅｘａｍｐｌｅ,ｈｉｇｈｓｔｒｅｎｇｔｈ,ｈｉｇｈｈａｒｄｎｅｓｓ,ｗｅａｒ,ｃｏｒｒｏｓｉｏｎ,ｏｘｉｄａｔｉｏｎａｎｄｓｈｏｃｋｒｅｓｉｓｔａｎｃｅｅｔｃ．,ａｎｄｉｓａｋｉｎｄｏｆｈｉｇｈｔｅｍｐｅｒａｔｕｒｅｓｔｒｕｃｔｕｒａｌｍａｔｅｒｉａｌｗｉｔｈｅｎｏｒｍｏｕｓｐｏｔｅｎｔｉａｌｉｔｉｅｓｆｏｒｆｕｔｕｒｅｄｅｖｅｌｏｐｍｅｎｔ．Ｂｕｔｈｉｇｈｃｏｓｔｆｏｒ…     

Effect of Y2O3, CeO2 on Sintering Properties of Si3N4 Ceramics

The effect of rare earth oxides Y203 or Ce02 on sintering properties of Si3N4 ceramics was studied and the mechanism of assisting action during sintering was analyzed. The results in dicate that the best sintering properties appear in Si3N4 ceramics with 5% Y203 or 8% CeO2. Secondary crystallites are formed at grain boundaries after heat treatment,which decreases the amount of glass phase and contributes to the improvement of high-temperature mechanical properties of silicon nitride.     

Preparation, Characterization and Photo-Catalytic Behavior of Y_2O_3/TiO_2 Composite Semiconductor Nanopowder

ＴｉＯ2 ｐｈｏｔｏ ｃａｔａｌｙｓｉｓｈａｓｂｅｅｎａｆｏｃｕｓｏｆｎｕｍｅｒｏｕｓｉｎｖｅｓｔｉｇａｔｉｏｎｓｉｎｒｅｃｅｎｔｙｅａｒｓ ,ｐａｒ ｔｉｃｕｌａｒｌｙｏｗｉｎｇｔｏｉｔｓａｐｐｌｉｃａｔｉｏｎｆｏｒｔｈｅｃｏｍ ｐｌｅｔｅｍｉｎｅｒａｌｉｚａｔｉｏｎｏｆｕｎｄｅｓｉｒａｂｌｅｏｒｇａｎｉｃｃｏｎ ｔａｍｉｎａｎｔｓｔｏＣＯ2 ,Ｈ2 Ｏａｎｄｉｎｏｒｇａｎｉｃｃｏｎ ｓｔｉｔｕｅｎｔ[1] .Ｈｏｗｅｖｅｒ,ｐｈｏｔｏ ｏｘｉｄａｔｉｏｎｉｓａｌｍｏｓｔｎｏｔｉｎｄｕｓｔｒｉａｌｌｙａｐｐｌｉｅ…     

Enhancement of secondary emission property of molybdenum cathode co-doped with La_2O_3 and Y_2O_3

La2O3 and Y2O3 co-doped Mo secondary emitters were prepared by three kinds of doping method combined with high temperature plasma sintering.The secondary electron emission property and microstructure of the cathodes were studied.It showed that the cathode prepared by liquid-liquid doping method exhibited the best emission property among all the samples prepared by liquid-solid doping,solid-solid doping and liquid-liquid doping methods due to a uniform distribution of different substances.RE2O3 existed unifo...     

Influence of dispersant on Y_2O_3:Eu~(3+) powders synthesized by combustion method

Y2O3:Eu3+ powders were synthesized by combustion method and the influence of dispersant was investigated.XRD analysis indicated that the particle size increased with a small amount of dispersant firstly and then decreased with a further increase of dispersant.The morphologies of the powders were studied by scanning electron microscopy(SEM) and high-resolution transmission electron microscopy(HRTEM).SEM images revealed that an appropriate amount of dispersant could reduce the agglomeration significantly.Due ...     

Dopant Behaviours of Sm_2O_3 on Microstructure and Properties of Barium Zirconium Titanate Ceramics

Ａｓｔｈｅｓｏｌｉｄｓｏｌｕｔｉｏｎｏｆｂａｒｉｕｍｚｉｒｃｏｎａｔｅａｎｄｂａｒｉｕｍｔｉｔａｎａｔｅ ,ｂａｒｉｕｍｚｉｒｃｏｎｉｕｍｔｉｔａｎａｔｅ(ＢＺＴ)ｃｅｒａｍｉｃｓｉｓｐｒｏｖｉｄｅｄｗｉｔｈｄｉｓｔｉｎｃｔｄｉｆｆｕ ｓｉｖｅｃｈａｒａｃｔｅｒｉｓｔｉｃｓｏｆｐｈａｓｅｔｒａｎｓｉｔｉｏｎ ,ｗｈｉｃｈｃａｎｂｅａｔｔｒｉｂｕｔｅｄｔｏｔｈｅｐａｒｔｉａｌｓｕｂｓｔｉｔｕｔｉｏｎｏｆＺｒ4 ｆｏｒｔｈｅｃａｔｉｏｎｓｌｏｃａｔｅｄａｔＢ ｓｉｔｅｓｏｆｔｈｅｐｅｒｏｖｓｋｉｔｅｌａｔｔｉ…     

