喷墨打印用墨水的发展现状

本文介绍了喷墨打印用墨水的发展现状，提供了具有优秀色彩输出的墨水配方，从染料结构、溶剂及添加剂等方面提出了提高染料的耐水、耐光牢度及打印品质的方法。     

新型喷墨打印墨水用水溶性染料

介绍了近年来研究开发用于喷墨打印墨水的新型水溶性染料的结构及合成方法,这些新型染料以偶氮类为主、属于酸性、直接或活性染料,用于墨水时具有较好的应用和牢度性能,其颜色包括黑色、品红色、黄色和青色。有43篇参考文献。     

喷墨印花的有机颜料印墨

用于喷墨印花印墨的着色剂中,有机颜料性能优于染料,但难度大、本文就有机颜料着色剂及亲水性改性处理作了较为详细的介绍,同时述及印花粘合剂及印墨的制造方法。     

Syntheses of polymeric dispersants for pigmented ink‐jet inks

Drop‐on‐demand ink‐jet inks made from dyes usually show poor light fastness and poor water fastness. Therefore, many researchers have introduced pigments into ink‐jet inks to overcome the defects of dye‐based ink. Pigmented ink needs sophisticated technology which disperses the pigments stably in low viscosity. Thus, adequate dispersants are essential to achieve stable dispersions of pigments for ink‐jet inks. This study describes syntheses of dispersants, properties of formulations and comparisons of performance with an existing ink to assess their suitability for commercial application.     

喷墨打印机颜料型油墨的最新进展

喷墨打印技术是一种非接触式的数字印刷技术,它将数码技术与传统的印刷技术合二为一。用于喷墨印刷的染料型墨水通常表现出差的耐光性和耐水性,因此将颜料引进到喷墨油墨中以克服染料型墨水的缺点是必然趋势。为了在低粘度下保持颜料稳定的分散,性能优异的合成分散剂对于获得稳定的颜料分散体是必不可少的。本文介绍了水性喷墨油墨的组分及各组分作用,对喷墨油墨的生产技术、发展前景进行了展望。     

Ink‐jet printing of cotton with natural dyes

Four natural dyes, annatto, cutch, pomegranate fruit rind, and golden dock, were used as colorants for the preparation of water‐based ink‐jet inks for digital textile printing. The physical and rheological properties (pH, conductivity, surface tension, and viscosity) of the inks were measured over a period of 90 days for the evaluation of ink stability and suitability for ink‐jet printing. The inks were found to be suitable and were used for the digital printing of cotton fabrics. The prints were subjected to wash, light, and rub fastness tests and colour measurements. Colour consistency and fastness results, especially after fixation, are comparable with those of synthetic dyes, which paves the way for the production of environmentally friendly ink‐jet inks using natural dyes for the digital printing of cotton through the formulation of suitable printing techniques.     

Preparation of pigmented ink‐jet ink by a combination of surface treatments and synthetic dispersant

Drop‐on‐demand ink‐jet inks prepared from dyes usually show inadequate light and water fastness. Thus, in our previous paper, we studied black pigmented ink‐jet inks with the aim of overcoming the drawbacks of dye‐based ink by employing a variety of synthetic dispersants with gas black. In this study, pigmented ink‐jet inks were prepared by a combination of the synthetic dispersant and the surface treatments of a furnace black that is more common than gas blacks. The results of this study show that the surface treatment of the furnace black and the use of the synthetic dispersant are useful in the preparation of ink‐jet inks and endow them with properties that are comparable with those of commercial ink‐jet inks.     

喷墨打印和喷墨印花用染料和有机颜料的进展

本篇是关于喷墨打印和喷墨印花用染料和有机颜料的综述文章。主要论述了用于纸张打印水性墨水的颜料和染料、纤维素纤维喷墨印花用活性染料、丝绸喷墨印花用酸性染料以及聚酯纤维喷墨印花用分散染料的进展情况。给出了组成各种墨水的典型配方。并预测了未来可能的发展趋势。     

Synthesis,stability and printing properties of a novel 2‐sulphophenoxy‐4‐chloro‐s‐triazine reactive dye for ink‐jet printing of wool

We report here the synthesis and characterisation of a new medium‐reactivity reactive dye containing 2‐sulphophenoxy‐4‐chloro‐s‐triazine, having enhanced the activity of the chlorine atom for further substitution by the functional groups carried by wool fibre. In addition, a dichloro‐s‐triazine dye was also synthesised for the purpose of comparison. The progress of synthesis reactions and purity of the dyes were determined using capillary electrophoresis and thin layer chromatography. The molecular structure and the chemical compositions of the synthesised dyes were confirmed using Fourier Transform–infrared spectral data and elemental analyses. The inks containing the synthesised dyes were formulated and ink‐jet‐printed onto wool fabrics and then the printed fabrics were steamed at 102°C. Compared with the dichloro‐s‐triazine dye, superior performance in terms of ink stability, K/S and dye fixation was observed for the new 2‐sulphophenoxy‐4‐chloro‐s‐triazine dye. In addition, the light fastness of the fabric printed with the inks containing the new dye was 0.5‐grade greater than that of the fabric printed with the inks containing the dichloro‐s‐triazine dye, and no changes in shade and staining were observed following wash fastness tests of the fabrics printed with the inks containing the new dye.     

Some Aspects of the Light Fastness of Reactive Azo-dyes on Cellulose under Wet Conditions

The photochemical behaviour of four reactive-azo dyes, (two dyes with poor wet light fastness and two dyes with normal wet light fastness) was examined to elucidate the mechanisms by which some reactive azo dyes, applied to cellulose, fade more rapidly when wet. In one case it was found that the major primary photochemical reaction is photoejection of electrons, which is enhanced in the aqueous environment, while in the second case, a back reaction between hydroxyl radicals and dye molecules is facilitated by the aqueous environment.     

墨水用黑色染料技术进展

介绍了国内对墨水行业的要求,墨水用染料技术性能及制造工艺;综述了墨水用黑色染料的技术进展,给出了一些最新开发的墨水用黑色染料的结构式。     

关于活性染料及分散染料色牢度几个热点问题的探讨

由于纺织品服装的染色牢度要求越来越高，特别是活性染料浅色染色物的耐晒牢度和深浓色织物的水洗牢度和湿摩擦牢度；分散染料染色物热迁移牢度等，成为提高纺织品服装质量的瓶颈，引起广泛关注的热点问题。本文就染料选用、助剂开发及染料加工工艺合理化进行详细探讨，给出解决办法。有15篇参考文献。     

Synthesis,characterization, and application of hetarylazo disperse colorants: Preparation and properties of ink-jet inks with active agents for polyester printing

The synthesis and characterization of two hetarylazo disperse colorants are described. These compounds were used for the preparation of ink-jet inks with and without active agents for polyester printing. The viscosity, conductivity, surface tension, and pH of these inks were studied over a period of time and discussed with respect to their structure and the active agent content. The particle size and particle size distribution of a representative ink containing a new synthesized hetarylazo compound were measured. All the prepared inks were proved to be suitable for ink-jet printing in terms of their particle size. Viscosity , surface tension, conductivity, and pH values of all inks, with and without active agent, were monitored over a period of 90 days and were related to the ink stability. The same properties were measured for an ink preparation with a commercial dye for comparison. The inks containing the new synthesized dyes were found to be more advantageous regarding most of the above properties, i.e., surface tension, viscosity, and conductivity. Contrarily pH values of all the preparations were unacceptable for ink-jet inks. The ink compositions containing the new synthesized compounds were applied by exhaustion (dyed) on polyester fabric. Fastness properties of the dyed polyester samples were excellent to very good in most cases. Color measurements of the dyed fabric were also performed. A qualitative determination of the aroma-active agent adsorbed on the fiber by the exhaustion method was achieved by the GC-MS method. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Synthesising polymeric dispersants to apply to carbon black pigmented mill bases for use in ink‐jet inks

Dyes are an important component of drop‐on‐demand ink‐jet inks and are commonly used in desktop printers. While they offer bright, vivid colour, these dyes exhibit poor light and water fastness. To combat this, researchers have started using pigmented ink‐jet inks instead of dye‐based inks to improve light and water fastness, but the pigments are insoluble in ink vehicles. To use pigments, dispersants must be applied; however, this is a delicate process because the properties of the dispersant substantially affect how the pigmented mill base must be prepared. In this study, polymeric dispersants are synthesised based on the properties and ratios of monomers and the molecular weights of polymers. In total, 14 types of polymeric dispersants are synthesised and examined, with special attention paid to the dispersing properties of particle size reduction and the stability of the pigmented mill base used to prepare drop‐on‐demand ink‐jet inks. This study describes the synthesis of the dispersants in terms of their suitability for commercial application.     