Dielectric Properties of CeO2 -Doped Ba( Zr, Ti)O3 Ceramics

The influence of additive amount of CeO2 on the properties of Ba(Ti, Zr)O3 (BTZ) capacitor ceramics prepared using conventional solid-state reaction method was investigated. The dielectric constant(ε) increases to a maximum when w( CeO2 ) is about 1.0% and then decreases again at higher doping concentration of CeO2. The dielectric constant gets a maximum while w ( CeO2 ) is about 1. 0%, and the dielectric loss is minimum while w ( CeO2 ) is0.5 %. CeO2 can decrease the curie temperature, widen the εr-T peak and decrease the absolute value of dielectric constant temperature coefficient. The influence mechanism of CeO2 additive on the properties of the BTZ ceramics was discussed. The results show that CeO2 additive influences the properties of BTZ ceramics by means of forming defect solid solution , shifting curie temperature peak effect, segregating in crystal boundary , and impeding grain growth.     

Preparation and Luminescence of Er^3＋ Doped Oxyfluoride Glass Ceramics Containing LaF3 Nanocrystals

Er^3＋ doped transparent oxyfluoride glass ceramics version and near infrared luminescence behavior of Er^3＋ in containing LaF3 nanocrystals were prepared and the up-conglasses heat-treating time and temperature, the size （varied from 0 to 19 and glass ceramics were investigated. With increasing nm） and crystallinity （varied from 0 to 47%） of LaF3 nanocrystals in the glass ceramics are increased. The up-conversion luminescence intensity of Er^3＋ ions in the glass ceramics is much stronger than that in the glasses The near infrared emission of Er^3＋ ions in and increased significantly with increasing heat-treating time and temperature the glass ceramics is found to be similar to that in the glasses.     

Spectroscopy of Pr^3＋4f5d Configuration in LaF3 Nanocrystals／Oxyfluoride Glass Ceramics

Theinterestofinvestigatingthe 4fn -15delectronicconfigurationofthetrivalentrareearth (RE)ionsisbasedonavarietyofapplicationsinthevacuumultra violet (VUV)regionofthespectrum ,suchasthede velopmentofplasmadisplaypanelsandmercury freefluorescenttubes[1] .Amo…     

Luminescent properties of praseodymium doped Y_2O_3 and LaAlO_3 nanocrystallites and polymer composites

Luminescent properties of Y2O3 and LaAlO3 nanopowders doped with Pr3+ ions and PMMA-based composite materials doped with these powders were reported.The set of active nanopowders differing in praseodymium ions concentration was prepared using sol-gel method and carefully characterized with respect to emission properties in the visible spectral range.In particular,the excitation and emission spectra were measured together with fluorescence decay profiles and the differences between optical properties of thes...     

Study on Mg PSZ Ceramics Doped with Y_2O_3 and CeO_2

ＭａｇｎｅｓｉａｐａｒｔｉａｌｌｙｓｔａｂｉｌｉｚｅｄＺｉｒｃｏｎｉａ(ＭｇＰＳＺ)ｈａｓｅｘｃｅｌｌｅｎｔｍｅｃｈａｎｉｃａｌｐｒｏｐｅｒｔｉｅｓ,ｓｕｃｈａｓｇｏｏｄｆｒａｃｔｕｒｅｔｏｕｇｈｎｅｓｓ,ｆｌｅｘｕｒａｌｓｔｒｅｎｇｔｈ,ａｎｄｔｈｅｒｍａｌｓｈｏｃｋｒｅｓｉｓｔａｎｃｅ.Ｔｈｅｒｅｆｏｒｅ,ＭｇＰＳＺｈａｓｂｅｅｎｕｓｅｄｉｎｉｎｄｕｓｔｒｙａｎｄｖａｒｉｏｕｓｆｉｅｌｄｓ.Ｈｏｗｅｖｅｒ,ｔｒａｄｉｔｉｏｎａｌＭｇＰＳＺｍａｔｅｒｉａｌｓｐｒｏｄｕｃｅｄｂｙｇｅｎｅｒａｌｍｅｔｈｏ…     

Effects of MgO on Properties of La_2O_3-TiO_2 Ceramics

Effects of MgO on Properties of La_2O_3-TiO_2 Ceramics     

Growth of CeO_2, Y_2O_3 Buffer Layers for YBCO Coated Conductor

~~Growth of CeO_2, Y_2O_3 Buffer Layers for YBCO Coated Conductor     

Effect of Y2O3 and Dy2O3 on Microstructure and Mechanical Behaviors of Aluminum Nitride Ceramics

The effects of two types of additives, Y2O3 and Dy2O3, on the sintering and mechanical behaviors of AlN ceramics were investigated. The experimental results show that the sintering temperature can be decreased and the mechanical behavior can be improved by adding rare earth in AlN ceramics. The strength of AlN ceramics with Y2O3 and Dy2O3 are 326 and 320 MPa, respectively, which are 97.6% and 93.9% higher than the un-doped AlN ceramics. The fracture behavior on the fracture surfaces of rare earth oxide AlN ceramics was found to be a mixed mode of transgranular fracture and intergranular fracture. As a result, it is concluded that the improvement of bending strength of AlN ceramics with Y2O3 and Dy2O3 addition are mainly achieved by strengthening the grain boundary.     