Ink-jet printing of cationised cotton using reactive inks

The ink-jet printing properties of cotton cationised with 2,3-epoxypropyltrimethylammonium chloride have been studied. Cyan, magenta, yellow and black reactive inks were used to print untreated and cationised cotton fabrics. The effect of cationic reagent concentration, steaming time, ink (colour) and print resolution were investigated, together with possible differences between the behaviour of the four inks. Colour yields, staining of the white grounds, penetration behaviour, print quality and fastness properties were evaluated.     

The effect of polycation on the light fastness of CI Acid Red 249

Cationic compounds are frequently used in direct dyeing processes and in ink-jet printing as dyefixing agents. In some cases, however, they can reduce the light fastness of dyes used. This report deals with the effect of a polycationic compound, Polyfix 601, on the light fastness of CI Acid Red 249, an anionic 2-phenylazo-1-naphthol dye, in aqueous solutions and in PVA films. As a comparison, the much smaller ammonium cation was used, which had no observable effect on hue or dye light fastness. However, some changes to the dye's physical properties were observed. The effect of the polycation is explained as a consequence of dye aggregation, facilitated by presence of polycation. Self-sensitised singlet oxygen seemed to play no part in dye photofading, but other oxygen species could participate in the process.     

Digital ink-jet printing of regenerated cellulose nanofibrous mats with reactive inks

The versatility of nanofibres enables them to be used for various technological applications such as filtration, biomedicine and healthcare, composites, protective and functional textiles. Recently, in addition to the functional properties of electrospun nanofibrous mats, their aesthetic properties have been explored. Herein, attempts have been made to develop digital ink-jet printing of regenerated cellulose nanofibrous mats with reactive inks. First, a cellulose acetate polymer was created to fabricate electrospun cellulose acetate nanofibrous mats, which were then converted into regenerated cellulose nanofibrous mats through deacetylation. Next, the cellulose nanofibrous mats were treated with an alkaline solution then coloured with four (cyan, magenta, yellow and black) commercially available reactive inks by a digital ink-jet printing method using a piezoelectric digital ink-jet printer. Various parameters were investigated, including the optimal concentration of the pretreatment agents, fixation temperature and time, colour yield and the absorbency of the electrospun nanofibrous mats. The digital ink-jet printed cellulose nanofibrous mats exhibited excellent colour yield and colour fastness properties. Morphological analysis through scanning electron microscopy and chemical analysis through Fourier Transform–infrared were also carried out.     

噻吩型偶氮分散染料的合成与应用性能研究

合成了六只蓝色噻吩型偶氮分散染料,并测试了染料的应用性能.讨论了染料的湿处理牢度等应用性能与染料分子结构的关系.结果表明,合成的六只分散染料具有良好的湿处理牢度、耐摩擦牢度及耐升华牢度;重氮组份相同时,偶合组分上带酯基结构的染料,其湿处理牢度优于带有乙酰氧乙基的染料.     

浅谈活性染料结构与性能的关系

本文介绍了活性染料的分类,通过实例阐述了活性染料结构对染料各项性能的影响。包括对色光、日晒牢度、固色率、溶解度、可拔性、纤维亲和力以及湿牢度的影响。     

含4-均三甲苯氨基蒽醌染料的合成

本文讨论了含4-（2’,4’,6’-三甲苯基）氨基蒽醌染料的合成,包括酸性染料和活性染料。这类染料染羊毛、聚酰胺、皮革及棉为艳蓝色和艳紫色,并具极好的耐光和耐湿处理牢度。