Effect of Y2O3 on Dielectric Properties of BaTiO3 Ceramics

Tiny amount of rare earth Y2O3 can restrain the growth of grains and broaden the peak of BaTiO3 ceramics.Proper characteristics of capacitance change with temperature were obtained. Meanwhile, the insulation resistance increased with the increasing contents of Y2O3. In this system, the cooperation of Y2O3 with Ho2O3 was also discussed.It is concluded that the insulation resistivity reduces if the content of Y2 O3 is below 0.25 %. With the increasing content of additives, weak-binding electrons in grains will be compensated by V"8a so the insulation resistivity increased. The breakdown voltage is enhanced to 15 kV · mm-1.     

Experimental and theoretical analysis on the charge transfer band of Y_2O_3:Eu nanocrystals

Nanocrystalline cubic Y2O3:Eu were prepared by combustion reaction.The crystal structure and morphology were analyzed by means of X-ray diffraction(XRD) and transmission electron microscopy(TEM).The luminescent properties of the powder were investigated.The charge transfer band position showed redshift from 241 to 251 nm,which was related to the change of the local surroundings of Eu3+ ions in nanocrystalline Y2O3:Eu.The ground-state electronic structure and charge transfer transition of both the bulk and nanocrystalline cubic Y2O3:Eu crystals were calculated by the ab initio self-consistent relativistic DV-Xα(discrete variational Xα) method.A complete 35-ion cluster was selected to simulate the local coordination surroundings of Eu doped in Y2O3 bulk crystals while five additional incomplete clusters were also selected to simulate the local surroundings of Eu ions in nanocrystals.It could be found that the charge transfer energies of the nanocrystalline Y2O3:Eu were less than that of the bulk counterpart,which was consistent with the redshift phenomenon of the CT band in the excitation spectrum of the nanocrystalline Y2O3:Eu.     

氧化物添加对BaO-TiO2-Al2O3-SiO2玻璃陶瓷介电性能的影响

采用烧结法制备工艺,成功制备了BaO-TiO₂-Al₂O₃-SiO₂玻璃陶瓷,以钛酸钡体系玻璃陶瓷为基础成分添加不同种类氧化物(Y2O3,Ni2O3,ZrO2),并采用X射线衍射(XRD),场发射扫描电镜(FESEM),精密阻抗分析仪测试仪(LCR)对添加不同氧化物玻璃陶瓷样品的析出相成分、微观结构和介电性能进行表征,研究了氧化物添加对BaO-TiO₂-Al₂O₃-SiO₂玻璃陶瓷性能的影响。研究结果表明:添加不同的氧化物并未改变BaO-TiO₂-Al₂O₃-SiO₂玻璃陶瓷的析出相种类,但能够促进基体中钙钛矿结构钛酸钡结晶相的生成。同时添加不同氧化物后样品的致密度均随烧结温度的升高呈现先增大后减小的变化趋势,在最适烧结温度下,氧化物的添加提高了不同烧结玻璃陶瓷样品的致密度,并优化了样品的介电性能。通过添加不同种类氧化物获得了同时具有高致密度和良好介电性能的玻璃陶瓷成分,当添加0.5%(质量分数)Ni₂O₃时,样品在最佳烧结温度1230°C下烧结获得最大致密度为98.6%,提高了1.65%,样品室温下的介电常数高达1100,提高了139.5%。     

Optical Spectroscopy of Er^3 , Er^3＋/Yb^3 ＋ Co-doped Bi2O3-GeO2-B2O3-ZnO Glasses

Optical Spectroscopy of Er~(3 ), Er~(3 )/Yb~(3 ) Co-doped Bi_2O_3-GeO_2-B_2O_3-ZnO Glasses     

Effect of refining slag containing Ce_2O_3 on steel cleanliness

The effect of pre-melting refining slag containing different contents of Ce2O3 on the absorption and modification of Al2O3 inclusion in an Al-killed steel was investigated through the slag/steel reaction experiment at 1600 oC.It was found that the replacement of 10 wt.% Al2O3 with Ce2O3 for 50 wt.%CaO-33 wt.%Al2O3-7 wt.%MgO-10 wt.%SiO2 refining slag promoted the slag absorption ability of alumina inclusion,which made the total oxygen content determined by infrared absorption method decrease from 100 to 25 ppm in 15 min.The Mg-Al-Ce-O type inclusion was also detected in the as-solidified samples by scanning electron microscopy(SEM).Thermodynamic analysis indicated that the Ce2O3.Al2O3 type inclusions would be formed with the cerium content in the range of 6.9 ppb to 3.6 ppm when the content of aluminum was 0.01 wt.%.